Synthesis and interface modification of oxide solid-state electrolyte-based all-solid-state lithium-ion batteries: Advances and perspectives

2020 ◽  
pp. 2130002
Author(s):  
Linchun He ◽  
Jin An Sam Oh ◽  
Jun Jie Jason Chua ◽  
Henghui Zhou
Keyword(s):  
Solid State ◽  
Interface Reaction ◽  
Lithium Ion ◽  
Oxide Ceramic ◽  
Energy Storage Devices ◽  
Solid State Electrolyte ◽  
Interface Modification ◽  
Storage Devices ◽  
The One ◽  
Safety And Stability

All-solid-state Li-ion batteries (ASSLiBs) are considered as promising next-generation energy storage devices, and the one that is based on oxide ceramic solid-state electrolyte (SSE) has attracted much attention for its high safety and stability in ambient conduction compared with that of used sulfur and polymer SSEs. However, the undeformable nature of the ceramic SSEs brings new issues such as poor interface bonding, limited contact area and limited cathode utilization for the ASSLiBs. In addition, the interface reaction and resistance are also obstacles for ASSLiBs application. In this review, we focus on the synthesis and electrochemical properties, interface modification and failure mechanism of ASSLiBs. Finally, perspectives of future researches on the ceramic SSEs-based ASSLiBs are discussed.

scholarly journals Local Ion Dynamics in Polycrystalline β-LiGaO2: A Solid-State NMR Study

2017 ◽  
Vol 231 (7-8) ◽  
Author(s):  
C. Vinod Chandran ◽  
Kai Volgmann ◽  
Suliman Nakhal ◽  
Reinhard Uecker ◽  
Elena Witt ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Ion ◽  
Resonance Spectroscopy ◽  
Ion Dynamics ◽  
Energy Storage Devices ◽  
Ion Motion ◽  
Storage Devices ◽  
Nmr Study ◽  
Materials Used ◽  
Lithium Ion Conductors

AbstractSolid-state nuclear magnetic resonance spectroscopy is an efficient technique to characterize dynamics and structure of materials. It has been widely used to elucidate ion dynamics in lithium ion conductors. Fast moving lithium ions are needed in energy storage devices, whereas slow ion motion is exploited in some materials used, for example, as blankets in fusion reactors.

A new approach for synthesizing bulk-type all-solid-state lithium-ion batteries

2019 ◽  
Vol 7 (16) ◽  
pp. 9748-9760 ◽  
Author(s):  
Linchun He ◽  
Chao Chen ◽  
Masashi Kotobuki ◽  
Feng Zheng ◽  
Henghui Zhou ◽  
...  
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Energy Density ◽  
Lithium Ion ◽  
Li Ion Batteries ◽  
Energy Storage Devices ◽  
New Approach ◽  
Storage Devices ◽  
Safety Issues ◽  
Li Ion

All-solid-state Li-ion batteries (ASSLiB) have been considered to be the next generation energy storage devices that can overcome safety issues and increase the energy density by replacing the organic electrolyte with inflammable solid electrolyte.

Further Evidence for Energy Landscape Flattening in the Superionic Argyrodites Li6+xP1−xMxS5I (M = Si, Ge, Sn)

2019 ◽  
Author(s):  
Saneyuki Ohno ◽  
Bianca Helm ◽  
Till Fuchs ◽  
Georg Dewald ◽  
Marvin Kraft ◽  
...  
Keyword(s):  
Solid State ◽  
Activation Barrier ◽  
Energy Landscape ◽  
General Mechanism ◽  
Ionic Conductors ◽  
Energy Storage Devices ◽  
Ion Conductor ◽  
Storage Devices ◽  
Open Questions ◽  
Sudden Decrease

<p>All-solid-state batteries are promising candidates for next-generation energy storage devices. Although the list of candidate materials for solid electrolytes has grown in the past decade, there are still many open questions concerning the mechanisms behind ionic migration in materials. In particular, the lithium thiophosphate family of materials has shown very promising properties for solid-state battery applications. Recently, the Ge-substituted Li<sub>6</sub>PS<sub>5</sub>I argyrodite was shown to be a very fast Li-ion conductor, despite the poor ionic conductivity of the unsubstituted Li<sub>6</sub>PS<sub>5</sub>I. Therein, the conductivity was enhanced by over three orders of magnitude due to the emergence of I<sup>−</sup>/S<sup>2−</sup>exchange, <i>i.e.</i>site-disorder, which led to a sudden decrease of the activation barrier with a concurrent flattening of the energy landscapes. Inspired by this work, two series of elemental substitutions in Li<sub>6+<i>x</i></sub>P<sub>1−<i>x</i></sub><i>M<sub>x</sub></i>S<sub>5</sub>I (<i>M</i>= Si and Sn) were investigated in this study and compared to the Ge-analogue. A sharp reduction in the activation energy was observed at the same <i>M</i><sup>4+</sup>/P<sup>5+</sup>composition as previously found in the Ge-analogue, suggesting a more general mechanism at play. Furthermore, structural analyses with X-ray and neutron diffraction indicate that similar changes in the Li-sublattice occur despite a significant variation in the size of the substituents, suggesting that in the argyrodites, the lithium substructure is most likely influenced by the occurring Li<sup>+</sup>– Li<sup>+</sup>interactions. This work provides further evidence that the energy landscape of ionic conductors can be tailored by inducing local disorder.</p>

scholarly journals Ionic Liquid Electrolytes for Electrochemical Energy Storage Devices

Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4000
Author(s):  
Eunhwan Kim ◽  
Juyeon Han ◽  
Seokgyu Ryu ◽  
Youngkyu Choi ◽  
Jeeyoung Yoo
Keyword(s):  
Ionic Liquid ◽  
Energy Storage ◽  
Lithium Ion ◽  
Electrochemical Energy Storage ◽  
Storage Device ◽  
Energy Storage Device ◽  
Energy Storage Devices ◽  
Storage Devices ◽  
Storage Ability ◽  
Electrochemical Energy

For decades, improvements in electrolytes and electrodes have driven the development of electrochemical energy storage devices. Generally, electrodes and electrolytes should not be developed separately due to the importance of the interaction at their interface. The energy storage ability and safety of energy storage devices are in fact determined by the arrangement of ions and electrons between the electrode and the electrolyte. In this paper, the physicochemical and electrochemical properties of lithium-ion batteries and supercapacitors using ionic liquids (ILs) as an electrolyte are reviewed. Additionally, the energy storage device ILs developed over the last decade are introduced.

scholarly journals The Importance of Interphases in Energy Storage Devices: Methods and Strategies to Investigate and Control Interfacial Processes

Physchem ◽  
2021 ◽  
Vol 1 (1) ◽  
pp. 26-44
Author(s):  
Chiara Ferrara ◽  
Riccardo Ruffo ◽  
Piercarlo Mustarelli
Keyword(s):  
Energy Storage ◽  
Solid Electrolyte Interphase ◽  
Lithium Ion ◽  
Lithium Metal ◽  
Energy Storage Devices ◽  
Storage Devices ◽  
Lithium Metal Batteries ◽  
And Control ◽  
Near Future

Extended interphases are playing an increasingly important role in electrochemical energy storage devices and, in particular, in lithium-ion and lithium metal batteries. With this in mind we initially address the differences between the concepts of interface and interphase. After that, we discuss in detail the mechanisms of solid electrolyte interphase (SEI) formation in Li-ion batteries. Then, we analyze the methods for interphase characterization, with emphasis put on in-situ and operando approaches. Finally, we look at the near future by addressing the issues underlying the lithium metal/electrolyte interface, and the emerging role played by the cathode electrolyte interphase when high voltage materials are employed.

scholarly journals Novel Practical Life Cycle Prediction Method by Entropy Estimation of Li-Ion Battery

Electronics ◽  
2021 ◽  
Vol 10 (4) ◽  
pp. 487
Author(s):  
Tae-Kue Kim ◽  
Sung-Chun Moon
Keyword(s):  
Lithium Ion Batteries ◽  
Prediction Method ◽  
Lithium Ion ◽  
Estimation Accuracy ◽  
Battery Life ◽  
Energy Storage Devices ◽  
Storage Devices ◽  
Basic Law ◽  
Life Problems ◽  
Li Ion

The growth of the lithium-ion battery market is accelerating. Although they are widely used in various fields, ranging from mobile devices to large-capacity energy storage devices, stability has always been a problem, which is a critical disadvantage of lithium-ion batteries. If the battery is unstable, which usually occurs at the end of its life, problems such as overheating and overcurrent during charge-discharge increase. In this paper, we propose a method to accurately predict battery life in order to secure battery stability. Unlike the existing methods, we propose a method of assessing the life of a battery by estimating the irreversible energy from the basic law of entropy using voltage, current, and time in a realistic dimension. The life estimation accuracy using the proposed method was at least 91.6%, and the accuracy was higher than 94% when considering the actual used range. The experimental results proved that the proposed method is a practical and effective method for estimating the life of lithium-ion batteries.

scholarly journals A germanium and zinc chalcogenide as an anode for a high-capacity and long cycle life lithium battery

RSC Advances ◽  
2019 ◽  
Vol 9 (60) ◽  
pp. 35045-35049
Author(s):  
Xu Chen ◽  
Jian Zhou ◽  
Jiarui Li ◽  
Haiyan Luo ◽  
Lin Mei ◽  
...  
Keyword(s):  
Energy Storage ◽  
High Performance ◽  
Lithium Battery ◽  
Large Scale ◽  
High Capacity ◽  
Lithium Ion ◽  
Energy Storage Devices ◽  
Storage Devices ◽  
Long Cycle Life ◽  
Zinc Chalcogenide

High-performance lithium ion batteries are ideal energy storage devices for both grid-scale and large-scale applications.

Flexible all-solid-state fiber-shaped Ni–Fe batteries with high electrochemical performance

2019 ◽  
Vol 7 (2) ◽  
pp. 520-530 ◽  
Author(s):  
Qiulong Li ◽  
Qichong Zhang ◽  
Chenglong Liu ◽  
Juan Sun ◽  
Jiabin Guo ◽  
...  
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Electrochemical Performance ◽  
High Capacity ◽  
Core Shell ◽  
Next Generation ◽  
Energy Storage Devices ◽  
Storage Devices

The fiber-shaped Ni–Fe battery takes advantage of high capacity of hierarchical CoP@Ni(OH)2 NWAs/CNTF core–shell heterostructure and spindle-like α-Fe2O3/CNTF electrodes to yield outstanding electrochemical performance, demonstrating great potential for next-generation portable wearable energy storage devices.

A flame-retardant polyimide interlayer with polysulfide lithium traps and fast redox conversion towards safety and high sulfur utilization Li-S batteries

Nanoscale ◽  
2022 ◽  
Author(s):  
Zhiyu Zhou ◽  
Zexiang Chen ◽  
Yang Zhao ◽  
Huifang Lv ◽  
Hualiang Wei ◽  
...  
Keyword(s):  
Energy Storage ◽  
Flame Retardant ◽  
Lithium Ion Battery ◽  
Lithium Ion ◽  
Energy Storage Devices ◽  
Storage Devices ◽  
Battery Technology ◽  
Redox Conversion ◽  
Lithium Sulfur ◽  
Made In

In recent years and following the progress made in lithium-ion battery technology, substantial efforts have been devoted to developing practical lithium-sulfur (Li–S) batteries for next-generation commercial energy storage devices. The...

scholarly journals Research on molecular energy storage

2021 ◽  
Vol 1 (3) ◽  
pp. 49-56
Author(s):  
S.M. Zuyev ◽  
◽  
R.A. Maleyev ◽  
YU.M. Shmatkov ◽  
M.YU. Khandzhalov ◽  
...  
Keyword(s):  
Comparative Analysis ◽  
Energy Storage ◽  
Lithium Ion Battery ◽  
Double Layer ◽  
Lithium Ion ◽  
Storage Device ◽  
Energy Storage Device ◽  
Energy Storage Devices ◽  
Storage Devices ◽  
Advantages And Disadvantages

This article provides a comparative analysis of various energy storage devices. A detailed review and analysis of molecular energy storage units is carried out, their main characteristics and parame-ters, as well as their application areas, are determined. The main types of molecular energy storage are determined: electric double layer capacitors, pseudo capacitors, hybrid capacitors. Comparison of the characteristics of various batteries is given. The parameters of various energy storage devices are presented. The analysis of molecular energy storage devices and accumulators is carried out. Ttheir advantages and disadvantages are revealed. It has been shown that molecular energy storage or double layer electrochemical capacitors are ideal energy storage systems due to their high specific energy, fast charging and long life compared to conventional capacitors. The article presents oscillograms of a lithium-ion battery with a voltage of 10.8 V at a pulsed load current of 2A of a laptop with and without a molecular energy storage device, as well as oscil-lograms of a laptop with DVD lithium-ion battery with a voltage of 10.8 V with a parallel shutdown of a molecular energy storage device with a capacity of 7 F and without it. The comparative analysis shows that when the molecular energy storage unit with a 7 F capacity is switched on and off, transient processes are significantly improved and there are no supply voltage dips. The dependenc-es of the operating time of a 3.6 V 600 mAh lithium-ion battery at a load of 2 A for powering mo-bile cellular devices with and without a molecular energy storage are given. It is shown that when the molecular energy storage device is switched on, the battery operation time increases by almost 20%.

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