Langmuir Isotherm and Pseudo Second Order Kinetic Model for the Biosorption of Methylene Blue Onto Rice Husk

Natural adsorbents as low-cost materials have been proved efficient for water remediation and have significant capacity for the removal of certain chemicals from wastewater. The present investigation aimed to use Citrullus colocynthis seeds (CCSs) and peels (CCPs) as an efficient natural adsorbent for methylene blue (MB) dye in an aqueous solution. The examined biosorbents were characterized using surface area analyzer (BET), scanning electron microscope (SEM), thermogravimetric analyzer (TGA) and Fourier transform infra-red (FT-IR) spectroscopy. Batch adsorption experiments were conducted to optimize the main factors influencing the biosorption process. The equilibrium data for the adsorption of MB by CCSs were best described by the Langmuir isotherm followed by the Freundlich adsorption isotherms, while the equilibrium data for MB adsorption by CCPs were well fitted by the Langmuir isotherm followed by the Temkin isotherm. Under optimum conditions, the maximum biosorption capacity and removal efficiency were 18.832 mg g−1 and 98.00% for MB-CCSs and 4.480 mg g−1 and 91.43% for MB-CCPs. Kinetic studies revealed that MB adsorption onto CCSs obeys pseudo-first order kinetic model (K1 = 0.0274 min−1), while MB adsorption onto CCPs follows the pseudo-second order kinetic model (K2 = 0.0177 g mg−1 min−1). Thermodynamic studies revealed that the MB biosorption by CCSs was endothermic and a spontaneous process in nature associated with a rise in randomness, but the MB adsorption by CCPs was exothermic and a spontaneous process only at room temperature with a decline in disorder. Based on the obtained results, CCSs and CCPSs can be utilized as efficient, natural biosorbents, and CCSs is promising since it showed the highest removal percentage and adsorption capacity of MB dye.

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Dyeing mechanism and photodegradation kinetics of gardenia yellow natural colorant

Textile Research Journal ◽

10.1177/0040517520958483 ◽

2020 ◽

pp. 004051752095848

Author(s):

Huiyu Jiang ◽

Xiaodong Hu ◽

Asfandyar Khan ◽

Jinbo Yao ◽

Muhammad Tahir Hussain

Keyword(s):

Kinetic Model ◽

Cotton Fabric ◽

Reaction Rate Constant ◽

Second Order ◽

Order Kinetic ◽

Natural Colorant ◽

Yellow Solution ◽

Order Kinetic Model ◽

Pseudo Second Order ◽

Dyeing Rate

In this study, gardenia yellow solution is used to dye 100% cotton fabric. The dyeing rate curve and adsorption isotherms were recorded to explore the thermodynamic model and to calculate the corresponding parameters. A definite concentration of gardenia yellow solution was placed under the xenon arc lamp for irradiation to test its photodegradability. Absorbance of the solution was measured at different degradation times and the corresponding varying curve of the absorbance was drawn to explore the photodegradation reaction order of the natural colorant and consistent parameters were calculated. The experimental results proved that the dyeing of cotton fabric with gardenia yellow colorant followed the pseudo second order kinetic model whereas adsorption isotherm followed the Langmuir model and the photodegradation process followed the second order kinetic model. Values of different parameters were calculated: reaction rate constant k = 2.26 × 10–3 (mg · L−1)1−m h−1, the correlation coefficient R2 = 0.994, and half decay time t1/2 = 5.82 h.

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Second-Order Kinetic Model for the Sorption of Cu(II) Ions in Aqueous Solutions of Zeolite NaA

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.560-561.1174 ◽

2012 ◽

Vol 560-561 ◽

pp. 1174-1177 ◽

Cited By ~ 2

Author(s):

Dimitar Petrov Georgiev ◽

Bogdan Iliev Bogdanov ◽

Yancho Hristov ◽

Irena Markovska

Keyword(s):

Kinetic Model ◽

Aqueous Solutions ◽

Kinetic Parameters ◽

Linear Equations ◽

Linear Method ◽

Second Order ◽

Order Kinetic ◽

Zeolite Naa ◽

Order Kinetic Model ◽

Pseudo Second Order

In this study, the sorption of Cu(II) ions in aqueous solutions of Zeolite NaA by performing batch kinetic sorption experiments. The equilibrium kinetic data were analyzed using the pseudo-second-order kinetic model. A comparison was made of the linear least-squares method and nonlinear method of the widely used pseudo-second-order kinetic model for the sorption of Cu(II) ions of Zeolite . Four pseudo-second-order kinetic linear equations are discussed. Kinetic parameters obtained from the four kinetic linear equations using the linear method differed but they were the same when using the non-linear method. Kinetic parameters obtained from four kinetic linear equations using the linear method differed. Equation type 1 pseudo-second-order kinetic model very well represented the kinetic of the adsorption Cu(II) ions by Zeolite NaA. Equation type 4 exhibited the worst fit. Present investigation showed that the non-linear method may be a better way to determine the kinetic parameters.

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Methylene Blue Dye Removal from Aqueous Media Using Activated Carbon Prepared by Lotus Leaves: Kinetic, Equilibrium and Thermodynamic Study

Acta Chimica Slovenica ◽

10.17344/acsi.2020.6311 ◽

2021 ◽

Vol 68 (2) ◽

pp. 363-373

Author(s):

Roya Salahshour ◽

Mehdi Shanbedi ◽

Hossein Esmaeili

Keyword(s):

Methylene Blue ◽

Activated Carbon ◽

Sorption Process ◽

Second Order ◽

Blue Dye ◽

Order Kinetic ◽

Methylene Blue Dye ◽

Order Kinetic Model ◽

Pseudo Second Order ◽

Lotus Leaves

In the present work, methylene blue was eliminated from aqueous solution using activated carbon prepared by lotus leaves. To perform the experiments, batch method was applied. Also, several analyses such as SEM, FTIR, EDAX and BET were done to determine the surface properties of the activated carbon. The results showed that the maximum sorption efficiency of 97.59% was obtained in initial dye concentration of 10 mg/L, pH of 9, adsorbent dosage of 4 g/L, temperature of 25 °C, contact time of 60 min and mixture speed of 400 rpm. Furthermore, the maximum adsorption capacity was determined 80 mg/g, which was a significant value. The experimental data was analyzed using pseudo-first order, pseudo-second order and intra-particle diffusion kinetic models, which the results showed that the pseudo-second order kinetic model could better describe the kinetic behavior of the sorption process. Also, the constant rate of the pseudo-second order kinetic model was obtained in the range of 0.0218–0.0345 g/mg.min. Moreover, the adsorption equilibrium was well described using Freundlich isotherm model. Furthermore, the thermodynamic studies indicated that the sorption process of methylene blue dye using the activated carbon was spontaneous and exothermic.

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Preparation and Characterization of Magadiite–Magnetite Nanocomposite with Its Sorption Performance Analyses on Removal of Methylene Blue from Aqueous Solutions

Polymers ◽

10.3390/polym11040607 ◽

2019 ◽

Vol 11 (4) ◽

pp. 607 ◽

Cited By ~ 10

Author(s):

Mingliang Ge ◽

Zhuangzhuang Xi ◽

Caiping Zhu ◽

Guodong Liang ◽

Guoqing Hu ◽

...

Keyword(s):

Methylene Blue ◽

Adsorption Isotherm ◽

Kinetic Model ◽

Aqueous Solutions ◽

Langmuir Adsorption Isotherm ◽

Order Kinetic ◽

Langmuir Adsorption ◽

Adsorption Performance ◽

Order Kinetic Model ◽

Pseudo Second Order

The magadiite–magnetite (MAG–Fe3O4) nanocomposite has great potential applications in the field of biomaterials research. It has been used as a novel magnetic sorbent, prepared by co-precipitation method. It has the dual advantage of having the magnetism of Fe3O4 and the high adsorption capacity of pure magadiite (MAG). MAG–Fe3O4 was characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and vibrating sample magnetometer (VSM). The results showed that Fe3O4 nanoparticles were deposited on the interlayer and surface of magadiite. MAG–Fe3O4 was treated as an adsorbent for methylene blue (MB) removal from aqueous solutions. The adsorption properties of MAG–Fe3O4 were investigated on methylene blue; however, the results showed that the adsorption performance of MAG–Fe3O4 improved remarkably compared with MA and Fe3O4. The adsorption capacity of MAG–Fe3O4 and the removal ratio of methylene blue were 93.7 mg/g and 96.2%, respectively (at 25 °C for 60 min, pH = 7, methylene blue solution of 100 mg/L, and the adsorbent dosage 1 g/L). In this research, the adsorption experimental data were fitted and well described using a pseudo-second-order kinetic model and a Langmuir adsorption isotherm model. The research results further showed that the adsorption performance of MAG–Fe3O4 was better than that of MAG and Fe3O4. Moreover, the adsorption behavior of MB on MAG–Fe3O4 was investigated to fit well in the pseudo-second-order kinetic model with the adsorption kinetics. The authors also concluded that the isothermal adsorption was followed by the Langmuir adsorption isotherm model; however, it was found that the adsorption of the MAG–Fe3O4 nanocomposite was a monolayer adsorption.

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Uranium (VI) Recovery from Black Shale Leaching Solutions Using Ion Exchange: Kinetics and Equilibrium Studies

Minerals ◽

10.3390/min10080689 ◽

2020 ◽

Vol 10 (8) ◽

pp. 689

Author(s):

Omirserik Baigenzhenov ◽

Alibek Khabiyev ◽

Brajendra Mishra ◽

M. Deniz Turan ◽

Merey Akbarov ◽

...

Keyword(s):

Kinetic Model ◽

Sorption Isotherm ◽

Room Temperature ◽

Sorption Kinetics ◽

Second Order ◽

Order Kinetic ◽

Strong Base ◽

Maximum Sorption Capacity ◽

Order Kinetic Model ◽

Pseudo Second Order

This work studies the removal of uranium ions from chemically leached solutions by sorption using two weak and two strong base anionites. Batch sorption experiments were performed to evaluate the optimum conditions at pH 1.2–2.2, 1.0 g resin dose for 1–12 h contact time at room temperature. These experiments addressed sorption kinetics and sorption isotherm. The maximum sorption capacity reached 55.8 mg/g at room temperature. The kinetics data are well described by the pseudo-second-order kinetic model at initial uranium concentration of 0.62 mg·L−1. To describe sorption kinetics pseudo-first-order, pseudo-second-order and intraparticle diffusion models were proposed. Studies indicated that the sorption of uranium can be fitted by a pseudo-second-order kinetic model very well. Equilibria were described by Langmuir, Freundlich, and Dubinin–Radushkevich equations. The experimental sorption isotherm is successfully described by the Langmuir model.

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Carbonized Lanthanum-Based Metal-Organic Framework with Parallel Arranged Channels for Azo-Dye Adsorption

Nanomaterials ◽

10.3390/nano10061053 ◽

2020 ◽

Vol 10 (6) ◽

pp. 1053

Author(s):

Krzysztof Cendrowski ◽

Karolina Opała ◽

Ewa Mijowska

Keyword(s):

Kinetic Model ◽

Adsorption Kinetics ◽

Hydrophobic Interactions ◽

Metal Organic Framework ◽

Second Order ◽

Order Kinetic ◽

Order Kinetic Model ◽

Metal Organic ◽

Pseudo Second Order ◽

Organic Framework

In this contribution, the synthesis of the metal−organic framework (MOF) based on lanthanum that exhibits trigonal prism shape is presented. The length of a single side of this structure ranges from 2 to 10 μm. The carbonized lanthanum-based organic framework (CMOF–La) maintained the original shape. However, the lanthanum oxide was reshaped in the form of rods during the carbonization. It resulted in the creation of parallel arranged channels. The unique structure of the carbonized structure motivated us to reveal its adsorption performance. Therefore, the adsorption kinetics of acid red 18 onto a carbonized metal−organic framework were conducted. Various physicochemical parameters such as initial dye concentration and pH of dye solution were investigated in an adsorption process. The adsorption was found to decrease with an increase in initial dye concentration. In addition, the increase in adsorption capacity was noticed when the solution was changed to basic. Optimal conditions were obtained at a low pH. Kinetic adsorption data were analyzed using the pseudo-first-order kinetic model, the pseudo-second-order kinetic model and the intraparticle diffusion model. The adsorption kinetics were well fitted using a pseudo-second-order kinetic model. It was found that the adsorption of anionic dye onto CMOF–La occurs by hydrophobic interactions between carbonized metal-organic framework and acid red 18.

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Characteristics of pseudo-second-order kinetic model for liquid-phase adsorption: A mini-review

Chemical Engineering Journal ◽

10.1016/j.cej.2009.02.024 ◽

2009 ◽

Vol 151 (1-3) ◽

pp. 1-9 ◽

Cited By ~ 214

Author(s):

Feng-Chin Wu ◽

Ru-Ling Tseng ◽

Shang-Chieh Huang ◽

Ruey-Shin Juang

Keyword(s):

Liquid Phase ◽

Kinetic Model ◽

Second Order ◽

Order Kinetic ◽

Liquid Phase Adsorption ◽

Order Kinetic Model ◽

Pseudo Second Order

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Equilibrium and kinetics studies for the adsorption of Ni2+ and Fe3+ ions from aqueous solution by graphene oxide

Polish Journal of Chemical Technology ◽

10.1515/pjct-2017-0058 ◽

2017 ◽

Vol 19 (3) ◽

pp. 120-129 ◽

Cited By ~ 11

Author(s):

Wojciech Konicki ◽

Małgorzata Aleksandrzak ◽

Ewa Mijowska

Keyword(s):

Graphene Oxide ◽

Kinetic Model ◽

Metal Ion ◽

Second Order ◽

Ion Concentration ◽

Isotherm Models ◽

Order Kinetic ◽

Intraparticle Diffusion Model ◽

Order Kinetic Model ◽

Pseudo Second Order

Abstract In this study, the adsorption of Ni2+ and Fe3+ metal ions from aqueous solutions onto graphene oxide (GO) have been explored. The effects of various experimental factors such as pH of the solution, initial metal ion concentration and temperature were evaluated. The kinetic, equilibrium and thermodynamic studies were also investigated. The adsorption rate data were analyzed using the pseudo-first-order kinetic model, the pseudo-second-order kinetic model and the intraparticle diffusion model. Kinetic studies indicate that the adsorption of both ions follows the pseudo-second-order kinetics. The isotherms of adsorption data were analyzed by adsorption isotherm models such as Langmuir and Freundlich. Equilibrium data fitted well with the Langmuir model. The maximum adsorption capacities of Ni2+ and Fe3+ onto GO were 35.6 and 27.3 mg g−1, respectively. In addition, various thermodynamic parameters, such as enthalpy (ΔHO), entropy (ΔSO) and Gibbs free energy (ΔGO), were calculated.

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