A new soy flour-polyepoxide adhesive system for making interior plywood

Holzforschung ◽  
2012 ◽  
Vol 66 (4) ◽  
Author(s):  
Jian Huang ◽  
Chunhong Li ◽  
Kaichang Li
Keyword(s):  
Water Resistance ◽  
Crosslinking Agent ◽  
Environmentally Friendly ◽  
Adhesive System ◽  
Soy Flour ◽  
Renewable Materials ◽  
Yellow Poplar ◽  
Crosslinking Agents

Abstract In this study, triglycidylamine (TGA) was synthesized and evaluated as a crosslinking agent for soy flour (SF) for making five-ply plywood from yellow poplar. Glycerol polyglycidyl ether (GPE) and trimethylolpropane triglycidyl ether (TTE) were also investigated as crosslinking agents for SF as adhesive for plywood. The plywood panels bonded with SF-TGA and SF-GPE adhesives did meet and those with SF-TTE adhesive did not meet the water-resistance requirement for interior application. The former two adhesives are formaldehyde-free, environmentally friendly, easy to use and readily available. They can be derived completely from renewable materials. The adhesion mechanisms are discussed in detail.

Terephthalaldehyde as better crosslinking agent in crosslinked chitosan hydrogel for selective removal of anionic dyes

2021 ◽  
Author(s):  
Madhvi Garg ◽  
Navneet Bhullar ◽  
Bharat Bajaj ◽  
Dhiraj Sud
Keyword(s):  
Crosslinking Agent ◽  
Selective Removal ◽  
Synthetic Dyes ◽  
Anionic Dyes ◽  
Chitosan Hydrogel ◽  
Ultrasound Radiation ◽  
Radiation Induced ◽  
Crosslinked Chitosan ◽  
Chitosan Hydrogels ◽  
Crosslinking Agents

The present manuscript reports the ultrasound radiation induced synthesis of grafted chitosan hydrogels (CAAT and CAAG) using terephthalaldehyde/glutaraldehyde as crosslinking agents and its application for removal of synthetic dyes from...

scholarly journals Design and Gas Separation Performance of Imidazolium Poly(ILs) Containing Multivalent Imidazolium Fillers and Crosslinking Agents

Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1388
Author(s):  
Kathryn E. O’Harra ◽  
Emily M. DeVriese ◽  
Erika M. Turflinger ◽  
Danielle M. Noll ◽  
Jason E. Bara
Keyword(s):  
Small Molecules ◽  
Crosslinking Agent ◽  
Gas Permeation ◽  
Polymeric Matrix ◽  
Separation Performance ◽  
Ionic Polymers ◽  
Co2 Solubility ◽  
Imidazolium Cations ◽  
Crosslinking Agents ◽  
Gas Separation Performance

This work introduces a series of vinyl-imidazolium-based polyelectrolyte composites, which were structurally modified via impregnation with multivalent imidazolium-benzene ionic liquids (ILs) or crosslinked with novel cationic crosslinkers which possess internal imidazolium cations and vinylimidazolium cations at the periphery. A set of eight [C4vim][Tf2N]-based membranes were prepared via UV-initiated free radical polymerization, including four composites containing di-, tri-, tetra-, and hexa-imidazolium benzene ILs and four crosslinked derivatives which utilized tri- and tetra- vinylimidazolium benzene crosslinking agents. Structural and functional characterizations were performed, and pure gas permeation data were collected to better understand the effects of “free” ILs dispersed in the polymeric matrix versus integrated ionic crosslinks on the transport behaviors of these thin films. These imidazolium PIL:IL composites exhibited moderately high CO2 permeabilities (~20–40 Barrer), a 4–7× increase relative to corresponding neat PIL, with excellent selectivities against N2 or CH4. The addition of imidazolium-benzene fillers with increased imidazolium content were shown to correspondingly enhance CO2 solubility (di- < tri- < tetra- < hexa-), with the [C4vim][Tf2N]: [Hexa(Im+)Benz ][Tf2N] composite showing the highest CO2 permeability (PCO2 = 38.4 Barrer), while maintaining modest selectivities (αCO2/CH4 = 20.2, αCO2/N2 = 23.6). Additionally, these metrics were similarly improved with the integration of more ionic content bonded to the polymeric matrix; increased PCO2 with increased wt% of the tri- and tetra-vinylimidazolium benzene crosslinking agent was observed. This study demonstrates the intriguing interactions and effects of ionic additives or crosslinkers within a PIL matrix, revealing the potential for the tuning of the properties and transport behaviors of ionic polymers using ionic liquid-inspired small molecules.

Glutaraldehyde-modified MUF adhesive system – Improved hot water resistance

2006 ◽  
Vol 65 (3) ◽  
pp. 251-253 ◽  
Author(s):  
M. L. Mamiński ◽  
J. Pawlicki ◽  
A. Zado ◽  
P. Parzuchowski
Keyword(s):  
Water Resistance ◽  
Adhesive System ◽  
Hot Water

scholarly journals Effect of carbon nanotubes on the properties of pmb and asphalt concrete

Vestnik MGSU ◽  
2015 ◽  
pp. 110-119 ◽  
Author(s):  
Svetlana Yur’evna Shekhovtsova ◽  
Marina Alekseevna Vysotskaya
Keyword(s):  
Asphalt Concrete ◽  
Water Resistance ◽  
Materials Science ◽  
Crosslinking Agent ◽  
Modern World ◽  
Progressive Development ◽  
Concrete Mixtures ◽  
Deformation Properties ◽  
Strength And Deformation ◽  
Modified Binder

In the modern world nanotechnologies are an integral part of successful and progressive development of all the areas of activity. Materials science is not an exception. The authors studied the method of nanomodification and its influence on the performance properties of polymer-modified binder (PMB) and asphalt concrete, produced on their basis. It is established that nanomodified PMB are less susceptible to aging, which is a consequence of the processes of peptization of asphalt-resin complexes (ARC) in the structure of the modified binder and the crosslinking with the polymer matrix. It is revealed that nanotubes (SWCN or MWCN) used as a modifier, act as crosslinking agent and the inhibitor of the aging process in a PMB. The influence of nanomodified PMB on strength and deformation properties of asphalt concrete is investigated. It was found out that the use of modified binder in the asphalt concrete mixtures enhances the water resistance of asphalt concrete, heat resistance and shear-resistance.

scholarly journals An Environmentally Friendly Phosphorus-Modified Cellulose/Silica Hybrid Hydrogel for Fire Prevention and Firefighting

2021 ◽  
Author(s):  
Hafezeh Nabipour ◽  
Hu Shi ◽  
Xin Wang ◽  
Xiangming Hu ◽  
Lei Song ◽  
...  
Keyword(s):  
Silica Nanoparticles ◽  
Crosslinking Agent ◽  
Environmentally Friendly ◽  
Fire Season ◽  
Fire Prevention ◽  
Hybrid Hydrogel ◽  
Water Binding ◽  
Ordinary Water ◽  
Modified Cellulose ◽  
Silica Hybrid

Abstract Wildfires have been recognized as a natural incident in some forests, however, fire season is now more severe and extensive, even in tropical rainforests in which fire could have damaging impacts. A hydrogel is a 3-D polymeric structure encompassing cross-linked and hydrophilic macromolecules. In comparison with water, hydrogels have shown some superiorities in terms of water-binding, cooling, and sealing, which make them be applied in forest fire prevention programs for improving fire-extinguishing performance. In this study, an environmentally friendly phosphorus-modified cellulose/silica hybrid hydrogel was prepared based on the modified methylcellulose by 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide–itaconic acid (DOPO-ITA) and silica nanoparticles. The storage (G') and loss (G") moduli increased with the increment of silica nanoparticles content, owing to the role of silica nanoparticles as crosslinking agent. In the fire prevention experiments, the grass treated with the methylcellulose@DOPO-ITA@silica hybrid hydrogel shows self-extinguishing behavior, whereas those treated with ordinary water or methylcellulose hydrogel can be easily ignited after one week. In the firefighting experiments, the methylcellulose@DOPO-ITA@silica hybrid hydrogel displays much shorter extinguishing time and lower consumption volume than ordinary water and the methylcellulose@DOPO-ITA hydrogel. This work presents an environmentally-friendly, non-toxic, and biodegradable cellulose-based hybrid hydrogel for fire prevention and firefighting of wildfires.

scholarly journals Synthesis and Characterization of Sucrose and Ammonium Dihydrogen Phosphate (SADP) Adhesive for Plywood

Polymers ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 1909 ◽  
Author(s):  
Zhongyuan Zhao ◽  
Shijing Sun ◽  
Di Wu ◽  
Min Zhang ◽  
Caoxing Huang ◽  
...  
Keyword(s):  
Time Course ◽  
Soybean Protein ◽  
Adhesive System ◽  
Wood Adhesive ◽  
Solid Content ◽  
Dihydrogen Phosphate ◽  
Ammonium Dihydrogen Phosphate ◽  
Renewable Materials ◽  
High Solid ◽  
Low Viscosity

The development of eco-friendly adhesives for wood composite products has been a major topic in the field of wood science and product engineering. Although the research on tannin-based and soybean protein-based adhesives has already reached, or at least nears, industrial implementation, we also face a variety of remaining challenges with regards to the push for sustainable adhesives. First, petroleum-derived substances remain a pre-requisite for utilization of said adhesive systems, and also the viscosity of these novel adhesives continues to limit its ability to serve as a drop-in substitute. Within this study, we focus upon the development of an eco-friendly plywood adhesive that does not require any addition of petroleum derived reagents, and the resultant liquid adhesive has both high solid contents as well as a manageably low viscosity at processing temperatures. Specifically, a system based on sucrose and ammonium dihydrogen phosphate (ADP) was synthesized into an adhesive with ~80% solid content and with viscosities ranging from 480–1270 mPa·s. The bonding performance of all adhesive-bound veneer specimens satisfied GB/T 9846-2015 standard at 170 °C hot pressing temperature. To better explain the system’s efficiency, in-depth chemical analysis was performed in an effort to understand the chemical makeup of the cured adhesives as well as the components over the time course of curing. Several new structures involving the fixation of nitrogen speak to a novel adhesive molecular network. This research provides a possibility of synthesizing an eco-friendly wood adhesive with a high solid content and a low viscosity by renewable materials, and this novel adhesive system has the potential to be widely utilized in the wood industry.

scholarly journals The Puncture and Water Resistance of Polyurethane- Impregnated Fabrics after UV Weathering

Polymers ◽  
2019 ◽  
Vol 12 (1) ◽  
pp. 15
Author(s):  
Antonella Patti ◽  
Domenico Acierno
Keyword(s):  
Experimental Data ◽  
Uv Radiation ◽  
Water Resistance ◽  
Uv Light ◽  
Crosslinking Agent ◽  
Waterborne Polyurethane ◽  
Impregnation Method ◽  
Polyurethane Dispersion ◽  
Spectroscopic Analyses ◽  
Before And After

Polyurethane is a polymer adaptable to different scientific and industrial requirements; nevertheless it is also extremely susceptible to UV radiation, which compromises the physical and mechanical functionality. In this framework, our study investigated the effect of waterborne polyurethane dispersion (WPUD) applied to a polyester (PET)-based fabric, through the impregnation method, on the puncturing and water resistance of the pristine material, before and after UV weathering. Results confirmed an increment of both features in the prepared fabrics, attributed to the PUR textile treatment; but a partially loss of the gained properties in the samples due to the UV weathering. In order to improve the efficiency of the impregnating dispersions, in protecting the durability of the treated materials, the addition of different UV light stabilizers, or/and of crosslinking agent into WPUD was also tested. From the experimental data, it can be concluded that formulations based on WPUD, containing both the crosslinker and UV organic absorber, have displayed an increment of their perforation and water resistance for the treated samples with respect to the starting textile, and contemporary have preserved the features against the UV light. Finally, microscopic and spectroscopic analyses have been performed as further characterization techniques of the samples surface.

Development and evaluation of new curing agents derived from glycerol for formaldehyde-free soy-based adhesives in wood composites

Holzforschung ◽  
2013 ◽  
Vol 67 (6) ◽  
pp. 659-665 ◽  
Author(s):  
Jian Huang ◽  
Kai Gu ◽  
Kaichang Li
Keyword(s):  
Bond Strength ◽  
Modulus Of Elasticity ◽  
Internal Bond ◽  
Water Resistance ◽  
Ammonium Hydroxide ◽  
Soy Flour ◽  
Modulus Of Rupture ◽  
Wood Composites ◽  
Curing Agents ◽  
Resistance Tests

Abstract Three novel curing agents (I, II, and III) were synthesized from epichlorohydrin and ammonium hydroxide. The combinations of soy flour (SF) with one of the curing agents (SF-I, SF-II, and SF-III) were investigated as adhesives for making interior plywood. Water resistance tests showed that plywood panels bonded with SF-I and SF-III adhesives met the requirements of interior plywood, whereas those bonded with SF-II did not. The modulus of rupture, modulus of elasticity, and internal bond strength of particleboard panels bonded with the SF-II adhesive all exceeded the corresponding minimum industrial requirements for M-2 grade particleboard.

scholarly journals Investigation on the Physical Properties of 100% Cotton Knit Fabric by Treating with Crossslinking Agents

2018 ◽  
Vol 8 (02) ◽  
Author(s):  
Imana Shahrin Tania ◽  
Md. Zulhash Uddin ◽  
Kawser Parveen Chowdhury
Keyword(s):  
Physical Properties ◽  
Textile Industry ◽  
Crosslinking Agent ◽  
Areal Density ◽  
Cotton Fabrics ◽  
Formaldehyde Content ◽  
Different Types ◽  
Chemical Companies ◽  
Finishing Agent ◽  
Crosslinking Agents

TApplication of crosslinking agent to impart wrinkle recovery property on cotton fabrics is very popular for textile industry. This paper represents the effect of different crosslinking agent on the physical properties and the wrinkle recovery of cotton knit fabric. Here five different types of crosslinking agent from three different chemical companies were used. The work was divided into two parts .At first; crosslinking agents were applied on cotton fabric than various related tests were done on the treated and untreated fabric. Better crease resistancy was found on the finishing agent having high formaldehyde content .The other important properties like tensile strength, dimensional stability, stiffness, abrasion resistance pilling resistance and areal density was studied here. Among them some properties were improved and some were fall down.

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