scholarly journals Application of Iron Oxide Nanomaterials for the Removal of Heavy Metals

2014 ◽  
Vol 2014 ◽  
pp. 1-14 ◽  
Author(s):  
Pragnesh N. Dave ◽  
Lakhan V. Chopda

In the 21st century water polluted by heavy metal is one of the environment problems. Various methods for removal of the heavy metal ions from the water have extensively been studied. Application of iron oxide nanaparticles based nanomaterials for removal of heavy metals is well-known adsorbents for remediation of water. Due to its important physiochemical property, inexpensive method and easy regeneration in the presence of external magnetic field make them more attractive toward water purification. Surface modification strategy of iron oxide nanoparticles is also used for the remediation of water increases the efficiency of iron oxide for the removal of the heavy metal ions from the aqueous system.

2018 ◽  
Vol 77 (10) ◽  
pp. 2355-2368 ◽  
Author(s):  
Khalida Naseem ◽  
Zahoor H. Farooqi ◽  
Muhammad Z. Ur Rehman ◽  
Muhammad A. Ur Rehman ◽  
Robina Begum ◽  
...  

Abstract This review is based on the adsorption characteristics of sorghum (Sorghum bicolor) for removal of heavy metals from aqueous media. Different parameters like pH, temperature of the medium, sorghum concentration, sorghum particle size, contact time, stirring speed and heavy metal concentration control the adsorption efficiency of sorghum biomass for heavy metal ions. Sorghum biomass showed maximum efficiency for removal of heavy metal ions in the pH range of 5 to 6. It is an agricultural waste and is regarded as the cheapest biosorbent, having high adsorption capacity for heavy metals as compared to other reported adsorbents, for the treatment of heavy metal polluted wastewater. Adsorption of heavy metal ions onto sorghum biomass follows pseudo second order kinetics. Best fitted adsorption isotherm models for removal of heavy metal ions on sorghum biomass are Langmuir and Freundlich adsorption isotherm models. Thermodynamic aspects of heavy metal ions adsorption onto sorghum biomass have also been elaborated in this review article. How adsorption efficiency of sorghum biomass can be improved by different physical and chemical treatments in future has also been elaborated. This review article will be highly useful for researchers working in the field of water treatment via biosorption processing. The quantitative demonstrated efficiency of sorghum biomass for various heavy metal ions has also been highlighted in different sections of this review article.


Author(s):  
Eman Noori Ali

One of the contaminants in wastewater is the heavy metals. Treatment of heavy metals is of great importance because they can be harmful and dangerous for human being health. Conventional removal methods used include: ultrafiltration, reverse osmosis, ion exchange, solvent extraction, sedimentation, and chemical precipitation, and each method has some disadvantages besides high costs. In this chapter, Moringa oleifera cake residue, Moringa oleifera press cake, and Moringa oleifera leaves are introduced as a proposed alternative to replace conventional methods for heavy metal ions’ removal. The results of using Moringa oleifera cake residue showed that iron (Fe) was fully removed; copper (Cu) and cadmium (Cd) were successfully removed up to 98% and reduction of lead (Pb) of 82.17%. The heavy metals were successfully reduced using Moringa oleifera press cake. The removal percentage of iron, copper, and chromium reached 69.99%, 88.86%, and 93.73%, respectively. Moringa oleifera leaves were used to remove Cd (II) from synthetic water; the optimization was performed and each parameter was affecting the Cd (II) removal with different percentages, but pH was insignificant. As a conclusion, the Moringa oleifera seeds and leaves can be considered as a promising alternative in water treatment for heavy metal ions removal.


2018 ◽  
Vol 4 (4) ◽  
pp. 487-492 ◽  
Author(s):  
Sheng Deng ◽  
GuangShan Zhang ◽  
Peng Wang

A PAR-functionalized fiber by microwave irradiation has both colorimetric detection and adsorption abilities for heavy metal ions.


2017 ◽  
Vol 788 ◽  
pp. 91-98 ◽  
Author(s):  
Sujit Deshmukh ◽  
Ganeshlenin Kandasamy ◽  
Ravi Kant Upadhyay ◽  
Gourav Bhattacharya ◽  
Debosmita Banerjee ◽  
...  

Molecules ◽  
2020 ◽  
Vol 25 (14) ◽  
pp. 3204
Author(s):  
Jingyun Jing ◽  
Congling Shi

Functionalized Tris[2-(dimethylamino) ethyl] amine (Me6TREN) ligands tethered-Fe3O4@Me6TREN nanoparticles (NPs) with a size of 150 nm were prepared to achieve classified and easy recovery of heavy metal ions in wastewater. The preparation of such NPs related to sequential silane ligand exchange and a following cure and Schiff base reactions for Fe3O4 NPs. Fe3O4@Me6TREN NPs as an effective nano-adsorbent of heavy metals exhibited significant differences in maximum adsorption capacity for Cr(III) (61.4 mg/g), Cu(II) (245.0 mg/g), Pb(II) (5.3 mg/g), and Cd(II) (1136.2 mg/g), in favor of classified removal of heavy metals from wastewater. Furthermore, Fe3O4@Me6TREN NPs can be regenerated by desorbing metal ions from NP surfaces eluted with ethylenediaminetetraacetic acid disodium salt (EDTA-Na2) aqueous, which endows such NPs promising potency as new nano-vectors for the removal of heavy metals.


2021 ◽  
Author(s):  
Süreyya Oğuz Tümay ◽  
Vildan Şanko ◽  
Ahmet Şenocak ◽  
Erhan Demirbaş

The iron oxide nanoparticle-based chemosensors composed of fluorescent components have been recently examined as promising platforms for separation, imaging and especially determination applications for heavy metal ions. Among the heavy...


2021 ◽  
Vol 21 (12) ◽  
pp. 5812-5834
Author(s):  
Rachana Yadwade ◽  
Saili Kirtiwar ◽  
Balaprasad Ankamwar

Bio-fabrication of iron oxide nanoparticles by using different sources of plants, plant parts and microbial cells have become a great topic of interest nowadays due to its eco-friendly nature. The stabilizing and capping agents in biological sources are biocompatible, stable and non-toxic which make its use beneficial for various biomedical applications. The bacteria are able to utilize metal ions and convert them into their respective nanoparticles by secreting different biomolecules. The plants and plant parts contain different types of phytochemicals which play a key role in synthesis and bio-fabrication of nanoparticles. Iron oxide nanoparticles are known to have various applications in the fields of medicine, environment etc. This review summarizes the applications of iron oxide nanoparticles as antimicrobial agent, drug delivery agent, material for removal of heavy metals and dyes from aqueous system etc. Due to these wide applications of iron oxide nanoparticles its demand in various fields is increasing considerably. This review describes different approaches which are used for biosynthesis of iron oxide nanoparticles and their applications. The review also summarizes about the surface modification strategies of iron oxide nanoparticles by using different polymers, polyelectrolytes which can be used for in-vivo applications.


2021 ◽  
Vol 904 (1) ◽  
pp. 012009
Author(s):  
A W Abd Byty ◽  
M A Gharbi ◽  
A H Assaf

Abstract Toxic metal pollutants in groundwater should be identified to prevent future health risks. In this paper, the presence of heavy metals in groundwater in the western region of Iraq was investigated. The heavy metals concentrations, including Ni2+, Co2+, Zn2+, Pb2+, Cr3+, Cd2+, As3+ and Hg2+ were explored in twenty selected aquifers near Rutba City and the results were presented as spatial distribution maps. Findings indicate that contamination with the investigated heavy metal ions possesses a serious threat to the study area’s groundwater quality when compared to WHO and IEPA guideline values. Thus, a new approach to remove or adsorb heavy metal ions can be developed for large-scale production and the safe use of these aquifers water. Results revealed that the highest concentrations in mg/L1 of 2.312 in w19, 1.098 in w2, 5.78 in w17, 0.292 in w9, 3.349 in w5, 0.32 in w13, 0.074 in w11 and 5.622 in w1 for Zn2+, Cr3+, As3+, Pb2+, Ni2+, Co2+, Cd2+ and Hg2+ were recorded, respectively.


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