Thermal Processing of Materials: From Basic Research to Engineering

Author(s):  
Yogesh Jaluria

This paper reviews the active and growing field of thermal processing of materials, with a particular emphasis on the linking of basic research with engineering aspects. In order to meet the challenges posed by new applications arising in electronics, telecommunications, aerospace, transportation, and other areas, extensive work has been done on the development of new materials and processing techniques in recent years. Among the materials that have seen intense interest and research activity over the last two decades are semiconductor and optical materials, composites, ceramics, biomaterials, advanced polymers, and specialized alloys. New processing techniques have been developed to improve product quality, reduce cost, and control material properties. However, it is necessary to couple research efforts directed at the fundamental mechanisms that govern materials processing with engineering issues that arise in the process, such as system design, control and optimization, process feasibility and selection of operating conditions to achieve desired product characteristics. Many traditional and emerging materials processing applications involve thermal transport, which plays a critical role in the determination of the quality and characteristics of the final product and in the operation, control, and design of the system. This review is directed at the heat and mass transfer phenomena underlying a wide variety of materials processing operations, such as optical fiber manufacture, crystal growth for semiconductor fabrication, casting, thin film manufacture, and polymer processing, and at the engineering aspects that arise in actual practical systems. The review outlines the basic and applied considerations in thermal materials processing, available solution techniques, and the effect of the transport on the process, the product and the system. The complexities that are inherent in materials processing, such as large material property changes, complicated and multiple regions, combined heat and mass transfer mechanisms, and complex boundary conditions are discussed. The governing equations and boundary conditions for typical processes, along with important parameters, common simplifications and specialized methods employed to study these processes are outlined. The field of thermal materials processing is quite extensive and only a few important techniques employed for materials processing are considered in detail. Among the processes discussed here are polymer extrusion, optical fiber drawing, casting, continuous processing, and chemical vapor deposition for the fabrication of thin films. The effect of heat and mass transfer on the final product, the nature of the basic problems involved, solution strategies, and engineering issues involved in the area are brought out. The current status and future trends are discussed, along with critical research needs in the area. The coupling between the research on the basic aspects of materials processing and the engineering concerns involved with practical processes and systems is discussed in detail.

2003 ◽  
Vol 125 (6) ◽  
pp. 957-979 ◽  
Author(s):  
Yogesh Jaluria

This paper reviews the active and growing field of thermal processing of materials, with a particular emphasis on the linking of basic research with engineering aspects. In order to meet the challenges posed by new applications arising in electronics, telecommunications, aerospace, transportation, and other areas, extensive work has been done on the development of new materials and processing techniques in recent years. Among the materials that have seen intense interest and research activity over the last two decades are semiconductor and optical materials, composites, ceramics, biomaterials, advanced polymers, and specialized alloys. New processing techniques have been developed to improve product quality, reduce cost, and control material properties. However, it is necessary to couple research efforts directed at the fundamental mechanisms that govern materials processing with engineering issues that arise in the process, such as system design and optimization, process feasibility, and selection of operating conditions to achieve desired product characteristics. Many traditional and emerging materials processing applications involve thermal transport, which plays a critical role in the determination of the quality and characteristics of the final product and in the operation, control, and design of the system. This review is directed at the heat and mass transfer phenomena underlying a wide variety of materials processing operations, such as optical fiber manufacture, casting, thin film manufacture, and polymer processing, and at the engineering aspects that arise in actual practical systems. The review outlines the basic and applied considerations in thermal materials processing, available solution techniques, and the effect of the transport on the process, the product and the system. The complexities that are inherent in materials processing, such as large material property changes, complicated and multiple regions, combined heat and mass transfer mechanisms, and complex boundary conditions, are discussed. The governing equations for typical processes, along with important parameters, common simplifications and specialized methods employed to study these processes are outlined. The field of thermal materials processing is quite extensive and only a few important techniques employed for materials processing are considered in detail. The effect of heat and mass transfer on the final product, the nature of the basic problems involved, solution strategies, and engineering issues involved in the area are brought out. The current status and future trends are discussed, along with critical research needs in the area. The coupling between the research on the basic aspects of materials processing and the engineering concerns in practical processes and systems is discussed in detail.


2000 ◽  
Vol 123 (2) ◽  
pp. 173-210 ◽  
Author(s):  
Yogesh Jaluria

There has been an explosive growth in the development of new materials and processing techniques in recent years to meet the challenges posed by new applications arising in electronics, telecommunications, aerospace, transportation, and other new and traditional areas. Semiconductor and optical materials, composites, ceramics, biomaterials, advanced polymers, and specialized alloys are some of the materials that have seen intense interest and research activity over the last two decades. New approaches have been developed to improve product quality, reduce cost, and achieve essentially custom-made material properties. Current trends indicate continued research effort in materials processing as demand for specialized materials continues to increase. Fluid flow that arises in many materials processing applications is critical in the determination of the quality and characteristics of the final product and in the control, operation, and optimization of the system. This review is focused on the fluid flow phenomena underlying a wide variety of materials processing operations such as optical fiber manufacture, crystal growth for semiconductor fabrication, casting, thin film manufacture, and polymer processing. The review outlines the main aspects that must be considered in materials processing, the basic considerations that are common across fluid flow phenomena involved in different areas, the present state of the art in analytical, experimental and numerical techniques that may be employed to study the flow, and the effect of fluid flow on the process and the product. The main issues that distinguish flow in materials processing from that in other fields, as well as the similar aspects, are outlined. The complexities that are inherent in materials processing, such as large material property changes, complicated domains, multiple regions, combined mechanisms, and complex boundary conditions are discussed. The governing equations and boundary conditions for typical processes, along with important parameters, common simplifications and specialized methods employed to study these processes are outlined. The field is vast and it is not possible to consider all the different techniques employed for materials processing. Among the processes discussed in some detail are polymer extrusion, optical fiber drawing, casting, continuous processing, and chemical vapor deposition for the fabrication of thin films. Besides indicating the effect of fluid flow on the final product, these results illustrate the nature of the basic problems, solution strategies, and issues involved in the area. The review also discusses present trends in materials processing and suggests future research needs. Of particular importance are well-controlled and well-designed experiments that would provide inputs for model validation and for increased understanding of the underlying fluid flow mechanisms. Also, accurate material property data are very much needed to obtain accurate and repeatable results that can form the basis for design and optimization. There is need for the development of innovative numerical and experimental approaches to study the complex flows that commonly arise in materials processing. Materials processing techniques that are in particular need of further detailed work are listed. Finally, it is stessed that it is critical to understand the basic mechanisms that determine changes in the material, in addition to the fluid flow aspects, in order to impact on the overall field of materials processing.


Author(s):  
Joonguen Park ◽  
Shinku Lee ◽  
Sunyoung Kim ◽  
Joongmyeon Bae

This paper discusses a numerical analysis of the heat and mass transfer characteristics in an autothermal methane reformer. Assuming local thermal equilibrium between the bulk gas and the surface of the catalyst, a one-medium approach for the porous medium analysis was incorporated. Also, the mass transfer between the bulk gas and the catalyst’s surface was neglected due to the relatively low gas velocity. For the catalytic surface reaction, the Langmuir–Hinshelwood model was incorporated in which methane (CH4) is reformed to hydrogen-rich gases by the autothermal reforming (ATR) reaction. Full combustion, steam reforming, water-gas shift, and direct steam reforming reactions were included in the chemical reaction model. Mass, momentum, energy, and species balance equations were simultaneously calculated with the chemical reactions for the multiphysics analysis. By varying the four operating conditions (inlet temperature, oxygen to carbon ratio (OCR), steam to carbon ratio, and gas hourly space velocity (GHSV)), the performance of the ATR reactor was estimated by the numerical calculations. The SR reaction rate was improved by an increased inlet temperature. The reforming efficiency and the fuel conversion reached their maximum values at an OCR of 0.7. When the GHSV was increased, the reforming efficiency increased but the large pressure drop may decrease the system efficiency. From these results, we can estimate the optimal operating conditions for the production of large amounts of hydrogen from methane.


Author(s):  
Виктор Григорьевич Чеверев ◽  
Евгений Викторович Сафронов ◽  
Алексей Александрович Коротков ◽  
Александр Сергеевич Чернятин

Существуют два основных подхода решения задачи тепломассопереноса при численном моделировании промерзания грунтов: 1) решение методом конечных разностей с учетом граничных условий (границей, например, является фронт промерзания); 2) решение методом конечных элементов без учета границ модели. Оба подхода имеют существенные недостатки, что оставляет проблему решения задачи для численной модели промерзания грунтов острой и актуальной. В данной работе представлена физическая постановка промерзания, которая позволяет создать численную модель, базирующуюся на решении методом конечных элементов, но при этом отражающую ход фронта промерзания - то есть модель, в которой объединены оба подхода к решению задачи промерзания грунтов. Для подтверждения корректности модели был проделан ряд экспериментов по физическому моделированию промерзания модельного грунта и выполнен сравнительный анализ полученных экспериментальных данных и результатов расчетов на базе представленной численной модели с такими же граничными условиями, как в экспериментах. There are two basic approaches to solving the problem of heat and mass transfer in the numerical modeling of soil freezing: 1) using the finite difference method taking into account boundary conditions (the boundary, for example, is the freezing front); 2) using the finite element method without consideration of model boundaries. Both approaches have significant drawbacks, which leaves the issue of solving the problem for the numerical model of soil freezing acute and up-to-date. This article provides the physical setting of freezing that allows us to create a numerical model based on the solution by the finite element method, but at the same time reflecting the route of the freezing front, i.e. the model that combines both approaches to solving the problem of soil freezing. In order to confirm the correctness of the model, a number of experiments on physical modeling of model soil freezing have been performed, and a comparative analysis of the experimental data obtained and the calculation results based on the provided numerical model with the same boundary conditions as in the experiments was performed.


Author(s):  
Juan Yin ◽  
Yi-wu Weng

This paper investigated performance characteristics analysis of catalytic combustion by utilizing 1-D models incorporated heat and mass transfer correlations. The 1-D numerical results were compared with 2-D models studies and experimental data. The performance characteristics were mainly the effects of operating conditions on methane conversion rate. The comparable analysis confirmed that 1-D model can success in predicting performance of catalytic combustion when empiric inter-phase heat and mass transfer correlations are used and appropriate operating conditions are chosen.


2006 ◽  
Vol 128 (11) ◽  
pp. 1142-1148 ◽  
Author(s):  
Chengqin Ren

Quick and accurate analysis of cooling tower performance, outlet conditions of moist air, and parameter profiles along the tower height is very important in rating and design calculations. This paper developed an analytical model for the coupled heat and mass transfer processes in counterflow cooling towers based on operating conditions more realistic than most conventionally adopted Merkel approximations. In modeling, values of the Lewis factor were not necessarily specified as unity. Effects of water loss by evaporation and water film heat transfer resistance were also considered in the model equations. Within a relatively narrow range of operating conditions, the humidity ratio of air in equilibrium with the water surface was assumed to be a linear function of the surface temperature. The differential equations were rearranged and an analytical solution was developed for newly defined parameters. The analytical model predicts the tower performances, outlet conditions, and parameter profiles quickly and accurately when comparing with the numerical integration of the original differential equations.


2007 ◽  
Vol 70 (3) ◽  
pp. 607-615 ◽  
Author(s):  
ABANI K. PRADHAN ◽  
YANBIN LI ◽  
JOHN A. MARCY ◽  
MICHAEL G. JOHNSON ◽  
MARK L. TAMPLIN

The increasing demand of ready-to-eat poultry products has led to serious concerns over product safety, and more emphasis has been placed on thorough cooking of products. In this study, processing conditions and thermal inactivation of Listeria innocua in chicken breast meats were evaluated during convection cooking in a pilot-plant scale air-steam impingement oven. A predictive model was developed by integrating heat and mass transfer models with a pathogen kinetics model to predict temperature, water content, product yield, and bacterial inactivation during air-steam impingement cooking. Skinless boneless chicken breasts were cooked at oven air temperatures of 177 and 200°C for 2 to 10 min at a humidity of 70 to 75% (moisture by volume) and an air velocity of 1 m/s at the exit of the nozzles. The reduction in Listeria in chicken breasts after 2 to 5 min of cooking was from 0.3 to 1.4 log CFU/g and from 0.8 to 1.8 log CFU/g at 177 and 200°C, respectively. After cooking for 10 min at both temperatures, no survivors were detected in any of the cooked chicken breasts from an initial bacterial concentration of 106 CFU/g. The standard errors of prediction for the endpoint center temperatures after 2 to 10 min of cooking were 2.8 and 3.0°C for air temperatures of 177 and 200°C, respectively. At 177 and 200°C, the median relative errors of prediction for water content were 2.5 and 3.7% and those for product yield were 5.4 and 8.4%, respectively. The developed model can be used as a tool to assist in evaluating thermal processing schedules for poultry products cooked in an air-steam impingement oven.


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