Rheometric Studies of Functional Polyurethane Foam Composite

Author(s):  
Sayavur I. Bakhtiyarov ◽  
Jimmie C. Oxley ◽  
James L. Smith ◽  
Philipp M. Baldovi ◽  
Dennis A. Siginer

A rheometric characterization of the functional Polyurethane (PU) foam composite with and without solid additives (aluminum flakes) were experimentally measured using a computer controlled mechanical spectrometer (rheometer) ARES-G2. It is determined that PU composite exhibits a strong time thickening and shear thinning behavior. The rheological behavior of this composite can be described with the power-law generalized non-Newtonian fluid model. The rheometric tests showed that the PU/Al mixture exhibits thermal thickening and shear thinning behavior with the yield stress. The system can be described with the power-law generalized non-Newtonian fluid (Ostwald-de-Waele) model. The effective viscosity of PU composite increases with both the testing time (exponentially) and the solid content (polynomial) in the mixture.

2017 ◽  
Vol 50 (3) ◽  
pp. 222-240
Author(s):  
Sayavur I Bakhtiyarov ◽  
Jimmie C Oxley ◽  
James L Smith ◽  
Philipp M Baldovi

The rheological dynamic characteristics of the functional Polyurethane composite as well as its compounds ( triethanolamine (TEOA) and toluene-2,4-diisocyanate (TDI)) with and without solid additives (aluminum flakes) were experimentally measured using a computer-controlled mechanical spectrometer (rheometer) ARES-G2. Rheological studies showed that both components behave as viscous Newtonian fluids. TEOA exhibits a strong temperature-thickening behavior. TEOA with aluminum flake additives behaves as a viscous Newtonian fluid. The effective viscosity of the two-phase mixture increases with the concentration of the aluminum additive and decreases with the temperature rise. The rheometric tests showed that the effective viscosity of the TDI/Al mixture increases with the aluminum content. The mixture exhibits thermal-thickening and shear-thinning behaviors with the yield stress. The system can be described with the Bingham plastic model. It is determined that TEOA/TDI composite exhibits a strong time-thickening and shear-thinning behaviors. The rheological behavior of this composite can be described with the power-law generalized non-Newtonian fluid model. The effective viscosity of TEOA/TDI/Al composite increases with both the testing time (exponentially) and the aluminum content (polynomial) in the mixture. However, these shear-thinning composites obey the power-law generalized non-Newtonian fluid model, and their flow curves can be described by the logarithmic law.


2017 ◽  
Vol 50 (4) ◽  
pp. 312-324
Author(s):  
Jimmie C Oxley ◽  
James L Smith ◽  
Sayavur I Bakhtiyarov ◽  
Philipp M Baldovi

The rheological dynamic characteristics of the functional polyurethane foam composite with solid additives (calcium iodate particles, aluminum flakes) were experimentally measured using an oscillatory rotational rheometer ARES-G2. Our previous studies demonstrated that the presence of the gas bubbles alters the rheology of the continuous liquid phase. The experimental tests results show that the apparent viscosity (the shear stress applied to a fluid divided by the shear rate) of the two-phase mixture increases with the concentration of the aluminum additive and decreases with the temperature rise. The rheological measurements showed that the functional foam exhibits a strong time-dependent and thixotropic (shear thinning) behavior. The rheological behavior of this composite can be described with the power law–generalized non-Newtonian fluid model. The apparent viscosity of the polyurethane increases with both the testing time (exponentially) and the solid content (polynomial) in the mixture. The measured rheological characteristics of the polyurethane-based functional foam will be helpful for material designers and developers.


Author(s):  
Robert Brewster

Abstract A friction factor correlation for laminar, hydrodynamically fully-developed pipe flows of shear-thinning non-Newtonian fluids is derived through analysis and asymptotic considerations. The specific non-Newtonian fluid model used is the Extended Modified Power Law (EMPL) model, which is functionally equivalent to the Cross model. The EMPL model spans the entire shear rate range from the low to the high shear rate Newtonian regions, and includes the intermediate shear rate power law region. The friction factor correlation has an explicit form and is a function of three dimensionless parameters, making it well-suited to design calculations. The overall accuracy of the correlation is 6.6%, though it is much better in most cases. Graphical results for the correlation, and deviations with respect to high-accuracy numerical calculations are presented and discussed.


2017 ◽  
Vol 826 ◽  
pp. 918-941 ◽  
Author(s):  
A. Bougouin ◽  
L. Lacaze ◽  
T. Bonometti

Experiments on the collapse of non-colloidal and neutrally buoyant particles suspended in a Newtonian fluid column are presented, in which the initial volume fraction of the suspension $\unicode[STIX]{x1D719}$, the viscosity of the interstitial fluid $\unicode[STIX]{x1D707}_{f}$, the diameter of the particles $d$ and the mixing protocol, i.e. the initial preparation of the suspension, are varied. The temporal evolution of the slumping current highlights two main regimes: (i) an inertial-dominated regime followed by (ii) a viscous-dominated regime. The inertial regime is characterized by a constant-speed slumping which is shown to scale as in the case of a classical inertial dam-break. The viscous-dominated regime is observed as a decreasing-speed phase of the front evolution. Lubrication models for Newtonian and power-law fluids describe most of situations encountered in this regime, which strongly depends on the suspension parameters. The temporal evolution of the propagating front is used to extract the rheological parameters of the fluid models. At the early stages of the viscous-dominated regime, a constant effective shear viscosity, referred to as an apparent Newtonian viscous regime, is found to depend only on $\unicode[STIX]{x1D719}$ and $\unicode[STIX]{x1D707}_{f}$ for each mixing protocol. The obtained values are shown to be well fitted by the Krieger–Dougherty model whose parameters involved, say a critical volume fraction $\unicode[STIX]{x1D719}_{m}$ and the exponent of divergence, depend on the mixing protocol, i.e. the microscale interaction between particles. On a longer time scale which depends on $\unicode[STIX]{x1D719}$, the front evolution is shown to slightly deviate from the apparent Newtonian model. In this apparent non-Newtonian viscous regime, the power-law model, indicating both shear-thinning and shear-thickening behaviours, is shown to be more appropriate to describe the front evolution. The present experiments indicate that the mixing protocol plays a crucial role in the selection of a shear-thinning or shear-thickening type of collapse, while the particle diameter $d$ and volume fraction $\unicode[STIX]{x1D719}$ play a significant role in the shear-thickening case. In all cases, the normalized effective consistency of the power-law fluid model is found to be a unique function of $\unicode[STIX]{x1D719}$. Finally, an apparent viscoplastic regime, characterized by a finite length spreading reached at finite time, is observed at high $\unicode[STIX]{x1D719}$. This regime is mostly observed for volume fractions larger than $\unicode[STIX]{x1D719}_{m}$ and up to a volume fraction $\unicode[STIX]{x1D719}_{M}$ close to the random close packing fraction at which the initial column remains undeformed on opening the gate.


Open Physics ◽  
2011 ◽  
Vol 9 (5) ◽  
Author(s):  
Kuppalapalle Vajravelu ◽  
Sreedharamalle Sreenadh ◽  
Palluru Devaki ◽  
Kerehalli Prasad

AbstractThe constitution of blood demands a yield stress fluid model, and among the available yield stress fluid models for blood flow, the Herschel-Bulkley model is preferred (because Bingham, Power-law and Newtonian models are its special cases). The Herschel-Bulkley fluid model has two parameters, namely the yield stress and the power law index. The expressions for velocity, plug flow velocity, wall shear stress, and the flux flow rate are derived. The flux is determined as a function of inlet, outlet and external pressures, yield stress, and the elastic property of the tube. Further when the power-law index n = 1 and the yield stress τ 0 → 0, our results agree well with those of Rubinow and Keller [J. Theor. Biol. 35, 299 (1972)]. Furthermore, it is observed that, the yield stress and the elastic parameters (t 1 and t 2) have strong effects on the flux of the non-Newtonian fluid flow in the elastic tube. The results obtained for the flow characteristics reveal many interesting behaviors that warrant further study on the non-Newtonian fluid flow phenomena, especially the shear-thinning phenomena. Shear thinning reduces the wall shear stress.


1997 ◽  
Vol 119 (4) ◽  
pp. 483-488 ◽  
Author(s):  
S. Usha ◽  
A. Ramachandra Rao

Peristaltic transport of two-layered power-law fluids in axisymmetric tubes is studied. Use of the power-law fluid model permits independent choice of shear thinning, shear thickening, or Newtonian fluids for the core and the peripheral layer. The interface between the two layers is determined from a transcendental equation in the core radius. The variation of the time-mean flow Q¯ with the pressure rise or drop over one wavelength Δp is studied. It is observed that a negative time-mean flow is achieved under free pumping (Δp = 0) for the wave forms considered here if one of the peripheral layer and core fluids is non-Newtonian. The rheology of the peripheral layer fluid is a dominant factor in producing a negative or positive mean flow. It is noticed that a sinusoidal wave always yields a positive mean flow for powerlaw fluids. The trapped bolus volume for sinusoidal peristaltic wave is observed to decrease with an increase in the rate of shear thinning of the core and the peripheral layer fluids.


2010 ◽  
Vol 65 (3) ◽  
pp. 151-160 ◽  
Author(s):  
Mehmet Pakdemirli ◽  
Pınar Sarı ◽  
Bekir Solmaz

The generalized hyperbolic non-Newtonian fluid model first proposed by Al-Zahrani [J. Petroleum Sci. Eng. 17, 211 (1997)] is considered. This model was successfully applied to some drilling fluids with a better performance in relating shear stress and velocity gradient compared to power-law and the Hershel-Bulkley model. Special flow geometries namely pipe flow, parallel plate flow, and flow between two rotating cylinders are treated. For the first two cases, analytical solutions of velocity profiles and discharges in the form of integrals are presented. These quantities are calculated by numerically evaluating the integrals. For the flow between two rotating cylinders, the differential equation is solved by the Runge-Kutta method combined with shooting. For all problems, the power-law approximation of the model is compared with the generalized hyperbolic model, too.


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