A high resolution multi-turn TOF mass analyzer

2019 ◽  
Vol 34 (36) ◽  
pp. 1942005 ◽  
Author(s):  
Vyacheslav Shchepunov ◽  
Michael Rignall ◽  
Roger Giles ◽  
Ryo Fujita ◽  
Hiroaki Waki ◽  
...  
Keyword(s):  
High Resolution ◽  
Mirror Symmetry ◽  
Rotational Symmetry ◽  
Optical Design ◽  
Resolving Power ◽  
Mass Analyzer ◽  
Rotationally Symmetric ◽  
Mass Resolving Power ◽  
Operational Modes ◽  
Drift Direction

An ion optical design of a high resolution multi-turn time-of-flight mass analyzer (MT-TOF MA) is presented. The analyzer has rotationally symmetric main electrodes with additional mirror symmetry about a mid-plane orthogonal to the axis of symmetry. Rotational symmetry allows a higher density of turns in the azimuthal (drift) direction compared to MT-TOF MAs that are linearly extended in the drift direction. Mirror symmetry about a mid-plane helps to achieve a high spatial isochronicity of the ions’ motion. The analyzer comprises a pair of polar-toroidal sectors S1 and S3, a pair of polar (trans-axial) lenses, and a pair of conical lenses for longitudinal and lateral focusing. A toroidal sector S2 located at the mid-plane of the analyzer has a set of embedded drift focusing segments providing focusing and spatial isochronicity in the drift direction. The ions’ drift in the azimuthal direction can be reversed by using dedicated reversing deflectors. This gives the possibility of several operational modes with different numbers of turns and passes in the drift direction. According to numerical simulations, the mass resolving power of the analyzer ranges from [Formula: see text]40 k (fwhm) at small (typically below ten) numbers of turns to [Formula: see text]450 k (fwhm) at 96 turns.

scholarly journals Applications and limitations of constrained high-resolution peak fitting on low resolving power mass spectra from the ToF-ACSM

2016 ◽  
Vol 9 (7) ◽  
pp. 3263-3281 ◽  
Author(s):  
Hilkka Timonen ◽  
Mike Cubison ◽  
Minna Aurela ◽  
David Brus ◽  
Heikki Lihavainen ◽  
...  
Keyword(s):  
High Resolution ◽  
Mass Spectra ◽  
Methanesulfonic Acid ◽  
Resolving Power ◽  
Sensitivity Analyses ◽  
Metal Species ◽  
Aerosol Mass ◽  
Peak Fitting ◽  
Mass Resolving Power ◽  
Low Mass

Abstract. The applicability, methods and limitations of constrained peak fitting on mass spectra of low mass resolving power (m∕Δm50 ∼ 500) recorded with a time-of-flight aerosol chemical speciation monitor (ToF-ACSM) are explored. Calibration measurements as well as ambient data are used to exemplify the methods that should be applied to maximise data quality and assess confidence in peak-fitting results. Sensitivity analyses and basic peak fit metrics such as normalised ion separation are employed to demonstrate which peak-fitting analyses commonly performed in high-resolution aerosol mass spectrometry are appropriate to perform on spectra of this resolving power. Information on aerosol sulfate, nitrate, sodium chloride, methanesulfonic acid as well as semi-volatile metal species retrieved from these methods is evaluated. The constants in a commonly used formula for the estimation of the mass concentration of hydrocarbon-like organic aerosol may be refined based on peak-fitting results. Finally, application of a recently published parameterisation for the estimation of carbon oxidation state to ToF-ACSM spectra is validated for a range of organic standards and its use demonstrated for ambient urban data.

scholarly journals Development of the Soft X-ray AGM–AGS RIXS beamline at the Taiwan Photon Source

2021 ◽  
Vol 28 (3) ◽  
Author(s):  
A. Singh ◽  
H. Y. Huang ◽  
Y. Y. Chu ◽  
C. Y. Hua ◽  
S. W. Lin ◽  
...  
Keyword(s):  
High Resolution ◽  
Optical Design ◽  
Charge Density Waves ◽  
Resolving Power ◽  
X Rays ◽  
X Ray ◽  
Compensation Principle ◽  
Wide Range ◽  
Energy Compensation ◽  
Photon Source

We report on the development of a high-resolution and highly efficient beamline for soft X-ray resonant inelastic X-ray scattering (RIXS) located at the Taiwan Photon Source. This beamline adopts an optical design that uses an active grating monochromator (AGM) and an active grating spectrometer (AGS) to implement the energy compensation principle of grating dispersion. Active gratings are utilized to diminish defocus, coma and higher-order aberrations, as well as to decrease the slope errors caused by thermal deformation and optical polishing. The AGS is mounted on a rotatable granite platform to enable momentum-resolved RIXS measurements with scattering angles over a wide range. Several high-precision instruments developed in-house for this beamline are described briefly. The best energy resolution obtained from this AGM–AGS beamline was 12.4 meV at 530 eV, achieving a resolving power of 4.2 × 104, while the bandwidth of the incident soft X-rays was kept at 0.5 eV. To demonstrate the scientific impact of high-resolution RIXS, we present an example of momentum-resolved RIXS measurements on a high-temperature superconducting cuprate, i.e. La2–x Sr x CuO4. The measurements reveal the A1g buckling phonons in superconducting cuprates, opening a new opportunity to investigate the coupling between these phonons and charge-density waves.

scholarly journals Optical Design and Optimization with Genetic Algorithm for High-Resolution Optics Applied to Underwater Remote-Sensing

2021 ◽  
Vol 11 (21) ◽  
pp. 10200
Author(s):  
Chun-Feng Chou ◽  
Cheng-Mu Tsai ◽  
Chao-Hsien Chen ◽  
Yung-Hao Wong ◽  
Yi-Chin Fang ◽  
...  
Keyword(s):  
Genetic Algorithm ◽  
High Resolution ◽  
Shallow Water ◽  
Deep Water ◽  
Optical Design ◽  
Chromatic Aberration ◽  
Resolving Power ◽  
Zoom Lens ◽  
Underwater Photography ◽  
Underwater Camera

In fields such as biology, archeology, and industry, underwater photogrammetry can be achieved using consumer-grade equipment. However, camera operations underwater differ considerably from those on land because underwater photogrammetry involves different optical phenomena. On the basis of the requirements and specifications of the marine vessel Polaris, we developed a novel underwater camera with prime and zoom lenses and a high resolving power. The camera can be used in the spectrum in shallow water and the blue–green spectrum in deep water. In the past, ordinary cameras would be placed in waterproof airtight boxes for underwater photography. These cameras were not optimized to the underwater spectrum and environment, resulting in no breakthroughs in resolving power. Furthermore, the use of the blue spectrum greatly increases during underwater and particularly deep-water surveying. Chromatic aberration and focus-point displacement generated by the shift from the shallow-water spectrum to the blue–green spectrum in deep water makes universal underwater photography even more difficult. Our proposed optical design aimed to overcome such challenges for the development of a high-resolution underwater surveying camera. We designed a prime lens and a zoom lens. We adopted a waterproof dome window on the outer surface as the basic structure and optimized it in accordance with the conditions of different water depths and spectra to obtain distortion within ±2% and high-resolution underwater imaging quality. For the zoom lens design, we employed a genetic algorithm in Zemax to attenuate chromatic aberration as a kind of extended optimization. This novel optical design that can be used in all waters is expected to greatly reduce the volume and weight of conventional underwater cameras by more than 50% and 60%, respectively, and increase their resolving power by 30–40%.

scholarly journals Ultra High-Mass Resolution Paper Spray by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry

2012 ◽  
Vol 2012 ◽  
pp. 1-6 ◽  
Author(s):  
Kevin D. Quinn ◽  
Charmion I. Cruickshank ◽  
Troy D. Wood
Keyword(s):  
Fourier Transform ◽  
High Resolution ◽  
Cyclotron Resonance ◽  
Lung Surfactant ◽  
Resolving Power ◽  
High Mass ◽  
Mass Analyzer ◽  
Ion Cyclotron Resonance ◽  
Paper Spray ◽  
Ion Cyclotron

Paper Spray Ionization is an atmospheric pressure ionization technique that utilizes an offline electro-osmotic flow to generate ions off a paper medium. This technique can be performed on a Bruker SolariX Fourier transform ion cyclotron resonance mass spectrometer by modifying the existing nanospray source. High-resolution paper spray spectra were obtained for both organic and biological samples to demonstrate the benefit of linking the technique with a high-resolution mass analyzer. Error values in the range 0.23 to 2.14 ppm were obtained for calf lung surfactant extract with broadband mass resolving power (m/Δm50%) above 60,000 utilizing an external calibration standard.

scholarly journals Applications and limitations of constrained high-resolution peak fitting on low resolving power mass spectra from the ToF-ACSM

2016 ◽  
Author(s):  
Hilkka Timonen ◽  
Mike Cubison ◽  
Minna Aurela ◽  
David Brus ◽  
Heikki Lihavainen ◽  
...  
Keyword(s):  
High Resolution ◽  
Mass Spectra ◽  
Resolving Power ◽  
Sensitivity Analyses ◽  
Metal Species ◽  
Aerosol Mass ◽  
Aerosol Mass Spectrometry ◽  
Peak Fitting ◽  
Mass Resolving Power ◽  
Low Mass

Abstract. The applicability, methods and limitations of constrained peak-fitting on mass spectra of low mass resolving power (m/dm50 ~ 500) recorded with a time-of-flight aerosol chemical speciation monitor (ToF-ACSM) are explored. Calibration measurements as well as ambient data are used to exemplify the methods that should be applied to maximise data quality and assess confidence in peak-fitting results. Sensitivity analyses and basic peak fit metrics such as normalised ion separation are employed to demonstrate which peak-fitting analyses commonly performed in high-resolution aerosol mass spectrometry are appropriate to perform on spectra of this resolving power. Information on aerosol sulphate, nitrate, sodium chloride, methanesulphonic acid as well as semi-volatile metal species retrieved from these methods is evaluated. The constants in a commonly used formula for the estimation of the mass concentration of hydrocarbon-like organic aerosol may be refined based on peak-fitting results. Finally, application of a recently-published parameterisation for the estimation of carbon oxidation state to ToF-ACSM spectra is validated for a range of organic standards and its use demonstrated for ambient urban data.

The High Resolution Scanning Transmission Electron Microscope

1974 ◽  
Vol 32 ◽  
pp. 316-317
Author(s):  
A. V. Crewe
Keyword(s):  
Electron Microscope ◽  
High Resolution ◽  
High Vacuum ◽  
Scanning Transmission Electron Microscope ◽  
Ultra High Vacuum ◽  
Resolving Power ◽  
Imaging Characteristics ◽  
Transmission Electron ◽  
Scanning Transmission ◽  
The Moment

The high resolution STEM is now a fact of life. I think that we have, in the last few years, demonstrated that this instrument is capable of the same resolving power as a CEM but is sufficiently different in its imaging characteristics to offer some real advantages.It seems possible to prove in a quite general way that only a field emission source can give adequate intensity for the highest resolution^ and at the moment this means operating at ultra high vacuum levels. Our experience, however, is that neither the source nor the vacuum are difficult to manage and indeed are simpler than many other systems and substantially trouble-free.

An Analysis of Dissociation of Molecules in a High Resolution Electron Microscope

1973 ◽  
Vol 31 ◽  
pp. 486-487
Author(s):  
Mihir Parikh
Keyword(s):  
Electron Microscope ◽  
High Resolution ◽  
Cross Sections ◽  
Resolving Power ◽  
Peak Intensity ◽  
Molecular Film ◽  
Resolution Electron ◽  
Dissociation Cross Section ◽  
High Resolution Electron Microscope ◽  
The Stability

It is well known that the resolution of bio-molecules in a high resolution electron microscope depends not just on the physical resolving power of the instrument, but also on the stability of these molecules under the electron beam. Experimentally, the damage to the bio-molecules is commo ly monitored by the decrease in the intensity of the diffraction pattern, or more quantitatively by the decrease in the peaks of an energy loss spectrum. In the latter case the exposure, EC, to decrease the peak intensity from IO to I’O can be related to the molecular dissociation cross-section, σD, by EC = ℓn(IO /I’O) /ℓD. Qu ntitative data on damage cross-sections are just being reported, However, the microscopist needs to know the explicit dependence of damage on: (1) the molecular properties, (2) the density and characteristics of the molecular film and that of the support film, if any, (3) the temperature of the molecular film and (4) certain characteristics of the electron microscope used

Practical High Resolution Microscopy

1968 ◽  
Vol 26 ◽  
pp. 302-303
Author(s):  
P. A. Marsh ◽  
T. Mullens ◽  
D. Price
Keyword(s):  
High Resolution ◽  
Magnetic Fields ◽  
Low Frequency ◽  
Resolving Power ◽  
Careful Attention ◽  
Electron Microscopes ◽  
The Relationship ◽  
High Resolution Microscopy ◽  
New Facilities

It is possible to exceed the guaranteed resolution on most electron microscopes by careful attention to microscope parameters essential for high resolution work. While our experience is related to a Philips EM-200, we hope that some of these comments will apply to all electron microscopes.The first considerations are vibration and magnetic fields. These are usually measured at the pre-installation survey and must be within specifications. It has been our experience, however, that these factors can be greatly influenced by the new facilities and therefore must be rechecked after the installation is completed. The relationship between the resolving power of an EM-200 and the maximum tolerable low frequency interference fields in milli-Oerstedt is 10 Å - 1.9, 8 Å - 1.4, 6 Å - 0.8.

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