Graphene nanocomposites: A review on processes, properties, and applications

2021 ◽  
pp. 152808372110242
Author(s):  
Kadir Bilisik ◽  
Mahmuda Akter
Keyword(s):  
Textile Industry ◽  
In Situ Polymerization ◽  
Resin Transfer Molding ◽  
Single Layer ◽  
Chemical Vapor ◽  
Synthesis Process ◽  
Graphene Nanocomposites ◽  
Transfer Molding ◽  
Potential Applications ◽  
Nano Graphene

In this paper, graphene, graphene/matrix, and graphene/fiber nanocomposites, including their synthesis process, fabrication, properties, and potential applications, were reviewed. It was found that several synthesis techniques for nanographene were developed, such as liquid-phase exfoliation and chemical vapor deposition. In addition, some fabrication processes of graphene/matrix and graphene/fiber-based nanocomposites were made, including in-situ polymerization, nanostitching in that single layer nano graphene plate could be interconnected by means of carbon nanotube stitching, resin transfer molding, and vacuum-assisted resin transfer molding. Several properties, including mechanical, thermal, and electrical, on the graphene nanoplatelets materials were summarized in this review paper. It was realized that graphene, graphene/matrix, and graphene/fiber nanocomposites have extraordinary mechanical, thermal, and electrical properties used in advanced engineering applications, including soft robotics, microelectronics, energy storage, biomedical and biosensors as well as textile industry.

Oxidation of CVD Growth Single-Layer Graphene

2013 ◽  
Vol 790 ◽  
pp. 7-10 ◽  
Author(s):  
Hui Gao ◽  
Yin Zhang
Keyword(s):  
Vapor Deposition ◽  
Acid Treatment ◽  
Oxidation Process ◽  
Single Layer ◽  
Chemical Vapor ◽  
Strong Acid ◽  
Single Layer Graphene ◽  
Layer Graphene ◽  
Potential Applications ◽  
Cvd Growth

Recently, oxidized chemical vapor deposition (CVD) growth graphene has drawn much attention due to its potential applications in the field of optoelectronics. In this article, we report a simple, scalable and efficient method to synthesize oxidized CVD growth single-layer graphene by the strong acid treatment. The results indicate that oxidation process successfully introduced more defects and oxygen-containing groups into the lattice of graphene.

Investigation on the mechanical and electrical properties of carbon nanotube/epoxy composites produced by resin transfer molding

2016 ◽  
Vol 51 (14) ◽  
pp. 2035-2043 ◽  
Author(s):  
Wei Liu ◽  
Baochun Wei ◽  
Fujun Xu
Keyword(s):  
Carbon Nanotube ◽  
Resin Transfer Molding ◽  
Chemical Vapor ◽  
Weight Fraction ◽  
Smart Structure ◽  
Chemical Vapor Deposition Method ◽  
Molding Process ◽  
Transfer Molding ◽  
Young’S Moduli ◽  
Mechanical And Electrical Properties

For industrial application of carbon nanotube/polymer composites, it is critical to produce composites in an efficient way. In this study, large size carbon nanotube buckypaper, which is directly produced by floating catalyst chemical vapor deposition method, was used to reinforce epoxy through conventional resin transfer molding process. The infiltration behavior of resin was analyzed, indicating that efficient carbon nanotube-epoxy interface has been formed near the surface of the composites. With 26.87% weight fraction of carbon nanotubes, the composites show a great enhancement in mechanical properties, that the failure strength and Young’s moduli increase from 45 MPa and 2.5 GPa to 254.39 MPa and 6.69 GPa with a large failure strain over 15%. In addition, the composite film is electrically conductive with a conductivity of 220 S/cm. It also shows linear piezoresistive effect with a gage factor tested to be 2.68, indicating a great potential in multifunctional smart structure applications.

Characterization of a monolayer graphitic structure

1994 ◽  
Vol 52 ◽  
pp. 760-761
Author(s):  
X. Lin ◽  
X. K. Wang ◽  
V. P. Dravid ◽  
J. B. Ketterson ◽  
R. P. H. Chang
Keyword(s):  
Three Dimensional ◽  
Single Layer ◽  
Synthesis Process ◽  
Graphitic Structure ◽  
Positive Gaussian Curvature ◽  
Graphitic Sheet ◽  
Structural And Electronic Properties ◽  
New Material ◽  
Hexagonal Network

For small curvatures of a graphitic sheet, carbon atoms can maintain their preferred sp2 bonding while allowing the sheet to have various three-dimensional geometries, which may have exotic structural and electronic properties. In addition the fivefold rings will lead to a positive Gaussian curvature in the hexagonal network, and the sevenfold rings cause a negative one. By combining these sevenfold and fivefold rings with sixfold rings, it is possible to construct complicated carbon sp2 networks. Because it is much easier to introduce pentagons and heptagons into the single-layer hexagonal network than into the multilayer network, the complicated morphologies would be more common in the single-layer graphite structures. In this contribution, we report the observation and characterization of a new material of monolayer graphitic structure by electron diffraction, HREM, EELS.The synthesis process used in this study is reported early. We utilized a composite anode of graphite and copper for arc evaporation in helium.

Novel organic, polymeric materials for electronics applications

2002 ◽  
Vol 722 ◽  
Author(s):  
Ram W. Sabnis ◽  
Mary J. Spencer ◽  
Douglas J. Guerrero
Keyword(s):  
Optical Density ◽  
Chemical Vapor ◽  
Polymeric Materials ◽  
Substantial Improvement ◽  
Polymeric Systems ◽  
Patterned Wafers ◽  
Visible Spectra ◽  
Potential Applications ◽  
Deep Ultraviolet ◽  
Deposited Films

AbstractNovel organic, polymeric materials and processes of depositing thin films on electronics substrates by chemical vapor deposition (CVD) have been developed and the lithographic behavior of photoresist coated over these CVD films at deep ultraviolet (DUV) wavelength has been evaluated. The specific monomers synthesized for DUV applications include [2.2](1,4)- naphthalenophane, [2.2](9,10)-anthracenophane and their derivatives which showed remarkable film uniformity on flat wafers and conformality over structured topography wafers, upon polymerization by CVD. The chemical, physical and optical properties of the deposited films have been characterized by measuring parameters such as thickness uniformity, solubility, conformality, adhesion to semiconductor substrates, ultraviolet-visible spectra, optical density, optical constants, defectivity, and resist compatibility. Scanning electron microscope (SEM) photos of cross-sectioned patterned wafers showed verticle profiles with no footing, standing waves or undercut. Resist profiles down to 0.10 νm dense lines and 0.09 νm isolated lines were achieved in initial tests. CVD coatings generated 96-100% conformal films, which is a substantial improvement over commercial spin-on polymeric systems. The light absorbing layers have high optical density at 248 nm and are therefore capable materials for DUV lithography applications. CVD is a potentially useful technology to extend lithography for sub-0.15 νm devices. These films have potential applications in microelectronics, optoelectronics and photonics.

scholarly journals Controlled Fabrication of Quality ZnO NWs/CNTs and ZnO NWs/Gr Heterostructures via Direct Two-Step CVD Method

Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1836
Author(s):  
Nicholas Schaper ◽  
Dheyaa Alameri ◽  
Yoosuk Kim ◽  
Brian Thomas ◽  
Keith McCormack ◽  
...  
Keyword(s):  
Direct Synthesis ◽  
Chemical Vapor ◽  
Single Walled Carbon Nanotubes ◽  
Materials Synthesis ◽  
Oxide Nanowires ◽  
Cvd Method ◽  
Thermal Actuators ◽  
Potential Applications ◽  
Walled Carbon Nanotubes ◽  
Scalable Production

A novel and advanced approach of growing zinc oxide nanowires (ZnO NWs) directly on single-walled carbon nanotubes (SWCNTs) and graphene (Gr) surfaces has been demonstrated through the successful formation of 1D–1D and 1D–2D heterostructure interfaces. The direct two-step chemical vapor deposition (CVD) method was utilized to ensure high-quality materials’ synthesis and scalable production of different architectures. Iron-based universal compound molecular ink was used as a catalyst in both processes (a) to form a monolayer of horizontally defined networks of SWCNTs interfaced with vertically oriented ZnO NWs and (b) to grow densely packed ZnO NWs directly on a graphene surface. We show here that our universal compound molecular ink is efficient and selective in the direct synthesis of ZnO NWs/CNTs and ZnO NWs/Gr heterostructures. Heterostructures were also selectively patterned through different fabrication techniques and grown in predefined locations, demonstrating an ability to control materials’ placement and morphology. Several characterization tools were employed to interrogate the prepared heterostructures. ZnO NWs were shown to grow uniformly over the network of SWCNTs, and much denser packed vertically oriented ZnO NWs were produced on graphene thin films. Such heterostructures can be used widely in many potential applications, such as photocatalysts, supercapacitors, solar cells, piezoelectric or thermal actuators, as well as chemical or biological sensors.

scholarly journals A Conceptional Approach of Resin-Transfer-Molding to Rosin-Sourced Epoxy Matrix Green Composites

Aerospace ◽  
2020 ◽  
Vol 8 (1) ◽  
pp. 5
Author(s):  
Sicong Yu ◽  
Xufeng Zhang ◽  
Xiaoling Liu ◽  
Chris Rudd ◽  
Xiaosu Yi
Keyword(s):  
Composite Laminates ◽  
Resin Transfer Molding ◽  
High Viscosity ◽  
Ramie Fiber ◽  
Liquid Composite Molding ◽  
Curing Agent ◽  
Molding Process ◽  
Transfer Molding ◽  
Low Viscosity ◽  
Composite Molding

In this concept-proof study, a preform-based RTM (Resin Transfer Molding) process is presented that is characterized by first pre-loading the solid curing agent onto the preform, and then injecting the liquid nonreactive resin with an intrinsically low viscosity into the mold to infiltrate and wet the pre-loaded preform. The separation of resin and hardener helped to process inherently high viscosity resins in a convenient way. Rosin-sourced, anhydrite-cured epoxies that would normally be regarded as unsuited to liquid composite molding, were thus processed. Rheological tests revealed that by separating the anhydrite curing agent from a formulated RTM resin system, the remaining epoxy liquid had its flowtime extended. C-scan and glass transition temperature tests showed that the preform pre-loaded with anhydrite was fully infiltrated and wetted by the liquid epoxy, and the two components were diffused and dissolved with each other, and finally, well reacted and cured. Composite laminates made via this approach exhibited roughly comparable quality and mechanical properties with prepreg controls via autoclave or compression molding, respectively. These findings were verified for both carbon and ramie fiber composites.

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