Significance of formed adherent complex by use of phosphorylated polyphenol coating

2017 ◽  
Vol 46 (3) ◽  
pp. 226-234
Author(s):  
Rachna Jain ◽  
Manish Kumar Bhadu ◽  
Keshave Swarnkar ◽  
Sumitesh Das

Purpose The purpose of this paper is to report on the use of phosphorylated polyphenol (PP)-coated galvanised iron (GI) surface to study the degradation of coating with different time intervals and long-term exposure in different salty media. Design/methodology/approach The as-obtained PP complex on GI was evident by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), energy dispersive spectroscopy (EDS) and scanning electron microscopy (SEM). The coated coupons were exposed to different salty media such as 3.5 per cent NaCl, 1.5 per cent Na2SO4 and tap water at set time intervals. Electrochemical polarisation was performed to study the anodic and cathodic polarisation behaviour at each time interval. Findings The adherent foliolate nanopattern of iron zinc phosphate and zinc dihydrogen phosphate on GI surface was evident by SEM, FT-IR, EDS and XRD. The coated coupons exhibited good corrosion resistance. This coating performs as an alternative to time-consuming multistep operations of phosphating treatment. Originality/value The mode of the experiment treatment using modified PP coating especially on GI in different corrosive exposures at set time intervals is a novel approach in this research.

2016 ◽  
Vol 63 (4) ◽  
pp. 316-326 ◽  
Author(s):  
Rachna Jain ◽  
Amit Sharma ◽  
Manish Kumar Bhadu ◽  
Keshave Swarnkar

Purpose The aim of this study was to evaluate the corrosion inhibition efficiency of steel samples in different environments before and after the treatment with rust metamorphose (RM), which is formulated in this research study and shows excellent adherence over the rusted surface of substrate because of the presence of the P-O-Fe bond. Design/methodology/approach An RM solution (phosphorylated polyphenol) was synthesised and characterised using Fourier transform infrared spectroscopy (FT-IR), and then the degree of protection offered by it to steel surfaces with and without the treatment with the RM solution in different atmospheres was evaluated;. Before and after treating with the RM solution, the corroded steel samples were characterised using X-ray diffraction (XRD), FT-IR, scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The study of the passive behaviours of the corroded steel samples and RM-treated steel samples was done in different simulated atmospheres. Findings This RM solution is phosphorylated polyphenol solution (proved by FT-IR), which acts as a corrosion inhibitor on corroded steel surfaces because of the formation of a passive and symmetric adherent layer of phosphorylated polyphenol–iron complex (confirmed by FT-IR, XRD, EDS, SEM and adhesion X test). The significant improvement in corrosion resistance in splash conditions of 3.5 per cent NaCl, tap water and 1.5 per cent Na2SO4 was found with the treatment of phosphorylated polyphenol-based RM. Originality/value The development of RM and its characterisation with performance evaluation in different atmospheres is a novel approach in this research.


2021 ◽  
Author(s):  
Amalanathan.M ◽  
Aravind.M ◽  
Sony Michael Mary.M ◽  
Razan A. Alshgari ◽  
Asma A. Alothman ◽  
...  

Abstract In this work, jasmine flower derived activated carbon were successfully synthesized by hydrothermal carbonization process at the different annealing temperature. The Crystallinity, phase, structural, morphological and optical properties of activated carbon were investigated using X-ray diffraction (XRD), Fourier Transform Infrared spectroscopy (FT-IR), Scanning electron microscopy (SEM), Transmission electron microscope (TEM), and UV-visible spectroscopy analysis. The graphitic phase of carbon was obtained from the XRD pattern. Surface morphology reveals irregular-shaped nanoparticles. The photodegradation of methylene blue (MB) was carried out under the visible light irradiation technique to study its photocatalytic activity. The activated carbon obtained at 400oC, 500oC and 600oC shows a photocatalytic degradation efficiency of 86%, 90%, and 94%, respectively. Antibacterial activity of activated carbon was examined against S. Aureus (MTCC-737) and E-Coli (MTCC- 443) microbial pathogens, and their potent antibacterial activity was examined from the zone of inhibition layer.


2019 ◽  
Vol 48 (5) ◽  
pp. 464-471
Author(s):  
Fatma Abdelghaffar ◽  
Rehab A. Abdelghaffar ◽  
Safia A. Mahmoud ◽  
Badria M. Youssef

Purpose This paper aims to improve the adsorption capacity of sugarcane bagasse (SCB) as a low-cost, attractive and effective adsorbent for dye removal from wastewater. Design/methodology/approach SCB is a cellulosic material; it was chemically modified with compounds containing cationic groups. The adsorption efficiency of unmodified and modified SCB was investigated with anionic dyes by studying various factors that affect modified SCB and adsorption. Findings X-ray diffraction, FT-IR spectra and nitrogen content were used to confirm the effect of existence of quaternary ammonium groups on modified SCB. The morphological structure of the modified and unmodified SCB has been demonstrated using electronic scanning microscopy. Research limitations/implications The modified SCB was chemically treated by Quat 188, which is commercially available in the solution of 3-chloro-2-hydroxypropyltrimethyl ammonium chloride. Practical implications Grafting cationic function groups on the surface of sugarcane by cationization treatment enhances its adsorption efficiency for anionic dyes. Originality/value The main value of this research was indicating a clear difference in the appearance of unmodified and modified SCB surfaces. Furthermore, it can be determined that the modified SCB absorbs more of the dyes.


2020 ◽  
Author(s):  
Greta Bajni ◽  
Corrado Camera ◽  
Tiziana Apuani

<p>Due to climate change and the strong relationships between landslides and atmospheric variables, the concept of a stationary landslide susceptibility appears limited. However, relating landslides with climatic predisposing and triggering factors is challenging, due to the lack of multitemporal event datasets. Rockfalls are even more challenging in this context, as their reaction to meteorological events is connected to widely variable characteristics (e.g. rock type, in situ stress, fracture network).</p><p>By exploiting and homogenizing a multitemporal rockfall inventory and meteorological datasets of the Aosta Valley Region (Western Italian Alps), the general goal of our study was to develop a procedure to decipher the effects of both the short- and long-term action of rainfall and freeze-thaw cycles on rockfalls occurrence, recognized as main forcing climatic variables in the classic literature. Our specific objective was to define synthetic and effective meteorological variables that can act as predictors in statistical landslide susceptibility models.</p><p>We analysed 168 rockfall events and meteorological data from 17 stations from 1990 to 2018 (reference period) distributed on an area 670 km<sup>2</sup>. The analysis was performed considering:</p><ul><li>Short term (hourly) precipitation expressed both by the intensity-duration characteristics of the single rockfall associated rainfall(1) and by the maximum cumulated rainfall in time intervals from 0.5 to 24 hours before the event(2);</li> <li>Long term precipitation (multiple episodes) expressed both by cumulated rainfall in time interval of 1 day to 60 days (3) and by the number of rainfall episodes occurred in 1- to 12-month time intervals before the event(4);</li> <li>Number of Freeze-thaw cycles in the year before the event, identified as temperature variation crossing the 0°C value(5).  </li> </ul><p>By comparing the statistical distribution, for the whole reference period, of the above mentioned climatic variables and the meteorological conditions before each rockfall event, we recognized four types of not ordinary climatic conditions. All conditions resulted to be associated to long term conditions of any time interval, while hourly intervals did not result significant. Type-a is associated to cumulated rainfall overcoming the 90<sup>th</sup> percentile of the historical time series(69 out of 168); Type-b to a number of rainfall episodes higher than the 75<sup>th</sup> percentile value(70 rockfalls out of 168); Type–c to a number to a number of freeze-thaw cycles higher than the 75<sup>th</sup> percentile value(66 out of 168); Type-d to a combination of these factors (47 out of 168). Only 5 rockfalls occurred during ordinary meteorological conditions, whereas the remaining 37 rockfalls could not being analysed due to the absence of complete meteorological data.</p><p>Based on these results, we defined a long term Intensity-duration and two episode-duration thresholds, each expressed by a power law equation. The number of times, in the reference period, of exceedance of the selected thresholds represent the synthetic variables to be spatialized by means of geostatistical techniques and tested within a statistical landslide susceptibility model.</p>


2018 ◽  
Vol 65 (4) ◽  
pp. 375-382 ◽  
Author(s):  
A.G. Mohan Das Gandhi ◽  
K. Soorya Prakash ◽  
V. Kavimani

Purpose This paper aims to examine the investigations made on the corrosion behaviour of magnesium (Mg) substrate electrodeposited using different nano-materials. Design/methodology/approach This study uses nano-materials such as those of reduced graphene oxide (r-GO), titanium-di-oxide (TiO2) and also r-GO/TiO2 nano-composites (dispersed through ultra-sonication process) at 3-min time interval. Crystalline nature of synthesized TiO2 is studied through X-ray diffraction and its pore volume is measured to be approximately 0.1851ccg-1 by Brunauer Emmett Teller analysis. Findings Surface morphology of the developed set of specimens inspected through scanning electron microscopy and energy dispersive spectroscopy establishes a clean surface coating and further witnesses for only minimal defects. Electrochemical behaviour of the developed coating is studied exhaustively using Tafel polarization and electrochemical impedance spectroscopy in 0.1 M Na2SO4 solution. Originality/value Incremental corrosion resistance exhibited by developed composite coating owes to the factors viz. chemical stability and hydrophobic tendency of TiO2 and r-GO; these known engineering facts resist the flow of ions into the corrosive media and thereby reduce the rate of corrosion.


2014 ◽  
Vol 7 (3) ◽  
pp. 303-315 ◽  
Author(s):  
Julie Winnard ◽  
Andy Adcroft ◽  
Jacquetta Lee ◽  
David Skipp

Purpose – Businesses are always seeking resilient strategies so they can weather unpredictable competitive environments. One source of unpredictability is the unsustainability of commerce's environmental, economic or social impacts and the limitations this places on businesses. Another is poor resilience causing erroneous and unexpected outputs. Companies prospering long-term must have both resilience and sustainability, existing in a symbiotic state. The purpose of this paper is to explore the two concepts and their relationship, their combined benefits and propose an approach for supporting decision makers to proactively build both characteristics. Design/methodology/approach – The paper looks at businesses as complex adaptive systems, how their resilience and sustainability can be defined and how these might be exhibited. It then explores how they can be combined in practice. Findings – The two qualities are related but have different purposes, moreover resilience has two major forms related to timescales. Both kinds of resilience are identified as key for delivering sustainability, yet the reverse is also found to be true. Both are needed to deliver either and to let businesses flourish. Practical implications – Although the ideal state of resilient sustainability is difficult to define or achieve, pragmatic ways exist to deliver the right direction of change in organisational decisions. A novel approach to this is explored based on transition engineering and robustness engineering. Originality/value – This paper links resilience and sustainability explicitly and develops a holistic pragmatic approach for working through their implications in strategic decision making.


2014 ◽  
Vol 665 ◽  
pp. 42-48
Author(s):  
Yan Mei Liu ◽  
Cun Liang Zhang ◽  
Shu Fang Lou ◽  
Qing Wang

Corrosion inhibitor-inorganic clay composite including 2-mercaptobenzimidazole (MBI) anions intercalating Zn-Al layered double hydroxides (LDHs) assembled via anion-exchange reaction. Powder X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectrum analysing and scanning electron microscopy (SEM) indicate that the MBI anion are successfully intercalated into the LDHs interlayer. The benzene plane is horizontal arrangement rather than vertical orientation in the interlayer spacing. The active anticorrosive property of AA2024 alloy with the active anticorrosion coating is evaluated by electrochemical impedance spectroscopy (EIS). The sol-gel coating doped with the LDHs clearly demonstrates long-term anticorrosive performances compared to the undoped sol-gel coating, due to the release of corrosion inhibitor from the LDHs.


INDIAN DRUGS ◽  
2019 ◽  
Vol 56 (02) ◽  
pp. 16-20
Author(s):  
U. R Nannapaneni ◽  
◽  
S. R. Rayapati

Here we report a novel biological approach for the formation of zinc nanoparticles using Guazuma ulmifolia (Lam) leaves. Zinc acetate was reduced with aqueous solution of Guazuma ulmifolia leave extracts. X-Ray diffraction (XRD) pattern reveals the formation of zinc nanoparticles, which shows crystallinity. Scanning electron microscopy (SEM) suggested particles size in the range of 46-96nm and spherical shape. UV absorption studies of zinc nano particles showed absorbance at 698nm and FT-IR studies of zinc nanoparticles confirmed the presence of bio active phyto-constituents in the formed nano particles. The DPPH free radical inhibition study confirmed that the synthesized zinc nano particles have potential radical inhibiting activity.


2022 ◽  
Vol 12 (1) ◽  
pp. 129-138
Author(s):  
Jing Zhang ◽  
Jie Liu ◽  
Hui Yan ◽  
Xuyu Wang ◽  
Huiyan Dong

Design and development of novel methods for the synthesis of metal nanopartilces (MNPs) was greatly attracted by research community due to various applications. We described a greener strategy for the synthesis of silver nanoformulation (Ag NF) using leaf extract of Ziziphus zizyphus and then surface functionalized using P(NIPAM-co-MQ). The synthesized AgNPs were characterized by UV-visible spectroscopy and Transmission electron microscopy. Further, the functionalized AgNPs were characterized XPS and x-ray diffraction studies. The design of bioactive and biocompatible Ag nanoformulation preparations have been provide promising alternative source for bacterial-related therapies. The developed Ag NF have demonstrated predominant bactericidal action with highinhibition rate and long-term efficiency against clinically approved bacterial pathogens (S. aureus and E. coli), which greatly contributed treatment of wound infections. The observations of the present study could provide new avenue for the antimicrobial treatment of wound therapy


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