scholarly journals High Absorption Electromagnetic Wave Properties of Composite CoFeO3 Synthesized by Simple Mechanical Alloying

2021 ◽  
Author(s):  
Heryanto Heryanto ◽  
Dahlang Tahir
Keyword(s):  
Electromagnetic Wave ◽  
Mechanical Alloying ◽  
Human Health ◽  
High Performance ◽  
Magnetic Domain ◽  
Interfacial Polarization ◽  
Multiple Reflections ◽  
Microwave Absorbing Materials ◽  
Transition Metal Atoms ◽  
Domain Loss

Abstract Electronic equipment demand is strongly correlated to the electromagnetic wave interference (EMI), which causes severe effects on human health. Microwave absorbing materials (MAMs) are one method to protect human health from EMI. Cobalt nanoparticles show high performance as MAMs. Here, we have synthesized CoFeO3 by simple mechanical alloying for increased multiple reflections, interfacial polarization, magnetic domain loss, electron spin loss, internal resonance, hoping electron, conductive loss, and multiple scattering for improved absorption of EMI waves. We determined the electronic properties from the Quantum Espresso (QE) and corresponding results are discussed. The metallic character comes from the d-state of transition metal atoms Fe (II) and Co which are sufficiently large in magnitude in the Fermi level of band structure and density of state (DOS) distribution. Crystallite size in the range of 13.6 to 18.7 nm with surface morphology shows irregular shapes of the particles. For CoFeO3 as MAMs, we found that the reflection loss (RL) is -55 dB (lower than the previous reported -43.2 dB) at 10-11 GHz for a thickness of 8 mm, indicating that this study shows high potential of CoFeO3 as an alternative composite for MAMs applications.

Core/shell structured C/ZnO nanoparticles composites for effective electromagnetic wave absorption

RSC Advances ◽  
2016 ◽  
Vol 6 (8) ◽  
pp. 6467-6474 ◽  
Author(s):  
Meikang Han ◽  
Xiaowei Yin ◽  
Sa Ren ◽  
Wenyan Duan ◽  
Litong Zhang ◽  
...  
Keyword(s):  
Electromagnetic Wave ◽  
Zno Nanoparticles ◽  
High Performance ◽  
Impedance Match ◽  
Core Shell ◽  
Effective Strategy ◽  
Electromagnetic Wave Absorption ◽  
Wave Absorption ◽  
Microwave Absorbing Materials ◽  
Absorbing Materials

Core/shell structured C/ZnO nanoparticles composite exhibits an effective strategy to design high-performance microwave absorbing materials with adjustable impedance match.

scholarly journals Carbonized wood with ordered channels decorated by NiCo2O4 for lightweight and high-performance microwave absorber

2021 ◽  
Vol 11 (1) ◽  
pp. 105-119
Author(s):  
Guangyu Qin ◽  
Xiaoxiao Huang ◽  
Xu Yan ◽  
Yunfei He ◽  
Yuhao Liu ◽  
...  
Keyword(s):  
High Performance ◽  
Low Cost ◽  
Interfacial Polarization ◽  
Growth Direction ◽  
Channel Structure ◽  
Light Weight ◽  
Multiple Reflections ◽  
Element Analysis ◽  
Environmental Friendliness ◽  
Carbonized Wood

AbstractWood-derived carbon has a 3D porous framework composed of through channels along the growth direction, which is a suitable matrix for preparing electromagnetic wave (EMW) absorbing materials with low cost, light weight, and environmental friendliness. Herein, the carbonized wood decorated by short cone-like NiCo2O4 (NiCo2O4@CW) with highly ordered straight-channel architecture was successfully manufactured through a facile calcination procedure. The horizontal arrangement of the through channels of NiCo2O4@CW (H-NiCo2O4@CW) exhibits a strong reflection loss value of -64.0 dB at 10.72 GHz with a thickness of 3.62 mm and a low filling ratio of 26 wt% (with the density of 0.98 g·cm-3), and the effective absorption bandwidth (EAB) is 8.08 GHz (9.92–18.0 GHz) at the thickness of 3.2 mm. The excellent microwave absorption (MA) property was ascribed to the ordered-channel structure with abundant interfaces and defects from NiCo2O4@CW, which could promote the interfacial polarization and dipole polarization. What is more, this advantageous structure increased the multiple reflections and scattering. Finite element analysis (FEA) simulation is carried out to detect the interaction between the prepared material and EMW when the ordered channels are arranged in different directions. This research provides a low-cost, sustainable, and environmentally friendly strategy for using carbonized wood to fabricate microwave absorbers with strong attenuation capabilities and light weight.

Morphology-dependent electromagnetic wave absorbing properties of iron-based absorbers: one-dimensional, two-dimensional, and three-dimensional classification

2019 ◽  
Vol 87 (2) ◽  
pp. 20901 ◽  
Author(s):  
Zehao Zhao ◽  
Zirui Jia ◽  
Hongjing Wu ◽  
Zhenguo Gao ◽  
Yi Zhang ◽  
...  
Keyword(s):  
Electromagnetic Wave ◽  
Electromagnetic Interference ◽  
High Performance ◽  
Low Cost ◽  
Impedance Matching ◽  
Three Dimensional ◽  
Microwave Absorbing Materials ◽  
Dimensional Classification ◽  
Absorbing Materials ◽  
Microwave Absorbing

Owing to the fast development of wireless techniques at the high-frequency range, the electromagnetic interference problem has been of increasing significance and attracting global attention. It is urgent to develop efficient microwave absorbing materials to attenuate the harmful electromagnetic wave. Iron and Fe-based composites are advantageous in the low-cost and attractive magnetic properties, so they have been widely studied in microwave absorption. This review focuses on the latest advances in nanostructured Fe-based materials including nanostructured iron, Fe/C (carbon nanotubes, nanofibers, nanocapsules, etc.), Fe/semiconductor (TiO2, MnO2, ZnO, SiO2, MoS2, etc.), Fe/polymer (polyaniline and polypyrrole), FeCo alloy, etc. However, most of these Fe-based materials suffer from the poor impedance matching and oxidation, which seriously impede their implementation as high-performance microwave absorbing materials. In this review, the main synthesis and modification methods, as well as the practical performance of Fe-based microwave absorbing materials are discussed. Moreover, challenges and perspectives of Fe-based composites for further development in microwave absorbing materials are proposed.

scholarly journals A Flexible Sandwich Structure Carbon Fiber Cloth with Resin Coating Composite Improves Electromagnetic Wave Absorption Performance at Low Frequency

Polymers ◽  
2022 ◽  
Vol 14 (2) ◽  
pp. 233
Author(s):  
Yuanjun Liu ◽  
Qianqian Lu ◽  
Jing Wang ◽  
Xiaoming Zhao
Keyword(s):  
Electromagnetic Wave ◽  
Carbon Fiber ◽  
Reflection Loss ◽  
High Speed ◽  
Control Variable ◽  
Low Frequency ◽  
Interfacial Polarization ◽  
Multiple Reflections ◽  
Carbon Fiber Cloth ◽  
Minimum Reflection Loss

In order to improve the electromagnetic wave absorbing performance of carbon fiber cloth at low frequency and reduce the secondary pollution caused by the shielding mechanism, a flexible sandwich composite was designed by a physical mixing coating process. This was composed of a graphene layer that absorbed waves, a carbon fiber cloth layer that reflected waves, and a graphite layer that absorbed transmitted waves. The influence of the content of graphene was studied by a control variable method on the electromatic and mechanical properties. The structures of defect polarization relaxation and dipole polarization relaxation of graphene, the interfacial polarization and electron polarization of graphite, the conductive network formed in the carbon fiber cloth, and the interfacial polarization of each part, combined together to improve the impedance matching and wave multiple reflections of the material. The study found that the sample with 40% graphene had the most outstanding absorbing performance. The minimum reflection loss value was −18.62 dB, while the frequency was 2.15 GHz and the minimum reflection loss value compared to the sample with no graphene increased 76%. The composites can be mainly applied in the field of flexible electromagnetic protection, such as the preparation of stealth tent, protective covers of electronic boxes, helmet materials for high-speed train drivers, etc.

scholarly journals Magnetic properties of (Bi1−xLax)(Fe,Co)O3 films fabricated by a pulsed DC reactive sputtering and demonstration of magnetization reversal by electric field

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Munusamy Kuppan ◽  
Daichi Yamamoto ◽  
Genta Egawa ◽  
Sivaperuman Kalainathan ◽  
Satoru Yoshimura
Keyword(s):  
Electric Field ◽  
Magnetization Reversal ◽  
High Performance ◽  
Magnetic Domain ◽  
Magnetic Film ◽  
Film Plane ◽  
Force Microscopy ◽  
Domain Structures ◽  
Pulsed Dc ◽  
Submicron Scale

Abstract(Bi1−xLax)(Fe,Co)O3 multiferroic magnetic film were fabricated using pulsed DC (direct current) sputtering technique and demonstrated magnetization reversal by applied electric field. The fabricated (Bi0.41La0.59)(Fe0.75Co0.25)O3 films exhibited hysteresis curves of both ferromagnetic and ferroelectric behavior. The saturated magnetization (Ms) of the multiferroic film was about 70 emu/cm3. The squareness (S) (= remanent magnetization (Mr)/Ms) and coercivity (Hc) of perpendicular to film plane are 0.64 and 4.2 kOe which are larger compared with films in parallel to film plane of 0.5 and 2.5 kOe. The electric and magnetic domain structures of the (Bi0.41La0.59)(Fe0.75Co0.25)O3 film analyzed by electric force microscopy (EFM) and magnetic force microscopy (MFM) were clearly induced with submicron scale by applying a local electric field. This magnetization reversal indicates the future realization of high performance magnetic device with low power consumption.

scholarly journals Interface Engineered Microcellular Magnetic Conductive Polyurethane Nanocomposite Foams for Electromagnetic Interference Shielding

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Guolong Sang ◽  
Pei Xu ◽  
Tong Yan ◽  
Vignesh Murugadoss ◽  
Nithesh Naik ◽  
...  
Keyword(s):  
Electromagnetic Interference ◽  
Magnetic Loss ◽  
Interfacial Polarization ◽  
Conductive Network ◽  
Shielding Effectiveness ◽  
Electromagnetic Interference Shielding ◽  
Multiple Reflections ◽  
Conduction Loss ◽  
Composite Foams ◽  
Emi Se

Abstract Lightweight microcellular polyurethane (TPU)/carbon nanotubes (CNTs)/ nickel-coated CNTs (Ni@CNTs)/polymerizable ionic liquid copolymer (PIL) composite foams are prepared by non-solvent induced phase separation (NIPS). CNTs and Ni@CNTs modified by PIL provide more heterogeneous nucleation sites and inhibit the aggregation and combination of microcellular structure. Compared with TPU/CNTs, the TPU/CNTs/PIL and TPU/CNTs/Ni@CNTs/PIL composite foams with smaller microcellular structures have a high electromagnetic interference shielding effectiveness (EMI SE). The evaporate time regulates the microcellular structure, improves the conductive network of composite foams and reduces the microcellular size, which strengthens the multiple reflections of electromagnetic wave. The TPU/10CNTs/10Ni@CNTs/PIL foam exhibits slightly higher SE values (69.9 dB) compared with TPU/20CNTs/PIL foam (53.3 dB). The highest specific EMI SE of TPU/20CNTs/PIL and TPU/10CNTs/10Ni@CNTs/PIL reaches up to 187.2 and 211.5 dB/(g cm−3), respectively. The polarization losses caused by interfacial polarization between TPU substrates and conductive fillers, conduction loss caused by conductive network of fillers and magnetic loss caused by Ni@CNT synergistically attenuate the microwave energy.

Interfacial polarization-induced high-k polymer dielectric film for high-performance triboelectric devices

Nano Energy ◽  
2021 ◽  
Vol 82 ◽  
pp. 105697
Author(s):  
Minsoo P. Kim ◽  
Chang Won Ahn ◽  
Youngsu Lee ◽  
Kyoungho Kim ◽  
Jonghwa Park ◽  
...  
Keyword(s):  
High Performance ◽  
Dielectric Film ◽  
Interfacial Polarization ◽  
Polymer Dielectric ◽  
High K

scholarly journals Direct Ink Writing of Highly Conductive MXene Frames for Tunable Electromagnetic Interference Shielding and Electromagnetic Wave-Induced Thermochromism

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Xinyu Wu ◽  
Tingxiang Tu ◽  
Yang Dai ◽  
Pingping Tang ◽  
Yu Zhang ◽  
...  
Keyword(s):  
Electromagnetic Wave ◽  
Electromagnetic Interference ◽  
High Performance ◽  
Normal Operation ◽  
List Type ◽  
Emi Shielding ◽  
Electromagnetic Interference Shielding ◽  
Direct Ink Writing ◽  
Aluminum Ions ◽  
Wave Induced

Highlights 3D printing of MXene frames with tunable electromagnetic interference shielding efficiency is demonstrated. Highly conductive MXene frames are reinforced by cross-linking with aluminum ions. Electromagnetic wave is visualized by electromagnetic-thermochromic MXene patterns. Abstract The highly integrated and miniaturized next-generation electronic products call for high-performance electromagnetic interference (EMI) shielding materials to assure the normal operation of their closely assembled components. However, the most current techniques are not adequate for the fabrication of shielding materials with programmable structure and controllable shielding efficiency. Herein, we demonstrate the direct ink writing of robust and highly conductive Ti3C2Tx MXene frames with customizable structures by using MXene/AlOOH inks for tunable EMI shielding and electromagnetic wave-induced thermochromism applications. The as-printed frames are reinforced by immersing in AlCl3/HCl solution to remove the electrically insulating AlOOH nanoparticles, as well as cross-link the MXene sheets and fuse the filament interfaces with aluminum ions. After freeze-drying, the resultant robust and porous MXene frames exhibit tunable EMI shielding efficiencies in the range of 25–80 dB with the highest electrical conductivity of 5323 S m−1. Furthermore, an electromagnetic wave-induced thermochromic MXene pattern is assembled by coating and curing with thermochromic polydimethylsiloxane on a printed MXene pattern, and its color can be changed from blue to red under the high-intensity electromagnetic irradiation. This work demonstrates a direct ink printing of customizable EMI frames and patterns for tuning EMI shielding efficiency and visualizing electromagnetic waves.

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