scholarly journals Pentafluorophenylammonium triflate: A Mild, Efficient and Reusable Catalyst for the Synthesis of 2-Arylbenzothiazole and 2-Arylbenzothiazoline Derivatives in a Green Chemical Approach

2021 ◽  
Vol 37 (1) ◽  
pp. 95-102
Author(s):  
Arup Datta
Keyword(s):  
Aqueous Medium ◽  
Environmentally Benign ◽  
Reusable Catalyst ◽  
One Pot ◽  
Benzothiazole Derivative ◽  
Chemical Approach ◽  
Effective Synthesis

In this work, one pot, simple and environmentally benign effective synthesis of 2-substituted benzothiazole and benzothiazoline derivatives are described in presence of PFPAT (pentafluorophenylammonium triflate) catalyst in water successfully. A series of benzothiazole derivative were synthesized by the reaction between 2-aminothiophenol and various aldehydes in good yields. Recyclability of the catalyst is observed for four times without loss of its activity in aqueous medium.

ChemInform Abstract: Nanodomain Cubic Cuprous Oxide as Reusable Catalyst in One-Pot Synthesis of 3-Alkyl/Aryl-3- (pyrrole-2-yl/indole-3-yl)-2-phenyl-2,3-dihydro-isoindolinones in Aqueous Medium.

ChemInform ◽  
2014 ◽  
Vol 45 (41) ◽  
pp. no-no
Author(s):  
Swarbhanu Sarkar ◽  
Nivedita Chatterjee ◽  
Manas Roy ◽  
Rammyani Pal ◽  
Sabyasachi Sarkar ◽  
...  
Keyword(s):  
Aqueous Medium ◽  
Cuprous Oxide ◽  
Reusable Catalyst ◽  
One Pot ◽  
Alkyl Aryl ◽  
One Pot Synthesis

scholarly journals Dowex 50W: A Green Mild Reusable Catalyst for the Synthesis of 2-Aryl Benzoxazole Derivatives in Aqueous Medium

2021 ◽  
Vol 37 (2) ◽  
pp. 341-347
Author(s):  
Arup Datta
Keyword(s):  
Aqueous Medium ◽  
Heterogeneous Catalyst ◽  
Environmentally Friendly ◽  
High Yield ◽  
Reusable Catalyst ◽  
One Pot ◽  
Simple Process ◽  
Effective Catalyst ◽  
Rapid Reaction ◽  
Environmentally Friendly Method

In this work simple efficient, one pot and environmentally friendly method was developed for the synthesis of 2-Aryl-1H-benzoxazole derivatives at 80º C using ortho-aminophenol and various aldehydes. It has been found that Dowex50W is an effective catalyst to prepare moderate to high yield of a variety of benzoxazole derivatives through a clean and simple process. Aqueous medium, green methodology, rapid reaction, reusability of heterogeneous catalyst are the great advantages of this protocol.

scholarly journals One-pot synthesis of (S)-2-(6-methoxynaphtalen-2-yl)propanoic acid, (S)-Naproxen using Preyssler and Keggin-type heteropolyacids as green and reusable catalysts

2009 ◽  
Vol 11 (3) ◽  
pp. 8-14 ◽  
Author(s):  
Ali Gharib ◽  
Mohsen Daneshtalab ◽  
J. Scheeren ◽  
Fatemeh Bamoharram ◽  
Mina Roshani ◽  
...  
Keyword(s):  
Enantioselective Synthesis ◽  
Environmentally Benign ◽  
Propanoic Acid ◽  
Reusable Catalyst ◽  
One Pot ◽  
Keggin Type ◽  
One Pot Synthesis

One-pot synthesis of (S)-2-(6-methoxynaphtalen-2-yl)propanoic acid, (S)-Naproxen using Preyssler and Keggin-type heteropolyacids as green and reusable catalysts A simple, clean and environmentally benign route to the enantioselective synthesis of (S)-2-(6-methoxynaphtalen-2-yl)propanoic acid, (S)-Naproxen 3 is described by using Preyssler heteropolyacid, H14[NaP5W30O110], as a green and reusable catalyst in water and in the presence of 1-(6-methoxynaphthalen-2-yl)propan-1-one 1, D-mannitol 2. The products were obtained in very good yields.

scholarly journals Chemoenzymatic one-pot reaction of noncompatible catalysts: combining enzymatic ester hydrolysis with Cu(i)/bipyridine catalyzed oxidation in aqueous medium

RSC Advances ◽  
2017 ◽  
Vol 7 (53) ◽  
pp. 33614-33626 ◽  
Author(s):  
Henning Sand ◽  
Ralf Weberskirch
Keyword(s):  
Aqueous Medium ◽  
Ester Hydrolysis ◽  
Environmentally Benign ◽  
One Pot ◽  
Benign Synthesis ◽  
Catalyzed Oxidation

Combination of a lipase (CALB) with a Cu/bipyridine catalyst for environmentally benign synthesis of aldehydes from their corresponding esters.

scholarly journals Nano-ZnO Catalyzed Multicomponent One-Pot Synthesis of Novel Spiro(indoline-pyranodioxine) Derivatives

2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Harshita Sachdeva ◽  
Rekha Saroj ◽  
Diksha Dwivedi
Keyword(s):  
Microwave Irradiation ◽  
Environmentally Benign ◽  
Conventional Heating ◽  
Reusable Catalyst ◽  
Zno Nanoparticle ◽  
Reaction Conditions ◽  
One Pot ◽  
Apparent Loss ◽  
Synthetic Procedure ◽  
Three Component Reaction

A simple catalytic protocol for the synthesis of novel spiro[indoline-pyranodioxine] derivatives has been developed using ZnO nanoparticle as an efficient, green, and reusable catalyst. The derivatives are obtained in moderate to excellent yield by one-pot three-component reaction of an isatin, malononitrile/ethylcyanoacetate, and 2,2-dimethyl-1,3-dioxane-4,6-dione in absolute ethanol under conventional heating and microwave irradiation. The catalyst was recovered by filtration from the reaction mixture and reused during five consecutive runs without any apparent loss of activity for the same reaction. The mild reaction conditions and recyclability of the catalyst make it environmentally benign synthetic procedure.

scholarly journals Amberlite IR-120 Catalyzed Green and Efficient One-Pot Synthesis of Benzylpyrazolyl Coumarin in Aqueous Medium

2021 ◽  
Vol 10 (3) ◽  
pp. 2525-2534
Keyword(s):  
Reaction Time ◽  
Aqueous Medium ◽  
Ethyl Acetoacetate ◽  
Low Cost ◽  
Cost Effective ◽  
High Yield ◽  
Phenyl Hydrazine ◽  
One Pot ◽  
Time Operation ◽  
Effective Synthesis

An efficient, green, and cost-effective synthesis of benzylpyrazolyl coumarin by one-pot four-component condensation of hydrazine hydrate or phenyl hydrazine, ethyl acetoacetate, aromatic aldehyde, and 4-hydroxycoumarin in the presence of Amberlite IR-120 as a catalyst in an aqueous medium has been reported. Shorter reaction time, operation simplicity, low cost of catalyst, and aqueous medium are key advantages of this method for synthesizing benzylpyrazolyl coumarin in moderate to high yield.

scholarly journals AN EFFICIENT, GREEN, CATALYST FREE SYNTHESIS AND CRYSTALLOGRAPHIC STUDY OF BENZO-4H-PYRANS IN AQUEOUS MEDIUM

2019 ◽  
Vol 9 (4-A) ◽  
pp. 280-289
Author(s):  
SEKAR SILAMBU SILAMBARASAN ◽  
A. Jamal Abdul Nasser
Keyword(s):  
Single Crystal ◽  
Aqueous Medium ◽  
Michael Addition ◽  
Aromatic Aldehydes ◽  
Environmentally Benign ◽  
Monoclinic Space Group ◽  
One Pot ◽  
Green Catalyst ◽  
Space Group ◽  
High Yields

A highly efficient and environmentally benign for the synthesis a of 2-amino-7-hydroxy-4-aryl-4H-chromene-3-carbonitrile derivatives (4a-n) in good to high yields (90%-97%) by one-pot three-component Michael addition reaction of malononitrile, aromatic aldehydes and resorcinol under reflux condition was developed in aqueous medium. Single crystal X-ray studies show that 4h crystallizes in the formula C22H15Cl2N2O2, Mr=410.26, Monoclinic, Space group P2(1)/c, a=12.753(9)Å, b=6.665(4)Å, c=24.050(14) Å, β=102.95(3)A° and 4i C16H10Cl2N2O2, Mr=333.16, Triclinic, Space group P-1, a=6.271(3)Å, b=18.697(5)Å, c =13.794(7) Å,  β =94.269(17)A°. The structure of the products were further confirmed by 1H NMR, 13C NMR, IR and Mass spectrum. Keywords: Benzopyrans, malononitrile, resorcinol, Michael addition, water mediated synthesis, single crystal XRD

scholarly journals H4SiW12O40Catalyzed One-Pot Synthesis of 12-Aryl-8,9,10,12-tetrahydrobenzo[a] Xanthen-11-ones Under Solvent-Free Conditions

2012 ◽  
Vol 9 (2) ◽  
pp. 786-790 ◽  
Author(s):  
A. Hassankhani ◽  
E. Mosaddegh ◽  
S. Y. Ebrahimipour
Keyword(s):  
Catalytic Activity ◽  
Solvent Free ◽  
Environmentally Benign ◽  
Reusable Catalyst ◽  
High Catalytic Activity ◽  
One Pot ◽  
Aryl Aldehydes ◽  
One Pot Synthesis ◽  
Solvent Free Conditions ◽  
The One

An efficient and environmentally benign protocol for the one-pot, three-component synthesis of 12-aryl-8,9,10,12-tetrahydro-benzo[a]xanthen-11-one derivatives by condensation of aryl aldehydes, 2-naphthol and dimedone using H4SiW12O40(SiWA) as a reusable catalyst with high catalytic activity was reported. The reaction was carried out at 100 ºC under solvent-free conditions within 15-40 min in 82-91% yield.

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