scholarly journals Spectroscopic (analytical) approach to gunshot residue analysis for shooting distance estimation: a systematic review

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Maxwell Abedi ◽  
Dan O. M. Bonsu ◽  
Isaac K. Badu ◽  
Richmond Afoakwah ◽  
Pooja Ahuja
Keyword(s):  
Spectroscopic Method ◽  
Residue Analysis ◽  
Distance Estimation ◽  
Gunshot Residue ◽  
Future Research ◽  
Sensitivity And Selectivity ◽  
A Current ◽  
Shooting Distance ◽  
Limited Sensitivity

Abstract Background The determination of the shooting distance using gunshot residue (GSR) analysis is crucial in the investigation and reconstruction of firearm-related crimes. However, the conventional chemographic method for GSR analysis is destructive and has limited sensitivity and selectivity. While the spectroscopic method has potential in GSR analysis for crime investigation, there is a current lack of consistency in the spectroscopic results obtained for shooting distance estimation via GSR analysis. Addressing such limitations will enhance the forensic capabilities of law enforcement and provide an added advantage to crime laboratories during an investigation. It will also reinforce the use of such spectroscopic data in a criminal investigation. Main text We obtained all peer-reviewed articles relevant to shooting distance estimation from searching Scopus, Web of Science, PubMed, and Google Scholar databases. We specifically searched the databases using the keywords “shooting distance,” “range of fire,” “gunshot residue,” “firearm discharge residue,” and “firearm-related crime” and obtained 3811 records. We further filtered these records using a combination of two basic keywords “gunshot residue” and “shooting distance estimations” yielding 108 papers. Following a careful evaluation of the titles, abstracts, and full texts, 40 original peer-reviewed articles on shooting distance estimation via GSR analysis were included in the study. The forgoing included additional sources (n = 5) we obtained from looking through the reference lists of the forensic articles we found. Short conclusion This paper discusses the current scope of research concerning the chemographic and spectroscopic analysis of GSR for shooting distance estimation. It also examines the challenges of these techniques and provides recommendations for future research.

scholarly journals Recent Developments in the Methods of Estimating Shooting Distance

2002 ◽  
Vol 2 ◽  
pp. 573-585 ◽  
Author(s):  
Arie Zeichner ◽  
Baruch Glattstein
Keyword(s):  
Distance Estimation ◽  
Instrumental Analysis ◽  
Gunshot Residue ◽  
The Past ◽  
Recent Developments ◽  
Shooting Distance

A review of developments during the past 10 years in the methods of estimating shooting distance is provided. This review discusses the examination of clothing targets, cadavers, and exhibits that cannot be processed in the laboratory. The methods include visual/microscopic examinations, color tests, and instrumental analysis of the gunshot residue deposits around the bullet entrance holes. The review does not cover shooting distance estimation from shotguns that fired pellet loads.

Comparison of SPE/d-SPE and QuEChERS-Based Extraction Procedures in Terms of Fungicide Residue Analysis in Wine Samples by HPLC–DAD and LC-QqQ-MS

2016 ◽  
Vol 99 (6) ◽  
pp. 1436-1443 ◽  
Author(s):  
Tomasz Tuzimski ◽  
Tomasz Rejczak ◽  
Dominika Pieniążek ◽  
Grzegorz Buszewicz ◽  
Grzegorz Teresiński
Keyword(s):  
Multiple Reaction Monitoring ◽  
Residue Analysis ◽  
High Sensitivity ◽  
Extraction Procedures ◽  
Multiple Reaction Monitoring Mode ◽  
Sensitivity And Selectivity ◽  
Dispersive Spe ◽  
Array Detection ◽  
Fungicide Residue

Abstract Two different extraction and clean-up protocols, based on either the SPE/dispersive SPE (d-SPE) or the quick, easy, cheap, effective, rugged, and safe approach, were optimized and compared for determination of six selected fungicides (benalaxyl, metalaxyl, triadimenol, tebuconazole, diniconazole, and epoxiconazole) in wine samples. The pilot study was performed by applying HPLC with diode-array detection, and optimized procedures were easily transferred to the LC triple-quadrupole MS system. Both extraction procedures presented good performance for all the analytes, with recoveries in the range of 70–132% and SDs ≤20%. The d-SPE clean-up step included in both procedures allows obtaining colorless extracts with the majority of coextracted matrix compounds removed. LC with electrospray ionization and tandem MS operating in the multiple reaction monitoring mode provide high sensitivity and selectivity for trace analysis. Both developed procedures were evaluated in terms of commercial wine sample analysis. In three wine samples, metalaxyl and tebuconazole residues were detected at concentrations from 0.14 to 30.7 ng/mL. Both approaches showed satisfactory feasibility for fungicide residue analysis in wine samples.

scholarly journals The effect of type of firearm and shooting distance on pattern distribution, particle dispersion and amount of gunshot residue

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Zainiharyati Mohd Zain ◽  
Siti Nurhazlin Jaluddin ◽  
Mohamed Izzharif Abdul Halim ◽  
Mohamed Sazif Mohamed Subri
Keyword(s):  
Particle Density ◽  
Distance Estimation ◽  
Target Material ◽  
Particle Dispersion ◽  
Gunshot Residue ◽  
Cotton Cloth ◽  
Minimal Amount ◽  
Pattern Distribution ◽  
Firing Distance ◽  
Shooting Distance

Abstract Background Evidence can be defined as the object’s availability and/or information that indicates whether a belief or proposition is true or valid. Gunshot residue (GSR) is an important evidence that can serve many roles in ballistic investigation such as shooting distance, type of firearm and ammunition used in shooting related to GSR. However, due to minimal amount of GSR that can be found in crime scene, suitable methods and technique are required in order to obtain the information from the evidence. This action is also known as evidence recovery. When a firearm is fired, soot or particles are discharged from any opening of the firearm and deposited at the vicinity of point of shooting. Results This study emphasized on the examination of the soot/particles produced and pattern distribution of GSR deposited on white cotton cloth target at varying shooting distances (from 3 to 50 cm) using a video spectral comparator. Pattern distribution and GSR particle density are the main factors in determining the shooting distances in clothing. Principle component analysis (PCA) and hierarchical clustering analysis (HCA) were used to classify firearms; the differences in the GSR pattern distribution are highly recognizable. This study showed that the relationship between the GSR particle dispersion and shooting distance was proportionally linear. The results obtained from the shooting test showed that the diameter of GSR distribution and the amount of residues being deposited from shots fired decreased at distances greater than 21 cm. Conclusion This study will help the investigators in determining the shooting distances and evaluating the firearms used. There is a promising method for examination of GSR pattern on the target material which is also important for firing distance estimation.

Pyrotechnic Residues in Gunshot Residue Analysis

1985 ◽  
Vol 43 ◽  
pp. 128-129
Author(s):  
H. M. Sagara ◽  
S. A. Schliebe ◽  
M. C. Kong
Keyword(s):  
Law Enforcement ◽  
Residue Analysis ◽  
Gunshot Residue ◽  
Particle Analysis ◽  
Dry Skin ◽  
X Ray ◽  
Skin Cells ◽  
Smokeless Powder ◽  
Carbon Coated ◽  
Detailed List

Particle analysis by scanning electron microscopy with energy-dispersive x- ray analysis is one of the current methods used in crime laboratories to aid law enforcement in identifying individuals who have recently fired or handled a firearm. During the discharge of a firearm, the high pressure caused by the detonation of the cartridge materials forces a portion of the generated gases through leaks in the firing mechanism of the weapon. These gases contain residues of smokeless powder, primer mixture, and contributions from the projectile itself. The condensation of these hot gases form discrete, micrometer-sized particles, which can be collected, along with dry skin cells, salts, and other hand debris, from the hands of a shooter by a simple adhesive lift technique. The examination of the carbon-coated adhesive lifts consist of time consuming systematic searches for high contrast particles of spherical morphology with the characteristic elemental composition of antimony, barium and lead. A detailed list of the elemental compositions which match the criteria for gunshot residue are discussed in the Aerospace report.

Self-leadership Training Review

2019 ◽  
Author(s):  
Andrew Sidwell ◽  
Michael Perry
Keyword(s):  
Leadership Training ◽  
Future Research ◽  
Training Methods ◽  
Current State ◽  
A Current

The purpose of this article was to examine the current state of self-leadership training. The authors analyzed all published, publicly available studies (in English) pertaining to self-leadership training methods, offering a current state of self-leadership training, and implications for future research.

UV spectroscopic method for determination of phenytoin in bulk and injection forms

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Quality Control ◽  
Spectrophotometric Method ◽  
Spectroscopic Method ◽  
Ich Guidelines ◽  
Precision And Accuracy ◽  
Routine Quality Control

Recent study was conducted to develop a simple UV spectrophotometric method to determine Phenytoin in bulk and injection form according to official requirement and validate as per ICH guidelines. λmax of Phenytoin was found 202 nm. Linearity existed perceived in the concentration assortment 2-8 μg/ml (r2 = 0.999) for the method. The method was validated pertaining to linearity, precision and accuracy studies, LOD and LOQ consistent with ICH guidelines. The existent method was establish to be simple, linear, precise, accurate as well as sensitive and can be applied for routine quality control enquiry for the analysis of Phenytoin in bulk and injection form.

Development and Validation of Derivative Spectroscopic Method for Simultaneous Estimation of Cefadroxil and Probenecid

2014 ◽  
Vol 7 (1) ◽  
pp. 2350-2355
Author(s):  
Pratik S Mehta ◽  
Pratik R. Patel ◽  
Rajesh R Parmar ◽  
M M K Modasiya ◽  
Dushyant A Shah
Keyword(s):  
Spectroscopic Method ◽  
Spectral Interference ◽  
Synthetic Mixture ◽  
Simultaneous Estimation ◽  
Zero Crossing ◽  
First Order ◽  
Derivative Spectroscopy ◽  
Development And Validation ◽  
Crossing Point

A novel, simple, accurate, sensitive, precise and economical derivative spectroscopic method was developed and validated for the determination of cefadroxil and probenecid in synthetic mixture. First order derivative spectroscopy method was adopted to eliminate spectral interference. The method obeys Beer’s Law in concentration ranges of 4-36 μg/ml for cefadroxil and of 5-25 μg/ml of probenecid. The zero crossing point for cefadroxil and probenecid was 260 nm and 237.8 nm respectively in 0.1N HCl. The method was validated in terms of accuracy, precision, linearity, limits of detection, limits of quantitation. This method has been successively applied to synthetic mixture and no interference from the synthetic mixture’s excipients was found.   

Simultaneous Determination of Alogliptin, Linagliptin, Saxagliptin, and Sitagliptin in Bulk Drug and Formulation by UPLC Q-TOF-MS

2020 ◽  
Vol 17 (1) ◽  
pp. 95-105
Author(s):  
Ramji Rathod ◽  
Faraat Ali ◽  
Amrish Chandra ◽  
Robin Kumar ◽  
Meenakshi Dahiya ◽  
...  
Keyword(s):  
Internal Standard ◽  
Gradient Elution ◽  
Ultra Performance Liquid Chromatography ◽  
Pharmaceutical Dosage Forms ◽  
Sensitivity And Selectivity ◽  
The Mean ◽  
Bulk Drug ◽  
Positive Ion ◽  
Higher Sensitivity

Background: A simple and sensitive Ultra Performance Liquid Chromatography-Mass Spectrometry method was developed and validated to measure the concentrations of Alogliptin (ALO), Linagliptin (LIN), Saxagliptin (SAX), and Sitagliptin (SIT) using Pioglitazone (PIO) as an internal standard. Methods: Chromatographic separation of six gliptins was achieved on a C-18 column (100×2.1 mm, 2.7 μm) using a mobile phase consisting of formic acid in water, 0.1%v/v: acetonitrile in gradient elution. Electrospray ionization (ESI) source was operated in the positive ion mode. Targeted MS/MS mode on a QTOF MS was used to quantify the drug utilizing the transitions of 340.1(m/z), 473.2 (m/z), 316.2 (m/z), 408.1 (m/z), and 357.1 (m/z) for ALO, LIN, SAX, SIT and PIO respectively. Results: As per ICH Q2R1 guidelines, a detailed validation of the method was carried out and the standard curves were found to be linear over the concentration ranges of 1516.0-4548.1 ng mL-1, 519.8- 1559.4 ng mL-1, 1531.4-4594.3 ng mL-1and 1519.6-4558.8 ng mL-1 for ALO, LIN, SAX and SIT respectively. Precision and accuracy results were within the acceptable limits. The mean recovery was found to be 98.8 _ 0.76 % (GEM), 102.2 _ 1.59 % (LIN), 95.3 _ 2.74 % (SAX) and 99.2 _ 1.75 % (SIT) respectively. Conclusions: The optimized validated UPLC QTOF-MS/MS method offered the advantage of shorter analytical times and higher sensitivity and selectivity. The optimized method is suitable for application in quantitative analysis of pharmaceutical dosage forms for QC laboratory.

scholarly journals Current Strategies for Studying the Natural and Synthetic Bioactive Compounds in Food by Chromatographic Separation Techniques

Processes ◽  
2021 ◽  
Vol 9 (7) ◽  
pp. 1100
Author(s):  
Wioletta Parys ◽  
Małgorzata Dołowy ◽  
Alina Pyka-Pająk
Keyword(s):  
Gas Chromatography ◽  
Bioactive Compounds ◽  
Residue Analysis ◽  
Food Products ◽  
Vital Role ◽  
Bioactive Molecules ◽  
Validation Parameters ◽  
Layer Chromatography ◽  
Natural And Synthetic

The present study summarizes the new strategies including advanced equipment and validation parameters of liquid and gas chromatography methods i.e., thin-layer chromatography (TLC), column liquid chromatography (CLC), and gas chromatography (GC) suitable for the identification and quantitative determination of different natural and synthetic bioactive compounds present in food and food products, which play an important role in human health, within the period of 2019–2021 (January). Full characteristic of some of these procedures with their validation parameters is discussed in this work. The present review confirms the vital role of HPLC methodology in combination with different detection modes i.e., HPLC-UV, HPLC-DAD, HPLC-MS, and HPLC-MS/MS for the determination of natural and synthetic bioactive molecules for different purposes i.e., to characterize the chemical composition of food as well as in the multi-residue analysis of pesticides, NSAIDs, antibiotics, steroids, and others in food and food products.

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