Air temperature is one of the most fundamental of all meteorological measurements and directly effects our everyday lives. It has been measured for centuries, using countless different techniques. One might assume that accurate air temperature measurements are readily made. Indeed, it is possible to make very accurate air temperature measurements but it can be a remarkably hard task, especially when limitations such as power consumption, reliability, and cost are involved. Errors in the measurement of air temperature in excess of 2 to 3°C are not uncommon in many networks. Errors of this magnitude are generally acceptable for the general public who is most interested in what clothes to wear for the day. However, numerical models at all scales of motion (mesoscale, synoptic scale, or climate models) are greatly affected by errors even as large as 1°C. Errors of just 1°C in a mesoscale model have been shown to be the deciding factor between no storms initiated and intense storms (Crook, 1996). In addition, errors as small as 0.2°C can change the prediction of a global climate model, depending on its dependency on initial conditions (DeFelice, 1998). Measurement of air temperature near the surface of the earth is facilitated by the vast array of temperature sensors and supporting electronic modules that are readily available. Accuracy is limited not by technology but by our ability to use it and by our ability to avoid exposure error, that is, to provide adequate coupling with the atmosphere. The preferred temperature scales are Celsius and Kelvin. These scales can be used almost interchangeably (except when absolute temperature is required) because a temperature difference of 1 K is equal to a temperature difference of 1°C. The Fahrenheit scale is still in general use by the U.S. public. Some common temperature reference points are shown in table 4-1. The triple point of water is the temperature and pressure where all three phases, gas, liquid, and solid, can coexist. Temperature sensors can be categorized according to the physical principle that they use: thermal expansion, thermoelectric, electrical resistance, electrical capacitance and some other effects.