The geochemistry and tectonic setting of the Demirköy pluton of the Srednogorie–Istranca granitoid chain, NW Turkey

1991 ◽  
Vol 55 (379) ◽  
pp. 249-256 ◽  
Author(s):  
A. Aykol ◽  
S. Tokel
Keyword(s):  
Upper Cretaceous ◽  
Tectonic Setting ◽  
Chemical Analyses ◽  
Light Rare Earth ◽  
Calc Alkaline ◽  
High Field Strength ◽  
Nw Turkey ◽  
Arc Setting ◽  
Subduction System ◽  
Light Rare Earth Elements

AbstractThe chain of Late Subhercynian granitoids can be traced along the Srednogorie-Istranca-Pontid belt. The Demirköy pluton outcrops in the Istranca segment. The rocks of the pluton range from diorite through grandiorite to perthite granite with granodiorite predominating. On the basis of 25 chemical analyses, the intrusive setting of the granitoid has been investigated. Calcic to calc-alkaline and peraluminous to metaluminous character indicate a subduction-related origin. Low to moderate concentrations of the large-ion lithophiles (LIL), high field strength elements (HFS), light rare earth elements (La, Ce) and low HFS/LIL ratios indicate a mantle-derived magma with subduction-related enrichment. Trace element discrimination diagrams such as Rb/Zr-Nb, Rb/Zr-Y, Rb-SiO2 and Rb-(Nb + Y), are particularly indicative of normal arc-setting for the samples.The Demirköy granitoid is chemically indistinguishable from the Upper Cretaceous granitoids of Strednogorie to the west and the Pontids to the east. This extensive maximum of plutonism can be considered as a time marker in the northern Tethys subduction system.

scholarly journals Petrology and Geochemical Features of Semporna Volcanic Rocks, South-east Sabah, Malaysia

2021 ◽  
Vol 50 (1) ◽  
pp. 9-21
Author(s):  
Elvaene James ◽  
Azman Abdul Ghani ◽  
Oluwatoyin O. Akinola ◽  
Junaidi Asis
Keyword(s):  
Volcanic Rocks ◽  
Geochemical Data ◽  
Magma Source ◽  
Light Rare Earth ◽  
Calc Alkaline ◽  
Ce Anomaly ◽  
Arc Setting ◽  
A Minor ◽  
Light Rare Earth Elements

The volcanic rocks in Semporna Peninsula, Sabah, Malaysia forms parts of the Miocene subjected slab during the Miocene-Pliocene orogeny. This study presents new petrographic and geochemical data of volcanic rocks in Semporna area. The volcanic rocks range in composition from basaltic andesite, andesite, dacite to rhyolite, with most of the volcanic shows calc-alkaline affinity with a minor tholeiitic feature. The trace elements shows enrichment in large-ion lithophile elements (LILE) and light rare earth elements (LREE) suggesting that the volcanic rocks have similar geochemical patterns and might come from similar magma source. The petrochemical data suggests that volcanic rocks of Semporna shows characteristic of subduction zone (negative Nb, Ta, and Ti). Decreasing magnitude of Europium anomalies from intermediate to acid lavas suggests an important role of plagioclase in the fractional crystallization. Negative Ce anomaly in part of Semporna volcanic rocks suggest that those volcanic rocks may related with emergence of oxygenated deep-sea environment. Tectonic diagrams showed that the Semporna volcanic rocks were formed in an island arc setting.

scholarly journals Examination of alteration and metasomatic zones based on the tectonic setting of the Kamoo region (northeast of Isfahan, Iran)

2020 ◽  
Vol 33 (02) ◽  
pp. 223-238
Author(s):  
Manouchehr Alahbakhshi ◽  
Reza Mehrnia ◽  
Mohammad Reza Espahbod ◽  
Afshin Ashja-Ardalan
Keyword(s):  
Rare Earth ◽  
Host Rock ◽  
Tectonic Setting ◽  
Iron Hydroxides ◽  
Light Rare Earth ◽  
Eu Anomaly ◽  
Exposed Part ◽  
Back Arc ◽  
Iron Grade ◽  
Light Rare Earth Elements

Kamoo region (northeast of Isfahan) has an anticline structure with a northwest-southeast trend. The exposed part of this anticline consists of siltstone-sandstone and Jurassic shale, which is located below the Cretaceous formation as an unconformity. Penetration by magmatic masses (dikes) and mineralization events are mainly related to fault systems and fractures in the region and follow the trend of the anticline. In addition, the intensity and variety of alterations are affected by tectonic factors, with alteration and metasomatic haloes having developed next to crushed areas. The alteration process is the main controller of mineral mass grade in the study area; therefore, iron grade in the Kamoo ore has increased by the effects of alteration. The alteration effects include propylitic haloes, iron hydroxides (limonite), and clay mineralization (argillic). The host rock consists of Jurassic shales with siltstone, sandstone, and Cretaceous limestone. Calcareous formations adjacent to granodiorite masses are the main hosts of iron skarns. The results of this study showed that the mineral samples from Kamoo were relatively rich in Light Rare Earth Elements (LREEs); the average La/Yb ratio is about 18.61 and Eu anomaly is between 0.52 and 1.94. Based on the findings of this study, the origin for Kamoo skarn was consistent with the model presented by Meinert, and the region’s mineralization and alteration characteristics correspond to the conditions prevailing in oceanic subduction and back-arc basin environments.

Emplacement mechanism of the Tafresh granitoids, central part of the Urumieh–Dokhtar Magmatic Arc, Iran: evidence from magnetic fabrics

2019 ◽  
Vol 156 (9) ◽  
pp. 1510-1526
Author(s):  
Davoud Raeisi ◽  
Hassan Mirnejad ◽  
Maryam Sheibi
Keyword(s):  
Tectonic Setting ◽  
Magnetic Fabric ◽  
Shape Parameters ◽  
Calc Alkaline ◽  
High Field Strength ◽  
Magmatic Arc ◽  
Arc Magmas ◽  
Magnetic Fabrics ◽  
Data Field ◽  
Emplacement Mechanism

AbstractGranitoid stocks crop out in the Ghahan and Sarbadan areas near Tafresh city, which is situated in the central part of the Urumieh–Dokhtar Magmatic Arc, Iran. The stocks, consisting of porphyritic and sub-granular diorite and granular granodiorite, intruded into Eocene volcano-sedimentary units. Normalized multi-element diagrams indicate that the analysed rocks are enriched in large-ion lithophile elements and depleted in high field strength elements. These geochemical features are typical of subduction-related calc-alkaline arc magmas. The stocks belong to the ferromagnetic and I-type granitoid series. Anisotropy of magnetic susceptibility provides information about the internal fabric of the granitoids. Susceptibility values range from 5.6 × 10−3 to more than 71.6 × 10−3, averaging 27.9 × 10−3 SI. Relatively low anisotropy values (P%) rarely exceed 10 %. Shape parameters (T) vary between −0.48 and +0.74, averaging + 0.2. Each stock is interpreted to contain a distinct feeder zone in which magnetic lineation plunges steeply (> 60°), suggesting that the magma ascended mainly in a NW–SE conduit and, to a lesser extent, in an E–W direction. Integration of magnetic fabric data, field observations and tectonic setting indicates that the shear zone that was developed between the Indes and Talkhab faults had created an opening into which the Ghahan and Sarbadan stocks were emplaced by way of creating a suitable tensional space for the ascent of magma.

Stratigraphy, geochemistry, and petrology of the Upper Cretaceous volcanic arc sequence north of Istanbul, Pontides, NW Turkey

2021 ◽  
Author(s):  
Cemre Ay ◽  
Gürsel Sunal ◽  
Aral I. Okay
Keyword(s):  
Black Sea ◽  
Upper Cretaceous ◽  
High Ratio ◽  
Primitive Mantle ◽  
Geochemical Data ◽  
The Black Sea ◽  
Calc Alkaline ◽  
High K ◽  
Nw Turkey ◽  
Pattern Display

<p>Upper Cretaceous arc-related volcanic and volcanoclastic units overlying the Paleozoic sedimentary rocks of the Istanbul Zone are a key unit related to the opening of the Black Sea as a back-arc basin. They formed as a result of north dipping subduction of the Neo-Tethys Ocean beneath Laurasia. We studied the Upper Cretaceous volcanic units north of Istanbul along several stratigraphic sections, and present new geochemical data from the volcanic rocks in order to understand Cretaceous geodynamic evolution of the İstanbul Zone.</p><p>The Upper Cretaceous  volcanic units north of Istanbul are divided into two formations. At the base there is a fore-arc turbidite succession,the İshaklı Formation, which is made up of volcaniclastic sandstone, shale, marl, tuff, debris flow horizons and epiclastic rocks of Turonian age. The İshaklı Formation is conformably overlain by the volcanoclastics,  tuffs, andesite and basalt lavas and agglomerates- the Riva Formation, which represents the arc/ intra-arc series.</p><p>Geochemically, basalts and basaltic andesites of the Riva Formation are low K calc-alkaline to medium-high K calc-alkaline and with magnesium numbers ranging from 32.6% to 51.5% Primitive mantle normalized spider diagram of trace elements show  enrichment in LILE elements (K, Rb, Sr, Cs, Ba, Th and U) and depletion in HFS elements ( Nb,Ta and Ti) . The high ratio of LILE/ HFS and negative Nb-Ta anomalies indicate that the volcanism evolved in subduction setting. Chondirite-normalized REE pattern display slight negative Eu anomalies and the La/Yb ratios of the samples range between 2,76 and 4,89. Our new geochemical, stratigraphical and the regional geological data suggest that north of Istanbul there was a transition from fore-arc deposition to arc volcanism during the Late Cretaceous opening of the Western Black Sea.  Considering the whole Pontide – Sredna-Gora Upper Cretaceous magmatic arc, it can be stated that calc-alkaline volcanism developed in relation to northward subduction of the Neo-Tethys oceanic lithosphere during the Turonian, and may have passed into high-K calc alkaline and shoshonitic magmatism as a result of the progressive extentional tectonism during the Campanian.</p>

Caractérisation, genèse et évolution géodynamique du terrain de Guerrero (Mexique occidental)

1992 ◽  
Vol 29 (11) ◽  
pp. 2478-2489 ◽  
Author(s):  
H. Lapierre ◽  
M. Tardy ◽  
C. Coulon ◽  
E. Ortiz Hernandez ◽  
J.-L. Bourdier ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Early Cretaceous ◽  
North American ◽  
Light Rare Earth ◽  
Calc Alkaline ◽  
The North ◽  
Guerrero Terrane ◽  
North American Craton ◽  
Light Rare Earth Elements

The Guerrero terrane (western Mexico) is composed of Late Jurassic – Early Cretaceous plutono-volcanic and volcano-sedimentary sequences of the Alisitos–Teloloapan arc that accreted to the North American craton at the end of the Early Cretaceous. The geodynamic evolution of the Guerrero terrane is that of the Alisitos–Teloloapan intraoceanic arc, partly built on continental crust and partly on oceanic crust. The growth of the arc was likely linked to the subduction of the Arperos and Olvidada basins fringing the North American borderland. The subduction was dipping west-south-west.The continent-based segment of the arc, which is presently exposed mainly in northwestern Mexico, is composed of aerial and submarine K-rich calc-alkaline basalts, andesites, and rhyolites and of siliceous pyroclastic rocks interbedded with Aptian–Albian bioclastic carbonates or red beds bearing dinosaurus foot prints. The calc-alkaline basalts and andesites show light rare earth elements enriched patterns and high concentrations in large ion lithophile elements. The siliceous andesites and rhyodacites display low contents in Y and heavy rare earth elements, uncommon for such calc-alkaline SiO2-saturated rocks. This depletion is likely linked to amphibole fractionation and to the presence of sphene and zircon, minerals known to concentrate the heavy rare earth elements.In contrast, the magmatic arc sequences built on oceanic crust, that crops out in central-southern areas of the Guerrero terrane, show an evolution with time. The activity of the arc began with depleted tholeiitic igneous rocks, followed first by mature tholeiitic basalts, then by calc-alkaline olivine basalts interbedded with micritic limestones and radiolarian oozes of Early Cretaceous age (Neocomian). At the end of the arc development, in Late Aptian–Albian, calc-alkaline pillow basalts and andesites erupted at the volcanic front whereas shoshonitic basalts emitted backwards. In the late Early Cretaceous, the arc drifted towards the north and collided with the craton. Arc tholeiites are characterized by flat rare earth element patterns or slightly depleted in light rare earth elements and by high εNd ratios. The calc-alkaline plutonic and volcanic rocks show light rare earth elements enriched patterns and their εNd ratios decrease with time. This decrease of the εNd ratios suggests that either the mantle source of the calc-alkaline rocks was contaminated by subducted terrigenous sediments derived from an old continental crust (North American craton) or that these calc-alkaline rocks derive from the partial melt of an oceanic island basalt source present in the mantle wedge. The shoshonitic features of the basalts are marked by the presence of sanidine in the groundmass and the high levels of K2O, Ba, and Sr of the unaltered rocks.

Petrogenesis and tectonic implications of Late Mesoproterozoic A1- and A2-type felsic lavas from the Huili Group, southwestern Yangtze Block

2019 ◽  
Vol 156 (08) ◽  
pp. 1425-1439 ◽  
Author(s):  
Dong-Bing Wang ◽  
Bao-Di Wang ◽  
Fu-Guang Yin ◽  
Zhi-Ming Sun ◽  
Shi-Yong Liao ◽  
...  
Keyword(s):  
Tectonic Setting ◽  
Yangtze Block ◽  
Isotopic Data ◽  
High Field Strength ◽  
Group I ◽  
Icp Ms ◽  
Basaltic Magmas ◽  
Group Ii ◽  
Arc Setting ◽  
Back Arc

AbstractThis paper presents new LA-ICP-MS zircon U–Pb chronology, whole-rock geochemical and zircon Hf isotopic data for the felsic lavas of the Huili Group from the southwestern Yangtze Block. LA-ICP-MS zircon U–Pb dating shows that these rocks were emplaced in Late Mesoproterozoic time (∼1028 to 1019 Ma). Relative to typical I-type and S-type granitoids, all the samples are characterized by low Sr and Eu, and high high-field-strength element contents, highTFeO/MgO, enriched rare earth element compositions and negative Eu anomalies, indicating that they share the geochemical signatures of A-type granitoid. They can be further divided into two groups: Group I and Group II. Group I are A1-type felsic rocks and were produced by fractional crystallization of alkaline basaltic magmas. The Group II felsic lavas belong to the A2-type and were derived by partial melting of a crustal source with mixing of mantle-derived magmas. Both Group I and Group II felsic lavas may erupt in a continental back-arc setting. The coexistence of A1- and A2-type rocks in the southwestern Yangtze Block suggests that they can occur in the same tectonic setting.

Alteration of volcanic rocks and genesis of kaolin deposits in the Şile Region, northern İstanbul, Turkey. Part II: differential mobility of elements

Clay Minerals ◽  
2003 ◽  
Vol 38 (4) ◽  
pp. 529-550 ◽  
Author(s):  
O. I. Ece ◽  
Z.-E Nakagawa
Keyword(s):  
Upper Cretaceous ◽  
Source Region ◽  
Volcanic Rocks ◽  
Crustal Contamination ◽  
Aegean Sea ◽  
Calc Alkaline ◽  
Tectonic Zone ◽  
Nw Turkey ◽  
Parent Rocks ◽  
Kaolin Deposit

AbstractIn the area of S° ile, NW Turkey, Upper Cretaceous calc-alkaline volcanic rocks with compositions ranging from andesite to rhyolite have been recognized. The most widespread rocks of the suite are andesites, which can be grouped into altered and fresh. The oldest altered andesites are the parent rocks for the kaolin deposits of the study area. The Upper Cretaceous volcanic suite consists of spilite, basalt, andesite, trachyandesite, trachyandesitic and hyaloandesitic dacite, rhyolite lavas, tuffs and agglomerates. The highly altered andesites are composed of plagioclase, pyroxene, hornblende, biotite, augite and very fine opaque minerals. During the Turonian, an E –W trending extensional magmatic arc was developed in the Istanbul Tectonic Zone of the oceanic Western Black Sea basin and intermediate volcanic rocks were emplaced, mostly calc-alkaline andesites, suggesting multi-stage magmatism. The significant features of the andesites are: (1) enrichment of LILE (Rb, Ba, K) over HFSE (Zr, Nb, Hf, Ti, Th, U, Y) and LREE (La –Sm), resulting in high Ba/Nb, Th/Nb, Ba/La, K/Ti and Th/La ratios; (2) depletion of LREE over HFSE, MREE and HREE, generating high La/Nb, Ce/Ti, La/Sm and La/Y values; and (3) depletion of Nb, Sr and Ti; all of which are typical of island arc magmatism, with possible back arc signature. The Th-Hf-Ta diagram for tectonomagmatic classification shows that the S° ile calc-alkaline rocks are similar to volcanic rocks from the Mariana Arc, the Aeolian Arc of Salina, Italy, the Skaros island in the Aegean Sea and Sardinia's ignimbrites. Moreover, relatively low La/Th and Ce/Pb ratios suggest that the source region of volcanism was enriched in LILE with respect to REE, indicating crustal contamination during melting.Highly weathered andesitic rocks, rich in smectite, were transported gradually and deposited in a lacustrine basin, a coal-forming dysaerobic environment, in which they were subject to post-depositional alteration, or in situkaolinization, to form a kaolin deposit in the presence of humic and fulvic acids. The mobility of major and trace elements and REEs during the progressive kaolinization of andesitic materials has been investigated to reveal the geochemical characteristics of Upper Cretaceous volcanic parent rocks and to explain mineralogical processes in a kaolin deposit as a daughter rock ‘end-product’ . Alteration is characterized by the loss of Si, Fe, Ca, Na and K, and by the gain of Al, Ti, Zr and LOI. Moreover, Ho, Er and Yb are immobile, and Hf, Zr and Nb are mobile. Th and U are slightly enriched in clay horizons with respect to the andesitic rocks. In addition, Cr, Ga, Nb and Ta enrichments indicate variable sources of terrigenous sediments and differential mobilities of elements in lake waters rich in organic acids. The anatase concentration increases in the <2 mm size fractions as subspherical particles and these precipitate at acidic conditions (pH ≈ 5) during early diagenesis.

Stratigraphy, structure and geochemistry of Archaean supracrustal rocks from Oqaatsut and Naajaat Qaqqaat, north-east Disko Bugt, West Greenland

1999 ◽  
pp. 65-78
Author(s):  
Henrik Rasmussen ◽  
Lars Frimodt Pedersen
Keyword(s):  
Tectonic Setting ◽  
Trace Element Geochemistry ◽  
Element Geochemistry ◽  
West Greenland ◽  
North West ◽  
North East ◽  
Metavolcanic Rocks ◽  
Arc Setting ◽  
Area North ◽  
Back Arc

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Rasmussen, H., & Frimodt Pedersen, L. (1999). Stratigraphy, structure and geochemistry of Archaean supracrustal rocks from Oqaatsut and Naajaat Qaqqaat, north-east Disko Bugt, West Greenland. Geology of Greenland Survey Bulletin, 181, 65-78. https://doi.org/10.34194/ggub.v181.5114 _______________ Two Archaean supracrustal sequences in the area north-east of Disko Bugt, c. 1950 and c. 800 m in thickness, are dominated by pelitic and semipelitic mica schists, interlayered with basic metavolcanic rocks. A polymict conglomerate occurs locally at the base of one of the sequences. One of the supracrustal sequences has undergone four phases of deformation; the other three phases. In both sequences an early phase, now represented by isoclinal folds, was followed by north-west-directed thrusting. A penetrative deformation represented by upright to steeply inclined folds is only recognised in one of the sequences. Steep, brittle N–S and NW–SE striking faults transect all rock units including late stage dolerites and lamprophyres. Investigation of major- and trace-element geochemistry based on discrimination diagrams for tectonic setting suggests that both metasediments and metavolcanic rocks were deposited in an environment similar to a modern back-arc setting.

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