scholarly journals Diffusion-based swelling in elastomers under low- and high-salinity brine

2018 ◽  
Vol 51 (1) ◽  
pp. 75-84
Author(s):  
Maaz Akhtar ◽  
Sayyad Zahid Qamar ◽  
Syed Murtuza Mehdi ◽  
Ahmad Hussain
Keyword(s):  
Oil And Gas ◽  
High Salinity ◽  
Analytical Models ◽  
Performance Factors ◽  
Low Salinity ◽  
Increase With Increase ◽  
Swelling Rate ◽  
Swelling Mechanism ◽  
Density Values ◽  
Salinity Water

Swelling elastomers are designed to swell when immersed into fluids like water, oil, or acid. The mechanism of swelling can be either diffusion or osmosis, initiating the imbibition of fluid inside the elastomer and progressively swelling it. Work presented here investigates diffusion as the swelling mechanism. Swelling experiments are conducted at two temperatures (room and 50°C) using water of different salinities (0.6% and 12%) as the swelling medium. Changes in volume, thickness, mass, and hardness are recorded. Measurements are taken before swelling and after 1, 2, 4, 7, 10, 16, 23, and 30 days of swelling. As expected, volume, thickness, and mass of the elastomer increase with increase in the number of swelling days, while hardness shows a decreasing trend. More variation is observed for all quantities in low-salinity brine as compared to high salinity, at both temperatures. However, density values are larger for high-salinity brine at both temperatures. Stokes–Einstein formula is used to determine the diffusion coefficients. Viscosity is measured using a Cannon–Fenske apparatus of size 50. Larger values of diffusion coefficient are found in low-salinity water at both temperatures, consistent with the higher amount of swelling and the faster swelling rate. These results and the diffusion-based approach will help in understanding the mechanics of swelling phenomenon. This work can aid in the development of new analytical and semi-analytical models that can predict seal pressure and other performance factors more accurately for applications in oil and gas wells.

CO2-saturated Salinity Environment Effects on Ni-Mo Alloys at Gas Hydrate Formation Temperatures

2019 ◽  
Author(s):  
Christopher Ozigagu ◽  
Ting Zhou ◽  
Stephen Sanders ◽  
Teresa Golden
Keyword(s):  
Corrosion Resistance ◽  
Deep Water ◽  
Gas Hydrate ◽  
Surface Characterization ◽  
Oil And Gas ◽  
High Salinity ◽  
Hydrate Formation ◽  
Test Solution ◽  
Low Salinity ◽  
Gas Hydrate Formation

Corrosion and gas hydrate formation are flow assurance problems that can cause serious safety problems in deep water environments. One aspect that has been given less attention is the corrosion behavior of materials in salinity environment where gas hydrate formation and CO2 (sweet) corrosion can both occur. This type of environment is common in oil and gas deep water environments. The aim of this work is to investigate the effects of CO2-saturated salinity environment on Ni-Mo alloys at gas hydrate formation temperatures using electrochemical, SEM/EDX, and XRD surface characterization techniques. The immersion test solutions were sweet low-salinity (CO2 + 1 wt% salt + 5 oC) and sweet high- salinity (CO2 + ~24 wt% salt + 5 oC) environments, respectively. The as-deposited Ni-Mo alloy coating has the highest corrosion resistance of 33.28 kΩ cm2. The corrosion resistance dropped to 14.36 kΩ cm2 and 11.11 kΩ cm2 after 20 hrs of immersion in the sweet low-salinity and sweet high-salinity test solutions respectively. From grazing incidence XRD, the (111) reflection peak of the Ni-Mo coating was depressed and broaden after immersion in both test solutions due to increase in oxide layer formation on the surface of the Ni-Mo coating. SEM revealed a cracked surface morphology after immersion in sweet high-salinity test solution and elemental analysis shows the presence of oxygen after immersion in both test solutions. The oxygen content increased from 1.70 wt% after immersion in sweet low-salinity test solution to 2.37 wt% after immersion in sweet high-salinity test solution.

Enhancing Heavy-Oil-Recovery Efficiency by Combining Low-Salinity-Water and Polymer Flooding

SPE Journal ◽  
2020 ◽  
pp. 1-17
Author(s):  
Yang Zhao ◽  
Shize Yin ◽  
Randall S. Seright ◽  
Samson Ning ◽  
Yin Zhang ◽  
...  
Keyword(s):  
Oil Recovery ◽  
Heavy Oil ◽  
High Salinity ◽  
Polymer Flooding ◽  
Heavy Oil Recovery ◽  
Sweep Efficiency ◽  
Low Salinity ◽  
Low Salinity Water ◽  
Salinity Water ◽  
Increased Oil Recovery

Summary Combining low-salinity-water (LSW) and polymer flooding was proposed to unlock the tremendous heavy-oil resources on the Alaska North Slope (ANS). The synergy of LSW and polymer flooding was demonstrated through coreflooding experiments at various conditions. The results indicate that the high-salinity polymer (HSP) (salinity = 27,500 ppm) requires nearly two-thirds more polymer than the low-salinity polymer (LSP) (salinity = 2,500 ppm) to achieve the target viscosity at the condition of this study. Additional oil was recovered from LSW flooding after extensive high-salinity-water (HSW) flooding [3 to 9% of original oil in place (OOIP)]. LSW flooding performed in secondary mode achieved higher recovery than that in tertiary mode. Also, the occurrence of water breakthrough can be delayed in the LSW flooding compared with the HSW flooding. Strikingly, after extensive LSW flooding and HSP flooding, incremental oil recovery (approximately 8% of OOIP) was still achieved by LSP flooding with the same viscosity as the HSP. The pH increase of the effluent during LSW/LSP flooding was significantly greater than that during HSW/HSP flooding, indicating the presence of the low-salinity effect (LSE). The residual-oil-saturation (Sor) reduction induced by the LSE in the area unswept during the LSW flooding (mainly smaller pores) would contribute to the increased oil recovery. LSP flooding performed directly after waterflooding recovered more incremental oil (approximately 10% of OOIP) compared with HSP flooding performed in the same scheme. Apart from the improved sweep efficiency by polymer, the low-salinity-induced Sor reduction also would contribute to the increased oil recovery by the LSP. A nearly 2-year pilot test in the Milne Point Field on the ANS has shown impressive success of the proposed hybrid enhanced-oil-recovery (EOR) process: water-cut reduction (70 to less than 15%), increasing oil rate, and no polymer breakthrough so far. This work has demonstrated the remarkable economical and technical benefits of combining LSW and polymer flooding in enhancing heavy-oil recovery.

The geochemical riddle of Mediterranean low-salinity gypsum deposits

2020 ◽  
Author(s):  
Giovanni Aloisi ◽  
Marcello Natalicchio ◽  
Laetitia Guibourdenche ◽  
Antonio Caruso ◽  
Francesco Dela Pierre
Keyword(s):  
High Salinity ◽  
Bound Water ◽  
Central Mediterranean ◽  
Saturation State ◽  
Low Salinity ◽  
Continental Runoff ◽  
Moderate Salinity ◽  
Salinity Water ◽  
The Mediterranean ◽  
Large Deposits

<p>Large deposits of gypsum accumulated in the marginal basins of the Mediterranean Sea during the Messinian Salinity Crisis. These form the marginal portions of the Mediterranean Salt Giant (MSG) that also occupies the deep, central Mediterranean basins. Although the marine, evaporitic origin of the MSG is undisputed, the analysis of gypsum fluid inclusions and of gypsum-bound water (d<sup>18</sup>O<sub>H2O</sub> and dD<sub>H2O</sub>) suggest that marginal basin gypsum formed from low- to moderate-salinity water masses (5 - 60 ‰), rather than from high-salinity brines (130 - 320 ‰), as expected during the evaporation of seawater.  The formation of low-salinity gypsum poses a fundamental geochemical problem: how can gypsum saturation conditions be met in marginal basins if evaporation does not concentrate marine water to high salinity? In other words, can gypsum saturation be attained by adding Ca<sup>2+</sup> and/or SO<sub>4</sub><sup>2-</sup> ions rather than by extracting water? We are exploring two geochemical scenarios to explain this phenomenon: (1) the addition of Ca<sup>2+</sup> and SO<sub>4</sub><sup>2-</sup> to marginal basins by continental runoff, and (2) the non-steady state addition of SO<sub>4</sub><sup>2-</sup> to marginal basins via the biogeochemical oxidation of reduced sulfur. Both scenarios may lead - at least theoretically - to the decoupling of saturation state from salinity that is suggested by gypsum geochemical signatures.</p>

scholarly journals The distribution of Recent Radiolaria in surficial sediments of the continental margin off northern Namibia

1983 ◽  
Vol 2 (1) ◽  
pp. 31-38 ◽  
Author(s):  
Simon Robson
Keyword(s):  
Continental Margin ◽  
High Salinity ◽  
Cold Water ◽  
Distribution Patterns ◽  
Abundant Species ◽  
High Salinity Water ◽  
Low Salinity ◽  
Apparent Correlation ◽  
Benguela Current ◽  
Salinity Water

Abstract. 47 Species of radiolaria have been identified from 30 surface sediment samples collected along transects across the continental margin of northern Namibia between the Kunene River and Walvis Bay. From the distribution patterns of the 24 most abundant species, it was possible to identify a warm water, high salinity population and a cold water, low salinity population. The distribution patterns of each population shows a close correspondence with the known positions of the Angola Current (warm, high salinity water) and the Benguela Current (cold, low salinity water) respectively. Two other trends are apparent from the overall radiolaria distribution; dilution of the nearshore samples by terrigeneous input and a strong preference for open ocean conditions. There is no apparent correlation with upwelling.

scholarly journals Yield and ion content in maize irrigated with saline water in a continuous or alternating system

2012 ◽  
Vol 42 (10) ◽  
pp. 1731-1737 ◽  
Author(s):  
Felipe de Sousa Barbosa ◽  
Claudivan Feitosa de Lacerda ◽  
Hans Raj Gheyi ◽  
Gabriel Castro Farias ◽  
Ricardo José da Costa Silva Júnior ◽  
...  
Keyword(s):  
High Salinity ◽  
Saline Water ◽  
Block Design ◽  
Management Strategies ◽  
Growth Yield ◽  
Maize Yield ◽  
High Salinity Water ◽  
Low Salinity ◽  
Salinity Water ◽  
Maize Plants

Irrigation with water containing salt in excess can affect crop development. However, management strategies can be used in order to reduce the impacts of salinity, providing increased efficiency in the use of good quality water. The objective of this research was to study the effects of use of high salinity water for irrigation, in continuous or cyclic manner, on vegetative growth, yield, and accumulation of ions in maize plants. Two experiments were conducted during the months from October to January of the years 2008/2009 and 2009/2010, in the same area, adopting a completely randomized block design with four replications. Irrigation was performed with three types of water with electrical conductivities (ECw) of 0.8 (A1), 2.25 (A2) and 4.5 (A3) dS m-1, combined in seven treatments including the control with low salinity water (A1) throughout the crop cycle (T1). Saline waters (A2 and A3) were applied continuously (T2 and T5) or in a cyclic way, the latter being formed by six irrigations with A1 water followed by six irrigations by eitherA2 or A3 water, starting with A1 at sowing (T3 and T6) or 6 irrigations with A2 or A3 water followed by 6 irrigations with A1 water (T4 and T7) . The use of low and high salinity water resulted in lower accumulation of potentially toxic ions (Na and Cl) and improvement in the Na/K balance in the shoots of maize plants. Application of saline water in a cyclic way also allows the substitution of about 50% of water of low salinity in irrigation, without negative impacts on maize yield.

Threatened habitat at Great Salt Lake: Importance of shallow-water and brackish habitats to Wilson’s and Red-necked phalaropes

The Condor ◽  
2019 ◽  
Vol 121 (2) ◽  
Author(s):  
Maureen G Frank ◽  
Michael R Conover
Keyword(s):  
High Salinity ◽  
Prey Availability ◽  
Salt Lake ◽  
Great Salt Lake ◽  
Hypersaline Lake ◽  
Low Salinity ◽  
Salinity Water ◽  
Threatened Habitat ◽  
Physical Features ◽  
Depth Water

Abstract Great Salt Lake (GSL) is the largest hypersaline lake in North America and is the fall staging area for a high proportion of North America’s Wilson’s Phalaropes (Phalaropus tricolor) and Red-necked Phalaropes (Phalaropus lobatus). Unfortunately, diversion of freshwater for agriculture and development has decreased the size of GSL by 48%. To assess the potential impact of a smaller GSL on phalaropes, we collected data from 2013 to 2015 from sites where large, dense flocks of phalaropes congregated and sites where there were no phalaropes. At each site, we measured the densities of invertebrates that were preyed upon by phalaropes, including larval and adult brine flies (Ephydridae), adult brine shrimp (Artemia franciscana), chironomid larvae (Chironomidae), and corixid adults (Corixidae). Abiotic characteristics measured included water depth, water salinity, water temperature, wind speed, and benthic substrate. We analyzed high-salinity sites separately from low-salinity sites because they contained different invertebrates. High-salinity sites were in Carrington and Gilbert bays and were relatively deep (mostly <2 m). At the high-salinity sites, phalaropes exhibited a preference for sites with an abundance of adult brine flies and for microbialite substrates. The low-salinity sites were in Ogden and Farmington bays and were shallow (<1 m). At low-salinity sites, large phalarope flocks were more likely to occur at sites that were shallower, less saline, and had a high biomass of benthic macroinvertebrates. Our results indicate that physical features and prey availability are both important in determining phalarope habitat use at GSL. Phalaropes prefer to use shallower parts of GSL and brackish waters. These areas will be especially impacted by decreased freshwater inflow into GSL.

scholarly journals Contrasting Response of the Eastern and Western North Atlantic Circulation to an Episodic Climate Event*

2011 ◽  
Vol 41 (9) ◽  
pp. 1630-1638 ◽  
Author(s):  
Ayan H. Chaudhuri ◽  
Avijit Gangopadhyay ◽  
James J. Bisagni
Keyword(s):  
North Atlantic ◽  
High Salinity ◽  
Scale Model ◽  
High Salinity Water ◽  
Low Salinity ◽  
The North ◽  
Basin Scale ◽  
Salinity Water ◽  
The North Atlantic ◽  
The North Atlantic Oscillation

Abstract Regional observational studies in the North Atlantic have noted significant hydrographical shifts in 1997–98 because of the episodic drop in the North Atlantic oscillation (NAO) during 1996. Investigation using a basin-scale model finds that, although the western North Atlantic (WNA) witnessed unusually low-salinity water by 1997, the eastern North Atlantic (ENA) simultaneously evidenced intrusions of high-salinity water at intermediate depths. This study shows that a major source of high salinity in the ENA is from the northward penetration of Mediterranean Outflow Water (MOW) that occurred concurrently with a westward shift of the subpolar front. The authors confirm that the low-salinity intrusion in the WNA is from enhanced Labrador Current flow. Results from climatological high- and low-NAO simulations suggest that the NAO-induced circulation changes that occurred in 1997–98 are a characteristic North Atlantic basin response to different forcing conditions during characteristic high- and low-NAO periods.

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