THE PHOTOCHEMICAL DECOMPOSITION OF SODIUM AZIDE

1966 ◽  
Vol 44 (6) ◽  
pp. 703-709 ◽  
Author(s):  
P. W. M. Jacobs ◽  
A. R. Tariq Kureishy
Keyword(s):  
Ultraviolet Light ◽  
Sodium Azide ◽  
Reaction Mechanisms ◽  
Linear Growth ◽  
Experimental Results ◽  
Dislocation Network ◽  
Metallic Sodium ◽  
Photochemical Decomposition ◽  
Good Agreement

When sodium azide is irradiated with ultraviolet light the rate of photolysis at first decreases and then becomes constant. Two reaction mechanisms are involved: the first occurs only in salt which has not previously been irradiated, whereas the second requires the presence of metallic sodium. These two reactions are interpreted as the formation and linear growth of nuclei in the dislocation network of the salt and an equation developed from this model gives good agreement with the experimental results. Incorporation of Fe3+ ions in NaN3 leads to a greater number of nucleus-forming sites.

A new dissociation mode for dislocations in silicon

1978 ◽  
Vol 36 (1) ◽  
pp. 346-347
Author(s):  
A. Ourmazd ◽  
G.R. Booker ◽  
C.J. Humphreys
Keyword(s):  
Detailed Examination ◽  
Experimental Results ◽  
Dislocation Network ◽  
Weak Beam ◽  
Phosphorus Doped

A (111) phosphorus-doped Si specimen, thinned to give a TEM foil of thickness ∼ 150nm, contained a dislocation network lying on the (111) plane. The dislocation lines were along the three <211> directions and their total Burgers vectors,ḇt, were of the type , each dislocation being of edge character. TEM examination under proper weak-beam conditions seemed initially to show the standard contrast behaviour for such dislocations, indicating some dislocation segments were undissociated (contrast A), while other segments were dissociated to give two Shockley partials separated by approximately 6nm (contrast B) . A more detailed examination, however, revealed that some segments exhibited a third and anomalous contrast behaviour (contrast C), interpreted here as being due to a new dissociation not previously reported. Experimental results obtained for a dislocation along [211] with for the six <220> type reflections using (g,5g) weak-beam conditions are summarised in the table below, together with the relevant values.

Inducing Frictional Force to Enhance the Transient Response in Beams

2019 ◽  
Vol 22 (2) ◽  
pp. 88-93
Author(s):  
Hamed Khanger Mina ◽  
Waleed K. Al-Ashtrai
Keyword(s):  
Numerical Analysis ◽  
Transient Response ◽  
Frictional Force ◽  
Damping Ratio ◽  
Experimental Results ◽  
Damping Capacity ◽  
Tightening Force ◽  
Contact Areas ◽  
Good Agreement ◽  
Ansys Workbench

This paper studies the effect of contact areas on the transient response of mechanical structures. Precisely, it investigates replacing the ordinary beam of a structure by two beams of half the thickness, which are joined by bolts. The response of these beams is controlled by adjusting the tightening of the connecting bolts and hence changing the magnitude of the induced frictional force between the two beams which affect the beams damping capacity. A cantilever of two beams joined together by bolts has been investigated numerically and experimentally. The numerical analysis was performed using ANSYS-Workbench version 17.2. A good agreement between the numerical and experimental results has been obtained. In general, results showed that the two beams vibrate independently when the bolts were loosed and the structure stiffness is about 20 N/m and the damping ratio is about 0.008. With increasing the bolts tightening, the stiffness and the damping ratio of the structure were also increased till they reach their maximum values when the tightening force equals to 8330 N, where the structure now has stiffness equals to 88 N/m and the damping ratio is about 0.062. Beyond this force value, increasing the bolts tightening has no effect on stiffness of the structure while the damping ratio is decreased until it returned to 0.008 when the bolts tightening becomes immense and the beams behave as one beam of double thickness.

PHOTOINDUCED NONLINEAR OCTUPOLAR POLARIZATION: TRANSIENT AND PERMANENT REGIMES

1996 ◽  
Vol 05 (04) ◽  
pp. 653-670 ◽  
Author(s):  
CÉLINE FIORINI ◽  
JEAN-MICHEL NUNZI ◽  
FABRICE CHARRA ◽  
IFOR D.W. SAMUEL ◽  
JOSEPH ZYSS
Keyword(s):  
Theoretical Analysis ◽  
Second Harmonic ◽  
Experimental Results ◽  
Polar Field ◽  
Rotational Spectrum ◽  
Dual Frequency ◽  
One Dimensional ◽  
Ethyl Violet ◽  
Disperse Red 1 ◽  
Good Agreement

An original poling method using purely optical means and based on a dual-frequency interference process is presented. We show that the coherent superposition of two beams at fundamental and second-harmonic frequencies results in a polar field with an irreducible rotational spectrum containing both a vector and an octupolar component. This enables the method to be applied even to molecules without a permanent dipole such as octupolar molecules. After a theoretical analysis of the process, we describe different experiments aiming at light-induced noncentrosymmetry performed respectively on one-dimensional Disperse Red 1 and octupolar Ethyl Violet molecules. Macroscopic octupolar patterning of the induced order is demonstrated in both transient and permanent regimes. Experimental results show good agreement with theory.

scholarly journals Comparison of Experimental and Numerical Transient Drop Deformation during Transition through Orifices in High-Pressure Homogenizers

2021 ◽  
Vol 5 (3) ◽  
pp. 32
Author(s):  
Benedikt Mutsch ◽  
Peter Walzel ◽  
Christian J. Kähler
Keyword(s):  
High Pressure ◽  
Visual Analysis ◽  
Imaging Technique ◽  
Extensional Flow ◽  
Droplet Breakup ◽  
Experimental Results ◽  
Drop Deformation ◽  
Droplet Deformation ◽  
Shadow Imaging ◽  
Good Agreement

The droplet deformation in dispersing units of high-pressure homogenizers (HPH) is examined experimentally and numerically. Due to the small size of common homogenizer nozzles, the visual analysis of the transient droplet generation is usually not possible. Therefore, a scaled setup was used. The droplet deformation was determined quantitatively by using a shadow imaging technique. It is shown that the influence of transient stresses on the droplets caused by laminar extensional flow upstream the orifice is highly relevant for the droplet breakup behind the nozzle. Classical approaches based on an equilibrium assumption on the other side are not adequate to explain the observed droplet distributions. Based on the experimental results, a relationship from the literature with numerical simulations adopting different models are used to determine the transient droplet deformation during transition through orifices. It is shown that numerical and experimental results are in fairly good agreement at limited settings. It can be concluded that a scaled apparatus is well suited to estimate the transient droplet formation up to the outlet of the orifice.

Simulation of Sphere’s Motion Induced by Shock Waves

2012 ◽  
Vol 134 (10) ◽  
Author(s):  
Dan Igra ◽  
Ozer Igra ◽  
Lazhar Houas ◽  
Georges Jourdan
Keyword(s):  
Shock Waves ◽  
Drag Coefficient ◽  
Drag Force ◽  
Stationary Flow ◽  
Experimental Results ◽  
Experimental Findings ◽  
Sphere Drag ◽  
Simulation Scheme ◽  
Good Agreement

Simulations of experimental results appearing in Jourdan et al. (2007, “Drag Coefficient of a Sphere in a Non-Stationary Flow: New Results,”Proc. R. Soc. London, Ser. A, 463, pp. 3323–3345) regarding acceleration of a sphere by the postshock flow were conducted in order to find the contribution of the various parameters affecting the sphere drag force. Based on the good agreement found between present simulations and experimental findings, it is concluded that the proposed simulation scheme could safely be used for evaluating the sphere’s motion in the postshock flow.

Viscoelastic Deformation of PC/ABS Alloy

2007 ◽  
Vol 353-358 ◽  
pp. 1229-1232
Author(s):  
Z.N. Yin ◽  
L.F. Fan ◽  
Tie Jun Wang
Keyword(s):  
Dynamic Mechanical Analysis ◽  
Relaxation Modulus ◽  
Mechanical Analysis ◽  
Experimental Results ◽  
Viscoelastic Deformation ◽  
Dynamic Mechanical ◽  
Storage And Loss Moduli ◽  
Static Relaxation ◽  
Comparison Of The Results ◽  
Good Agreement

Dynamic Mechanical Analysis (DMA) and static relaxation tests are carried out to study the viscoelastic deformation of PC/ABS alloy with blending ratio of PC to ABS being 50/50. A modified approach is developed to calculate the relaxation modulus of PC/ABS alloy from the DMA experimental results of storage and loss moduli. Comparison of the results obtained from DMA and static relaxation tests is presented and good agreement is found.

Influence of the Morphology on the Optical Properties of Nanocermet Films: A Renormalization Approach

1990 ◽  
Vol 195 ◽  
Author(s):  
S. Berthier ◽  
K. Driss-Khodja
Keyword(s):  
Optical Properties ◽  
Critical Exponents ◽  
Inhomogeneous Media ◽  
Experimental Results ◽  
Percolation Transition ◽  
Position Space ◽  
Renormalization Approach ◽  
2D And 3D ◽  
Good Agreement ◽  
Effective Medium Models

ABSTRACTIn order to take into account the actual morphology of the inhomogeneous media, we have developed, effective medium models based on a 2D and 3D position space renormalization /1,2/. These models predict the dipolar resonance and the percolation transition with critical exponents in good agreement with theoretical values and fairly reproduce most of the experimental results, whatever the concentration is. Further more, this allows a valuable comparison of the predictions of our models when applied on different lattices like real digitized TEM of cermet films or randomly occupied lattices.

Experimental Study and Finite Analysis on Flexural Capacity of Laminated Glass

2011 ◽  
Vol 243-249 ◽  
pp. 258-262
Author(s):  
Jun Chen ◽  
Jia Lv ◽  
Qi Lin Zhang ◽  
Zhi Xiong Tao ◽  
Jun Chen
Keyword(s):  
Experimental Results ◽  
Laminated Glass ◽  
Test Results ◽  
Design Code ◽  
Flexural Capacity ◽  
Equivalent Thickness ◽  
High Rise ◽  
Safety Glass ◽  
Current Design ◽  
Good Agreement

Laminated glass has been increasing widely used in high rise buildings as a kind of safety glass in recent years. So we should analyze its material property. In this paper, we use flexural experiments and ANSYS program to analyze the main factors that affect the flexural capacity of the laminated glass. The test results show that the flexural capacity is closely related to film. And the ANSYS program had got good agreement with the experimental results. Comparison of experimental results with calculated ones indicates that the current design code will lead to conservative results and the equivalent thickness of laminated glasses provided in the code should be further discussed.

Thermal Management of Surface Mount Power Magnetic Components

1999 ◽  
Vol 122 (4) ◽  
pp. 323-327
Author(s):  
G. Refai-Ahmed ◽  
M. M. Yovanovich
Keyword(s):  
Heat Transfer ◽  
Power Loss ◽  
Numerical Study ◽  
Lower Surface ◽  
Experimental Results ◽  
Surface Mount ◽  
Conduction Heat Transfer ◽  
Magnetic Components ◽  
Underfill Material ◽  
Good Agreement

A numerical and experimental study of conduction heat transfer from low power magnetic components with gull wing leads was conducted to determine the effects of distributing the power loss between the core, the winding and the thermal underfill on the thermal resistance. The numerical study was conducted in the power loss ratio range of 0.5⩽PR⩽1.0, where the only active power loss was from the winding at PR=1. In addition, the effect of the thermal underfill material between the substrate and the lower surface of the magnetic package on the thermal performance of the magnetic device was also examined. For comparison, a test was conducted on a magnetic component at PR=1, without thermal underfill. This comparison revealed good agreement between the numerical and experimental results. Finally, a general model was proposed for conduction heat transfer from the surface mount power magnetic packages. The agreement between the model and the experimental results was within 8 percent. [S1043-7398(00)00704-0]

scholarly journals Numerical Simulations of V-Shaped Plates Subjected to Blast Loadings: A Validation Study

2016 ◽  
Vol 10 (11) ◽  
pp. 203
Author(s):  
Mohd Zaid Othman ◽  
Qasim H. Shah ◽  
Muhammad Akram Muhammad Khan ◽  
Tan Kean Sheng ◽  
M. A. Yahaya ◽  
...  
Keyword(s):  
Numerical Simulation ◽  
Numerical Simulations ◽  
Variable Mass ◽  
Blast Loading ◽  
Experimental Results ◽  
Average Difference ◽  
Simulation Results ◽  
Blast Loadings ◽  
Carrier Vehicle ◽  
Good Agreement

A series of numerical simulations utilizing LS-DYNA was performed to determine the mid-point deformations of V-shaped plates due to blast loading. The numerical simulation results were then compared with experimental results from published literature. The V-shaped plate is made of DOMEX 700 and is used underneath an armour personal carrier vehicle as an anti-tank mine to mitigate the effects of explosion from landmines in a battlefield. The performed numerical simulations of blast loading of V-shaped plates consisted of various angles i.e. 60°, 90°, 120°, 150° and 180°; variable mass of explosives located at the central mid-point of the V-shaped vertex with various stand-off distances. It could be seen that the numerical simulations produced good agreement with the experimental results where the average difference was about 26.6%.

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