The impact of lipid shell composition of perfluorocarbon nanodroplets on size distribution and acoustic droplet vaporization and cavitation dynamics

2021 ◽  
Vol 150 (4) ◽  
pp. A28-A28
Author(s):  
Phoebe J. Welch ◽  
Craig R. Forest ◽  
Chengzhi Shi
Keyword(s):  
Size Distribution ◽  
Acoustic Droplet Vaporization ◽  
Droplet Vaporization ◽  
Shell Composition ◽  
The Impact

scholarly journals Size-Dependent Thermo- and Photoresponsive Plasmonic Properties of Liquid Crystalline Gold Nanoparticles

Materials ◽  
2020 ◽  
Vol 13 (4) ◽  
pp. 875
Author(s):  
Aleksander Promiński ◽  
Ewelina Tomczyk ◽  
Mateusz Pawlak ◽  
Agnieszka Jędrych ◽  
Józef Mieczkowski ◽  
...  
Keyword(s):  
Size Distribution ◽  
Long Range ◽  
Self Assembly ◽  
Liquid Crystalline ◽  
High Yield ◽  
Condensed State ◽  
Organic Shell ◽  
Yield Production ◽  
Shell Composition ◽  
The Impact

Achieving remotely controlled, reversibly reconfigurable assemblies of plasmonic nanoparticles is a prerequisite for the development of future photonic technologies. Here, we obtained a series of gold-nanoparticle-based materials which exhibit long-range order, and which are controlled with light or thermal stimuli. The influence of the metallic core size and organic shell composition on the switchability is considered, with emphasis on achieving light-responsive behavior at room temperature and high yield production of nanoparticles. The latter translates to a wide size distribution of metallic cores but does not prevent their assembly into various, switchable 3D and 2D long-range ordered structures. These results provide clear guidelines as to the impact of size, size distribution, and organic shell composition on self-assembly, thus enhancing the smart design process of multi-responsive nanomaterials in a condensed state, hardly attainable by other self-assembly methods which usually require solvents.

scholarly journals Evaluating model parameterizations of submicron aerosol scattering and absorption with in situ data from ARCTAS 2008

2016 ◽  
Vol 16 (14) ◽  
pp. 9435-9455 ◽  
Author(s):  
Matthew J. Alvarado ◽  
Chantelle R. Lonsdale ◽  
Helen L. Macintyre ◽  
Huisheng Bian ◽  
Mian Chin ◽  
...  
Keyword(s):  
Optical Properties ◽  
Size Distribution ◽  
Aerosol Size Distribution ◽  
Visible Radiation ◽  
Submicron Aerosol ◽  
In Situ Data ◽  
Aerosol Absorption ◽  
Aerosol Scattering ◽  
The Impact

Abstract. Accurate modeling of the scattering and absorption of ultraviolet and visible radiation by aerosols is essential for accurate simulations of atmospheric chemistry and climate. Closure studies using in situ measurements of aerosol scattering and absorption can be used to evaluate and improve models of aerosol optical properties without interference from model errors in aerosol emissions, transport, chemistry, or deposition rates. Here we evaluate the ability of four externally mixed, fixed size distribution parameterizations used in global models to simulate submicron aerosol scattering and absorption at three wavelengths using in situ data gathered during the 2008 Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) campaign. The four models are the NASA Global Modeling Initiative (GMI) Combo model, GEOS-Chem v9-02, the baseline configuration of a version of GEOS-Chem with online radiative transfer calculations (called GC-RT), and the Optical Properties of Aerosol and Clouds (OPAC v3.1) package. We also use the ARCTAS data to perform the first evaluation of the ability of the Aerosol Simulation Program (ASP v2.1) to simulate submicron aerosol scattering and absorption when in situ data on the aerosol size distribution are used, and examine the impact of different mixing rules for black carbon (BC) on the results. We find that the GMI model tends to overestimate submicron scattering and absorption at shorter wavelengths by 10–23 %, and that GMI has smaller absolute mean biases for submicron absorption than OPAC v3.1, GEOS-Chem v9-02, or GC-RT. However, the changes to the density and refractive index of BC in GC-RT improve the simulation of submicron aerosol absorption at all wavelengths relative to GEOS-Chem v9-02. Adding a variable size distribution, as in ASP v2.1, improves model performance for scattering but not for absorption, likely due to the assumption in ASP v2.1 that BC is present at a constant mass fraction throughout the aerosol size distribution. Using a core-shell mixing rule in ASP overestimates aerosol absorption, especially for the fresh biomass burning aerosol measured in ARCTAS-B, suggesting the need for modeling the time-varying mixing states of aerosols in future versions of ASP.

scholarly journals Experimental-numerical studies of the effect of cell structure on the mechanical properties of polypropylene foams

e-Polymers ◽  
2020 ◽  
Vol 20 (1) ◽  
pp. 713-723
Author(s):  
Wei Gong ◽  
Tuan-Hui Jiang ◽  
Xiang-Bu Zeng ◽  
Li He ◽  
Chun Zhang
Keyword(s):  
Mechanical Properties ◽  
Size Distribution ◽  
Cell Size ◽  
Cell Structure ◽  
Structure Parameters ◽  
Cell Size Distribution ◽  
Numerical Studies ◽  
Polypropylene Foam ◽  
The Impact ◽  
The Relationship

AbstractThe effects of the cell size and distribution on the mechanical properties of polypropylene foam were simulated and analyzed by finite element modeling with ANSYS and supporting experiments. The results show that the reduced cell size and narrow size distribution have beneficial influences on both the tensile and impact strengths. Decreasing the cell size or narrowing the cell size distribution was more effective for increasing the impact strength than the tensile strength in the same case. The relationship between the mechanical properties and cell structure parameters has a good correlation with the theoretical model.

scholarly journals Impact of vehicular emissions on the formation of fine particles in the Sao Paulo Metropolitan Area: a numerical study with the WRF-Chem model

2016 ◽  
Vol 16 (2) ◽  
pp. 777-797 ◽  
Author(s):  
A Vara-Vela ◽  
M. F. Andrade ◽  
P. Kumar ◽  
R. Y. Ynoue ◽  
A. G. Muñoz
Keyword(s):  
Size Distribution ◽  
Metropolitan Area ◽  
Atmospheric Aerosols ◽  
Fine Particles ◽  
Sao Paulo ◽  
Vehicular Emissions ◽  
São Paulo ◽  
Mass Size Distribution ◽  
Mass Size ◽  
The Impact

Abstract. The objective of this work is to evaluate the impact of vehicular emissions on the formation of fine particles (PM2.5;  ≤  2.5 µm in diameter) in the Sao Paulo Metropolitan Area (SPMA) in Brazil, where ethanol is used intensively as a fuel in road vehicles. The Weather Research and Forecasting with Chemistry (WRF-Chem) model, which simulates feedbacks between meteorological variables and chemical species, is used as a photochemical modelling tool to describe the physico-chemical processes leading to the evolution of number and mass size distribution of particles through gas-to-particle conversion. A vehicular emission model based on statistical information of vehicular activity is applied to simulate vehicular emissions over the studied area. The simulation has been performed for a 1-month period (7 August–6 September 2012) to cover the availability of experimental data from the NUANCE-SPS (Narrowing the Uncertainties on Aerosol and Climate Changes in Sao Paulo State) project that aims to characterize emissions of atmospheric aerosols in the SPMA. The availability of experimental measurements of atmospheric aerosols and the application of the WRF-Chem model made it possible to represent some of the most important properties of fine particles in the SPMA such as the mass size distribution and chemical composition, besides allowing us to evaluate its formation potential through the gas-to-particle conversion processes. Results show that the emission of primary gases, mostly from vehicles, led to a production of secondary particles between 20 and 30 % in relation to the total mass concentration of PM2.5 in the downtown SPMA. Each of PM2.5 and primary natural aerosol (dust and sea salt) contributed with 40–50 % of the total PM10 (i.e. those  ≤  10 µm in diameter) concentration. Over 40 % of the formation of fine particles, by mass, was due to the emission of hydrocarbons, mainly aromatics. Furthermore, an increase in the number of small particles impaired the ultraviolet radiation and induced a decrease in ozone formation. The ground-level O3 concentration decreased by about 2 % when the aerosol-radiation feedback is taken into account.

Trapping patterns during capillary displacements in disordered media

2022 ◽  
Vol 933 ◽  
Author(s):  
Fanli Liu ◽  
Moran Wang
Keyword(s):  
Numerical Simulations ◽  
Pore Size Distribution ◽  
Pore Size ◽  
Size Distribution ◽  
Disordered Media ◽  
Pore Geometry ◽  
Control Parameters ◽  
Pore Throat ◽  
The Impact ◽  
Theoretical Analyses

We investigate the impact of wettability distribution, pore size distribution and pore geometry on the statistical behaviour of trapping in pore-throat networks during capillary displacement. Through theoretical analyses and numerical simulations, we propose and prove that the trapping patterns, defined as the percentage and distribution of trapped elements, are determined by four dimensionless control parameters. The range of all possible trapping patterns and how the patterns are dependent on the four parameters are obtained. The results help us to understand the impact of wettability and structure on trapping behaviour in disordered media.

Development of Model for Acoustic Noise Generated from Bedload in Rivers 

2021 ◽  
Author(s):  
Mohamad Nasr ◽  
Thomas Geay ◽  
Sébastien Zanker ◽  
Recking Alain
Keyword(s):  
Grain Size ◽  
Size Distribution ◽  
Impact Velocity ◽  
Acoustic Noise ◽  
Acoustic Power ◽  
Bedload Transport ◽  
Empirical Formulas ◽  
Impact Rate ◽  
Flux Measurements ◽  
The Impact

<p>Quantifying bedload transport is important for many applications such as river management and hydraulic structures protection. Bedload flux measurements can be achieved using physical sampler methods. However, these methods are expensive, time-consuming, and difficult to operate during high discharge events. Besides, these methods do not permit to capture the spatial and temporal variability of bedload transport flux. Recently, alternative measuring technologies have been developed to continuously monitor bedload flux and grain size distribution using passive or active sensors. Among them, the hydrophone was used to monitor bedload transport by recording the sounds generated by bedload particles colliding on the river bed (referred as self-generated noise SGN). The acoustic power of SGN was correlated with bedload flux in field experiments. To better understand these experimental results and to estimate measurement uncertainties, we developed a theoretical model to simulate the SGN. The model computes an estimation of the power spectral density (PSD)by considering the contribution of all signals generated by impacts between bedload particles and the riverbed, and accounting for the attenuation of the acoustic signal between the source and the hydrophone position due to river propagation effects,. In this model, we</p><p>The energy of acoustic noise generated from the collision between two particles is mainly dependent on the transported particles' diameter and the impact velocity. We tested different empirical formulas for the estimation of the number of impact (impact rate) and the impact velocity depending on particle size and hydraulic conditions. To characterize the acoustic power losses as a function of distance and frequency, we used an attenuation function which was experimentally calibrated for different French rivers.</p><p>We tested the model on a field dataset comprising acoustic and bedload flux measurements. The results indicate that the PSD model allows estimating acoustic power (in between a range of one order of magnitude) for most of the rivers considered.  The model sensitivity was evaluated. In particular, we observed that it is very sensitive to the empirical formulas used to determine the impact rate and impact speed. In addition, special attention should be kept in mind on the assumption of the grain size distribution of riverbed which can generate large variability in some rivers particularly in rivers with a significant sand fraction.</p>

Sign in / Sign up

Export Citation Format

Share Document