scholarly journals Variability in the Chemical Composition of Eugenia biflora Essential Oils from the Brazilian Amazon

2019 ◽  
Vol 14 (12) ◽  
pp. 1934578X1989243
Author(s):  
Pablo Luis B. Figueiredo ◽  
Henryck A. Fernandes ◽  
Alberto Ray C. da Silva ◽  
Nayara Sabrina F. Alves ◽  
William N. Setzer ◽  
...  
Keyword(s):  
Principal Component Analysis ◽  
Essential Oils ◽  
Principal Component ◽  
Hierarchical Cluster ◽  
Brazilian Amazon ◽  
Economic Potential ◽  
Caryophyllene Oxide ◽  
North Brazil ◽  
Chemical Variability ◽  
First Time

Eugenia species are well known for their great economic potential as edible fruits. The leaves of 4 Eugenia biflora specimens (Ebi-1 to Ebi-4) were sampled in the Caratateua Island, Pará state, Brazilian Amazon. Then, the essential oils were hydrodistilled, analyzed by gas chromatography (GC) and GC mass spectroscopy, and their volatile compositions submitted to multivariate analysis (principal component analysis and hierarchical cluster analysis). Ebi-1 and Ebi-2 specimens were classified in the caryophyllene group, with significant content for the sesquiterpenes ( E)-caryophyllene (16.8% and 11.4%) and caryophyllene oxide (28.6% and 20.5%). Ebi-3 specimen was grouped into the cadinane group, characterized by the presence of α-cadinol (14.7%), an oxygenated sesquiterpene. EBI-4 specimen was inserted into the aromadendrane group, with the predominance of the sesquiterpenes globulol (9.8%), germacrene B (7.9%), and γ-elemene (3.1%). Based on the results, a remarkable chemical variability was observed in the oils of Eugenia biflora with occurrence in Pará state, North Brazil. This work is presenting for the first time its caryophyllene, cadinane, and aromadendrane profiles.

scholarly journals Chemical and Enantioselective Analysis of the Essential Oils from Different Morphological Structures of Ocotea quixos (Lam.) Kosterm

Plants ◽  
2021 ◽  
Vol 10 (10) ◽  
pp. 2171
Author(s):  
Gianluca Gilardoni ◽  
Mayra Montalván ◽  
Marjorie Vélez ◽  
Omar Malagón
Keyword(s):  
Principal Component Analysis ◽  
Cluster Analysis ◽  
Essential Oil ◽  
Essential Oils ◽  
Hierarchical Cluster Analysis ◽  
Principal Component ◽  
Hierarchical Cluster ◽  
Methyl Cinnamate ◽  
Enantiomerically Pure ◽  
Enantioselective Analysis

The traditional Ecuadorian spice Ishpingo, characterized by a strong cinnamon-like aroma, is constituted by the dry cupules of Amazonian species Ocotea quixos. Nevertheless, bark and leaves also present aromatic properties and are sometimes used as substitutes. In the present study, the essential oils, distilled from these morphological structures, are comparatively analyzed for their chemical and enantiomeric compositions. A total of 88 components were identified with 2 orthogonal GC columns, whereas 79, corresponding to more than 94%, were also quantified with at least 1 column. Major compounds were (E)-methyl cinnamate in cupules (35.9–34.2%), (E)-cinnamaldehyde in bark (44.7–47.0%), and (E)-cinnamyl acetate (46.0–50.4%) in leaves. For what concerns the enantioselective analysis, 10 chiral terpenes and terpenoids were detected, of which 6 were present as enantiomeric pairs in at least 1 essential oil, the others being enantiomerically pure. Both quantitative and enantioselective analyses were submitted to Principal Component Analysis (PCA) and Hierarchical Cluster Analysis (HCA), where their results confirmed significative difference among the three products.

Quality evaluation of tugaksheeree samples by ATR-FTIR spectroscopy using multicomponent analysis

2020 ◽  
Vol 10 ◽  
Author(s):  
Nikunj D. Patel ◽  
Niranjan S. Kanaki
Keyword(s):  
Principal Component Analysis ◽  
Cluster Analysis ◽  
Quality Evaluation ◽  
Principal Component ◽  
Hierarchical Cluster ◽  
Attenuated Total Reflectance ◽  
Chemometric Methods ◽  
Total Reflectance ◽  
Fingerprint Region ◽  
Ftir Technique

Background: Numerous Ayurvedic formulations contains tugaksheeree as key ingredient. Tugaksheereeis the starch gained from the rhizomes of two plants, Curcuma angustifoliaRoxb. (Zingiberaceae) and Marantaarundinacea (MA) Linn. (Marantaceae). Objective: The primary concerns in quality assessment of Tugaksheeree occur due to adulteration or substitution. Method: In current study, Fourier transform infrared (FTIR) technique with attenuated total reflectance (ATR) facility was used to evaluate tugaksheeree samples. Total 10 different samples were studied and transmittance mode was kept to record the spectra devoid of pellets of KBR. Further treatment was given with multi component tools by considering fingerprint region of the spectra. Multivariate analysis was performed by various chemometric methods. Result: Multi component methods like Principal Component Analysis (PCA), and Hierarchical Cluster Analysis (HCA)were used to discriminate the tugaksheeree samples using Minitab software. Conclusion: This method can be used as a tool to differentiate samples of tugaksheeree from its adulterants and substitutes.

scholarly journals Evaluation of volatile constituents, exudation of resin and occurrence of galls of Protium aracouchini (Aubl.) Marchand

2021 ◽  
Vol 5 (3) ◽  
pp. 88
Author(s):  
Thiago Augusto Araujo Correia Lima (in memorian) ◽  
Leonardo Pinto Cunha ◽  
José Eduardo Lahoz da Silva Ribeiro ◽  
Marcia Ortiz Mayo Marques ◽  
Maria da Paz Lima
Keyword(s):  
Essential Oil ◽  
Essential Oils ◽  
Chemical Constituents ◽  
Brazilian Amazon ◽  
High Concentration ◽  
Forest Reserve ◽  
Volatile Constituents ◽  
Aerial Parts ◽  
First Time ◽  
Time Information

Protium aracouchini (Aubl.) Marchand [sin Icica aracouchini Aubl.], which occurs in the Adolpho Ducke Forest Reserve, in the Brazilian Amazon, was evaluated for the presence of galls, for resin exudation and the composition of the essential oils from the aerial parts and the resin. The experiment to stimulate the exudation of resin from the trunk was conducted using a 2-chloroethylphosphonic acid solution. The resin produced after 40 days and the aerial parts had their essential oils extracted in a Clevenger apparatus and the volatile chemical constituents were analyzed using GC/MS. The non-oxygenated sesquiterpenes α-copaene (21.15%) and α-gurjunene (13.69%), in addition to the oxygenated sesquiterpene spathulenol (10.32%), were detected as the majority constituents of the essential oil of the leaves, and a concentration similar to that of α-gurjunene was found in the branches (13.28%). The resin essential oil showed a high concentration of hydrocarbon monoterpenes (76.49%) with a predominance of α-pinene (17.57%) and limonene (46.11%). Four gall morphotypes were found associated with this species. The present study reports for the first time information on the volatile constituents and the resinous potential of P. aracouchini, and registers the morphotypes of the galls that help in the taxonomy of the species.

scholarly journals Chemical Variation and Implications on Repellency Activity of Tephrosia vogelii (Hook f.) Essential Oils Against Sitophilus zeamais Motschulsky

Agriculture ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 164
Author(s):  
Nasifu Kerebba ◽  
Adebola O. Oyedeji ◽  
Robert Byamukama ◽  
Simon K. Kuria ◽  
Opeoluwa O. Oyedeji
Keyword(s):  
Chemical Composition ◽  
Essential Oils ◽  
Principal Component ◽  
Sitophilus Zeamais ◽  
Chemical Variability ◽  
Tephrosia Vogelii ◽  
Dry Seasons ◽  
Alkyl Benzenes ◽  
Eastern Uganda ◽  
Repellency Activity

The aim of this research is to characterize the variation in the chemical composition of Tephrosia vogelii essential oils from different locations and to investigate the repellency of essential oils against Sitophilus zeamais. Chemical variability in the components of T. vogelii essential oils from eastern Uganda was identified using principal component analysis (PCA) and agglomerative hierarchical clustering (AHC). Based on the profiles of the compounds of the farnesene family, three chemotypes were found: farnesol (chemotype 1), springene (β-springene and α-springene) and β-farnesene were all distinctive in chemotype 2 and a mixed variety of farnesol and springene. In the three cases, alkyl benzenes (o-xylene, m-xylene and ethylbenzene) were significant components in the oil. The compounds 1,4-dihydroxy-p-menth-2-ene, 6,10-dimethyl-5,9-undecadien-2-one, and 3,4-dimethyl-3-cyclohexen-1-carboxaldehyde were other prominent constituents. The yields of the essential oils did not vary significantly, however the chemical composition varied with harvesting time during the rainy and dry seasons. In choice repellency tests, chemotype 1 and chemotype 2 were more active against Sitophilus zeamais than the mixed chemotype. Farnesol was found to be effective only at a higher concentration as a repellent against S. zeamais. We therefore hypothesize that farnesol is a key player in this and we demonstrated the weak repellency of this compound. However, further study that aims to optimize and standardize the varieties and harvesting period is needed for recommendation to smallhold farmers.

scholarly journals Multivariate characteristics of selected grass varieties for seed production

2019 ◽  
Vol 55 (No. 2) ◽  
pp. 83-86
Author(s):  
Marzena Iwańska ◽  
Danuta Martyniak ◽  
Marcin Martyniak ◽  
Dariusz Gozdowski
Keyword(s):  
Principal Component Analysis ◽  
Growth Rate ◽  
Cluster Analysis ◽  
Seed Production ◽  
Plant Resistance ◽  
Hierarchical Cluster Analysis ◽  
Multivariate Analyses ◽  
Principal Component ◽  
Hierarchical Cluster ◽  
Festuca Rubra

Data were obtained in a field experiment carried out at Plant Breeding and Acclimatization Institute Radzikow (central Poland) in 2009–2011. The aim of this study was a multivariate evaluation of 13 advanced lines and cultivars of Festuca rubra, taking into account traits important in seed production. Eleven traits of the grasses and plant resistance to diseases were evaluated. On the basis of multivariate analyses, i.e. hierarchical cluster analysis and principal component analysis, groups of varieties were separated and described, relationships between the traits were evaluated as well. The traits with the biggest influence on multivariate diversity of examined varieties were correlated with the first principal component i.e. height of plants, seeds yield, growth rate of plants, leaf width and time to beginning of earing.  

scholarly journals Effects of Gender and Geographical Origin on the Chemical Composition and Antiradical Activity of Baccharis myriocephala and Baccharis trimera

Foods ◽  
2020 ◽  
Vol 9 (10) ◽  
pp. 1433
Author(s):  
Suzana Struiving ◽  
Ana Carolina Mendes Hacke ◽  
Edésio Luiz Simionatto ◽  
Dilamara Riva Scharf ◽  
Cláudia Vargas Klimaczewski ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Ethyl Acetate ◽  
Essential Oils ◽  
Antiradical Activity ◽  
Principal Component ◽  
Hierarchical Cluster ◽  
Gas Chromatography Mass Spectrometry ◽  
Array Detector ◽  
Chemical Compositions ◽  
Baccharis Trimera

This study aimed to characterize and compare essential oils and ethyl acetate fractions obtained in basic and acidic conditions from both male and female Baccharis species (Baccharis myriocephala and Baccharis trimera) from two different Brazilian regions. Samples were characterized according to their chemical compositions and antiradical activity by 2,2-diphenyl-1-picrylhydrazyl (DPPH) and 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) assays. Principal component analysis (PCA) provided a clear separation regarding the chemical composition of essential oils from the samples obtained from different regions by using gas chromatography–mass spectrometry with flame-ionization detection (GC-MS-FID). PCA also revealed that gender and region of plant collections did not influence the chemical composition and antiradical activity of ethyl acetate fractions, which was corroborated with hierarchical cluster analysis (HCA) data. High performance liquid chromatography with diode-array detector (HPLC-DAD) identified significant quantities of flavonoids and phenolic acids in the fractions obtained in basic and acidic fractions, respectively. The obtained results clearly demonstrated that the geographical region of plant collection influenced the chemical composition of essential oils from the studied Baccharis species. Moreover, the obtained fractions were constituted by several antiradical compounds, which reinforced the usage of these species in folk medicine.

Essential oil composition of two yarrow taxonomic forms

2010 ◽  
Vol 5 (3) ◽  
pp. 346-352 ◽  
Author(s):  
Asta Judzentiene ◽  
Danute Mockute
Keyword(s):  
Chemical Analysis ◽  
Essential Oil ◽  
Essential Oils ◽  
Essential Oil Composition ◽  
Achillea Millefolium ◽  
Caryophyllene Oxide ◽  
Oil Composition ◽  
Plant Organs ◽  
First Time

AbstractDifferences in essential oil composition of wild Achillea millefolium L., collected at five habitats in Lithuania, where plants with pink (f. rosea) and white (f. millefolium) flowers grow together, were reported. For the first time, oils of different plant organs (inflorescences and leaves) of both forms from every population were analysed in detail. Chemical analysis was performed by GC and GC-MS. The most predominant constituents of the oils were nerolidol (9.4–31.9%, in 11 out of 20 samples), caryophyllene oxide (8.4–23.0%, 4 leaf oils), ß-pinene (8.0–15.2%, 2 samples), eudesmol (11.8–15.8%, 2 leaf oils) and 1,8-cineole (11.9%, one inflorescence oil). Domination of nerolidol was mostly characteristic of A. millefolium f. rosea essential oils (in 8 out of 10 oils). The inflorescences biosynthesised markedly larger amounts of nerolidol and ß-pinene than those of the leaves. An opposite correlation was observed for caryophyllene oxide and eudesmol. Chamazulene (≤2.7%) was determined only in six oils. The 65 identified constituents made up 75.4–96.5% of the oils.

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