Retarded illite crystallinity caused by stressinduced sub-grain boundaries in illite

Clay Minerals ◽  
2000 ◽  
Vol 35 (4) ◽  
pp. 693-708 ◽  
Author(s):  
G. Giorgetti ◽  
I. Memmi ◽  
D. R. Peacor
Keyword(s):  
Grain Boundaries ◽  
Crystal Size ◽  
Low Grade ◽  
Strain Rates ◽  
Illite Crystallinity ◽  
Grade Metamorphism ◽  
Three Samples ◽  
Mean Size ◽  
The Mean ◽  
Transantarctic Mountains

AbstractAn XRD-TEM study was carried out on low-grade metapelites (Transantarctic Mountains) to determine the cause of apparent inconsistences in grade as determined by IC and independent geologic relations. The illite crystallinity (IC) data indicate that the three units investigated (BT, RBT, MS) were affected by very low- (IC = 0.24°Δ2θ in BT) to low-grade metamorphism (0.19°Δ2θ in MS). In all three samples, mica crystals are of a size typical of the epizone, but the mean size increases from BT to RBT and MS, due to the increasing strain features from BT to MS. These results indicate that strain-induced reduction in crystal size was retained in BT samples (with anomalously high IC values). Microtextures in RBT and MS (with smaller IC) samples suggest a recovery of sub-grain boundaries. A decrease in crystal size may occur with increasing grade where strain rates are high relative to the rate of recrystallization.

Low-grade metamorphism in the Scottish Southern Uplands terrane: deciphering the patterns of accretionary burial, shearing and cryptic aureoles

2000 ◽  
Vol 91 (3-4) ◽  
pp. 521-537 ◽  
Author(s):  
R. J. Merriman ◽  
B. Roberts
Keyword(s):  
Shear Zone ◽  
High Strain ◽  
Low Grade ◽  
Strain Rates ◽  
Illite Crystallinity ◽  
Regional Pattern ◽  
Grade Metamorphism ◽  
Block Movement ◽  
Granitic Intrusions ◽  
Present Pattern

ABSTRACTSystematic studies of metapelitic grade linked with the geological re-survey of the Southern Uplands have been used to generate a contoured metamorphic map currently covering nearly two-thirds of the terrane. These studies, based on approximately one pelite sample per 2·5 km2, have used XRD measurements of clay mineral reaction progress, particularly illite crystallinity, to delineate zones of diagenesis and low-grade metamorphism in the imbricated Ordovician and Silurian strata. The regional pattern revealed by metapelitic zonal sequences does not agree with earlier observations that grade increases across the strike, from SE to NW. Instead, the map shows considerable variations in metamorphic trends, including patterns of grade increasing from older into younger strata, indicative of accretionary burial. Other patterns identified include those generated by high strain rates in the Moniaive Shear Zone (MSZ), and by extensive low-temperature cryptic aureoles associated with late granitic intrusions. The present pattern is the result of uplift that generated normal movement on reactivated thrust faults and differential block movement on NW-trending faults.Regional metamorphic patterns were generated by burial and underplating in an accretionary thrust stack. Subduction was initiated in the early Caradoc and probably ceased in the early Wenlock. Metapelitic patterns suggest that two levels of accretion are exposed in the terrane. Strata accreted to the toe of the prism and stacked above the décollement zone are typically at late diagenetic grade. Underplated strata below the décollement are typically at anchizonal grades with moderate to well-developed slaty cleavage. Coherent thrust-bounded tracts of strata at both levels were rotated and buried to produce a syntectonic depth-controlled pattern of meta-morphism. Shear zone metamorphism at depths of 12 km or more was probably confined to the underplated lower level of the thrust stack, and Devonian granitic intrusions were also emplaced mainly within the underplated strata.

Batch Precipitation of Lead Iodide

1994 ◽  
Vol 59 (6) ◽  
pp. 1301-1304
Author(s):  
Jaroslav Nývlt ◽  
Stanislav Žáček
Keyword(s):  
Aqueous Solution ◽  
Particle Size ◽  
Particle Size Distribution ◽  
Size Distribution ◽  
Crystal Size ◽  
Lead Nitrate ◽  
Lead Iodide ◽  
Constant Rate ◽  
Mean Size ◽  
The Mean

Lead iodide was precipitated by a procedure in which an aqueous solution of potassium iodide at a concentration of 0.03, 0.10 or 0.20 mol l-1 was stirred while an aqueous solution of lead nitrate at one-half concentration was added at a constant rate. The mean size of the PbI2 crystals was determined by evaluating the particle size distribution, which was measured sedimentometrically. The dependence of the mean crystal size on the duration of the experiment exhibited a minimum for any of the concentrations applied. The reason for this is discussed.

Low-grade metamorphism and accretion tectonics: Southern Uplands terrain, Scotland

1985 ◽  
Vol 49 (352) ◽  
pp. 335-344 ◽  
Author(s):  
A. E. S. Kemp ◽  
G. H. J. Oliver ◽  
J. R. Baldwin
Keyword(s):  
Subduction Zones ◽  
Structural Data ◽  
Low Grade ◽  
Structural Level ◽  
Concomitant Increase ◽  
Illite Crystallinity ◽  
Grade Metamorphism ◽  
Trench Slope ◽  
Reflectance Data ◽  
Trajectory Characteristic

AbstractPrevious studies of low-grade metamorphism in the Southern Uplands accretionary terrain indicated prehnite-pumpellyite facies/anchizone conditions developed throughout the area, except for local preservation of trench-slope sediments and an accreted seamount at zeolite facies/advanced diagenetic grade. New graptolite reflectance data are presented that show a general northward increase in temperature in the Southern Uplands. The results from two cross-strike traverses in the southern and central belts in contemporaneous sequences, using illite crystallinity, illite lateral spacing (bo) , and graptolite reflectance, indicate the development of systematic accretion-related low-grade metamorphism. Well-developed and constant anchizone conditions occur throughout the NE (Langholm) traverse, associated with common, F1 accretion-related folding and a regionally penetrative S1 cleavage. In the SW (Kirkcudbright) traverse, however, the youngest, last accreted packets are preserved at a transitional diagenetic stage and lack a penetrative S1 cleavage. Illite crystallinity, graptolite reflectance, and bo increase systematically northward through earlier accreted packets, reaching values of the NE traverse only at the northern end. The concomitant increase of bo with illite crystallinity suggests the relatively high P-low T trajectory characteristic of subduction zones. Integration of metamorphic and structural data relates increasing intensity of aceretion-related F1 folding, developmertt of S1 fabric, and onset of later fold phases to grade of metamorphism and structural level within the accretionary pile.

Structural Changes in a 304-Type Austenitic Stainless Steel Processed by Multiple Hot Rolling

2011 ◽  
Vol 409 ◽  
pp. 730-735 ◽  
Author(s):  
Zhanna Yanushkevich ◽  
Andrey Belyakov ◽  
Rustam Kaibyshev
Keyword(s):  
Stainless Steel ◽  
Austenitic Stainless Steel ◽  
Dynamic Recrystallization ◽  
Grain Boundaries ◽  
Hot Rolling ◽  
Structural Changes ◽  
The Other ◽  
Dynamic Processes ◽  
Mean Size ◽  
The Mean

The microstructure evolution and the dynamic processes of grain refinement in a 304-type austenitic stainless steel during multiple calibre hot rolling at temperatures of 700-1000°C were studied. The structural changes are characterized by the elongation of original grains towards the rolling axis and the development of new fine grains, the mean size of which decreases with decreasing the deformation temperature. During multiple rolling at 1000°C, the new grains resulted from the development of discontinuous dynamic recrystallization involving a bulging of frequently corrugated grain boundaries. On the other hand, the new grain boundaries leading to remarkable refinement of original microstructure were developed at temperatures below 800°C as a result of continuous strain-induced reactions.

Significance of illite crystallinity and bo values of K-white mica in lowgrade metamorphic rocks, North Hill End Synclinorium, New South Wales, Australia

1985 ◽  
Vol 49 (352) ◽  
pp. 357-364 ◽  
Author(s):  
R. Offler ◽  
E. Prendergast
Keyword(s):  
Early Carboniferous ◽  
Geothermal Gradient ◽  
White Mica ◽  
Low Grade ◽  
Illite Crystallinity ◽  
The North ◽  
South Wales ◽  
The Mean ◽  
Two Populations

AbstractA study of low-grade metamorphism in late Silurian to early Carboniferous rocks in the North Hill End Synclinorium and adjacent anticlinoria has been made by the determination of illite crystallinity and bo values of K-white mica in eighty slates and phyllites. Illite crystallinity values vary from 0.40 Δ°2θ on the Molong Anticlinorium to 0.12 Δ°2θ within the axis of the synclinorium, suggesting anchizonal to epizonal metamorphic conditions. This is in agreement with previous observations on Ca-Al-hydrosilicate assemblages which indicated a change from prehnite-pumpellyite facies in the anticlinoria adjacent to the synclinorium to middle greenschist facies in the axis. Local variations in crystallinity are attributed to variation in ak+ in fluids migrating along cleavage zones.The mean bo value obtained from the pelites is 9.017 Å (σn = 0.008; n = 80) which is in close agreement with that obtained from part of the adjacent Capertee Anticlinorium (x̄ = 9.019 Å; σn = 0.007; n = 52). However, ‘t’ tests indicate that two bo populations are present in the synclinorium (x̄ = 9.019 and 9.022 Å), with the lower values concentrated in the southern portion of this structure. The two populations are considered to be the result of slightly different metamorphic conditions prevailing during the deformation of the rocks in the synclinorium. A higher geothermal gradient affecting rocks giving the lower bo values is attributed to the presence of granitoids at shallower depths than elsewhere in the synclinorium.

Illite Crystallinity Mapping of Very Low Grade Metamorphism of Triassic Metapelites in the Zoigê Area, Western China

2012 ◽  
Vol 86 (1) ◽  
pp. 96-105 ◽  
Author(s):  
TANG Yan ◽  
SANG Longkang ◽  
YUAN Yanming ◽  
YU Jishun ◽  
ZHANG Yunpeng ◽  
...  
Keyword(s):  
Western China ◽  
Low Grade ◽  
Illite Crystallinity ◽  
Grade Metamorphism

scholarly journals The connectivity of crystallite agglomerates in low-density firn at Kohnen station, Dronning Maud Land, Antarctica

2008 ◽  
Vol 49 ◽  
pp. 114-120 ◽  
Author(s):  
J. Freitag ◽  
S. Kipfstuhl ◽  
S.H. Faria
Keyword(s):  
Crystal Size ◽  
Three Dimensional ◽  
Grain Boundary Sliding ◽  
Size Distributions ◽  
Coordination Numbers ◽  
Dronning Maud Land ◽  
Mean Size ◽  
Surface Section ◽  
Boundary Sliding ◽  
The Mean

AbstractIn this study, the three-dimensional (3-D) microstructure of polar firn is investigated by means of X-ray microfocus computer tomography (mCT). Basic topological properties including the Euler and coordination numbers are derived from the reconstructed 3-D volume images. It is shown that sample volumes of about 4 cm3 are representative for polar firn in terms of their connectivity. The connectivity function defined as the change of Euler number with structure size is calculated via image-processing routines. It is used to split the ice phase at small bridges into single crystallite agglomerates. The bond-size distributions and the mean size of the agglomerates are estimated. All μCT measurements were carried out on the uppermost 9 m of a shallow firn core (B35) drilled during the 2005/06 field campaign at Kohnen station, Dronning Maud Land (DML), Antarctica. The results are compared with estimates from classical two-dimensional (2-D) surface section observations. The 3-D approach confirms the linear relationship between coordination number and density which hitherto has only been derived from 2-D observations. Layers of buried snow dunes show a stronger connectivity than layers of moderate crystal size and density. The formation of agglomerates made of crystallites is a common feature of polar firn in DML. It is proposed that the growth of agglomerates leads to reduced critical densities for the transition between the densification regime of grain boundary sliding and plastic deformation.

Continuous Precipitation of Lead Iodide

1994 ◽  
Vol 59 (7) ◽  
pp. 1503-1510
Author(s):  
Stanislav Žáček ◽  
Jaroslav Nývlt
Keyword(s):  
Growth Rate ◽  
Particle Size ◽  
Crystal Size ◽  
Crystal Growth Rate ◽  
Laboratory Model ◽  
Lead Iodide ◽  
Secondary Nucleation ◽  
Equimolar Ratio ◽  
Continuous Precipitation ◽  
The Mean

Lead iodide was precipitated from aqueous solutions of 0.015 - 0.1 M Pb(NO3)2 and 0.03 - 0.2 M KI in the equimolar ratio using a laboratory model of a stirred continuous crystallizer at 22 °C. After reaching the steady state, the PbI2 crystal size distribution was measured sedimentometrically and the crystallization kinetics was evaluated based on the mean particle size. Both the linear crystal growth rate and the nucleation rate depend on the specific output of the crystallizer. The system crystallization constant either points to a significant effect of secondary nucleation by the mechanism of contact of the crystals with the stirrer blade, or depends on the concentrations of the components added due to the micromixing mechanism.

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