The study of volcanic rocks characterization of Sinabung Volcano erupted on September 15, 2017. The volcanic rocks crystal system was performed with XRD, elemental analysis and microstructure with SEM-EDX. Volcanic rocks contain: Anorthite phase 87,11 (wt%), Triclinic crystal, lattice constant, a = 8.1742 Å, b = 12,844 Å, c = 14,204 Å; Quartz phase 2.26%, Hexagonal crystals, lattice constants, a = 4,799 Å, b = 4,799 Å, c = 5,379 Å; Cristobalite phase 7.72 (wt%), Tetragonal crystals, lattice constants a = 4,970 Å, b = 6,990 Å, c = 6,998 Å; Alunite phase 2.91 (wt%), Hexagonal crystals, lattice constants, a = 6,990 Å, b = 6,990 Å, c = 17,282 Å.