Investigation of the Cross-Section Stratifications of Icons Using Micro-Raman and Micro-Fourier Transform Infrared (FT-IR) Spectroscopy

2018 ◽  
Vol 72 (8) ◽  
pp. 1258-1271 ◽  
Author(s):  
Dimitra Lazidou ◽  
Dimitrios Lampakis ◽  
Ioannis Karapanagiotis ◽  
Costas Panayiotou
Keyword(s):  
Raman Spectroscopy ◽  
Fourier Transform ◽  
Cross Section ◽  
Cross Sections ◽  
Lead White ◽  
Chrome Yellow ◽  
Micro Raman Spectroscopy ◽  
Ft Ir ◽  
The Cross ◽  
Ft Ir Spectroscopy

The cross-section stratifications of samples, which were removed from six icons, are studied using optical microscopy, micro-Raman spectroscopy, and micro-Fourier transform infrared (FT-IR) spectroscopy. The icons, dated from the 14th to 19th centuries, are prominent examples of Byzantine painting art and are attributed to different artistic workshops of ​​northern Greece. The following materials are identified in the cross-sections of the icon samples using micro-Raman spectroscopy: anhydrite; calcite; carbon black; chrome yellow; cinnabar; gypsum; lead white; minium; orpiment; Prussian blue; red ochre; yellow ochre; and a paint of organic origin which can be either indigo ( Indigofera tinctoria L. and others) or woad ( Isatis tinctoria L.). The same samples are investigated using micro-FT-IR which leads to the following identifications: calcite; calcium oxalates; chrome yellow; gypsum; kaolinite; lead carboxylates; lead sulfate (or quartz); lead white; oil; protein; Prussian blue; saponified oil; shellac; silica; and tree resin. The study of the cross-sections of the icon samples reveals the combinations of the aforementioned inorganic and organic materials. Although the icons span over a long period of six centuries, the same stratification comprising gypsum ground layer, paint layers prepared by modified “egg tempera” techniques (proteinaceous materials mixed with oil and resins), and varnish layer is revealed in the investigated samples. Moreover, the presence of three layers of varnishes, one at the top and other two as intermediate layers, in the cross-section analysis of a sample from Virgin and Child provide evidence of later interventions.

scholarly journals Spectroscopic investigation of two Serbian icons painted on canvas

2015 ◽  
Vol 80 (6) ◽  
pp. 805-817 ◽  
Author(s):  
Ljiljana Damjanovic ◽  
Olgica Marjanovic ◽  
Milica Maric-Stojanovic ◽  
Velibor Andric ◽  
Ubavka Mioc
Keyword(s):  
Raman Spectroscopy ◽  
Fourier Transform ◽  
Linseed Oil ◽  
Orthodox Church ◽  
Lead White ◽  
X Ray ◽  
Micro Raman Spectroscopy ◽  
Green Earth ◽  
Materials Used ◽  
Different Parts

Multianalytical study of two Serbian icons, ?The Virgin and Child? and ?St. Petka?, painted on canvas by unknown authors was performed in order to identify materials used as pigments, binders and ground layer. Investigated icons belong to the Museum of the Serbian Orthodox Church in Belgrade. Samples, collected from different parts of the icons, were analysed by: optical microscopy (OM), energy dispersive X-Ray fluorescence (EDXRF), Fourier transform infrared (FTIR) and micro-Raman spectroscopy. Obtained results reveal presence of the following pigments: Prussian blue, ultramarine, green earth, iron oxides, lead white and zinc white. Linseed oil was used as a binder. Materials used for ground layers were gypsum, calcite, baryte and lead white. Gilded surface of the icon ?The Virgin and Child? was made of gold. Gilded surface on the frame of this icon was made of imitation of gold i.e. Schlagmetal, since EDXRF spectroscopy showed presence of copper and zinc, while gold was not detected. Based on style and art historian consideration as well as on obtained results for corresponding pigments and binder both icons were the most probably made at the end of 19th or beginning of the 20th century.

scholarly journals Investigating Antibacterial Effects of Garlic (Allium sativum) Concentrate and Garlic-Derived Organosulfur Compounds on Campylobacter jejuni by Using Fourier Transform Infrared Spectroscopy, Raman Spectroscopy, and Electron Microscopy

2011 ◽  
Vol 77 (15) ◽  
pp. 5257-5269 ◽  
Author(s):  
Xiaonan Lu ◽  
Barbara A. Rasco ◽  
Jamie M. F. Jabal ◽  
D. Eric Aston ◽  
Mengshi Lin ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Raman Spectroscopy ◽  
Fourier Transform ◽  
Ir Spectroscopy ◽  
Campylobacter Jejuni ◽  
Cell Injury ◽  
Organosulfur Compounds ◽  
Content Type ◽  
Ft Ir ◽  
Ft Ir Spectroscopy

ABSTRACTFourier transform infrared (FT-IR) spectroscopy and Raman spectroscopy were used to study the cell injury and inactivation ofCampylobacter jejunifrom exposure to antioxidants from garlic.C. jejuniwas treated with various concentrations of garlic concentrate and garlic-derived organosulfur compounds in growth media and saline at 4, 22, and 35°C. The antimicrobial activities of the diallyl sulfides increased with the number of sulfur atoms (diallyl sulfide < diallyl disulfide < diallyl trisulfide). FT-IR spectroscopy confirmed that organosulfur compounds are responsible for the substantial antimicrobial activity of garlic, much greater than those of garlic phenolic compounds, as indicated by changes in the spectral features of proteins, lipids, and polysaccharides in the bacterial cell membranes. Confocal Raman microscopy (532-nm-gold-particle substrate) and Raman mapping of a single bacterium confirmed the intracellular uptake of sulfur and phenolic components. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were employed to verify cell damage. Principal-component analysis (PCA), discriminant function analysis (DFA), and soft independent modeling of class analogs (SIMCA) were performed, and results were cross validated to differentiate bacteria based upon the degree of cell injury. Partial least-squares regression (PLSR) was employed to quantify and predict actual numbers of healthy and injured bacterial cells remaining following treatment. PLSR-based loading plots were investigated to further verify the changes in the cell membrane ofC. jejunitreated with organosulfur compounds. We demonstrated that bacterial injury and inactivation could be accurately investigated by complementary infrared and Raman spectroscopies using a chemical-based, “whole-organism fingerprint” with the aid of chemometrics and electron microscopy.

Experimental Studies Of Multilayer Glass Structures On Compression, Compression With Bending And Simple Bending

2019 ◽  
pp. 22-30
Keyword(s):  
Cross Section ◽  
Cross Sections ◽  
Applied Load ◽  
Experimental Studies ◽  
Strength Properties ◽  
Research Topic ◽  
Normative Values ◽  
Laminated Glass ◽  
The Cross ◽  
Experimental Values

The work of multilayer glass structures for central and eccentric compression and bending are considered. The substantiation of the chosen research topic is made. The description and features of laminated glass for the structures investigated, their characteristics are presented. The analysis of the results obtained when testing for compression, compression with bending, simple bending of models of columns, beams, samples of laminated glass was made. Overview of the types and nature of destruction of the models are presented, diagrams of material operation are constructed, average values of the resistance of the cross-sections of samples are obtained, the table of destructive loads is generated. The need for development of a set of rules and guidelines for the design of glass structures, including laminated glass, for bearing elements, as well as standards for testing, rules for assessing the strength, stiffness, crack resistance and methods for determining the strength of control samples is emphasized. It is established that the strength properties of glass depend on the type of applied load and vary widely, and significantly lower than the corresponding normative values of the strength of heat-strengthened glass. The effect of the connecting polymeric material and manufacturing technology of laminated glass on the strength of the structure is also shown. The experimental values of the elastic modulus are different in different directions of the cross section and in the direction perpendicular to the glass layers are two times less than along the glass layers.

scholarly journals Total cross sections of eγ → $$ eX\overline{X} $$ processes with X = μ, γ, e via multiloop methods

2021 ◽  
Vol 2021 (1) ◽  
Author(s):  
Roman N. Lee ◽  
Alexey A. Lyubyakin ◽  
Vyacheslav A. Stotsky
Keyword(s):  
Cross Section ◽  
Cross Sections ◽  
Elliptic Integral ◽  
High Energy ◽  
Calculation Methods ◽  
Complete Elliptic Integral ◽  
Total Cross Sections ◽  
Multiloop Calculation ◽  
The Cross ◽  
Analytical Expressions

Abstract Using modern multiloop calculation methods, we derive the analytical expressions for the total cross sections of the processes e−γ →$$ {e}^{-}X\overline{X} $$ e − X X ¯ with X = μ, γ or e at arbitrary energies. For the first two processes our results are expressed via classical polylogarithms. The cross section of e−γ → e−e−e+ is represented as a one-fold integral of complete elliptic integral K and logarithms. Using our results, we calculate the threshold and high-energy asymptotics and compare them with available results.

scholarly journals Asymptotic Behavior of Stable Structures Made of Beams

2021 ◽  
Author(s):  
Georges Griso ◽  
Larysa Khilkova ◽  
Julia Orlik ◽  
Olena Sivak
Keyword(s):  
Asymptotic Behavior ◽  
Cross Section ◽  
Cross Sections ◽  
Linear Elasticity ◽  
Circular Cross Section ◽  
Linear Elasticity Theory ◽  
Linear Elastic ◽  
The Cross ◽  
Small Rotation ◽  
Stable Structures

AbstractIn this paper, we study the asymptotic behavior of an $\varepsilon $ ε -periodic 3D stable structure made of beams of circular cross-section of radius $r$ r when the periodicity parameter $\varepsilon $ ε and the ratio ${r/\varepsilon }$ r / ε simultaneously tend to 0. The analysis is performed within the frame of linear elasticity theory and it is based on the known decomposition of the beam displacements into a beam centerline displacement, a small rotation of the cross-sections and a warping (the deformation of the cross-sections). This decomposition allows to obtain Korn type inequalities. We introduce two unfolding operators, one for the homogenization of the set of beam centerlines and another for the dimension reduction of the beams. The limit homogenized problem is still a linear elastic, second order PDE.

ISOSPIN DECOMPOSITION OF pp → NNππ CROSS SECTIONS — DO WE SEE A SIGN OF Δ(1600) EXCITATION IN THE nnπ+π+ CHANNEL?

2009 ◽  
Vol 24 (02n03) ◽  
pp. 450-453
Author(s):  
◽  
T. SKORODKO ◽  
M. BASHKANOV ◽  
D. BOGOSLOWSKY ◽  
H. CALÉN ◽  
...  
Keyword(s):  
Cross Section ◽  
Cross Sections ◽  
Differential Cross ◽  
Pion Production ◽  
Significant Contribution ◽  
Differential Cross Sections ◽  
Pp Collisions ◽  
Theoretical Predictions ◽  
Order Of Magnitude ◽  
The Cross

The two-pion production in pp-collisions has been investigated in exclusive measurements from threshold up to Tp = 1.36 GeV . Total and differential cross sections have been obtained for the channels pnπ+π0, ppπ+π-, ppπ0π0 and also nnπ+π+. For intermediate incident energies Tp > 1 GeV , i.e. in the region, which is beyond the Roper excitation but at the onset of ΔΔ excitation the total ppπ0π0 cross section falls behind theoretical predictions by as much as an order of magnitude near 1.2 GeV, whereas the nnπ+π+ cross section is a factor of five larger than predicted. A model-unconstrained isospin decompostion of the cross section points to a significant contribution of an isospin 3/2 resonance other than the Δ(1232). As a possible candidate the Δ(1600) is discussed.

scholarly journals The Cross Section for the J = 0 → 2 Rotational Excitation of Hydrogen by Slow Electrons

1969 ◽  
Vol 22 (6) ◽  
pp. 715 ◽  
Author(s):  
RW Crompton ◽  
DK Gibson ◽  
AI McIntosh
Keyword(s):  
Momentum Transfer ◽  
Cross Section ◽  
Cross Sections ◽  
Vibrational Excitation ◽  
The Cross ◽  
Excitation Processes ◽  
Slow Electrons ◽  
And Diffusion ◽  
Momentum Transfer Cross Section ◽  
Section Analysis

The results of electron drift and diffusion measurements in parahydrogen have been analysed to determine the cross sections for momentum transfer and for rotational and vibrational excitation. The limited number of possible excitation processes in parahydrogen and the wide separation of the thresholds for these processes make it possible to determine uniquely the J = 0 → 2 rotational cross section from threshold to 0.3 eV. In addition, the momentum transfer cross section has been determined for energies less than 2 eV and it is shown that, near threshold, a vibrational cross section compatible with the data must lie within relatively narrow limits. The problems of uniqueness and accuracy inherent in the swarm method of cross section analysis are discussed. The present results are compared with other recent theoretical and experimental determinations; the agreement with the most recent calculations of Henry and Lane is excellent.

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