Thermodynamic Analysis of Titanium Dioxide Nanotube Synthesis Process for Sustainability Improvement

Author(s):  
Bingbing Li ◽  
Hong-Chao Zhang ◽  
Chris Yuan

Sustainability of nanomanufacturing has triggered tremendous research interest in recent years, especially the energy consumption and environmental impacts of nanomaterial. TiO2 nanotube is a typical material with broad application potential. In this paper a thermodynamic analysis model integrating the energy consumption and exergy losses is presented for sustainability improvement of TiO2 nanotube synthesis process. This thermodynamic model was validated by the TiO2 nanotube electrochemical anodization process. Comparisons of energy consumption, exergy losses and environmental impacts of five main stages showed the effective sustainability improvement potential. This work can be extended to sustainability improvement of other similar nanomaterial synthesis processes.

2020 ◽  
Vol 993 ◽  
pp. 1456-1464
Author(s):  
Yu Long Jiao ◽  
Feng Gao ◽  
Jun Xie

The nickel cobalt manganese ternary (NCM) cathode material is one of the important parts of power lithium battery. The NCM cathode material production process including the Li2CO3 preparation, precursor preparation and synthesis process of cathode materials is resource-and energy- intensive, thus it leads to relatively severe environment pollution. In this article, life cycle assessment of NCM cathode material production using coprecipitation method in China was conducted based on ReCiPe method. The environmental impacts of the main processes were calculated. The main factors and sources causing environmental pressure were identified. The results indicated that the precursor production contributed the most to environmental impacts in the NCM cathode material production. The energy consumption of the precursor production was 612MJ, accounting for 94.6% of the total energy consumption of NCM production. The environmental impacts of the CoSO4 production and NiSO4 production were the main contributors to that of the precursor production. The primary cobalt and nickel resources in China with lower grade and difficult mining led to the high energy consumption of these two kinds of raw materials. Therefore, the development and utilization of the secondary cobalt and nickel metals will be a great potential to reduce environmental impacts of NCM production.


2020 ◽  
Vol 5 (1) ◽  
pp. 563-572
Author(s):  
Iman Golpour ◽  
Mohammad Kaveh ◽  
Reza Amiri Chayjan ◽  
Raquel P. F. Guiné

AbstractThis research work focused on the evaluation of energy and exergy in the convective drying of potato slices. Experiments were conducted at four air temperatures (40, 50, 60 and 70°C) and three air velocities (0.5, 1.0 and 1.5 m/s) in a convective dryer, with circulating heated air. Freshly harvested potatoes with initial moisture content (MC) of 79.9% wet basis were used in this research. The influence of temperature and air velocity was investigated in terms of energy and exergy (energy utilization [EU], energy utilization ratio [EUR], exergy losses and exergy efficiency). The calculations for energy and exergy were based on the first and second laws of thermodynamics. Results indicated that EU, EUR and exergy losses decreased along drying time, while exergy efficiency increased. The specific energy consumption (SEC) varied from 1.94 × 105 to 3.14 × 105 kJ/kg. The exergy loss varied in the range of 0.006 to 0.036 kJ/s and the maximum exergy efficiency obtained was 85.85% at 70°C and 0.5 m/s, while minimum exergy efficiency was 57.07% at 40°C and 1.5 m/s. Moreover, the values of exergetic improvement potential (IP) rate changed between 0.0016 and 0.0046 kJ/s and the highest value occurred for drying at 70°C and 1.5 m/s, whereas the lowest value was for 70°C and 0.5 m/s. As a result, this knowledge will allow the optimization of convective dryers, when operating for the drying of this food product or others, as well as choosing the most appropriate operating conditions that cause the reduction of energy consumption, irreversibilities and losses in the industrial convective drying processes.


Materials ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 510
Author(s):  
Wangzhu Cao ◽  
Kunfeng Chen ◽  
Dongfeng Xue

Nanoscale engineering of regular structured materials is immensely demanded in various scientific areas. In this work, vertically oriented TiO2 nanotube arrays were grown by self-organizing electrochemical anodization. The effects of different fluoride ion concentrations (0.2 and 0.5 wt% NH4F) and different anodization times (2, 5, 10 and 20 h) on the morphology of nanotubes were systematically studied in an organic electrolyte (glycol). The growth mechanisms of amorphous and anatase TiO2 nanotubes were also studied. Under optimized conditions, we obtained TiO2 nanotubes with tube diameters of 70–160 nm and tube lengths of 6.5–45 μm. Serving as free-standing and binder-free electrodes, the kinetic, capacity, and stability performances of TiO2 nanotubes were tested as lithium-ion battery anodes. This work provides a facile strategy for constructing self-organized materials with optimized functionalities for applications.


2011 ◽  
Vol 80-81 ◽  
pp. 714-718
Author(s):  
Yun Kai Gao ◽  
Da Wei Gao

The seal deformation of automotive door is caused by the door compression forces, including non-linear elastic force and non-linear damping force. The working principles of them are analyzed and a new simplified analysis model is built. Based on the Bernoulli equation and the law of conservation of mass, the mathematical models are established to calculate energy consumption of the seal system. According to the analysis results, the energy consumption of non-linear elastic force and non-linear damping force are respectively 84% and 16% of the total energy consumption of the seal system. At last, the calculation data is compared with the test data and the error is less than 5%, so the calculation method proposed in this paper is observed to be accurate.


Nanomaterials ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 2924
Author(s):  
Suriyakumar Dasarathan ◽  
Mukarram Ali ◽  
Tai-Jong Jung ◽  
Junghwan Sung ◽  
Yoon-Cheol Ha ◽  
...  

Vertically aligned Fe, S, and Fe-S doped anatase TiO2 nanotube arrays are prepared by an electrochemical anodization process using an organic electrolyte in which lactic acid is added as an additive. In the electrolyte, highly ordered TiO2 nanotube layers with greater thickness of 12 μm, inner diameter of approx. 90 nm and outer diameter of approx. 170 nm are successfully obtained. Doping of Fe, S, and Fe-S via simple wet impregnation method substituted Ti and O sites with Fe and S, which leads to enhance the rate performance at high discharge C-rates. Discharge capacities of TiO2 tubes increased from 0.13 mAh cm−2(bare) to 0.28 mAh cm−2 for Fe-S doped TiO2 at 0.5 C after 100 cycles with exceptional capacity retention of 85 % after 100 cycles. Owing to the enhancement of thermodynamic and kinetic properties by doping of Fe-S, Li-diffusion increased resulting in remarkable discharge capacities of 0.27 mAh cm−2 and 0.16 mAh cm−2 at 10 C, and 30 C, respectively.


2021 ◽  
Vol 308 ◽  
pp. 01010
Author(s):  
Shen Yizhi ◽  
Wei Minrui ◽  
Hou Bowen

Due to the accelerated industrial and urbanization development, climate change, and increasing populations and life quality expectations, the issue of drinking water shortage has raised much public awareness. The desalination system has been widely applied to accommodate the growing demand for clean water resources despite the continuous concerns about its relatively higher energy consumption and environmental footprints. This research conducted a case study in the Tampa Bay Regional Surface Water Treatment Plant and Tampa Bay Seawater Desalination Plant in Florida, U.S. It analysed the performance and environmental impacts of conventional and desalination water supply systems on three sides: energy consumption, carbon footprint, and solid waste. Potential negative effects of both water supply systems are generally associated with surface water ecology, groundwater aquifers, coastal environment, and marine organisms. Various environmental impact mitigation plans have been proposed to prevent or restore the detriments caused by carbon dioxide emissions, plant construction, and concentrated brine discharge. Due to the deficiency in freshwater resources, desalination technology is more promising through proper regulations and regional sustainable development.


2012 ◽  
Vol 538-541 ◽  
pp. 2015-2019
Author(s):  
Zhen Zhe Li ◽  
Xiao Ming Pan ◽  
Ming Ren ◽  
Mei Qin Li ◽  
Gui Ying Shen

With the heightened concern for energy consumption and environment conservation, the interest on fuel cell HEV (hybrid electric vehicle) has been greatly increased. In this study, a numerical model for the cooling system of batteries was constructed. Using the constructed analysis model, the material of the cartridge and the cartridge width were checked for improving the performance of the cooling system of batteries. The performance was changed by using different cartridge material, and the cartridge width also has an effect to the performance of the cooling system of batteries as shown in the analysis results. The constructed model and method can be used to investigate the performance of the cooling system of batteries.


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