Fatty Acid Derived Compounds – the Dominant Volatile Class of the Essential Oil Poor Sonchus Arvensis Subsp. Uliginosus (Bieb.) Nyman

2009 ◽  
Vol 4 (3) ◽  
pp. 1934578X0900400 ◽  
Author(s):  
Niko Radulović ◽  
Polina Blagojević ◽  
Radosav Palić

Chemical composition of the essential oil hydrodistilled from aerial parts of Sonchus arvensis subsp. uliginosus is reported for the first time. GC and GC-MS analyses of the oil enabled the identification of 114 components that represented 97.4% of the total oil. Main identified constituents were heneicosane (28.4%), ( Z)-3-hexen-1-ol (19.0%), ( E)-2-hexen-1-ol (11.6%), 1-eicosanol (7.5%) and tricosane (5.3%). Fatty acid derived compounds (“green leaf” volatiles, alkanes, n-alkenes, n-aldehydes and n-alcohols) were by far predominant (89.4%). A much lower percentage of shikimate metabolites (5.0%), carotenoid-derived compounds (1.7%) and terpenoids (0.9%) has also been detected in the oil. Compositions of the essential oils of S. arvensis subsp. uliginosus and other 18 randomly chosen species, characterized by a wide range of essential oil yields, belonging to different plant genera, were compared using multivariate statistical analysis. The results strongly suggest that the main volatiles of essential oil poor species (yields less then 0.1%) are fatty acid- and carotenoid derived compounds, while essential oil rich taxa (essential oil yields much higher then 0.1%) are generally characterized by the specific production of mono- and sesquiterpenoids, and/or phenylpropanoids.

2014 ◽  
Vol 9 (7) ◽  
pp. 1934578X1400900
Author(s):  
Rajesh K. Joshi

The chemical composition of the hydro-distilled essential oil obtained from the flowering aerial parts of Vernonia albicans DC. (Asteraceae) was analyzed by gas chromatography equipped with a flame ionization detector (GC-FID) and gas chromatography coupled with a mass spectrometry (GC/MS). Thirty-nine compounds have been identified, representing 97.5% of the total oil. The major constituents were β-caryophyllene (34.3%), γ-amorphene (19.5%), 9-epi-β-caryophyllene (6.9%), and α-pinene (6.9%). The oil was found to be rich in sesquiterpene hydrocarbons (73.9%).


2014 ◽  
Vol 9 (2) ◽  
pp. 1934578X1400900
Author(s):  
Rajesh K. Joshi

The essential oil obtained from the aerial parts of Croton bonplandianus Baill. was analyzed by gas chromatography (GC) and gas chromatography/mass spectrometry (GC/MS). A total of 37 compounds have been identified, representing 96.2% of the total oil. The main constituents were identified as β-caryophyllene (16.7%), germacrene D (14.7%), borneol (8.3%), Z-β-damascenone (6.(%), isobornyl acetate (6.2%), α-humulene (6.1%), germacrene A (5.2%) and caryophyllene oxide (4.5%). The oil was rich in sesquiterpene hydrocarbons (60.1%).


2012 ◽  
Vol 7 (9) ◽  
pp. 1934578X1200700 ◽  
Author(s):  
Megil J. McNeil ◽  
Roy B. R. Porter ◽  
Lawrence A. D. Williams

The chemical composition of the essential oil obtained from the aerial parts of Cleome serrata by hydrodistillation was analyzed by employing GC-FID, GC-MS and RI. Fourteen compounds comprising 90.4% of the total oil composition were characterized. The main components identified were ( Z)-phytol (53.0%) and di(2-ethylhexyl)-phthalate (DEHP) (14.7%). The oil was evaluated for its in vitro antimicrobial activities against nine pathogenic microorganisms using the filter paper disc diffusion method. Moderate antimicrobial activity was observed against five of the pathogens assayed. In addition, the essential oil was tested against the sweet potato weevil, Cylas formicarius elegantulus. Strong knockdown insecticidal activity was observed.


2007 ◽  
Vol 2 (7) ◽  
pp. 1934578X0700200 ◽  
Author(s):  
Chandan S. Chanotiya ◽  
Chandra S. Mathela

The essential oil from the aerial parts of Tanacetum nubigenum Wallich ex DC collected from the Milam glacier moraine showed the presence of 73 compounds, of which 69, representing 87.9% of the total oil, have been identified, with bornyl acetate (39.7%), borneol (10.6%), ( E)-β-farnesene (6.6%) and 1,8-cineole (5.8%) as major constituents, while the oil from the plant material from the Pindari glacier area contained a total of 81 compounds, of which 77 have been identified. This oil was characterized by the presence of (3 R, 6 R)-linalool oxide acetate (69.4%), β-eudesmol (3.2%), selin-11-en-4α-ol (3.2%) and (3.2% and 1.2%, respectively) for compounds ( E) and ( Z)-2-(2,4-hexadiynylidene)-1,6-dioxospiro [4,4] non-3-ene, respectively. The major constituents of the essential oils from the aerial parts were separated and characterized by GC, GC/MS and 1D- and 2D-NMR spectroscopy. The chemical differences between the two essential oils place them as distinct chemical races or chemotypes.


2010 ◽  
Vol 5 (1) ◽  
pp. 1934578X1000500 ◽  
Author(s):  
Anne Orav ◽  
Janne Sepp ◽  
Tiiu Kailas ◽  
Mati Müürisepp ◽  
Elmar Arak ◽  
...  

Variations in the essential oil composition of aerial parts of pineapple weed (Chamomilla suaveolens (Pursh) Rydb.) growing wild in Estonia, were determined using GC/FID and GC/MS. Forty-four components were identified, representing over 90% of the total oil. Nine compounds have not been mentioned in the literature before. The principal biologically active compounds in C. suaveolens oils were (Z)-en-yne-dicycloether (17.0 – 40.7%), (E)-β-farnesene (19.5– 32.2%), geranyl isovaleriate (8.4 –18.4%), palmitic acid (0.3 – 9.4%) and myrcene (1.1 – 7.9%). The investigation seems to approve the benefit of using aerial parts of pineapple weed as the substitute for flowers.


2011 ◽  
Vol 76 (4) ◽  
pp. 523-528 ◽  
Author(s):  
Ram Verma ◽  
Rajendra Padalia ◽  
Chandan Chanotiya ◽  
Amit Chauhan ◽  
Anju Yadav

Hydrodistilled essential oil of the aerial parts of Laggera crispata (Vahl) Hepper & Wood, collected from the Kumaon region of the western Himalayas was analysed by gas chromatography and gas chromatography-Mass Spectrometry. Eighty constituents, accounting for 83.9 % of the total oil composition, were identified. The oil was mainly dominated by sesquiterpenoids (45.3 %) and benzenoid compounds (33.9 %). Among them, 2,5-dimethoxy-p-cymene (32.2 %), 10-epi-?-eudesmol (14.7 %), ?-caryophyllene (6.9 %), and caryophyllene oxide (5.4 %) were major components of the oil.


2013 ◽  
Vol 8 (8) ◽  
pp. 1934578X1300800
Author(s):  
Rajesh K. Joshi

The hydro-distilled essential oil obtained from the flowering aerial parts of Lepidagathis fasciculata Nees was analyzed by gas chromatography equipped with a flame ionization detector (GC-FID) and gas chromatography coupled with mass spectrometry (GC/MS). A total of 38 compounds have been identified, representing 91.2% of the total oil. The major constituents were δ-cadinene (14.4 %), γ-curcumene (9.8%), sandaracopimarinal (6.6%), germacrene D-4-ol (6.1%), cembrene (5.0%), β-calacorene (3.6%), ar-curcumene (3.3%), trans–4,10-epoxy-amorphane (3.2%), abietatriene (2.9%), and α-cubebene (2.8%). The oil was rich in sesquiterpene hydrocarbons (43.8%).


2013 ◽  
Vol 8 (3) ◽  
pp. 1934578X1300800
Author(s):  
Rajesh K. Joshi

The essential oil composition from the aerial parts of Baccharoides lilacina (Dalzell & A. Gibson) M. R. Almeida was analyzed by gas chromatography (GC) and gas chromatography/mass spectrometry (GC/MS). A total of 41 compounds have been identified, representing 97.4% of the total oil. The main constituents were identified as β-caryophyllene (27.7%), epi-α-cadinol (25.1%), caryophyllene oxide (9.9%), α-muurolol (7.6%), α-cadinene (6.1%) and α-cadinol 4.5%). The oil was found to be rich in oxygenated sesquiterpenes (47.1%) and sesquiterpene hydrocarbons (46.2%).


Author(s):  
Belbache Hanene ◽  
Mechehoud Youcef ◽  
Chalchat Jean-Claude ◽  
Figueredo Gilles ◽  
Chalard Pierre ◽  
...  

The essential oil of the aerial parts of Centaurea sempervirens L. (Asteraceae), synonym : Cheirolophus sempervirens (L.) Pomel, was obtained by steam distillation and analyzed by GC-FID and GC-MS. 30 components were identified corresponding to 78.5% of the total oil. Among the identified constituents, oxygenated compounds represented 33.4%, from which 21.2% were hydrocarbons, 10.7% were sesquiterpenes. The non oxygenated compounds were hydrocarbons (9.8%). Phthalates represented 35.3% of the total oil. The major components were 6,10,14-trimethylpentadecan-2-one (12.4%) and epi-torilenol (5.1%). This is the first report on the chemical composition of the essential oil of this species.


2015 ◽  
Vol 39 ◽  
pp. 49-55 ◽  
Author(s):  
H. Ouakouak ◽  
M. Chohra ◽  
M. Denane

Aerial parts of Mentha pulegium L. collected from south east of Algeria (Reguiba, El-Oued) possessed an essential oil in 2.34% (v/w) yield. GC and GC-MS analysis of the oil revealed recognition of Thirty-seven compounds, representing 95.02% (area percent) of the total oil composition. Oil was rich in Oxygenated hydrocarbons, exhibited higher percentage of Pulegone (46.31%) followed by Piperitenone (23.3%), Menthone (6.2%) and Limonene (4.7%). The antioxidant activity by DPPH free radical scavenging bioassay (IC50 = 157 µl/ml).


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