scholarly journals Equilibrium modeling of mono and binary sorption of Cu(II) and Zn(II) onto chitosan gel beads

2016 ◽  
Vol 37 (4) ◽  
pp. 485-501 ◽  
Author(s):  
Józef Nastaj ◽  
Małgorzata Tuligłowicz ◽  
Konrad Witkiewicz
Keyword(s):  
Metal Ion ◽  
Ph Value ◽  
Experimental Studies ◽  
Process Conditions ◽  
Optimal Process ◽  
Sorption Data ◽  
Gel Beads ◽  
Two Component ◽  
Equilibrium Data ◽  
Chitosan Gel

Abstract The objective of the work are in-depth experimental studies of Cu(II) and Zn(II) ion removal on chitosan gel beads from both one- and two-component water solutions at the temperature of 303 K. The optimal process conditions such as: pH value, dose of sorbent and contact time were determined. Based on the optimal process conditions, equilibrium and kinetic studies were carried out. The maximum sorption capacities equaled: 191.25 mg/g and 142.88 mg/g for Cu(II) and Zn(II) ions respectively, when the sorbent dose was 10 g/L and the pH of a solution was 5.0 for both heavy metal ions. One-component sorption equilibrium data were successfully presented for six of the most useful three-parameter equilibrium models: Langmuir-Freundlich, Redlich-Peterson, Sips, Koble-Corrigan, Hill and Toth. Extended forms of Langmuir-Freundlich, Koble-Corrigan and Sips models were also well fitted to the two-component equilibrium data obtained for different ratios of concentrations of Cu(II) and Zn(II) ions (1:1, 1:2, 2:1). Experimental sorption data were described by two kinetic models of the pseudo-first and pseudo-second order. Furthermore, an attempt to explain the mechanisms of the divalent metal ion sorption process on chitosan gel beads was undertaken.

scholarly journals Study on Aqueous Enzymatic Extraction Process of Common Pistache Oil

2021 ◽  
Vol 251 ◽  
pp. 02058
Author(s):  
Feng Xuehua ◽  
Tao Ali ◽  
Song Zurong ◽  
Gong Panpan
Keyword(s):  
Ph Value ◽  
Orthogonal Experiment ◽  
Extraction Process ◽  
Optimal Time ◽  
Process Conditions ◽  
Optimal Process ◽  
Enzymatic Extraction ◽  
Hydrolysis Time ◽  
Aqueous Enzymatic Extraction ◽  
The Common

The aqueous enzymatic method was applied to extract the common pistache oil and the optimal extraction process conditions were identified. By observing the effect of enzymatic hydrolysis time, pH value, temperature on aqueous enzymatic extraction process and performing the orthogonal experiment based on the single factor test, the optimal process parameters were obtained, namely, the optimal time, temperature, and pH value were respectively 3 h, 50℃, and 7 with a final extraction rate of 25.38 %.

scholarly journals Effective removal of heavy metal ions from aqueous solutions using a new chelating resin poly [2,5-(1,3,4-thiadiazole)-benzalimine]: kinetic and thermodynamic study

2015 ◽  
Vol 6 (2) ◽  
pp. 310-324 ◽  
Author(s):  
Selvaraj Dinesh Kirupha ◽  
Selvaraj Kalaivani ◽  
Thangaraj Vidhyadevi ◽  
Periyaraman Premkumar ◽  
Palanithamy Baskaralingam ◽  
...  
Keyword(s):  
Metal Ions ◽  
Metal Ion ◽  
Ph Value ◽  
Thermo Gravimetric Analysis ◽  
Kinetic Studies ◽  
Ion Concentration ◽  
Chelating Resin ◽  
Gravimetric Analysis ◽  
Equilibrium Data ◽  
Experimental Values

A novel poly [2,5-(1,3,4-thiadiazole)-benzalimine] abbreviated as TDPI adsorbent was synthesized using simple polycondensation technique. The synthetic route involves the preparation of 2,5-diamino-1,3,4-thiadiazole from 2,5-dithiourea and subsequent condensation with terephthalaldehyde. The resin was chemically characterized using Fourier transform infrared (FT-IR), 1H-NMR, and 13C-NMR spectroscopic analysis. Surface morphology and thermal stability were analyzed using scanning electron microscopy (SEM) and thermo-gravimetric analysis (TGA). The effect of the pH value of solution, contact time, adsorbent dose, and initial metal ion concentration were investigated by batch equilibrium adsorption experiments. Kinetic studies show that the adsorption of metal ions onto the resin proceeds according to the pseudo-second-order model and the equilibrium data were best interpreted by the Redlich–Peterson isotherm. The experimental values of the adsorption capacities of Pb2+, Cu2+, Ni2+, and Cd2+ on to TDPI could reach up to 437.2, 491.6, 493.7, and 481.9 mg.g−1 respectively. The exothermic nature of the process, the affinity of the adsorbent towards the metal ions and the feasibility of the process are explained in the thermodynamic parameters. The resin stability and re-usability studies suggest that the resin is chemically stable (0.3 N HCl and H2SO4) and could be regenerated without any serious decline in performance.

scholarly journals OPTIMIZATION OF NICKEL (II) AND CHROMIUM (III) REMOVAL FROM CONTAMINATED WATER USING SORGHUM BICOLOR

2017 ◽  
Vol 36 (3) ◽  
pp. 960-972
Author(s):  
LT Adewoye ◽  
SI Mustapha ◽  
AG Adeniyi ◽  
JO Tijani ◽  
MA Amoloye ◽  
...  
Keyword(s):  
Sorghum Bicolor ◽  
Metal Ion ◽  
Ion Concentration ◽  
Optimum Process ◽  
Process Conditions ◽  
Order Kinetic ◽  
Freundlich Model ◽  
Adsorbent Dosage ◽  
Equilibrium Data ◽  
Pseudo Second Order

A central composite design (CCD) under the response surface methodology (RSM)was used to study the effect of three adsorption variables (pH, initial concentration, and adsorbent dosage) in order to determine the optimum process conditions for the adsorptions of Ni (II) and Cr (III) onto sulphuric acid modified sorghum bicolor activated carbon (SBAC).This study yielded removal efficiency of 98.89 % for Ni (II) and 94.27 % for Cr (III) ion under optimal conditions of pH (8), initial metal ion concentration (25 mg/L), adsorbent dosage (10 mg) and pH (7), initial metal ion concentration (5 mg/L), dosage (15 mg);respectively. Statistical analysis of variance results showed a good correlation existed between the experimental and predicted data with R2 values of 0.99 for Ni and 0.98 for Cr. The equilibrium data for Ni (II) adsorption was best described using Freundlich model while Langmuir model best fit Cr (III) adsorption. The mechanism of adsorption for both Ni and Cr adsorptions on SBAC followed Pseudo second order kinetic model.  http://dx.doi.org/10.4314/njt.v36i3.41

Selective Solid-Phase Extraction of Zinc(II) from Environmental Water Samples Using Ion Imprinted Activated Carbon

2015 ◽  
Vol 98 (1) ◽  
pp. 206-212 ◽  
Author(s):  
Elham Moniri ◽  
Homayon Ahmad Panahi ◽  
Khaledeh Aghdam ◽  
Amir Abdollah Mehrdad Sharif
Keyword(s):  
Activated Carbon ◽  
Metal Ion ◽  
Ph Value ◽  
Solid Phase ◽  
Environmental Water ◽  
Scatchard Analysis ◽  
Sorption Data ◽  
Chelating Sorbent ◽  
Ion Imprinted

Abstract A simple ion imprinted amino-functionalized sorbent was synthesized by coupling activated carbon withiminodiacetic acid, a functional compound for metal chelating, through cyanoric chloride spacer. The resulting sorbent has been characterized using FTIR spectroscopy, elemental analysis, and thermogravimetricanalysis and evaluated for the preconcentration and determination of trace Zn(II) in environmental watersamples. The optimum pH value for sorption of the metal ion was 6–7.5. The sorption capacity of the functionalized sorbent was 66.6 mg/g. The chelating sorbent can be reused for 10 cycles of sorption-desorption without any significant change in sorptioncapacity. A recovery of 100% was obtained for the metal ion with 0.5 M nitric acid as the eluent. Compared with nonimprinted polymer particles, the preparedZn-imprinted sorbent showed high adsorption capacity, significant selectivity, and good site accessibility for Zn(II). Scatchard analysis revealed that the homogeneous binding sites were formed in the polymer. The equilibrium sorption data of Zn(II) by modified resin were analyzed by Langmuir, Freundlich, Temkin, and Redlich-Peterson models. Based on equilibriumadsorption data, the Langmuir, Freundlich, and Temkin constants were determined as 0.139, 12.82, and 2.34, respectively, at 25°C.

scholarly journals Chemical Modification and Characterization of Yeast Cells for Extraction of Metal Ion in Water Sample

2014 ◽  
Vol 10 (8) ◽  
pp. 3037-3041
Author(s):  
Homayon Ahmad Panahi
Keyword(s):  
Water Sample ◽  
Metal Ion ◽  
Sea Water ◽  
Ph Value ◽  
Yeast Cells ◽  
Nickel Ions ◽  
Cibacron Blue ◽  
Chemically Modified ◽  
Equilibrium Data

A novel biosorbent is prepared by coupling a cibacron blue to yeast cells. The chemically modified yeast cells with mentioned ligand has been characterized by Fourier transform infrared spectroscopy and elemental analysis and applied for the preconcentration and extraction of trace Ni(II) from water samples. The optimum pH value for sorption of the nickel ions was 8. The sorption capacity of yeast cells- cibacron blue is 12.2 mg. g−1. A recovery of 91.4% was obtained for Ni(II) when eluted with 0.5 M HCl/HNO3 (3:1). The equilibrium data of Ni(II) adsorption on yeast cells- cibacron blue was analyzed using Langmuir model. The method was applied for Ni(II) determination in sea water sample.

Research on Anti-Felting Finishing Process of Wool Knitted Fabric with Protease

2011 ◽  
Vol 383-390 ◽  
pp. 5492-5495 ◽  
Author(s):  
Hua E Wang
Keyword(s):  
Ph Value ◽  
Orthogonal Experiment ◽  
Acid Protease ◽  
Process Conditions ◽  
Knitted Fabric ◽  
Optimal Process ◽  
Technical Parameters ◽  
Finishing Process ◽  
Protease Treatment ◽  
Energy Saving Technology

In this paper, acid protease treatment was studied on anti-felting finishing of wool knitted fabric and the optimal process conditions were obtained by orthogonal experiment. The technical parameters were hydrogen peroxide concentration 40mL/L, temperature 45°C, time 45min, pH value 8, concentration of protease 5 % (owf), pH value 5, temperature 40°C and time 35min. Through this process, the felt resistance property of wool knitted fabric has been improved greatly. Because of low temperature, energy consumption, environmental pollution, this process belongs to environmental protection and energy saving technology.

Kinetic and thermodynamic study of the adsorption of calcium onto sugar beet pulp

2016 ◽  
pp. 565-570
Author(s):  
Huang Qin ◽  
Zhu Si-ming ◽  
Zeng Di ◽  
Yu Shu-juan
Keyword(s):  
Sugar Beet ◽  
Adsorption Equilibrium ◽  
Ph Value ◽  
Hard Water ◽  
Sugar Beet Pulp ◽  
Order Kinetic ◽  
Factors Affecting ◽  
Isotherm Equation ◽  
Equilibrium Data ◽  
Beet Pulp

Sugar beet pulp (SBP) was used as low value adsorbent for the removal of calcium from hard water. Batch experiments were conducted to determine the factors affecting adsorption of the process such as pH value and Ca concentration. The adsorption equilibrium of Ca2+ by the SBP is reached after 100min and a pseudo second-order kinetic model can describe the adsorption process. The initial concentrations of Ca varied from 927 to 1127mgCa2+/L. A dose of 30g/L sugar beet pulp was sufficient for the optimum removal of calcium. The overall uptake of Ca ions by sugar beet pulp has its maximum at pH=8. The adsorption equilibrium data fitted well with the Langmuir adsorption isotherm equation.

Adsorption Characteristics of Phenol in Aqueous Solution by Pinus massoniana Biochar

2013 ◽  
Vol 295-298 ◽  
pp. 1154-1160 ◽  
Author(s):  
Guo Zhi Deng ◽  
Xue Yuan Wang ◽  
Xian Yang Shi ◽  
Qian Qian Hong
Keyword(s):  
Aqueous Solution ◽  
Ph Value ◽  
Pinus Massoniana ◽  
Isotherm Models ◽  
Order Kinetic ◽  
Adsorbent Dosage ◽  
Salt Ions ◽  
Equilibrium Data ◽  
Order Kinetic Model ◽  
Pseudo Second Order

The objective of this paper is to investigate the feasibility of phenol adsorption from aqueous solution by Pinus massoniana biochar. Adsorption conditions, including contact time, initial phenol concentration, adsorbent dosage, strength of salt ions and pH, have been investigated by batch experiments. Equilibrium can be reached in 24 h for phenol from 50 to 250 mg• L-1. The optimum pH value for this kind of biochar is 5.0. The amount of phenol adsorbed per unit decreases with the increase in adsorbent dosage. The existence of salt ions makes negligible influence on the equilibrium adsorption capacity. The experimental data is analyzed by the Freundlich and Langmuir isotherm models. Equilibrium data fits well to the Freundlich model. Adsorption kinetics models are deduced and the pseudo-second-order kinetic model provides a good correlation for the adsorbent process. The results show that the Pinus massoniana biochar can be utilized as an effective adsorption material for the removal of phenol from aqueous solution.

Experimental Studies on a Mineral Containing Titanium in Baoding Area

2013 ◽  
Vol 826 ◽  
pp. 34-37 ◽  
Author(s):  
Guo Zhen Liu ◽  
Shu Juan Dai ◽  
Li Mei Bai ◽  
Yu Xin Ma ◽  
Yong Zhang
Keyword(s):  
Magnetic Separation ◽  
High Intensity ◽  
Ph Value ◽  
Experimental Studies ◽  
Mineral Processing ◽  
Shaking Table ◽  
Gravity Concentration

The main elements can be recovered for mineral processing in a mineral containing titanium of Baoding area were Ti, Fe and V, and the elements in the main gangue minerals were Si and Al. Gravity concentration, gravity concentration-high intensity magnetic separation and gravity concentration-flotation tests were performed on the ore sample respectively. The results showed that, in the test of shaking table, when the grinding fineness was -0.074mm 93%, the productivity of concentrate can reach 32.24%; when grinding fineness was -0.074mm 93%, after gravity concentration-magnetic separation, 30.25% of concentrate productivity can be attained; when the grinding fineness was -0.074mm 85%, after gravity concentration-flotation, the productivity of concentrate was 3.31%. Maybe it's the condition of the tests wasn't controlled well, especially adjusting pH value in the flotation stage, it's hard to control, so the results were not very good.

Sorption Profile and Thermodynamic Characteristics of Nitrosonaphthol Functionalized Sorbent for Metal Ion Enrichment

2005 ◽  
Vol 70 (9) ◽  
pp. 1341-1356 ◽  
Author(s):  
Saima Q. Memon ◽  
Muhammad I. Bhanger ◽  
Muhammad Y. Khuhawar
Keyword(s):  
Metal Ion ◽  
Tap Water ◽  
Thermodynamic Characteristics ◽  
Chelating Agent ◽  
Standard Addition ◽  
Absorption Spectrometry ◽  
Sorption Data ◽  
Maximum Sorption ◽  
Styrene Divinylbenzene ◽  
Two Phases

A simple and reliable method has been developed using styrene-divinylbenzene-based polymeric material containing 1-nitroso-2-naphthol as chelating agent, to concentrate ultratrace amounts of Ni(II) and Cu(II) ions in aqueous samples. Sorption of both the ions on the new synthetic resin under static and dynamic conditions has been investigated. The sorption has been optimized with respect to pH, shaking and contact time of two phases. Maximum sorption has been achieved from solution of pH 5-8 after 8 min of agitation. Total saturation capacities were 516 ± 2 and 316 ± 2.5 μmol g-1 for Ni(II) and Cu(II) ions, respectively. The lowest concentration for quantitative recovery (98 ± 1%) is 1.33 and 5 ppb with the preconcentration factor of 750 and 200 for Ni(II) and Cu(II), respectively. Monitoring of the influence of diverse ions on the sorption of metal ions has revealed that phosphate, hydrogencarbonate and citrate reduce the sorption to some extent. Under optimum conditions the sorption data followed Langmuir, Freundlich, and Dubinin-Radushkevich isotherms. The kinetics and thermodynamics of sorption are studied in detail. The sorption procedure is utilized to preconcentrate these ions prior to their determination in tea, human hair, and tap water samples by atomic absorption spectrometry using direct and standard addition methods.

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