Molecular modeling of porphyrin-based conjugates and subphthalocyanine aggregates
A theoretical study was carried out on both porphyrin-based conjugates (with interest in the so-called artificial photosynthesis) and subphthalocyanine aggregates (with potential applications as new materials for optoelectronics, solar energy and other uses). A simple molecular orbital model for studying the role of the spacer groups in the electron transfer in porphyrin-quinone conjugates was developed. The influence of the π-π interaction, hydrogen association and covalent linkage on the stability and structural features in porphyrin-porphyrin complexes as well as the charge separation in donor-acceptor porphyrin dimers, were reproduced. Theoretical models suggest the potential feasibility of SubPc's aggregative processes leading to nanometer-sized fully aromatic fullerene-like molecular architectures.