scholarly journals Elementary steps in heterogeneous catalysis: The basis for environmental chemistry

2017 ◽  
Vol 22 (1-2) ◽  
pp. 11-41 ◽  
Author(s):  
Gerhard Ertl ◽  
Maria Zielińska ◽  
Małgorzata Rajfur ◽  
Maria Wacławek

Abstract Catalysis is an alternative way for reaching an immediate formation of a product, because of a lower energy barrier (between the molecules and the catalysts). Heterogeneous catalysis comprises the acceleration of a chemical reaction through interaction of the molecules involved with the surface of a solid. It is a discipline, which involves all the different aspects of chemistry: inorganic and analytical chemistry in order to characterize the catalysts and the forms of these catalysts. The industrial chemistry puts all these things together to understand the solid chemical handling, chemical reaction and energy engineering and the heat and mass transfer in these catalytic processes. Very often there are more than one, but several products, then the role of the catalyst is not so much related to activity, but to selectivity. The underlying elementary steps can now be investigated down to the atomic scale as will be illustrated mainly with two examples: the oxidation of carbon monoxide (car exhaust catalyst) and the synthesis of ammonia (the basis for nitrogen fertilizer). There is a huge market for the catalysts themselves despite of their high costs. A large fraction is used for petroleum refineries, automotive and industrial cleaning processes. The catalytic processes is a wide field and there are still many problems concerning energy conservation and energy transformation, so there is much to do in the future.

2016 ◽  
Vol 6 (2) ◽  
pp. 363-378 ◽  
Author(s):  
C. H. Collett ◽  
J. McGregor

Carbonaceous deposits on heterogeneous catalysts are traditionally associated with catalyst deactivation. However, they can play a beneficial role in many catalytic processes, e.g. dehydrogenation, hydrogenation, alkylation, isomerisation, Fischer–Tropsch, MTO etc. This review highlights the role and mechanism by which coke deposits can enhance catalytic performance.


1995 ◽  
Vol 149 ◽  
pp. 72-84
Author(s):  
J. Bland-Hawthorn

AbstractAt optical and infrared wavelengths, imaging Fabry-Perot devices are used in three different ways: (i) to obtain a single spectrum of a diffuse source which fills a large fraction of the aperture, (ii) to obtain a monochromatic image within a field defined by the Jacquinot spot, and (iii) to obtain a spectrum at each pixel position over a wide field by tuning the etalon. We review the theoretical basis for Fabry-Perot photometry and summarize the calibration procedures for the different applications. We discuss methods for recognizing and dealing with artefacts (scattered light, atmospheric effects, etc.) which can seriously comprise the photometric integrity of the data if left untreated.


2020 ◽  
Vol 493 (1) ◽  
pp. 899-921
Author(s):  
Mélanie Habouzit ◽  
Alice Pisani ◽  
Andy Goulding ◽  
Yohan Dubois ◽  
Rachel S Somerville ◽  
...  

ABSTRACT Cosmic voids, the underdense regions of the cosmic web, are widely used to constrain cosmology. Voids contain few, isolated galaxies, presumably expected to be less evolved and preserving memory of the pristine Universe. We use the cosmological hydrodynamical simulation Horizon-AGN coupled to the void finder vide to investigate properties of galaxies in voids at z = 0. We find that, closer to void centres, low-mass galaxies are more common than their massive counterparts. At a fixed dark matter halo mass, they have smaller stellar masses than in denser regions. The star formation rate of void galaxies diminishes when approaching void centres, but their specific star formation rate slightly increases, suggesting that void galaxies form stars more efficiently with respect to their stellar mass. We find that this cannot only be attributed to the prevalence of low-mass galaxies. The inner region of voids also predominantly hosts low-mass black holes (BHs). However, the BH mass-to-galaxy mass ratios resemble those of the whole simulation at z = 0. Our results suggest that even if the growth channels in cosmic voids are different from those in denser environments, voids grow their galaxies and BHs in a similar way. While a large fraction of the BHs have low Eddington ratios, we find that $\text{$\sim$} 20{{\ \rm per\ cent}}$ could be observed as active galactic nuclei with $\log _{10} L_{\rm 2\!-\!10 \, keV}=41.5\!-\!42.5 \, \rm erg\, s^{-1}$. These results pave the way to future work with larger next-generation hydro-simulations, aiming to confirm our findings and prepare the application on data from upcoming large surveys such as Prime Focus Spectrograph, Euclid, and Wide Field Infrared Survey Telescope.


MRS Bulletin ◽  
2006 ◽  
Vol 31 (9) ◽  
pp. 669-674 ◽  
Author(s):  
J.K. Nørskov ◽  
M. Scheffler ◽  
H. Toulhoat

AbstractSolid surfaces are used extensively as catalysts throughout the chemical industry, in the energy sector, and in environmental protection. Recently, density functional theory has started providing new insight into the atomic-scale mechanisms of heterogeneous catalysis, helping to interpret the large amount of experimental data gathered during the last decades. This article shows how density functional theory can be used to describe the state of the surface during reactions and the rate of catalytic reactions. It will also show how we are beginning to understand the variation in catalytic activity from one transition metal to the next. Finally, the prospects of using calculations to guide the development of new catalysts in industry will be discussed.


2020 ◽  
Vol 643 ◽  
pp. A113 ◽  
Author(s):  
K. Ackley ◽  
L. Amati ◽  
C. Barbieri ◽  
F. E. Bauer ◽  
S. Benetti ◽  
...  

Context. Gravitational wave (GW) astronomy has rapidly reached maturity, becoming a fundamental observing window for modern astrophysics. The coalescences of a few tens of black hole (BH) binaries have been detected, while the number of events possibly including a neutron star (NS) is still limited to a few. On 2019 August 14, the LIGO and Virgo interferometers detected a high-significance event labelled S190814bv. A preliminary analysis of the GW data suggests that the event was likely due to the merger of a compact binary system formed by a BH and a NS. Aims. In this paper, we present our extensive search campaign aimed at uncovering the potential optical and near infrared electromagnetic counterpart of S190814bv. We found no convincing electromagnetic counterpart in our data. We therefore use our non-detection to place limits on the properties of the putative outflows that could have been produced by the binary during and after the merger. Methods. Thanks to the three-detector observation of S190814bv, and given the characteristics of the signal, the LIGO and Virgo Collaborations delivered a relatively narrow localisation in low latency – a 50% (90%) credible area of 5 deg2 (23 deg2) – despite the relatively large distance of 267 ± 52 Mpc. ElectromagNetic counterparts of GRAvitational wave sources at the VEry Large Telescope collaboration members carried out an intensive multi-epoch, multi-instrument observational campaign to identify the possible optical and near infrared counterpart of the event. In addition, the ATLAS, GOTO, GRAWITA-VST, Pan-STARRS, and VINROUGE projects also carried out a search on this event. In this paper, we describe the combined observational campaign of these groups. Results. Our observations allow us to place limits on the presence of any counterpart and discuss the implications for the kilonova (KN), which was possibly generated by this NS–BH merger, and for the strategy of future searches. The typical depth of our wide-field observations, which cover most of the projected sky localisation probability (up to 99.8%, depending on the night and filter considered), is r ∼ 22 (resp. K ∼ 21) in the optical (resp. near infrared). We reach deeper limits in a subset of our galaxy-targeted observations, which cover a total ∼50% of the galaxy-mass-weighted localisation probability. Altogether, our observations allow us to exclude a KN with large ejecta mass M ≳ 0.1 M⊙ to a high (> 90%) confidence, and we can exclude much smaller masses in a sub-sample of our observations. This disfavours the tidal disruption of the neutron star during the merger. Conclusions. Despite the sensitive instruments involved in the campaign, given the distance of S190814bv, we could not reach sufficiently deep limits to constrain a KN comparable in luminosity to AT 2017gfo on a large fraction of the localisation probability. This suggests that future (likely common) events at a few hundred megaparsecs will be detected only by large facilities with both a high sensitivity and large field of view. Galaxy-targeted observations can reach the needed depth over a relevant portion of the localisation probability with a smaller investment of resources, but the number of galaxies to be targeted in order to get a fairly complete coverage is large, even in the case of a localisation as good as that of this event.


2014 ◽  
Vol 70 (a1) ◽  
pp. C1181-C1181
Author(s):  
Hidetaka Kasai ◽  
Kenichi Kato ◽  
Akihiro Hori ◽  
Masaki Takata ◽  
Susumu Kitagawa ◽  
...  

In situ synchrotron X-ray powder diffraction can be one of the most powerful probes to investigate the structure evolution by a chemical reaction thanks to simultaneity of data collection. It is not, however, with ease to produce a homogeneous chemical reaction in the limited spaces, which is essential to see an atomic-scale structure evolution. We have developed an in situ capillary cell for both high-temperature H2reduction and precise humidity control at the SPring-8 BL44B2. We successfully applied this in situ system to an electronic conductor LaSr3Fe3O10, which is transformed into an ionic conductor by the two-step chemical treatments [1]. LaSr3Fe3O10has a triple-layer structure with a FeO6octahedral unit. One triple layer is bonded with another layer through van der Waals interaction. Structure refinements with in situ synchrotron powder diffraction data revealed that the H2reduction at 613 K produced in-plane oxygen vacancies, which resulted in suppression of the interlayer interaction. We found from charge density studies and Raman spectroscopy measurements that the following humidification intercalated H2O and OH-into the interlayer and intralayer, respectively. That means that H2O plays a role for suppression of three-dimensional electronic conductivity, stabilizing the intercalation structure. On the other hand, the OH-ions behave as carriers for ionic conductivity, maintaining the charge neutrality in the intralayer. Finally we determined the composition of the ionic conductor to be LaSr3Fe3O8.0(OH)1.2·2H2O, which indicates a transformation of LaSr3Fe3O10into an OH-ionic conductor. In the presentation, I will discuss the OH-ionic conduction channel based on electrostatic potentials obtained from charge densities.


Author(s):  
Ken-ichi Tanaka ◽  
Yuji Matsumoto ◽  
Takaya Fujita ◽  
Yuji Okawa

Catalysts ◽  
2019 ◽  
Vol 9 (8) ◽  
pp. 674
Author(s):  
Claudia Espro ◽  
Francesco Mauriello

Industrial chemistry is changing its fossil distinctiveness into a new green identity by using renewable resources [...]


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