scholarly journals Research on the Properties of Low Temperature and Anti-UV of Asphalt with Nano-ZnO/Nano-TiO2/Copolymer SBS Composite Modified in High-Altitude Areas

2020 ◽  
Vol 2020 ◽  
pp. 1-15 ◽  
Author(s):  
Xiangbing Xie ◽  
Tao Hui ◽  
Yaofei Luo ◽  
Han Li ◽  
Guanghui Li ◽  
...  

Strong ultraviolet light and low-temperature are the typical environmental characteristics in high-altitude areas. The performance of SBS-modified asphalt in the above environmental characteristics needs further study. To improve the resistance ultraviolet (UV) ageing and low-temperature performance of copolymer- (SBS-) modified asphalt, an SBS-modified asphalt containing nano-ZnO and nano-TiO2 is proposed. In this paper, nano-ZnO, nano-TiO2, and SBS were used as modifiers with the silane coupling agent (KH-560) as the nanomaterial surface modification. The orthogonal test table was used to analyse the effects of the three modifiers on the physical properties of modified asphalt at different dosages. On this basis, the physical properties, low-temperature properties, and ageing indices (carbonyl index and sulfoxide index) were studied for base asphalt, SBS-modified asphalt, nano-ZnO/SBS-modified asphalt, and nano-ZnO/nano-TiO2/SBS composite-modified asphalt before and after photoaging. The content changes of characteristic elements (Zn and Ti) in the nano-ZnO/nano-TiO2/SBS composite-modified asphalt before and after ageing were studied by scanning electron microscopy with energy dispersive spectroscopy (SEM/EDS), and the UV ageing mechanism was revealed. The results indicate that two nanoparticles show the best compatibility with asphalt after surface modification and can improve the binding ability between SBS and base asphalt. The orthogonal test analysis shows that nano-ZnO has a highly significant effect on the low- and high-temperature performance of the nano-ZnO/nano-TiO2/SBS composite-modified asphalt, and nano-TiO2 has a significant effect on the high-temperature performance. Three optimal composite-modified systems for base asphalt including 4% nano-ZnO/1.5% nano-TiO2/3.2% SBS were proposed and had the best antiaging ability. Compared with the sulfoxide index, the carbonyl index changed most obviously before and after ageing. Additionally, the results reveal that nano-TiO2 has a good absorption effect at a wavelength of 365 nm (ultraviolet light), while nano-ZnO is liable to photolysis, and its activity decreases at this wavelength.

2013 ◽  
Vol 753-755 ◽  
pp. 734-740 ◽  
Author(s):  
Li Wan ◽  
Shao Peng Wu ◽  
Min Lei ◽  
Kim Jenkins

Currently, rejuvenator seal which is one of the preventive maintenance methods is more widely used due to its economic benefits and convenience. This paper described the chemical and rheological evaluation of the aged styrene butadiene styrene modified asphalt (ASMA) treated by two rejuvenator sealer materials (RSMs). First the ASMA was rejuvenated by mixing with the RSMs. Then the ASMA and two rejuvenated binders were re-aged by 10h PAV test. At last, the new binder, ASMA, rejuvenated ASMAs, re-aged binders were tested by Dynamic shear rheometer (DSR) and Fourier Transform Infrared Spectroscopy (FTIR). The results showed that the first aging of the new binder had a significant decrease of the low temperature performance and slight improvement of the high temperature performance. In addition, the high temperature performance increased obviously after 10h PAV test. Two RSMs could significantly soften the aged binder due to increase of maltene content existing in the RSMs, and the rejuvenated binder exhibited a better low performance after the 10h PAV test. However they cannot restore the low temperature completely because that RSMs cannot remedy the degradation of SBS modifier and remove the carbonyl produced in the aging progress.


Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 771
Author(s):  
Yu Sun ◽  
Dongpo He

The mixture of styreneic methyl copolymers (SMCs) normal temperature-modified asphalt and styrene-butadiene styrene block copolymer (SBS)-modified asphalt (SMCSBS) compound-modified asphalt was investigated in this study. The viscosity and temperature properties of compound modified asphalt (SMCSBS) were studied by Brookfield rotary viscosity test. Dynamic shear rheometer (DSR) and bending beam rheometer (BBR) were used to test SMCSBS compound modified asphalt with different SMC additions. Finally, the microstructure and physicochemical properties of SMCSBS were evaluated by scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR), and the modification mechanism of the SMCSBS was studied. The results show that the viscosity of the compound-modified asphalt added with SMC is improved, which is conducive to improving its workability. With the increase of SMC content, the high-temperature performance of the compound modified asphalt firstly increases and then decreases with the increase of SMC content. When the content of SMC is 12%, its high-temperature performance is the best. Compared with SBS-modified asphalt, the SMCSBS has better low-temperature performance, and the creep stiffness S and creep rate m of the SMC with different content are better than that of SBS. Finally, the microcosmic characteristics show that the SMC can give full play to its characteristics and can be uniformly dispersed in SBS modified asphalt. SMC is essentially a surfactant, which can reduce the viscosity and construction temperature by changing the surface tension and surface free energy of asphalt molecules. The curing agent of epoxy resin is slowly cross-linked and cured after contacting with air to form a certain strength, thus improving the road performance of the asphalt mixture.


2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Guangyuan Wu ◽  
Haitao Zhang ◽  
Junfeng Sun ◽  
Tengjiang Yu

Purpose In order to evaluate the rheological properties of asphalt more comprehensively and effectively, and to explore and discuss the practicability of relevant models in the evaluation of the rheological properties of asphalt. Design/methodology/approach Based on the rheological and viscoelastic theories, temperature scanning, frequency scanning and multiple stress creep recovery (MSCR) tests of different modified asphalt were carried out by dynamic shear rheometer (DSR) to obtain relevant viscoelastic parameters and evaluate the high temperature properties of different modified asphalt. Based on the time-temperature equivalence principle, the main curve was constructed to study the viscoelastic properties of asphalt in a wider frequency domain. The main curve was fitted with the CAM model, and the rheological properties of different modified asphalt were evaluated through the analysis of model parameters. The creep stiffness and creep velocity of different modified asphalt were obtained through the rheological test of bending beam (BBR), and the low-temperature performance of different modified asphalt was analyzed by using Burgers model to fit the creep compliance. Findings The results show that the high temperature rheological properties of several modified asphalt studied in the test are ranked from best to worst as follows: PE modified asphalt > SBS modified asphalt > SBR modified asphalt. Short-term aging can improve the high temperature performance of asphalt, and different types of modifiers can promote or inhibit this improvement effect. Based on BBR test and Burgers model fitting analysis, SBR modified asphalt has the best low temperature performance, followed by SBS modified asphalt, while PE modified asphalt has poor low temperature performance, so it is not suitable to be used as road material in low temperature area. Originality/value Combined with effective evaluation methods, the rheological properties of asphalt at different temperatures and angles were systematically evaluated, and the evolution of rheological properties of asphalt characterized by model parameters was further analyzed by advanced model simulation.


2014 ◽  
Vol 575 ◽  
pp. 238-244 ◽  
Author(s):  
Ji Wei Han ◽  
Ya Nan Cui ◽  
Zhen Li ◽  
Chao Li ◽  
Zhen Zheng Liu

About more than 90% highway have adopted asphalt concrete pavement in China. A lot of quality problems appeared in the highway pavement due to freezing-thawing circulations under the condition of low temperature. The scanning electron microscope (SEM) was utilized to observe the microstructure of styrene-butadiene-styrene (SBS) modified asphalt and rubber powder modified asphalt before and after the salt freezing. Also three routine indicators (penetration, softening point and ductility) for the two kinds of asphalt were tested before and after the salt freezing. The analysis results showed that the temperature susceptibility of SBS modified asphalt and rubber powder modified asphalt were all increased and the high temperature performance and low temperature performance of both asphalt were reduced after the salt freezing cycles as the same time the performance of rubber modified asphalt after salt freezing cycle was superior to SBS modified asphalt by comparing the basic indicators of them.


2014 ◽  
Vol 1079-1080 ◽  
pp. 152-155
Author(s):  
Yuan Yuan Wang ◽  
Lu Sun

Using the waste pavement materials can not only save resources such as bitumen and aggregate, but also reduce the pollution of environment. In this study, the high temperature performance and the moisture stability of recycled SBS modified asphalt mixture were evaluated by rutting test, immersion Marshall Test and freeze-thaw splitting routine test. In addition, the low temperature performance of recycled modified mixture was also analyzed by Fénix test whose operation was simple. The tests results illustrated that it was advantageous to improve the high temperature performance of recycled mixture and it has less influence on moisture stability with the addition of RAP. However, it had a significant adverse effect on the low temperature performance for recycled SBS modified asphalt mixture with a large quantity of RAP content. Therefore, it suggests that the RAP content for recycled SBS modified mixture is not too high.


2013 ◽  
Vol 477-478 ◽  
pp. 1175-1178
Author(s):  
Ling Zou ◽  
Jing Wei Ne ◽  
Weng Gang Zhang

70# and 90# matrix asphalt mixture with MaR were studied through dynamic modulus test, rutting test, freeze-thaw splitting test, bending test to study the applicability of the Modifying agent of rubber plastic compound (MaR) in matrix asphalt mixture.Test results were Compared with SBSI-C modified asphalt mixture.The results indicate that: high-temperature stability of MaR+70# asphalt mixture is as well as SBSI-C modified asphalt mixture,and is bettere than MaR+90# asphalt mixture; water stability of MaR+90# asphalt mixture is bettere than SBSI-C modified asphalt mixture and MaR+70# asphalt mixture; low temperature performance of MaR+90# asphalt mixture is bettere than MaR+70# asphalt mixture, but is worse than modified asphalt mixture SBSI-C ; MaR+70# asphalt mixture can be first used in area of resisting high temperature and rutting, MaR+90# asphalt mixture can be used if the water stability performance and low temperature performance are considered.


2014 ◽  
Vol 505-506 ◽  
pp. 260-264
Author(s):  
Bai Lin Wang ◽  
Min Nan Zheng ◽  
Jie Zhang ◽  
Jiu Guang Geng

SBS modified asphalt has good performance of high temperature and low temperature, it is widely used in high-grade asphalt pavement engineering. But the aging will influence the using performance of asphalt, we select four dosages of modifier and aging for different time, Experimental results show that with the increase of aging time, asphalt penetration is reduced, softening point is elevated, ductility is decreased. According to the macro physical index analysis, find that SBS modified asphalt’s anti-aging performance is improved.


2014 ◽  
Vol 599 ◽  
pp. 282-286 ◽  
Author(s):  
Chun Gang Zhang ◽  
Yan Jun Xie ◽  
Lin Chun Meng ◽  
Qin Yong Li

This paper investigated into the application of fiber-enhanced asphalt mixture in surface layer of the large longitudinal slope pavement of Xi-Sang Highway. Asphalt mixture with and without polyester fiber were used. Focus is on resistance of deformation at high temperature and flexibility at low temperature. Fiber-enhanced asphalt mixture with dynamic stability above 7000 passes/mm indicated excellent rutting resistance. The high temperature dynamic modulus of fiber-enhanced asphalt mixture was much higher than conventional SBS modified asphalt mixture. Three-point blending test result indicated that the maximum flexural strain of fiber-enhance asphalt mixture reached 4180μm/m. It was concluded that fiber-enhanced asphalt mixture was suit to be used in surface layer of the large longitudinal slope pavement of Xi-Sang Highway.


2021 ◽  
Vol 293 ◽  
pp. 02029
Author(s):  
Tang-Baoli ◽  
Ren-yongqiang ◽  
Chen-Xiangmei ◽  
Hou-Huifang ◽  
Liang-Jianping

In order to study the high temperature performance of LM-S modified asphalt mixture and SBS modified asphalt mixture, repeated loading creep test was used to study the influence of temperature and deviatoric stress on the axial permanent deformation of the two kinds of asphalt mixture. At the same time, Permanent deformation, ε@5000, flow number FN and creep rate were select to evaluation of high temperature performance from different directions. The results show that the ε@5000 and creep rate are failed in the condition of high temperature and large deviatoric stress, so it hast widely practicable. The flow number FN is also limited by the conditions, which leads to the distortion of the flow number at lower temperature and smaller deviatoric stress so it is not easy to direct used as the evaluation index. Axial permanent deformation can reflect the permanent deformation in different cycles which is an excellent index to evaluate the high temperature performance of the two kinds of asphalt mixture, it is recommended to use axial permanent deformation to compare the LM-S modified asphalt mixture and SBS modified asphalt mixture The experimental results show that the axial permanent deformation of the LM-S modified asphalt mixture is always less than that of SBS modified asphalt mixture,it indicating that the high temperature rutting resistance of the LM-S modified asphalt mixture is better than that of SBS modified asphalt mixture.


Materials ◽  
2021 ◽  
Vol 14 (17) ◽  
pp. 4910
Author(s):  
Ping Zhang ◽  
Lan Ouyang ◽  
Lvzhen Yang ◽  
Yi Yang ◽  
Guofeng Lu ◽  
...  

As environmentally friendly materials, carbon black and bio-oil can be used as modifiers to effectively enhance the poor high-temperature and low-temperature performance of base asphalt and its mixture. Different carbon black and bio-oil contents and shear time were selected as the test influencing factors in this work. Based on the Box–Behnken design (BBD), carbon black/bio-oil composite modified asphalt was prepared to perform the softening point, penetration, multiple stress creep and recovery (MSCR), and bending beam rheometer (BBR) tests. The response surface method (RSM) was used to analyze the test results. In addition, the base asphalt mixtures and the optimal performance carbon black/bio-oil composite modified asphalt mixtures were formed for rutting and low-temperature splitting tests. The results show that incorporating carbon black can enhance the asphalt’s high-temperature performance by the test results of irrecoverable creep compliance (Jnr) and strain recovery rate (R). By contrast, the stiffness modulus (S) and creep rate (M) test results show that bio-oil can enhance the asphalt’s low-temperature performance. The quadratic function models between the performance indicators of carbon black/bio-oil composite modified asphalt and the test influencing factors were established based on the RSM. The optimal performance modified asphalt mixture’s carbon black and bio-oil content was 15.05% and 9.631%, and the shear time was 62.667 min. It was revealed that the high-temperature stability and low-temperature crack resistance of the carbon black/bio-oil composite modified asphalt mixture were better than that of the base asphalt mixture because of its higher dynamic stability (DS) and toughness. Therefore, carbon black/bio-oil composite modified asphalt mixture can be used as a new type of choice for road construction materials, which is in line with green development.


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