Thermal stability, mechanical properties, and gamma radiation shielding performance of polyvinyl chloride/Pb(NO3)2 composites

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Sayed A. Waly ◽  
Ahmed M. Abdelreheem ◽  
Mohamed M. Shehata ◽  
Omayma A. Ghazy ◽  
Zakaria I. Ali
Keyword(s):  
Thermal Stability ◽  
Attenuation Coefficient ◽  
Polyvinyl Chloride ◽  
Polymer Matrix ◽  
Composite Films ◽  
Mass Attenuation Coefficient ◽  
Radiation Shielding ◽  
Point Sources ◽  
Linear Attenuation Coefficient ◽  
Mass Attenuation

Abstract Radiation shielding composites based on polyvinyl chloride (PVC) reinforced with different weight ratios of Pb(NO3)2 (5, 10, and 20 wt%) were prepared using the solution-casting technique. Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), scanning electron microscopy, and tensile testing method were used to characterize the PVC composite films. FTIR and XRD investigations illustrate the structural change and modification of the as-prepared PVC composites. The morphological analysis of the composite revealed that Pb(NO3)2 was dispersed uniformly within PVC polymer matrix. TGA revealed that the incorporation of Pb(NO3)2 improved the thermal stability of the investigated composites, whereas adding Pb(NO3)2 to the polymer matrix worsened its tensile properties. The as-prepared composite films were investigated for radiation-shielding of gamma-rays radioactive point sources (241Am, 133Ba, 137Cs, and 60Co). Linear attenuation coefficient (μ, cm−1), mass attenuation coefficient (μ/ρ, cm2/g), and half-value layer (HVL, cm) have been estimated from the obtained data using the MicroShield program. Reasonable agreement was attended between theoretical and experimental results. The deviation between the experiment and theoretical values of mass attenuation coefficient is being to be lower than 9%, and this can be correlated to the good distribution of Pb(NO3)2. The results revealed that adding Pb(NO3)2 to PVC polymer composites improved their mass attenuation coefficient.

scholarly journals Study of some γ-ray attenuation parameters for new shielding materials composed of nano ZnO blended with high density polyethylene

2019 ◽  
Vol 34 (4) ◽  
pp. 342-352 ◽  
Author(s):  
Zainab Alsayed ◽  
Mohamed Badawi ◽  
Ramadan Awad ◽  
Abouzeid Thabet ◽  
Ahmed El-Khatib
Keyword(s):  
Attenuation Coefficient ◽  
Polymer Matrix ◽  
High Density Polyethylene ◽  
Gamma Ray ◽  
Mass Attenuation Coefficient ◽  
Radiation Shielding ◽  
High Density ◽  
Linear Attenuation Coefficient ◽  
Nano Zno ◽  
Mass Attenuation

The extensive utilization of radiation is rapidly developing worldwide involving abundant fields like medical, industrial, research, and nuclear facilities. This makes the need for studying radiation shielding materials and their properties more urgent than ever. In the present study, bulk and nano ZnO were mixed by the same ratio each time (10, 20, 30, and 40 wt.%), with high-density polyethylene as a polymer matrix and characterized by X-ray diffraction. The results confirmed the good dispersion of bulk and nano ZnO particles within the polymer matrix. The prepared composite samples were used in different thicknesses as gamma ray shielding materials, and the heaviness was calculated and compared to lead. Using HPGe detector at specific energies (59.53, 356.01, 661.66, 1173.33, and 1332.50 keV) for different radioactive point sources (241Am, 133Ba, 137Cs, and 60Co), the mass attenuation coefficient for the samples was measured experimentally. Depending upon the obtained values, the linear attenuation coefficient, half-value layer, tenth value layer, heaviness and relaxation length were estimated. Using the XCOM database, the values of linear attenuation coefficient, mass attenuation coefficient, and other parameters were calculated theoretically for the bulk ZnO blended with high-density polyethylene. The obtained results were compared to the experimental values for nano and bulk ZnO blended with high density polyethylene. The radiation shielding behavior of nano ZnO blended with high density polyethylene was found to be more promising and efficient for radiation protection against gamma ray.

scholarly journals Estimation of the X/γ- ray shielding properties of different glass system using Monte Carlo Simulation

2021 ◽  
Vol 12 (2) ◽  
pp. 1117-1122
Author(s):  
Ayano Shanko, MD, Et. al.
Keyword(s):  
Monte Carlo Simulation ◽  
Monte Carlo ◽  
Attenuation Coefficient ◽  
Mass Attenuation Coefficient ◽  
Radiation Shielding ◽  
Glass System ◽  
Effective Electron ◽  
X Ray ◽  
Shielding Properties ◽  
Mass Attenuation

The aim of the research is to estimate the X-ray shielding properties of different glass systems using Monte Carlo Simulation. X-ray glass is also known as radiation shielding glass. Glass provides protection against the absorption of energy radiation. The shielding layer is formed by a high concentration of lead and barium. The mass attenuation coefficient, the effective atomic number and the effective electron density are used to determine the position of gamma-ray photons in matter. Shield characterization in terms of mass attenuation coefficient (μm), transmission fraction (T), effective atomic numbers (Zeff), half-value layer (HVL) and exposure build-up. factor (EBF) of a glass system is estimated by the Monte Carlo Simulation. The random sampling and statistical analysis are computed using the monte carlo simulation. Various external factors are considered as the input parameters. The different composition of the glass will be examined using the Monte Carlo simulation and the shielding capability would be determined for the various samples.

Investigation and Characterization of Gamma Radiation Shielding Capacity of Heavy Minerals-Based Composite Materials

2020 ◽  
Vol 6 (4) ◽  
Author(s):  
Mohammad Asaduzzaman Chowdhury ◽  
Md. Bengir Ahmed Shuvho ◽  
Md Azizul Islam ◽  
Muhammad Borhan Uddin ◽  
Ruhul Amin Khan
Keyword(s):  
Composite Materials ◽  
Gamma Radiation ◽  
Attenuation Coefficient ◽  
Mass Attenuation Coefficient ◽  
Radiation Shielding ◽  
Integrated System ◽  
Heavy Minerals ◽  
Linear Attenuation Coefficient ◽  
Density Surface ◽  
Effects Of Radiation

Abstract Radiation shielding is an indispensable ingredient in the design of an integrated system to attenuate the effects of radiation during various operations such as space, aircraft, and nuclear plant. Discerning and exploiting the properties of composite materials compatible for radiation shielding in those applications are therefore primary obligation. In this study, we present here the results of control, ilmenite-, and garnet-based composites radiation shielding capabilities. The gamma radiation shielding competency of control, ilmenite-, and garnet-based composite materials has been examined by using linear attenuation coefficient, mass attenuation coefficient (MAC), tenth value layer (TVL), and half value layer (HVL). A comparison among those composite materials has been studied to find out the best one for radiation shielding material. Factors influencing the radiation shielding capabilities such as mechanical properties, thermal properties, density, surface morphology, and Fourier-transform infrared spectroscopy (FTIR) analysis have been studied in comparative investigations. In this work, we show that garnet-based composite material has viable radiation shielding performances as compared to the control and ilmenite-based composites. Garnet-based composite exhibits lower impact energy to withstand against gamma radiation as compared to the other tested shielding materials.

scholarly journals Photon Shielding Characterization of SiO2-PbO-CdO-TiO2 Glasses for Radiotheraphy Shielding Application

2021 ◽  
pp. 32-38
Author(s):  
Idris M. Mustapha ◽  
Atimga B. James ◽  
Sulayman M. Bello
Keyword(s):  
Attenuation Coefficient ◽  
Energy Region ◽  
Effective Atomic Number ◽  
Mean Free Path ◽  
Mass Attenuation Coefficient ◽  
Photoelectric Effect ◽  
High Energy ◽  
Radiation Shielding ◽  
Sudden Increase ◽  
Mass Attenuation

In this study, photon attenuation parameters of (30-x) SiO2–15PbO–10CdO-xTiO2, with x = 0, 2, 4, 6, 8 and 10% mol, were determined and their application as shielding material were discussed. The WinXCOM software was used to determine the mass attenuation coefficient of the studied glasses for the energy range (0.015-15MeV). The mass attenuation coefficient of the glass samples first decline up to 0.09 MeV and slightly increase abruptly and then declined uniformly for all the glasses to approximately zero after about 10 MeV.   The effective atomic number (Zeff) was also calculated for the glass samples and were observe to raise from 0.015 to 0.02 MeV and then decreased between 0.02-5 MeV. On account of the dominance of the photoelectric effect in the low energy region, there was a sudden increase in Zeff at about 0.08 MeV close to the absorption edge of the Pb (0.088 MeV). The rapid increment was observed at 0.1–1.5 MeV by transcending typical Compton scattering interaction at intermediate energies for Zeff'’s and began to decrease in the same form again. The lower Zeff   values were found in low and high energy region for all SPCT glasses. The calculated mean free path, half value layer and tenth value layer values were observe to decline as the TiO2 doping of the glasses increased which accounts for the  three photon interaction mechanisms effectiveness in the variation of MFP and HVL values with energy. It can be concluded that SPCT glasses may be considered an alternative material for radiation shielding practices.

scholarly journals Experimental Investigation of Radiation Shielding Competence of Bi2O3-CaO-K2O-Na2O-P2O5 Glass Systems

Materials ◽  
2021 ◽  
Vol 14 (17) ◽  
pp. 5061
Author(s):  
Dalal Abdullah Aloraini ◽  
Aljawhara H. Almuqrin ◽  
M. I. Sayyed ◽  
Hanan Al-Ghamdi ◽  
Ashok Kumar ◽  
...  
Keyword(s):  
Attenuation Coefficient ◽  
Gamma Ray ◽  
Effective Atomic Number ◽  
Mass Attenuation Coefficient ◽  
Radiation Shielding ◽  
The Other ◽  
Linear Attenuation Coefficient ◽  
Attenuation Coefficients ◽  
Positive Effect ◽  
Theoretical Results

The gamma-ray shielding features of Bi2O3-CaO-K2O-Na2O-P2O5 glass systems were experimentally reported. The mass attenuation coefficient (MAC) for the fabricated glasses was experimentally measured at seven energy values (between 0.0595 and 1.33 MeV). The compatibility between the practical and theoretical results shows the accuracy of the results obtained in the laboratory for determining the MAC of the prepared samples. The mass and linear attenuation coefficients (MACs) increase with the addition of Bi2O3 and A4 glass possesses the highest MAC and LAC. A downward trend in the linear attenuation coefficient (LAC) with increasing the energy from 0.0595 to 1.33 MeV is found. The highest LAC is found at 1.33 MeV (in the range of 0.092–0.143 cm−1). The effective atomic number (Zeff) follows the order B1 > A1 > A2 > A3 > A4. This order emphasizes that increasing the content of Bi2O3 has a positive effect on the photon shielding proficiencies owing to the higher density of Bi2O3 compared with Na2O. The half value layer (HVL) is also determined and the HVL for the tested glasses is computed between 0.106 and 0.958 cm at 0.0595 MeV. The glass with 10 mol% of Bi2O3 has lower HVL than the glasses with 0, 2.5, 5, and 7.5 mol% of Bi2O3. So, the A4 glass needs a smaller thickness than the other glasses to shield the same radiation. As a result of the reported shielding parameters, inserting B2O3 provides lower values of these three parameters, which in turn leads to the development of superior photons shields.

Gamma radiation shielding properties of glasses within the TeO2-TiO2-ZnO system

2019 ◽  
Vol 107 (6) ◽  
pp. 517-522 ◽  
Author(s):  
M. Almatari
Keyword(s):  
Gamma Radiation ◽  
Attenuation Coefficient ◽  
Atomic Number ◽  
Effective Atomic Number ◽  
Mean Free Path ◽  
Mass Attenuation Coefficient ◽  
Radiation Shielding ◽  
Glass System ◽  
Shielding Properties ◽  
Mass Attenuation

Abstract Radiations are widely used in hospitals and health services in radiotherapy and molecular imaging using x-ray and gamma radiation which considered as the most penetrating radiations and very difficult to shield. In this study, the radiation shielding properties of different zinc oxide (ZnO) concentrations of the (95-x)TeO2-5TiO2-xZnO (x=5, 10, 15, 20, 25, 30 and 40 mol%) glass system was investigated to be introduced as a new transparency effective shielding material. In order to study shielding properties, mass attenuation coefficients in the energy range of 0.015–15 MeV photon energies for the current glass system were calculated using ParShield software. Moreover, half value layer, mean free path and effective atomic number were evaluated using the obtained attenuation coefficient. The results indicated that if ZnO was added to the current glass system the mass attenuation coefficient will be decreased as well as effective atomic number values. The highest mass attenuation coefficient at all energies was found to be in TT5Z5 glass sample as well as the effective atomic number value.

Gamma-Rays Absorption Studies of PbO-SiO2 Glass System

2010 ◽  
Vol 93-94 ◽  
pp. 71-74
Author(s):  
N. Chanthima ◽  
Jakrapong Kaewkhao ◽  
Weerapong Chewpraditkul ◽  
Pichet Limsuwan
Keyword(s):  
Attenuation Coefficient ◽  
Effective Atomic Number ◽  
Mass Attenuation Coefficient ◽  
Radiation Shielding ◽  
Glass System ◽  
Interaction Cross Section ◽  
Absorption Studies ◽  
Total Interaction ◽  
Better Than ◽  
Mass Attenuation

Mass attenuation coefficient, total interaction cross-section and effective atomic number of xPbO:(100-x)SiO2, where 30 x 70 (% weight), glass system have been investigated at 662 keV on the basis of the mixture rule. The results are in good agreement with the theoretical values, calculated by WinXCom. The mass attenuation coefficient increases with PbO content, due to higher probability of photoelectric absorption in glass. However, Compton scattering gives dominant contribution to the total mass attenuation coefficient for the glass samples studied. The shielding properties of the glass samples are also better than ordinary shielding concretes and commercial window glasses. These results indicate that the glass systems prepared in this study has a potential to be used as radiation shielding materials.

scholarly journals The Vital Role of La2O3 on the La2O3-CaO-B2O3-SiO2 Glass System for Shielding Some Common Gamma Ray Radioactive Sources

Materials ◽  
2021 ◽  
Vol 14 (17) ◽  
pp. 4776 ◽  
Author(s):  
Hanan Al-Ghamdi ◽  
Mengge Dong ◽  
M. I. Sayyed ◽  
Chao Wang ◽  
Aljawhara H. Almuqrin ◽  
...  
Keyword(s):  
Attenuation Coefficient ◽  
Gamma Ray ◽  
Effective Atomic Number ◽  
Mean Free Path ◽  
Mass Attenuation Coefficient ◽  
Vital Role ◽  
Radiation Shielding ◽  
Linear Attenuation Coefficient ◽  
Sio2 Glass

The role La2O3 on the radiation shielding properties of La2O3-CaO-B2O3-SiO2 glass systems was investigated. The energies were selected between 0.284 and 1.275 MeV and Phy-X software was used for the calculations. BLa10 glass had the least linear attenuation coefficient (LAC) at all the tested energies, while BLa30 had the greatest, which indicated that increasing the content of La2O3 in the BLa-X glasses enhances the shielding performance of these glasses. The mass attenuation coefficient (MAC) of BLa15 decreases from 0.150 cm2/g to 0.054 cm2/g at energies of 0.284 MeV and 1.275 MeV, respectively, while the MAC of BLa25 decreases from 0.164 cm2/g to 0.053 cm2/g for the same energies, respectively. At all energies, the effective atomic number (Zeff) values follow the trend BLa10 < BLa15 < BLa20 < BLa25 < BLa30. The half value thickness (HVL) of the BLa-X glass shields were also investigated. The minimum HVL values are found at 0.284 MeV. The HVL results demonstrated that BLa30 is the most space-efficient shield. The tenth value layer (TVL) results demonstrated that the glasses are more effective attenuators at lower energies, while decreasing in ability at greater energies. These mean free path results proved that increasing the density of the glasses, by increasing the amount of La2O3 content, lowers MFP, and increases attenuation, which means that BLa30, the glass with the greatest density, absorbs the most amount of radiation.

Radiation shielding properties of mortars containing heavyweight particles

Kerntechnik ◽  
2021 ◽  
Vol 86 (1) ◽  
pp. 64-69
Author(s):  
N. U. Kockal ◽  
A. Cesur ◽  
S. F. Ozmen
Keyword(s):  
Mass Attenuation Coefficient ◽  
Radiation Shielding ◽  
Point Sources ◽  
Calcareous Sand ◽  
Heavy Particles ◽  
Attenuation Coefficients ◽  
High Purity Germanium ◽  
Mass Attenuation Coefficients ◽  
Shielding Properties ◽  
Mass Attenuation

Abstract In this study the radiation shielding properties of mortar samples were investigated. The samples were created by replacing heavyweight particles of iron, steel and chromium waste by calcareous sand in different volume percentages. Additionally, the effects of the physical properties of particles and samples on shielding properties is also discussed. In the scope of this work, the radiation shielding properties of mortar samples were measured by determining the values of mass attenuation coefficients by means of an experimental setup consisting of 133Ba, 137Cs and 60Co standard point sources and high purity germanium (HPGe) detector. It’s concluded that the highest mass attenuation coefficient values among the heavy particles were achieved by chromium particles. However, all the high-density particles used in the study improved the radiation shielding properties of the mortars considerably compared to ordinary mortars.

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