Bacterial and phytoplankton responses to nutrient and pH changes during short term in situ experiments in two acidified lakes

Andra, the French national radioactive waste management agency, is in charge of studying the possibility of disposal of High Level activity Wastes (HLW) in deep geological repositories. The concept of HLW cells consists of horizontal micro-tunnels of about 0.7 m in diameter, equipped with a steel casing. In order to ensure the reliability of the casing, particularly with respect to Stress Corrosion Cracking (SCC), several in-situ experiments dedicated to the analysis of its short term mechanical and corrosion behavior have been performed at Andra’s Underground Research Laboratory (URL) as well as in surface laboratory. Reduced and full scale in-situ experiments consisting of equipping boreholes parallel to the major horizontal stress (σH) with instrumented steel tubing, have been performed to analyze the mechanisms involved in the casing/rock interface. The main characteristics of the short term mechanical load applied by the rock have been determined from local strain and convergence measurements. Although in-situ stress is isotropic in the section of boreholes parallel to σH, measurements exhibit a strongly anisotropic load. SCC experiments conducted on different steel grades, in contact with the clay host rock containing CO2/H2 revealed that general corrosion is the main type of corrosion expected for steel casings. However, the selected steel casing must have a sufficiently high yield strength (above 400 MPa) to reduce the risk of early stage plasticity due to host rock anisotropic convergence and thus to overcome SCC. API5LX65 steel seems to meet both mechanical and corrosion requirements, therefore being likely the appropriate material for the manufacture of the casing.

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In situ micro-FTIR spectroscopic investigations of synthetic ammonium phengite under pressure and temperature

European Journal of Mineralogy ◽

10.5194/ejm-32-469-2020 ◽

2020 ◽

Vol 32 (5) ◽

pp. 469-482

Author(s):

Nada Abdel-Hak ◽

Bernd Wunder ◽

Ilias Efthimiopoulos ◽

Monika Koch-Müller

Keyword(s):

Ambient Temperature ◽

Ambient Pressure ◽

Local Symmetry ◽

Short Term ◽

Stability Range ◽

Piston Cylinder ◽

In Situ Experiments ◽

Diamond Anvil ◽

Kinetic Effects

Abstract. Phengite is known to be an important mineral in the transport of alkalis and water to upper mantle depths. Since ammonium (NH4+) can substitute for K+ in K-bearing minerals, phengite is thus a potential host to transport nitrogen into the mantle. However, the temperature and pressure conditions at which devolatilisation of NH4-bearing phengite occurs are not well constrained. In this study, NH4-phengite (NH4)(Mg0.5Al1.5)(Al0.5Si3.5)O10(OH)2 was synthesised in piston-cylinder experiments at 700 ∘C and 4.0 GPa. Its devolatilisation behaviour was studied by means of in situ micro-FTIR (Fourier transform infrared) spectroscopy under low and high temperatures from −180 up to 600 ∘C at ambient pressure using a Linkam cooling–heating stage and pressures up to 42 GPa at ambient temperature in diamond anvil cell (DAC) experiments. In addition to these short-term in situ experiments, we performed quenched experiments where the samples were annealed for 24 h at certain temperatures and analysed at room conditions by micro-FTIR spectroscopy. Our results can be summarised as follows: (1) an order–disorder process of the NH4+ molecule takes place with temperature variation at ambient pressure; (2) NH4+ is still retained in the phengite structure up to 600 ∘C, and the expansion of the NH4+ molecule with heating is reversible for short-term experiments; (3) kinetic effects partly control the destabilisation of NH4+ in phengite; (4) ammonium loss occurs at temperatures near dehydration; (5) NH4+ in phengite is apparently distorted above 8.6 GPa at ambient temperature; and (6) the local symmetry of the NH4+ molecule is lowered/descended/reduced by increasing pressure (P) or decreasing temperature (T), and the type and mechanism of this lowered symmetry is different in both cases. The current study confirms the wide stability range of phengite and its volatiles and thus has important implications for the recycling of nitrogen and hydrogen into the deep Earth. Moreover, it is considered as a first step in the crystallographic determination of the orientation of the NH4+ molecule in the phengite structure.

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Short-term effects of Ca(OH)2 additions on phytoplankton biomass: A comparison of laboratory and in situ experiments

Water Research ◽

10.1016/0043-1354(95)00273-1 ◽

1996 ◽

Vol 30 (5) ◽

pp. 1285-1294 ◽

Cited By ~ 16

Author(s):

Y. Zhang ◽

E.E. Prepas

Keyword(s):

Phytoplankton Biomass ◽

Short Term ◽

In Situ Experiments ◽

Short Term Effects

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An in situ and ex situ TEM study of the formation of thin cobalt silicide films by molecular beam epitaxy on the silicon (100) surface

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s042482010010648x ◽

1988 ◽

Vol 46 ◽

pp. 884-885

Author(s):

D. Loretto ◽

J. M. Gibson ◽

S. M. Yalisove ◽

R. T. Tung

Keyword(s):

Molecular Beam Epitaxy ◽

Molecular Beam ◽

Defect Density ◽

High Vacuum ◽

Ultra High Vacuum ◽

Ex Situ ◽

Metal Base ◽

In Situ Experiments ◽

Potential Applications

The cobalt disilicide/silicon system has potential applications as a metal-base and as a permeable-base transistor. Although thin, low defect density, films of CoSi2 on Si(111) have been successfully grown, there are reasons to believe that Si(100)/CoSi2 may be better suited to the transmission of electrons at the silicon/silicide interface than Si(111)/CoSi2. A TEM study of the formation of CoSi2 on Si(100) is therefore being conducted. We have previously reported TEM observations on Si(111)/CoSi2 grown both in situ, in an ultra high vacuum (UHV) TEM and ex situ, in a conventional Molecular Beam Epitaxy system.The procedures used for the MBE growth have been described elsewhere. In situ experiments were performed in a JEOL 200CX electron microscope, extensively modified to give a vacuum of better than 10-9 T in the specimen region and the capacity to do in situ sample heating and deposition. Cobalt was deposited onto clean Si(100) samples by thermal evaporation from cobalt-coated Ta filaments.

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Electron and ion irradiation-induced dissolution of mechanical twins in the intermetalic U3Si: An in situ HVEM study

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100155232 ◽

1989 ◽

Vol 47 ◽

pp. 652-653

Author(s):

Charles W. Allen ◽

Robert C. Birtcher

Keyword(s):

Elevated Temperatures ◽

Ion Irradiation ◽

Ion Beam ◽

National Laboratory ◽

Argonne National Laboratory ◽

Heavy Ion ◽

High Energy ◽

Mechanical Twinning ◽

In Situ Experiments

The uranium silicides, including U3Si, are under study as candidate low enrichment nuclear fuels. Ion beam simulations of the in-reactor behavior of such materials are performed because a similar damage structure can be produced in hours by energetic heavy ions which requires years in actual reactor tests. This contribution treats one aspect of the microstructural behavior of U3Si under high energy electron irradiation and low dose energetic heavy ion irradiation and is based on in situ experiments, performed at the HVEM-Tandem User Facility at Argonne National Laboratory. This Facility interfaces a 2 MV Tandem ion accelerator and a 0.6 MV ion implanter to a 1.2 MeV AEI high voltage electron microscope, which allows a wide variety of in situ ion beam experiments to be performed with simultaneous irradiation and electron microscopy or diffraction.At elevated temperatures, U3Si exhibits the ordered AuCu3 structure. On cooling below 1058 K, the intermetallic transforms, evidently martensitically, to a body-centered tetragonal structure (alternatively, the structure may be described as face-centered tetragonal, which would be fcc except for a 1 pet tetragonal distortion). Mechanical twinning accompanies the transformation; however, diferences between electron diffraction patterns from twinned and non-twinned martensite plates could not be distinguished.

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A computer-control program for TEM in situ fatigue experiments

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100155074 ◽

1989 ◽

Vol 47 ◽

pp. 620-621

Author(s):

Kenneth S. Vecchio ◽

John A. Hunt

Keyword(s):

Slow Crack Growth ◽

Computer Control ◽

Control Program ◽

Video Tape ◽

Computer Control System ◽

Transmission Electron ◽

In Situ Experiments ◽

Tremendous Amount ◽

And Control

In-situ experiments conducted within a transmission electron microscope provide the operator a unique opportunity to directly observe microstructural phenomena, such as phase transformations and dislocation-precipitate interactions, “as they happen”. However, in-situ experiments usually require a tremendous amount of experimental preparation beforehand, as well as, during the actual experiment. In most cases the researcher must operate and control several pieces of equipment simultaneously. For example, in in-situ deformation experiments, the researcher may have to not only operate the TEM, but also control the straining holder and possibly some recording system such as a video tape machine. When it comes to in-situ fatigue deformation, the experiments became even more complicated with having to control numerous loading cycles while following the slow crack growth. In this paper we will describe a new method for conducting in-situ fatigue experiments using a camputer-controlled tensile straining holder.The tensile straining holder used with computer-control system was manufactured by Philips for the Philips 300 series microscopes. It was necessary to modify the specimen stage area of this holder to work in the Philips 400 series microscopes because the distance between the optic axis and holder airlock is different than in the Philips 300 series microscopes. However, the program and interfacing can easily be modified to work with any goniometer type straining holder which uses a penrmanent magnet motor.

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Coliform transport in a pristine reservoir: modeling and field studies

Water Science & Technology ◽

10.2166/wst.1998.0124 ◽

1998 ◽

Vol 37 (2) ◽

pp. 137-144 ◽

Cited By ~ 11

Author(s):

Elisa Garvey ◽

John E. Tobiason ◽

Michael Hayes ◽

Evelyn Wolfram ◽

David A. Reckhow ◽

...

Keyword(s):

Model Development ◽

Fate And Transport ◽

Field Studies ◽

Meteorological Conditions ◽

Reservoir Modeling ◽

Vertical Circulation ◽

Quality Model ◽

Circulation Patterns ◽

In Situ Experiments

This paper reports on field studies and model development aimed at understanding coliform fate and transport in the Quabbin Reservoir, an oligotrophic drinking water supply reservoir. An investigation of reservoir currents suggested the importance of wind driven phenomena, and that both lateral and vertical circulation patterns exist. In-situ experiments of coliform decay suggested dependence on light intensity and yielded an appropriate decay coefficient to be used in CE-QUAL-W2, a two-dimensional hydrodynamic and water quality model. Modeling confirmed the sensitivity of reservoir outlet concentration to vertical variability within the reservoir, meteorological conditions, and location of coliform source.

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Upscaling THM modeling from small-scale to full-scale in-situ experiments in the Callovo-Oxfordian claystone

International Journal of Rock Mechanics and Mining Sciences ◽

10.1016/j.ijrmms.2020.104582 ◽

2021 ◽

Vol 144 ◽

pp. 104582

Author(s):

D.M. Seyedi ◽

C. Plúa ◽

M. Vitel ◽

G. Armand ◽

J. Rutqvist ◽

...

Keyword(s):

Full Scale ◽

Small Scale ◽

In Situ Experiments

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Memory Effect on a LDH/zeolite A Composite: An XRD In Situ Study

Materials ◽

10.3390/ma14092102 ◽

2021 ◽

Vol 14 (9) ◽

pp. 2102

Author(s):

Breno G. P. Bezerra ◽

Lindiane Bieseki ◽

Mariele I. S. de Mello ◽

Djalma R. da Silva ◽

Cristiane B. Rodella ◽

...

Keyword(s):

Memory Effect ◽

Inert Atmosphere ◽

Effect Study ◽

Physical Mixture ◽

Zeolite A ◽

Three Samples ◽

In Situ Experiments ◽

Double Hydroxide ◽

Rehydration Process

In this memory effect study, hydrotalcite-type compounds in the lamellar double hydroxide-like (LDH)/zeolite A composite material were analyzed using X-Ray Diffration XRD) in situ experiments. Three samples were analyzed: Al,Mg-LDH, Al,Mg-LDH/ZA composite, and a physical mixture (50/50 wt%) of zeolite A and Al,Mg-LDH. The Al,Mg-LDH sample was treated at 500 °C in an O2 atmosphere and subsequently rehydrated. The Al,Mg-LDH/ZA composites had three treatments: one was performed at 300 °C in a He atmosphere, and two treatments were performed with an O2 atmosphere at 300 and 500 °C. In the physical mixture, two treatments were carried out under O2 flow at 500 °C and under He flow at 300 °C. Both went through the rehydration process. All samples were also analyzed by energy dispersive spectroscopy (EDS) and scanning electron microscopy (SEM). The results show that the LDH phase in the Al,Mg-LDH/ZA compounds has memory effects, and thus, the compound can be calcined and rehydrated. For the LDH in the composite, the best heat treatment system is a temperature of 300 °C in an inert atmosphere.

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