scholarly journals Effect of Surfactants on Gas Holdup in Shear-Thinning Fluids

2017 ◽  
Vol 2017 ◽  
pp. 1-7 ◽  
Author(s):  
Shaobai Li ◽  
Siyuan Huang ◽  
Jungeng Fan

In this study, the gas holdup of bubble swarms in shear-thinning fluids was experimentally studied at superficial gas velocities ranging from 0.001 to 0.02 m·s−1. Carboxylmethyl cellulose (CMC) solutions of 0.2 wt%, 0.6 wt%, and 1.0 wt% with sodium dodecyl sulfate (SDS) as the surfactant were used as the power-law (liquid phase), and nitrogen was used as the gas phase. Effects of SDS concentration, rheological behavior, and physical properties of the liquid phase and superficial gas velocity on gas holdup were investigated. Results indicated that gas holdup increases with increasing superficial gas velocity and decreasing CMC concentration. Moreover, the addition of SDS in CMC solutions increased gas holdup, and the degree increased with the surfactant concentration. An empirical correlation was proposed for evaluating gas holdup as a function of liquid surface tension, density, effective viscosity, rheological property, superficial gas velocity, and geometric characteristics of bubble columns using the experimental data obtained for the different superficial gas velocities and CMC solution concentrations with different surfactant solutions. These proposed correlations reasonably fitted the experimental data obtained for gas holdup in this system.

2005 ◽  
Vol 70 (12) ◽  
pp. 1533-1544 ◽  
Author(s):  
Ivica Stamenkovic ◽  
Olivera Stamenkovic ◽  
Ivana Bankovic-Ilic ◽  
Miodrag Lazic ◽  
Vlada Veljkovic ◽  
...  

Gas holdup was investigated in a gas-liquid and gas-liquid-solid reciprocating plate column (RPC) under various operation conditions. Aqueous carboxymethyl cellulose (sodium salt, CMC) solutions were used as the liquid phase, the solid phase was spheres placed into interplate spaces, and the gas phase was air. The gas holdup in the RPC was influenced by: the vibration intensity, i.e., the power consumption, the superficial gas velocity, the solids content and the rheological properties of the liquid phase. The gas holdup increased with increasing vibration intensity and superficial gas velocity in both the two- and three-phase system. With increasing concentration of the CMC PP 50 solution (Newtonian fluid), the gas holdup decreased, because the coalescence of the bubbles was favored by the higher liquid viscosity. In the case of the CMC PP 200 solutions (non-Newtonian liquids), the gas holdup depends on the combined influence of the rheological properties of the liquid phase, the vibration intensity and the superficial gas velocity. The gas holdup in the three-phase systems was greater than that in the two-phase ones under the same operating conditions. Increasing the solids content has little influence on the gas holdup. The gas holdup was correlated with the power consumption (either the time-averaged or total power consumption) and the superficial gas velocity.


2009 ◽  
pp. 183-192
Author(s):  
Ivana Sijacki ◽  
Radmilo Colovic ◽  
Milenko Tokic ◽  
Predrag Kojic

Simple empirical correlations were developed to predict gas holdup, liquid circulation time, downcomer liquid velocity and volumetric mass transfer coefficient in dilute alcohol solutions in bubble columns and draft tube airlift reactors with single orifice sparger. Also, new experiments were conducted with diluted alcohol solutions to n-octanol, expanding the experimental data from C1 up to C8. The proposed empirical correlations include, beside the superficial gas velocity, the alcohol chain length as the only factor to characterize the liquid phase. The suggested correlations have shown good agreement between the calculated and the experimental data.


2021 ◽  
Vol 12 (4) ◽  
pp. 5004-5011

The present research investigated the effect of solid properties on the gas holdup of the fluidization bed bubble columns (FBCS). All experiments were performed in the constant clear tap water of 80 cm height. The range of solid particle diameters was 0.7 – 2 mm with two different densities of 1075 and 1200 kg/m3, superficial air velocities 4 – 7 cm/s. It was observed that there are proportional relationships between superficial gas velocity and particle diameter with the gas holdup. While an inverse relationship between solid concentration and particle density with the gas holdup. Mathematical and statistical analysis was also used as a powerful way to represent the gas hold up as a function of different operating conditions.


Author(s):  
Dinesh V. Kalaga ◽  
Vishal Bhusare ◽  
H.J. Pant ◽  
Jyeshtharaj B. Joshi ◽  
Shantanu Roy

Abstract Industrial gas-liquid processes such as oxidation, hydrogenation, Fischer-Trospch synthesis, liquid-phase methanol synthesis, and nuclear fission are exothermic in nature; the reactor of choice for such processes is, therefore, a bubble column equipped with heat exchanging internals. In addition to maintaining the desired process temperature, the heat exchanging vertical tube internals are used to control flow structures and liquid back mixing. The present work reports the experimentally measured gas hold-up, mean liquid velocity and liquid phase turbulent kinetic energy, using the Radioactive Particle Tracking (RPT) technique, in a 120 mm diameter bubble column equipped with dense vertical tube internals covering 23 % of the total cross-sectional area of the column. The effect of superficial gas velocity (44–265 mm/s) on gas hold-up, mean liquid velocity and turbulent kinetic energy is presented and discussed. It has been inferred from the experimental results that the vertical tube internal located at the center of the column plays a vital role in affecting the hydrodynamics when compared to the conventional internal configurations reported in the literature. For the chosen dense internal configuration, the cross-sectional distribution of the gas holdup, mean liquid velocity and turbulent kinetic energy show asymmetry for all the superficial gas velocities investigated. The overall gas holdup and the liquid turbulence increases with an increase in the superficial gas velocity. The strong liquid circulation velocities have been seen upon the insertion of the dense internals.


Author(s):  
Arsam Behkish ◽  
Romain Lemoine ◽  
Laurent Sehabiague ◽  
Rachid Oukaci ◽  
Badie I Morsi

The total gas holdup and the holdup of large gas bubbles were predicted in bubble column reactors (BCRs) and slurry bubble column rectors (SBCRs) using two Back-Propagation Neural Networks (BPNNs). Over 3880 and 1425 data points for gas holdup and Large gas bubble holdup respectively, covering wide ranges of gas-liquid-solid physical properties, operating variables, reactor geometry, and gas sparger type/size, were employed to develop, train and validate the two neural networks. The developed BPNN for gas holdup has a topology of [14,9-7,1] and was able to predict the trained and untrained data with an average absolute relative error (AARE), standard deviation, and regression coefficient (R2) of 16, 19 and 90%, respectively. The developed BPNN for large gas bubble holdup has a topology of [14,8,1] and was capable of predicting the trained and untrained data with AARE, standard deviation, and R2 of 10, 14 and 93%, respectively. The BPNNs were then used to predict the effects of pressure, superficial gas velocity, temperature and catalyst loading on the total syngas holdup for Low-Temperature Fischer-Tropsch (LTFT) synthesis carried out in a 5 m ID SBCR. The predicted total syngas holdup appeared to increase with increasing reactor pressure, superficial gas velocity and the number of orifices in the gas sparger. The predicted syngas holdup, however, was found to decrease with increasing catalyst loading and reactor temperature. Also, under similar LTFT operating conditions (P = 3 MPa, T = 513 K, CW = 30 and 50 wt%), the total syngas holdup values predicted for H2/CO ratio of 2:1 and cobalt-based catalyst are consistently lower than those obtained for H2/CO ratio of 1:1 and iron oxide catalyst in the superficial gas velocity range from 0.005 to 0.4 m/s. These predictions are in perfect agreement with reported literature trends, which underscore the reliability and validity of the developed BPNNs in predicting the total syngas holdup and the holdup of large gas bubbles in large-scale bubble columns and SBCRs operating under industrial conditions.


Energies ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4329
Author(s):  
Radek Šulc ◽  
Jan Dymák

The gas–liquid hydrodynamics and mass transfer were studied in a concentric tube internal jet-loop airlift reactor with a conical bottom. Comparing with a standard design, the gas separator was equipped with an adjustable deflector placed above the riser. The effect of riser superficial gas velocity uSGR on the total gas holdup εGT, homogenization time tH, and overall volumetric liquid-phase mass transfer coefficient kLa was investigated in a laboratory bioreactor, of 300 mm in inner diameter, in a two-phase air–water system and three-phase air–water–PVC–particle system with the volumetric solid fraction of 1% for various deflector clearances. The airlift was operated in the range of riser superficial gas velocity from 0.011 to 0.045 m/s. For the gas–liquid system, when reducing the deflector clearance, the total gas holdup decreased, the homogenization time increased twice compared to the highest deflector clearance tested, and the overall volumetric mass transfer coefficient slightly increased by 10–17%. The presence of a solid phase shortened the homogenization time, especially for lower uSGR and deflector clearance, and reduced the mass transfer coefficient by 15–35%. Compared to the gas–liquid system, the noticeable effect of deflector clearance was found for the kLa coefficient, which was found approx. 20–29% higher for the lowest tested deflector clearance.


Author(s):  
Chunxi Lu ◽  
Nana Qi ◽  
Kai Zhang ◽  
Jiaqi Jin ◽  
Hu Zhang

An external liquid circulation is introduced into a traditional internal loop reactor in order to improve liquid circulation and increase the interface between gas and liquid phases. The effects of superficial gas velocity and external liquid circulation velocity on local and overall gas holdups are explored experimentally and numerically in the loop section of a combined gas-liquid contactor, which consists of a liquid spray, sieve plates and an internal loop with external liquid circulation. Local gas holdup is measured experimentally by a double-sensor conductivity probe. Numerical simulations are conducted in the platform of a commercial software package, ANSYS CFX 10.0. Gas holdup and other information are obtained by solving the governing equations of mass and momentum balances for gas and liquid phases in a hybrid mesh system. Both measured and simulated results indicate that local, section-averaged, and overall gas holdups increase with an increase of the superficial gas velocity. The downcomer tube for circulating external liquid has a significant influence in the gas-distributor and the downcomer-tube action regions rather than in the upper draft-tube and the gas-liquid separation regions. Good agreement between measured and predicted data suggests that CFD simulation together with experimental investigation can be employed to develop novel gas-liquid contactors with a complex geometrical configuration.


2008 ◽  
Vol 41 (7) ◽  
pp. 578-584 ◽  
Author(s):  
Katsumi Nakao ◽  
Keiji Furumoto ◽  
Fumio Azakami ◽  
Toru Hasuoka ◽  
Tetsuya Imura ◽  
...  

Author(s):  
Xi Zhang ◽  
Ping Zhu ◽  
Shuaichao Li ◽  
Wenyuan Fan ◽  
Jingyan Lian

Abstract A numerical simulation was performed to study the hydrodynamics of micro-bubble swarm in bubble column with polyacrylamide (PAM) aqueous solution by using computational fluid dynamics coupled with population balance models (CFD-PBM). By considering rheological characteristics of fluid, this approach was able to accurately predict the features of bubble swarm, and validated by comparing with the experimental results. The gas holdup, turbulent kinetic energy and liquid velocity of bubble column have been elucidated by considering the influences of superficial gas velocity and gas distributor size respectively. The results show that with the rise of the superficial gas velocity, the gas holdup and its peak width increase significantly. Especially, the curve peak corresponding to high gas velocity tends to drift obviously toward the right side. Except for the occurrence of a smooth holdup peak at the column center under the condition of the moderate distributor size, the gas holdups for the small and large distributor sizes become flat in the radial direction respectively. The distribution of turbulent kinetic energy presents an increasingly asymmetrical feature in the radial direction and also its variation amplitude enhances obviously with the rise of gas velocity. The increase in gas distributor size can enhance markedly turbulent kinetic energy as well as its overall influenced width. At the low and moderate superficial gas velocity, the curves of the liquid velocity in radial direction present the Gaussian distributions, whereas the perfect distribution always is broken in the symmetry for high gas velocity. Both liquid velocities around the bubble column center and the ones near both column walls go up consistently with the gas distributor size, especially near the walls at the large distributor size condition.


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