scholarly journals Nanocellulose and nanoclay as reinforcement materials in polymer composites: A review

2020 ◽  
Vol 16 (2) ◽  
pp. 145-153
Author(s):  
Fathin Najihah Nor Mohd Hussin ◽  
Roswanira Abdul Wahab ◽  
Nursyafreena Attan

The advancement of nanotechnology has opened a new opportunity to develop nanocomposites using nanocellulose (NC) and nanoclay (NCl). Researchers have regarded these nanocomposites as promising substitutes for conventional polymers because of their characteristic and useful features, which include exceptional strength and stiffness, low weight, and low environmental impact. These features of NC and NCl explain their multifarious applications across many sectors. Here we review NC and NCl as well as various reinforced polymer composites that are made up of either of the two nanomaterials. The structural and physicochemical properties of NC and NCl are highlighted, along with the mechanical behavior and thermal properties of NC. Current nanomaterial hybrid biopolymers for the production of novel high-performance polymer nanocomposites are also discussed with respect to their mechanical properties.

2019 ◽  
Vol 28 ◽  
pp. 2633366X1989062 ◽  
Author(s):  
Mehdi Derradji ◽  
Djalal Trache ◽  
Abdelkhalek Henniche ◽  
Abdeljalil Zegaoui ◽  
Aboubakr Medjahed ◽  
...  

Taking into consideration the latest advances in both ceramic and polymer fields, a new generation of high-performance polymer composites based on the state-of-the-art MXene (Ti3C2(OH)2) ceramics and one of the leading high-performance thermosets, namely the phthalonitrile resins, is presented. The synergistic combination between the two phases led to nanocomposites exhibiting an outstanding thermal stability with starting decomposition temperatures not less than 484°C for 3 wt% of nanoloading. The tensile properties were as high as those obtained with fiber-reinforced polymer composites. For instance, the tensile strength reached its highest value of 276 MPa for the maximum loading of 3 wt%. The morphological studies carried out by scanning and transmission electron microscopies corroborated the improvements of the thermal and mechanical properties. Undoubtfully, such materials expected to be used in extreme conditions can be seen as the next generation of ceramics-reinforced polymer composites.


2021 ◽  
Vol 17 ◽  
Author(s):  
Tushar T. Hawal ◽  
Maharudra S. Patil ◽  
Siddalinga Swamy ◽  
Raviraj M. Kulkarni

: Graphene as a nanofiller has gained tremendous importance in polymer nanocomposites for many applications. The attractive properties of graphene related to mechanical, electrical, and thermal domains pose a lucrative means of reinforcing the polymers to obtain the needed properties. The rise in the use of polymers supports this trend and urges the researchers to excavate the hidden plethora of nanocomposite materials for multifunctional applications. In this review, an overview is provided on graphene-based materials which have been used extensively in various fields, such as batteries, aerospace, automobile and biomedical fields. An increasing trend of graphene usage by many researchers as a nanofiller in polymer composites, its types, processing methods are highlighted with suitable applications to assimilate the updates in the development of graphene nanocomposites.


Fibers ◽  
2018 ◽  
Vol 6 (3) ◽  
pp. 58 ◽  
Author(s):  
Antonin Knob ◽  
Jaroslav Lukes ◽  
Lawrence Drzal ◽  
Vladimir Cech

Compatible interlayers must be coated on reinforcing fibers to ensure effective stress transfer from the polymer matrix to the fiber in high-performance polymer composites. The mechanical properties of the interlayer, and its interfacial adhesion on both interfaces with the fiber and polymer matrix are among the key parameters that control the performance of polymer composite through the interphase region. Plasma-synthesized interlayers, in the form of variable materials from polymer-like to glass-like films with a Young’s modulus of 10–52 GPa, were deposited on unsized glass fibers used as reinforcements in glass fiber/polyester composites. Modulus Mapping (dynamic nanoindentation testing) was successfully used to examine the mechanical properties across the interphase region on cross-sections of the model composite in order to distinguish the fiber, the interlayer, and the modified and bulk polymer matrix. The interfacial shear strength for plasma-coated fibers in glass fiber/polyester composites, determined from the microindentation test, was up to 36% higher than those of commercially sized fibers. The effects of fiber pretreatment, single and double interlayers, and post-treatment of the interlayer on interfacial shear strength were also discussed. Functional interlayers with high shear yield strength and controlled physicochemical properties are promising for high-performance polymer composites with a controlled interphase.


Polymers ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 438
Author(s):  
Ching Hao Lee ◽  
Abdan Khalina ◽  
Seng Hua Lee

Plant fibers have become a highly sought-after material in the recent days as a result of raising environmental awareness and the realization of harmful effects imposed by synthetic fibers. Natural plant fibers have been widely used as fillers in fabricating plant-fibers-reinforced polymer composites. However, owing to the completely opposite nature of the plant fibers and polymer matrix, treatment is often required to enhance the compatibility between these two materials. Interfacial adhesion mechanisms are among the most influential yet seldom discussed factors that affect the physical, mechanical, and thermal properties of the plant-fibers-reinforced polymer composites. Therefore, this review paper expounds the importance of interfacial adhesion condition on the properties of plant-fiber-reinforced polymer composites. The advantages and disadvantages of natural plant fibers are discussed. Four important interface mechanism, namely interdiffusion, electrostatic adhesion, chemical adhesion, and mechanical interlocking are highlighted. In addition, quantifying and analysis techniques of interfacial adhesion condition is demonstrated. Lastly, the importance of interfacial adhesion condition on the performances of the plant fiber polymer composites performances is discussed. It can be seen that the physical and thermal properties as well as flexural strength of the composites are highly dependent on the interfacial adhesion condition.


2021 ◽  
Vol 5 (5) ◽  
pp. 130
Author(s):  
Tan Ke Khieng ◽  
Sujan Debnath ◽  
Ernest Ting Chaw Liang ◽  
Mahmood Anwar ◽  
Alokesh Pramanik ◽  
...  

With the lightning speed of technological evolution, the demand for high performance yet sustainable natural fibres reinforced polymer composites (NFPCs) are rising. Especially a mechanically competent NFPCs under various loading conditions are growing day by day. However, the polymers mechanical properties are strain-rate dependent due to their viscoelastic nature. Especially for natural fibre reinforced polymer composites (NFPCs) which the involvement of filler has caused rather complex failure mechanisms under different strain rates. Moreover, some uneven micro-sized natural fibres such as bagasse, coir and wood were found often resulting in micro-cracks and voids formation in composites. This paper provides an overview of recent research on the mechanical properties of NFPCs under various loading conditions-different form (tensile, compression, bending) and different strain rates. The literature on characterisation techniques toward different strain rates, composite failure behaviours and current challenges are summarised which have led to the notion of future study trend. The strength of NFPCs is generally found grow proportionally with the strain rate up to a certain degree depending on the fibre-matrix stress-transfer efficiency. The failure modes such as embrittlement and fibre-matrix debonding were often encountered at higher strain rates. The natural filler properties, amount, sizes and polymer matrix types are found to be few key factors affecting the performances of composites under various strain rates whereby optimally adjust these factors could maximise the fibre-matrix stress-transfer efficiency and led to performance increases under various loading strain rates.


2021 ◽  
Vol 13 ◽  
Author(s):  
Md. Faruk Hossen ◽  
Md. Ali Asraf ◽  
Md. Kudrat-E-Zahan ◽  
C. M. Zakaria

: The research on jute fiber reinforced polymer composites is an emergent concern with the development of new materials due to its significant properties like economical, partially biodegradable and environment friendly. It is wondered that the hydrophilic nature of jute fiber negatively affects the interfacial interaction with hydrophobic polymeric materials in the composite which then affects the resultant mechanical, microstructural and physico-chemical absorption properties. In order to overcome this fact, researchers have been carried out some techniques for fiber surface chemical treatments. On the other hand, due to the low processing costs and design flexibility, thermoplastics deal many benefits over thermoset polymers, and polyethylene shows excellent processing behaviors such as: low density, low cost, considerable flex life, outstanding surface hardness, scratch resistance and good electrical insulator. Beside the traditional thermoplastic and thermosetting polymers, montmorillonite nanoclay are also receiving attention to manufacture fiber polymer nanocomposites for industrial and household applications as well. The review is considered to highlight the progress of jute fiber reinforced polymer nanocomposites. The study also focuses on the several features of juter polymer composites and nanocomposites as a function of fiber chemical treatments.


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