Elemental characterization of gold-plated costume jewelry using particle-induced X-ray emission

2018 ◽  
Vol 28 (01n02) ◽  
pp. 43-49
Author(s):  
Rafaela Debastiani ◽  
Ivanessa da Silveira Almansa ◽  
Liana Appel Boufleur ◽  
Tatiele Martins Ferrari ◽  
Cláudia Telles de Souza ◽  
...  
Keyword(s):  
Elemental Composition ◽  
Toxic Elements ◽  
Rutherford Backscattering Spectrometry ◽  
Protective Layer ◽  
High Concentration ◽  
Porto Alegre ◽  
X Ray ◽  
Cu Alloy ◽  
Elemental Characterization

Nine gold-plated costume jewelries bought in the street market of Porto Alegre and from Chinese websites were investigated through Particle-Induced X-ray Emission (PIXE) and Rutherford Backscattering Spectrometry (RBS) in order to verify their elemental composition and distribution. The analyzed costume jewelries were made of Cu-based alloys with Ni, Zn, Sn and Al. Elements such as Ag, Al, Bi, Cd, Co and Fe were found in minor amounts in some particular samples. Through RBS, it was possible to distinguish the bulk from the gold-plated layer. Toxic elements as Ni and Cd were found in at least one sample. The high concentration of Ni comes from the bulk Cu-alloy below the Au layer. In this case, the Au acts as a protective layer separating the Ni from the user’s skin.

scholarly journals MOVPE Growth of Quaternary (Al,Ga,In)N for UV Optoelectronics

2000 ◽  
Vol 5 (S1) ◽  
pp. 412-424
Author(s):  
Jung Han ◽  
Jeffrey J. Figiel ◽  
Gary A. Petersen ◽  
Samuel M. Myers ◽  
Mary H. Crawford ◽  
...  
Keyword(s):  
Room Temperature ◽  
Rutherford Backscattering Spectrometry ◽  
Optoelectronic Devices ◽  
Lattice Parameter ◽  
X Ray Diffraction ◽  
X Ray ◽  
Peak Energy ◽  
Movpe Growth ◽  
Pl Emission

We report the growth and characterization of quaternary AlGaInN. A combination of photoluminescence (PL), high-resolution x-ray diffraction (XRD), and Rutherford backscattering spectrometry (RBS) characterizations enables us to explore the contours of constant- PL peak energy and lattice parameter as functions of the quaternary compositions. The observation of room temperature PL emission at 351nm (with 20% Al and 5% In) renders initial evidence that the quaternary could be used to provide confinement for GaInN (and possibly GaN). AlGaInN/GaInN MQW heterostructures have been grown; both XRD and PL measurements suggest the possibility of incorporating this quaternary into optoelectronic devices.

Isolation and characterization of lignocellulosic fiber from jute bast by the organic solvent degumming system: an alkali-free method

2021 ◽  
pp. 004051752110154
Author(s):  
Zhihui Qin ◽  
Shuyuan Zhao ◽  
Liu Liu ◽  
Zhaohe Shi ◽  
Longdi Cheng ◽  
...  
Keyword(s):  
National Standards ◽  
X Ray Diffraction ◽  
High Concentration ◽  
X Ray ◽  
Lignocellulosic Fibers ◽  
Lignocellulosic Fiber ◽  
Isolation And Characterization ◽  
Alkali Consumption ◽  
Scanning Electron

Degumming is the dominant method for insolating lignocellulosic fibers in textile applications. Traditional alkaline degumming (TAL), as a common method, requires a high-concentration alkali and has been a severe challenge to the environment. In the research reported here, the possibility of innovative jute degumming by organic solvents 1-2 propylene glycol and a combination of additive green oxygen (GO-OS) was studied. The results revealed that fibers could be extracted by this system (under condition of 0.9% GO-OS, 180°C, 120 min), and obtained fibers with higher breaking tenacity (7.1 cN/dtex), yield (65.7%), breaking elongation (2.87%) and residual gum (11.7%), which all meet the requirement of the relevant Chinese Textile National Standards. Notably, the required reaction time (120 min) of the GO-OS system was 180 min shorter than that of the TAL method. Furthermore, the modifications introduced by the degumming effect on physicochemical aspects were characterized and confirmed by Fourier transform infrared spectroscopy, scanning electron microscopy and X-ray diffraction. This study provides a promising degumming method for separating jute lignocellulose without acid and alkali consumption.

MOVPE Growth of Quaternary (Al,Ga,In)N for UV Optoelectronics

1999 ◽  
Vol 595 ◽  
Author(s):  
Jung Han ◽  
Jeffrey J. Figiel ◽  
Gary A. Petersen ◽  
Samuel M. Myers ◽  
Mary H. Crawford ◽  
...  
Keyword(s):  
Room Temperature ◽  
Rutherford Backscattering Spectrometry ◽  
Optoelectronic Devices ◽  
Lattice Parameter ◽  
X Ray Diffraction ◽  
X Ray ◽  
Peak Energy ◽  
Movpe Growth ◽  
Pl Emission

AbstractWe report the growth and characterization of quaternary AlGaInN. A combination of photoluminescence (PL), high-resolution x-ray diffraction (XRD), and Rutherford backscattering spectrometry (RBS) characterizations enables us to explore the contours of constant- PL peak energy and lattice parameter as functions of the quaternary compositions. The observation of room temperature PL emission at 351nm (with 20% Al and 5% In) renders initial evidence that the quaternary could be used to provide confinement for GaInN (and possibly GaN). AlGaInN/GaInN MQW heterostructures have been grown; both XRD and PL measurements suggest the possibility of incorporating this quaternary into optoelectronic devices.

X-ray diffraction characterization of the decomposition behavior of γMn phase in a Mn-30at.%Cu alloy

1999 ◽  
Vol 40 (9) ◽  
pp. 993-998 ◽  
Author(s):  
Fuxing Yin ◽  
Yoshiaki Ohsawa ◽  
Akira Sato ◽  
Kohji Kawahara
Keyword(s):  
X Ray Diffraction ◽  
X Ray ◽  
Cu Alloy ◽  
Decomposition Behavior

Forensic application of total reflection X-ray fluorescence spectrometry for elemental characterization of ink samples

2010 ◽  
Vol 65 (2) ◽  
pp. 167-170 ◽  
Author(s):  
Sangita Dhara ◽  
N.L. Misra ◽  
S.D. Maind ◽  
Sanjukta A. Kumar ◽  
N. Chattopadhyay ◽  
...  
Keyword(s):  
Total Reflection ◽  
Fluorescence Spectrometry ◽  
Forensic Application ◽  
X Ray ◽  
Elemental Characterization

Advanced Micro-chemical Investigation of Golden Threads from Romanian Byzantine Embroideries by Micro-Particle Induced X-ray Emission (micro-PIXE)

2019 ◽  
Vol 70 (6) ◽  
pp. 1956-1959
Author(s):  
Zizi Ileana Balta ◽  
Ioana Demetrescu ◽  
Irina Petroviciu ◽  
Mihai Lupu
Keyword(s):  
Trace Elements ◽  
Spatial Distribution ◽  
Optical Microscopy ◽  
Elemental Composition ◽  
Depth Profiling ◽  
Composition Distribution ◽  
X Ray ◽  
Constituent Elements ◽  
Elemental Maps

In the present study, golden threads from two, apparently identical, medieval epitrachelions considered masterpieces of the Romanian Byzantine embroidery art, were investigated by using Micro-Particle Induced X-ray Emission (micro-PIXE) and optical microscopy. PIXE measurements allowed to accurate identify the elemental composition, distribution of the trace elements, the layered structures (depth profiling) and thicknesses of the gold layer. Useful information for the characterization of the gilded silver threads due to elemental maps concerning the constituent elements spatial distribution in the sample was also obtained.

Metallurgical characterization of mechanically alloyed MoNiAl-WC reinforced Fe matrix composite

2020 ◽  
Vol 62 (12) ◽  
pp. 1199-1204
Author(s):  
Tanju Teker ◽  
S. Osman Yilmaz
Keyword(s):  
Matrix Composites ◽  
Interface Bonding ◽  
X Ray Diffraction ◽  
Mechanically Alloyed ◽  
Surface Mapping ◽  
Energy Dispersion Spectroscopy ◽  
X Ray ◽  
Metallurgical Characterization ◽  
Elemental Characterization

Abstract MoNiAl-WC reinforced Fe matrix composites were obtained by mechanical alloying. The effect of various reinforcement ratios on microstructure change, elemental characterization and phase transformation were examined by using optical microscopy, scanning electron microscopy, energy dispersion spectroscopy, X-ray diffraction, elemental surface mapping and a microhardness test. Fe and MoNiAl-WC compound and powder mixtures were synthesized by MA and nanocrystalline solid solution was obtained. The increase in the reinforcement ratio reduced grain size in the structure and increased the carbide ratio. The composite demonstrated excellent metallurgical qualities and interface bonding. Moreover, it was found that the amount of porosities increased with increasing reinforcement. X-Ray analysis showed the formation of NiAl, Al3Ni and WC phases.

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