scholarly journals Nanomechanical and dynamic mechanical properties of rubber–wood–plastic composites

2021 ◽  
Vol 11 (1) ◽  
pp. 167-175
Author(s):  
Yonghui Zhou ◽  
David Hui ◽  
Yuxuan Wang ◽  
Mizi Fan

Abstract This article presents the assessment of bulk and in situ mechanical properties of rubber–wood–plastic composites (RubWPC) and their correlations, aiming to obtain a thorough understanding of mechanical behaviour of RubWPC, which is an essential prerequisite in realising their optimal design and applications. Dynamic mechanical analysis results showed that the composites treated with multiple coupling agents (combination of maleic anhydride polyethylene [MAPE] and bis(triethoxysilylpropyl)tetrasulfide and combination of MAPE and vinyltrimethoxysilane) exhibited greater storage modulus than both the untreated and single coupling agent treated composites owing to their superior interfacial bonding quality. The shift of relaxation peak and T g towards higher temperatures observed in the treated composites confirmed the enhancement of interfacial interaction and adhesion. Nanoindentation analysis suggested that the composite with optimised interface (MAPE and Si69 treated) possessed better nanomechanical property (elastic modulus) due to the resin penetration into cell lumens and vessels and the reaction between cell walls and coupling agents.

Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1406
Author(s):  
Daoyuan Chen ◽  
Mingjin Ding ◽  
Zhixiong Huang ◽  
Yanbing Wang

In order to study the dynamic mechanical properties of styrene–acrylic latex with a core/shell structure, a variety of latexes were synthesized by semi-continuous seeded emulsion polymerization based on “particle design” with the same material. The latexes were characterized by rotary viscosimeter, dynamic light scattering (DLS), Fourier transform infrared spectroscopy (FTIR), transmission electron microscope (TEM), dynamic mechanical analysis (DMA), and universal testing machine. The effects of difference at the glass transition temperature (Tg) of core and shell and the introduction of the “transition layer” on the damping and mechanical properties of latex film were studied. The results indicate that as the Tg of core and shell gets closer, the better the compatibility of core and shell, from phase separation to phase continuity. Furthermore, the introduction of the “transition layer” can effectively improve the tensile strength and tan δ (max) of the latex film. The tensile strength and maximum loss factor (f = 1 Hz) of latex with the “transition layer” increased by 36.73% and 29.11% respectively compared with the latex without the “transition layer”. This work provides a reference for the design of emulsion for damping coating.


2017 ◽  
Vol 54 (3) ◽  
pp. 543-545 ◽  
Author(s):  
Yusrina Mat Daud ◽  
Kamarudin Hussin ◽  
Azlin Fazlina Osman ◽  
Che Mohd Ruzaidi Ghazali ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
...  

Preparation epoxy based hybrid composites were involved kaolin geopolymer filler, organo-montmorillonite at 3phr by using high speed mechanical stirrer. A mechanical behaviour of neat epoxy, epoxy/organo-montmorillonite and its hybrid composites containing 1-8phr kaolin geopolymer filler was studied upon cyclic deformation (three-point flexion mode) as the temperature is varies. The analysis was determined by dynamic mechanical analysis (DMA) at frequency of 1.0Hz. The results then expressed in storage modulus (E�), loss modulus (E�) and damping factor (tan d) as function of temperature from 40 oC to 130oC. Overall results indicated that E�, E�� and Tg increased considerably by incorporating optimum 1phr kaolin geopolymer in epoxy organo-montmorillonite hybrid composites.


2019 ◽  
Vol 39 (6) ◽  
pp. 508-514
Author(s):  
Yannan He ◽  
Zhiqiang Yu

Abstract The thermal and dynamic mechanical properties of epoxy composites filled with zirconium diboride/nano-alumina (ZrB2/Al2O3) multiphase particles were investigated by means of differential scanning calorimetry, dynamic thermo-mechanical analysis, and numerical simulation. ZrB2/Al2O3 particles were surface organic functional modified by γ-glycidoxypropyltrimethoxysilane for the improvement of their dispersity in epoxy matrix. The results indicated that the curing exotherm of epoxy resin decreased significantly due to the addition of ZrB2/Al2O3 multiphase particles. In comparison to the composites filled with unmodified particles, the modified multiphase particles made the corresponding filling composites exhibit lower curing reaction heat, lower loss modulus, and higher storage modulus. Generally speaking, the composites filled with 5 wt% modified multiphase particles presented the best thermal stability and thermo-mechanical properties due to the better filler-matrix interfacial compatibility and the uniform dispersity of modified particles. Finite element analysis also suggested that the introduction of modified ZrB2/Al2O3 multiphase particles increased the stiffness of the corresponding composites.


2019 ◽  
Vol 14 ◽  
pp. 155892501986880 ◽  
Author(s):  
Liyong Tian ◽  
Di Wang ◽  
Qufu Wei

Tires might be the first technically significant composite out of rubber and play a vital role in the overall performance of a car. The essential functions of a tire rely to a great extent on the properties of tire cords. Polyester and nylon cords make up the majority of synthetic fibers used in tires. A new kind of polyester cord has been developed combining the performance characteristics of both polyester and nylon cords. This article examines the dynamic mechanical properties of this nylon-like polyester tire cord by adopting dynamic mechanical analysis, Instron, and DISC fatigue experiments, as well as its dynamic adhesion property using flex fatigue experiment. It demonstrated that the dynamic complex modulus of the nylon-like polyester cord was higher than that of nylon 6 cord but lower than that of standard polyester cord, which was a favorable characteristic when it came to replacing nylon 6 cord with nylon-like polyester cord in tires. Under cyclic loading, hysteresis loss of nylon 6 cord > nylon 66 cord > nylon-like polyester cord > standard polyester cord was observed. In the DISC experiment, nylon-like polyester had a similar compression resistance property to that of nylon 6 cord. At a temperature below 85°C, nylon-like polyester cord maintained roughly the same level of residual ratio of dynamic adhesion, but beyond this temperature point, nylon 6 exhibited a better performance.


2018 ◽  
Vol 53 (1) ◽  
pp. 65-72 ◽  
Author(s):  
MK Gupta ◽  
Rohit Singh

In the present work, a novel physical treatment (PLA coating) of sisal fibres and its influence on the water absorption, static and dynamic mechanical properties of its composites has been presented. The treated sisal fibres were used consisted of alkali treatment and PLA coating to fabricate its polyester-based composites by hand lay-up technique keeping constant fibres content as 20 wt.% . Water absorption analysis was carried out in terms of water uptake (%), and sorption, diffusion and permeability coefficient. In addition, static properties were examined in terms of tensile, flexural and impact test, and dynamic mechanical analysis was performed in terms of storage modulus [Formula: see text], loss modulus [Formula: see text], damping [Formula: see text] and glass transition temperature [Formula: see text]. It was reported that the PLA-coated sisal composites showed the best performance in water absorption, mechanical and dynamic mechanical properties than pure sisal and alkali-treated sisal composites. There were 33%, 49%, 48%, and 27% improvement in water resistance, tensile strength, flexural strength and impact strength, respectively, of PLA-coated sisal composites as compared to that of pure sisal composite.


2015 ◽  
Vol 815 ◽  
pp. 496-502
Author(s):  
Yu Kong ◽  
Jia Cao Yang ◽  
Xiao Jun Wang ◽  
Gang Zhang ◽  
Sheng Ru Long ◽  
...  

Poly (arylene sulfide sulfone)/glass fiber cloth composites (PASS/GFC) were prepared through compression moulding. The optimum processing conditions including temperature, time and pressure were discussed in detail. The cross-linking reaction, mechanical and dynamic mechanical properties were also characterized. The results showed that the optimum processing temperature, pressure and time were 325 °C, 5 MPa and 15 min, respectively. The thioether group (-S-) was oxidized and converted to sulfoxide (-SO-) and sulfone (-SO2-) groups during the crosslinking reaction proved by Fourier transform infrared spectrometer. The mechanical and dynamic mechanical analysis measurements showed that mechanical properties, including tensile, bending, impact and storage modulus increased continuously with an increase of the GFC contents.


2013 ◽  
Vol 712-715 ◽  
pp. 111-114 ◽  
Author(s):  
Tian Ming Gao ◽  
Mao Fang Huang ◽  
Rui Hong Xie ◽  
Hong Lian Chen

Surface modified nanocrystalline cellulose (NCC) was prepared by silicon-69, and then blended into natural rubber latex to prepare nanocomposites. The nanocomposites properties of tensile properties, tear strength, morphology and thermal dynamic mechanical properties were measured by mechanical property testing, scanning electron microscopy (SEM), and dynamic mechanical analysis (DMA), respectively. The results showed that modified NCC is homogeneously distributed throughout NR matrix, which leads to the enhancement on mechanical properties. Moreover, the storage modulus (E) of modified nanocellulose filled NR is higher than unmodified nanocellulose filled NR, and the tanδ is reversed.


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