scholarly journals Phytoextraction of heavy metal from sewage sludge by plants

2010 ◽  
Vol 58 (5) ◽  
pp. 27-34
Author(s):  
Jaroslava Bartlová ◽  
Barbora Badalíková ◽  
Jan Hrubý ◽  
Vasil Gjurov
Keyword(s):  
Heavy Metals ◽  
Sewage Sludge ◽  
Aboveground Biomass ◽  
Treatment Plant ◽  
Sweet Clover ◽  
Mining Operations ◽  
Lead And Cadmium ◽  
North East ◽  
Average Annual Temperature ◽  
Cadmium And Lead

In 2008 and 2009, studies made contents of cadmium and lead in the soil and their uptake by non-traditional plants were studied in a small-plot trial. At the same time also the effect of bio-algeen preparations on phytoextraction of heavy metals by these plants was investigated. Experimental plots were established on the reclaimed land after closing down mining operations in the town of Žacléř (North-East Bohemia) where a layer of sewage sludge from a wastewater treatment plant 0.6–0.8 m thick was subsequently applied. The locality is situated in the altitude of 612 m, its average annual temperature is about 6.8 °C and the mean annual precipitations are 857 mm. Analyses revealed higher concentrations of heavy metals in the applied sewage sludge. The average concentrations of lead and cadmium were 180 mg . kg−1 and 6.89 mg . kg−1, respectively. The experiment had two variants: Variant 1 – sewage sludge without any other substances, and Variant 2 – sewage sludge + bio-algeen preparations (B. A. S-90 or B. A. Root Concentrate). To find the most suitable plant species for the phytoextraction of cadmium and lead, the following non-traditional plants were cultivated in both variants: fodder mallow (Malva verticillata L.), rye (Secale cereale L. var. multicaule METZG. ex ALEF.) and white sweet clover (Melilotus alba MEDIC.). The highest accumulation of cadmium and lead in the aboveground biomass was found out in rye, viz 14.89 mg . kg−1 DM and 14.89 mg . kg−1 DM of Cd and Pb, respectively., As compared with other plants under study, white sweet clover exhibited the significantly lowest capability to extract both heavy metals from soil (viz 0.22 and 3.20 mg . kg−1 DM of Cd and Pb, respectively). A positive effect of bio-algeen on phytoextraction of cadmium and lead was evident in all plants. The highest yield of aboveground biomass was recorded on the plot with white sweet clover with added alginate (496 g . m−2). Of plants under study, the fodder mallow seems to be the most suitable crop for the phytoextraction of both metals (0.35 and 5.87 mg . m−2 of Cd and Pb, respectively).

scholarly journals Regulatory and technological prerequisites of the use of sewage sludge for the production of organic fertilizers

2020 ◽  
pp. 162-170
Author(s):  
R. Edgecock ◽  
V. V. Bratishko ◽  
I. V. Zinchenko ◽  
S. H. Karpus ◽  
D. O. Milko ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Sewage Sludge ◽  
Municipal Wastewater ◽  
Raw Materials ◽  
Sewage Treatment ◽  
Sewage Treatment Plant ◽  
Treatment Plant ◽  
Raw Material ◽  
Organic Fertilizers ◽  
Mineral Fertilizers

Annotation Purpose. Summarize the regulatory and technological requirements for the production of organic (organo-mineral) fertilizers on the base of sewage sludge. Methods. Analysis and generalization of the requirements of regulatory documents on the management of organic waste and their use as raw materials for the production of organic fertilizers and soil improvers. Results. The current legislative, departmental and regulatory documentary base in Ukraine concerning the treatment of sediment resulting from biological sewage treatment at municipal wastewater treatment plants for its further use in agriculture as fertilizers is analysed. Indicators are identified and analysed to determine the possibility, feasibility, efficiency and scope of organic fertilizers produced using sewage sludge. The analysis of changes in the content of organic matter and total nitrogen in the sewage sludge during its storage at the sewage treatment plant sites is presented. The technological feasibility of using sludge of different shelf life in composting production has been determined. Conclusions 1. The regulatory framework of Ukraine contains a sufficiently complete list of indicators that should be met by organic raw materials (sewage sludge) for further use as organic fertilizers. Some of these indicators – bio security and heavy metals content – can be improved in the composting process of fertilizers. 2. Fresh sediment, as well as sediment accumulated in the last late autumn and winter periods, is of main value for use as a raw material in the production of organic fertilizers. 3. The use in the production of compost sludge stored on sludge sites for a period of half a year or more requires special control of the process of decontamination. In this case, it is advisable to use additional means of wastewater decontamination. Keywords: heavy metals, manure, humus, decontamination, composting, organic fertilizers, sewage sludge.

Decontamination of Heavy Metals From Municipal Sewage Sludge (MSS) by Electrokinetic Remediation

2019 ◽  
Author(s):  
A. Ribeiro ◽  
J. Araújo ◽  
A. Mota ◽  
R. Campos ◽  
C. Vilarinho ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Sewage Sludge ◽  
Municipal Wastewater ◽  
Treatment Plant ◽  
Operation Time ◽  
Electrokinetic Remediation ◽  
Permeable Reactive Barrier ◽  
Municipal Sewage ◽  
Municipal Sewage Sludge ◽  
Reactive Barrier

Abstract A large quantity of sludges resulting from the treatment of MWWTP (Municipal Wastewater Treatment Plant) effluent is generated annually following the increase of population density and acceleration of urbanization. Sludge production in Europe has been predicted by around 12 million tons in 2020. As a solid waste, appropriate disposal of Municipal Sewage Sludge (MSS) has been taken seriously due to its larger volume and toxic substances such as heavy metals. Electrokinetic remediation has more advantages in heavy metals uptake compared to other technologies, due to the ability to treat soils in-situ and to remove heavy metals from soils. In this work, it was studied the remediation of MSS by the electrokinetic remediation coupled with activated carbon (AC) as a permeable reactive barrier (PRB). It was applied an electric current of 3 V cm−1 and it was used an AC/sludge ratio of 30 g kg−1 of contaminated sludge for the preparation of the PRB. In each trial, the evolution of cadmium (Cd), lead (Pb), copper (Cu), chromium (Cr), nickel (Ni) and zinc (Zn) removal from the sludge were evaluated. Results proved that this process is perfectly suited for the removal of chromium, nickel and zinc metals from the sludge. At the end of the operation time, it was achieved a maximum removal rate of 56% for chromium, 73% for nickel and 99% for zinc, with initial concentrations of 2790 mg kg−1, 2840 mg kg−1, and 94200 mg kg−1, respectively. Based on these results, it was proved the technical viability of the proposed technology (electrokinetic with AC as a permeable reactive barrier) to treat municipal sewage sludges.

scholarly journals Effect of Diatomite on the Accumulation of Lead and Cadmium in the Body of White Rats

2021 ◽  
Vol 37 ◽  
pp. 00144
Author(s):  
Vasily I. Dorozhkin ◽  
Natalia A. Brichko ◽  
Natalia S. Pavlova ◽  
Galina I. Pavlenko
Keyword(s):  
Heavy Metals ◽  
Animal Husbandry ◽  
Cadmium Accumulation ◽  
The Body ◽  
Feed Additive ◽  
Lead And Cadmium ◽  
White Rats ◽  
Accumulation Of Metals ◽  
Livestock Products ◽  
Cadmium And Lead

Every year, pollution by eco-toxicants of natural and anthropogenic origin is becoming more and more acute. Some of the most toxic among them are heavy metals, especially cadmium and lead. These elements do not decompose. Once released into the environment, these elements continue to circulate in water, soil, and air for a very long time, accumulating in plants and livestock products. Therefore, there is a problem of obtaining safe agricultural products in areas contaminated with heavy metals. In animal husbandry, synthetic and natural enterosorbents are used for obtaining safe products. For example, such enterosorbents are shungites, bentonites, diatomites, clays. We tested diatomite from the Kamyshlovskoye deposit at a dose of 5.0 g/kg of feed to reduce cadmium accumulation and lead during their combined intake. We investigated the feed intake of a combination of cadmium and lead at doses of 5.0 and 50.0 mg/kg feed. The result of this experiment is the accumulation of metals in the liver, kidneys, and bones, and, in addition, in the testes. The use of diatomite to reduce the accumulation of heavy metals has not been successful. There is an increase in lead accumulation in the liver, kidneys, and testes. The content of cadmium in diatomite is 3.86 ± 0.20 mg/kg, lead – 105.0 ± 7.2 mg/kg. The results obtained indicate that diatomite as a feed additive to reduce lead and cadmium intoxication did not show protective properties.

scholarly journals RISK ANALYSIS OF ACCUMULATION OF HEAVY METALS FROM SEWAGE SLUDGE IN SOIL FROM THE SEWAGE TREATMENT PLANT IN STARACHOWICE

2019 ◽  
Vol 11 (4) ◽  
pp. 287-295
Author(s):  
ROBERT KOWALIK ◽  
◽  
JAROSŁAW GAWDZIK ◽  
BARBARA GAWDZIK ◽  
◽  
...  
Keyword(s):  
Heavy Metals ◽  
Sewage Sludge ◽  
Risk Analysis ◽  
Sewage Treatment ◽  
Sewage Treatment Plant ◽  
Treatment Plant

WAYS OF REDUCING IONS HEAVY METALS IN SEWAGE SLUDGE

2013 ◽  
Vol 3 (4S) ◽  
pp. 26-29
Author(s):  
Tatiana E GRISHINA ◽  
Elena A FEDOROVA
Keyword(s):  
Heavy Metals ◽  
Wastewater Treatment ◽  
Sewage Sludge ◽  
Wastewater Treatment Plant ◽  
Treatment Plant

The analysis of the composition and considered how to dispose of sewage sludge wastewater treatment plant at Nizhny Novgorod content of heavy metals in the last decade, the ways of reducing the amount of heavy metals in sewage sludge.

scholarly journals Assessment of Heavy Metal Pollution and Potential Ecological Risk in Sewage Sludge from Municipal Wastewater Treatment Plant Located in the Most Industrialized Region in Poland—Case Study

2019 ◽  
Vol 16 (13) ◽  
pp. 2430 ◽  
Author(s):  
Malwina Tytła
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Wastewater Treatment ◽  
Risk Factor ◽  
Sewage Sludge ◽  
Ecological Risk ◽  
Treatment Plant ◽  
Potential Ecological Risk ◽  
Pollution Level ◽  
Chemical Forms

This study aimed to assess the pollution and potential ecological risk of seven heavy metals (Cd, Cr, Cu, Hg, Ni, Pb, and Zn) in the sewage sludge collected from a wastewater treatment plant (WWTP), located in the most industrialized region of Poland (Silesian Voivodeship). The concentrations of heavy metals were determined using inductively coupled plasma optical spectrometry (ICP-OES) and cold vapor atomic absorption spectrometry (CVAAS). The chemical forms (chemical speciation) of heavy metals were determined using the three-step chemical sequential extraction procedure, developed by the Community Bureau of Reference (BCR). To assess the pollution level and potential ecological risk, the following indices were used: Geoaccumulation Index (Igeo), Potential Ecological Risk Factor (ER), Individual Contamination Factor (ICF), Risk Assessment Code (RAC), and Ecological Risk Factor (ERF)—the author’s index. Sludge samples were collected at successive stages of processing. The results revealed that the activated sludge process and sludge thickening have a significant impact on heavy metal distribution, while anaerobic digestion and dehydration decrease their mobility. The most dominant metals in the sludge samples were Zn and Cu. However, the content of heavy metals in sewage sludge did not exceed the permissible standards for agricultural purposes. The concentrations of heavy metals bound to the immobile fractions exhibited higher concentrations, compared to those bound to mobile fractions (except Zn). The values of the total indices indicated that sludge samples were moderately to highly contaminated with Zn, Hg, Cd, Cu, and Pb, of which only Hg, Cd, and Cu posed a potential ecological risk, while according to the speciation indices, sludge samples were moderately to very highly polluted with Zn, Cu, Cd, Cr, and Ni, of which Zn, Ni, and Cd were environmentally hazardous. The obtained results proved that assessment of the pollution level and potential ecological risk of heavy metals in sewage sludge requires knowledge on both their total concentrations and their chemical forms. Such an approach will help prevent secondary pollution of soils with heavy metals, which may influence the reduction of health risks associated with the consumption of plants characterized by a high metal content.

scholarly journals Chemical Analysis of Rock and Water from dug Wells in a Residential Area in Lagos State, Nigeria

2015 ◽  
Vol 7 (2) ◽  
pp. 122
Author(s):  
Mopelola Omotoso ◽  
Ibrahim Amoo
Keyword(s):  
Heavy Metals ◽  
Underground Water ◽  
Polluted Water ◽  
Contaminated Water ◽  
Adsorbent Dosage ◽  
Lead And Cadmium ◽  
Metals Removal ◽  
Lagos State ◽  
Dug Wells ◽  
Cadmium And Lead

Samples of rock deposit dug out from wells at Alimosho local government in Lagos state, Nigeria were characterized for chemical composition and ultimate utilization. Fourier Transform Infrared Spectroscopy (FTIR), X-Ray diffraction (XRD) and Atomic Absorption Spectroscopy (AAS) were used to identify the rock as a mixed clay rock containing 35.04% Illite, 25.64% Illite plus Quartz, 22.20% Kaolinite and 17.09% Feldspar. This was corroborated by cation determination that showed the rock to be predominantly clayey rock. The mean concentrations of lead and copper in water of the wells in the rock location are 0.004mg/L and 0.05mg/L respectively while cadmium is less than detectable limit. The well water in the area studied is therefore not contaminated by these heavy metals. Heavy metals removal by the mixed clay from polluted underground water was studied using AAS. A general increase of sorption was observed with increase in the adsorbent dosage. 20g of the rock adsorbed a higher percentage of copper (80.23%) than lead and cadmium that were 70.25% and 65.83% respectively. The percentage of heavy metals adsorbed confirms the use of mixed clay minerals as a contaminants removal from the underground polluted water. The rock adsorbed copper readily than cadmium and lead. The maximum amount of lead removed from the contaminated underground water of the defunct battery site across the adsorbent dosage (5g, 10g, 15g and 20g) were 1.20mg/L, 3.19mg/L, 3.69mg/L and 4.09mg/L respectively indicating the effect of increase in adsorbent dosage in remediating the lead contaminated water. This data showed that the rock can be used to remove these heavy metals from contaminated water.

scholarly journals The immobilisation of heavy metals from sewage sludge ash in geopolymer mortars

2020 ◽  
Vol 322 ◽  
pp. 01026
Author(s):  
Mateusz Sitarz ◽  
Tomasz Zdeb ◽  
João Castro Gomes ◽  
Erick Grünhäuser Soares ◽  
Izabela Hager
Keyword(s):  
Heavy Metals ◽  
Sewage Sludge ◽  
Municipal Wastewater ◽  
Sewage Treatment ◽  
Sewage Treatment Plant ◽  
Treatment Plant ◽  
Fluidised Bed ◽  
The European Union ◽  
Sewage Sludge Ash ◽  
Sludge Ash

Sewage sludge is a semi-solid waste material created as a result of the sewage treatment of industrial or municipal wastewater. Because the laws and regulations of the European Union require not only a reduction in waste generation but also the preparation of waste for reuse and disposal, it is necessary to look for new methods of the application of sewage sludge as part of sustainable waste management. In this study, ash formed as a result of the combustion of sewage sludge from the sewage treatment plant in Płaszów, Krakow in a fluidised bed furnace at a temperature of around 800°C was used. Sewage sludge ash (SSA) contains over 30% SiO2 and approx. 10% Al2O3, which indicates potential applications in geopolymer materials. In this study, samples of geopolymer mortars with a binder containing sewage sludge ash as well as fly ash (FA) and ground granulated blast furnace slag (GGBFS) were prepared. The mechanical parameters were determined after 2, 7, 14, and 28 days. The results show that the sewage sludge ash-based geopolymer shows binding properties at ambient temperature and, depending on the presence of FA and/or GGBFS, the compressive strength varies from 5 to 45 MPa after 28 days. The aim of the research was also to determine the total content of heavy metals (Sb, As, Cr, Cd, Cu, Ni, Pb, Hg, Zn) in the raw materials used and their leachability from the structure of the hardened materials. Immobilisation of heavy metals is very promising. Based on the results of tests, it seems possible to use SSA in geopolymer materials, but not as the main component of the binder.

scholarly journals From laboratory experiment to large scale application: case studies of the phytoremediation of chemical agents of agents of the sludge fields at Kharkiv wastewater treatment plant, Ukraine

2007 ◽  
pp. 227-237
Author(s):  
Nataliia Suchkova ◽  
Yuri Vergeles
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Wastewater Treatment ◽  
Sewage Sludge ◽  
Large Scale ◽  
Municipal Wastewater ◽  
Treatment Plant ◽  
Heavy Metal Accumulation ◽  
Municipal Wastewater Treatment ◽  
In Situ Experiments

The contamination of the sewage sludge fields of municipal wastewater treatment plants (WWTPs) by heavy metals, hydrocarbons or other pollutants is a major environmental problem. Sludge can retain up to 96% of all the metals entering the WWTPs in sewage, therefore, when it is disposed to land, heavy metals will be accumulated in the soil. Effects of heavy metal accumulation are long lasting and even permanent. Phytotoxicity is the main problem, although metals can be transferred directly to man via vegetables and other crops or indirectly via animals, primarily cattle, eating herbage (zootoxic). The common metals in sludge are Zn, Cu, Ni, Pb, Cr, and Cd which are generally the most toxic metal found in high concentration.Conventional treatment techniques of contaminated territory suffer from serious shortcomings which limit their applicability and efficiency. These include high cost and maintenance requirements, the need to transfer the contamination from one medium to another, and the extended duration of the operation. Alternatives to these treatments lie in in­situ phytoremediation. Plants are among the most tolerant organisms to pollution, which emphasizes their utility for the detoxification or degradation of pollutants. The concept of phytoremediation was inspired by the discovery of hyper-accumulators, most of which belong to the botanical families Brassicaceae, Poaceae, Papilionaceae, Caryophyllaceae, and Asteraceae, which provide most of the candidates for heavy metal phytoremediation. Two other families are important - the Salicaceae with the genera Salix and Populus, which are effective against a range of pollutants; and the Betaceae which contribute species effective against salt ions and small (few rings) polycyclic aromatic hydrocarbons (PAHs). Some Asteraceae species have been shown to be good phytoremediants of radionuclide pollution [ I ].This paper summarizes the results obtained from laboratory, as well as from in-situ experiments (sludge fields at Kharkiv's WWTP, total area is approx. 126 ha) which focused on phytoremediation methodologies for the removal of heavy metals from sewage sludge.

scholarly journals SPECIFIC FEATURES OF DISTRIBUTION OF MINERALS IN ORGANS AND TISSUES OF HERRING SPECIES (CLUPEIDAE) IN CASPIAN SEA

2021 ◽  
Vol 2021 (1) ◽  
pp. 100-106
Author(s):  
Tatiana Ershova ◽  
Vyacheslav Fedorovich Zaitsev ◽  
Vladimir Chaplygin ◽  
Asylbek Shakhmuratovich Kanbetov
Keyword(s):  
Heavy Metals ◽  
Caspian Sea ◽  
Chemical Elements ◽  
Electrothermal Atomization ◽  
The Caspian Sea ◽  
Lead And Cadmium ◽  
Zinc Cadmium ◽  
Definition Of ◽  
Cadmium And Lead ◽  
Standard Techniques

Research objective was to identify the specific features of distribution of microelements (zink, manganese, lead, cadmium) in organs and tissues of black-backed shad Alosa kessleri kessleri (Grimm, 1887) and Dolginsky herring Alosa braschnikowii braschnikowii (Borodin, 1904) caught in the Caspian Sea. Accumulated in the tissues and organs of fish in concentrations exceeding the maximum permissible limits, heavy metals pose a danger to human health. Sampling was carried out by the standard techniques, definition of minerals was made by method of atomic and absorbing spectroscopy using an atomic and absorbing spectrometer with electrothermal atomization of MGA-915 MD. The analysis of the obtained data showed that distribution of minerals in the organs and tissues of the studied herring species had a similar pattern: the highest concentrations of minerals were registered in the gills and liver, the smallest - in muscle tissue. In comparison with black-backed shad the organs and tissues of Dolginsky herring had higher concentrations of chemical elements. Zinc has been found to accumulate mainly in the liver; manganese, lead and cadmium - in the gills. Accumulation of zinc, cadmium and lead in the studied bodies and tissues of fishes exceeded acceptable level.

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