Thermodynamic and kinetics investigation of homogeneous and heterogeneous nucleation

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Atefeh Khaleghi ◽  
Seyed Mojtaba Sadrameli ◽  
Mehrdad Manteghian
Keyword(s):  
Nucleation Rate ◽  
Heterogeneous Nucleation ◽  
Review Paper ◽  
Nucleation Theory ◽  
Classical Nucleation Theory ◽  
Homogeneous Part ◽  
Future Studies ◽  
Fundamental Process

AbstractNucleation is a fundamental process widely studied in different areas of industry and biology. This review paper comprehensively discussed the principles of classical nucleation theory (primary homogeneous), and heterogeneous nucleation. In the homogeneous part, the nucleation rate in the transient and intransient state is monitored and also heterogeneous nucleation is covered. Finally, conclusions have been deduced from the collected works studied here, and offers for future studies are proposed.

scholarly journals Low-temperature nucleation anomaly in silicate glasses shown to be artifact in a 5BaO·8SiO2 glass

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Xinsheng Xia ◽  
D. C. Van Hoesen ◽  
Matthew E. McKenzie ◽  
Randall E. Youngman ◽  
K. F. Kelton
Keyword(s):  
Nucleation Rate ◽  
Experimental Approach ◽  
Cluster Formation ◽  
Heating Time ◽  
Silicate Glasses ◽  
Nucleation Theory ◽  
Classical Nucleation Theory ◽  
Real Phenomenon ◽  
Satisfactory Answer ◽  
Over 40 Years

AbstractFor over 40 years, measurements of the nucleation rates in a large number of silicate glasses have indicated a breakdown in the Classical Nucleation Theory at temperatures below that of the peak nucleation rate. The data show that instead of steadily decreasing with decreasing temperature, the work of critical cluster formation enters a plateau and even starts to increase. Many explanations have been offered to explain this anomaly, but none have provided a satisfactory answer. We present an experimental approach to demonstrate explicitly for the example of a 5BaO ∙ 8SiO2 glass that the anomaly is not a real phenomenon, but instead an artifact arising from an insufficient heating time at low temperatures. Heating times much longer than previously used at a temperature 50 K below the peak nucleation rate temperature give results that are consistent with the predictions of the Classical Nucleation Theory. These results raise the question of whether the claimed anomaly is also an artifact in other glasses.

scholarly journals Nucleation Behavior of a Single Al-20Si Particle Rapidly Solidified in a Fast Scanning Calorimeter

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2920
Author(s):  
Qin Peng ◽  
Bin Yang ◽  
Benjamin Milkereit ◽  
Dongmei Liu ◽  
Armin Springer ◽  
...  
Keyword(s):  
Cooling Rate ◽  
Rapid Solidification ◽  
Heterogeneous Nucleation ◽  
Nucleation Theory ◽  
Classical Nucleation Theory ◽  
Solidification Behavior ◽  
Nucleation Kinetics ◽  
Nucleation Behavior ◽  
Nucleation Undercooling ◽  
Primary Si

Understanding the rapid solidification behavior characteristics, nucleation undercooling, and nucleation mechanism is important for modifying the microstructures and properties of metal alloys. In order to investigate the rapid solidification behavior in-situ, accurate measurements of nucleation undercooling and cooling rate are required in most rapid solidification processes, e.g., in additive manufacturing (AM). In this study, differential fast scanning calorimetry (DFSC) was applied to investigate the nucleation kinetics in a single micro-sized Al-20Si (mass%) particle under a controlled cooling rate of 5000 K/s. The nucleation rates of primary Si and secondary α-Al phases were calculated by a statistical analysis of 300 identical melting/solidification experiments. Applying a model based on the classical nucleation theory (CNT) together with available thermodynamic data, two different heterogeneous nucleation mechanisms of primary Si and secondary α-Al were proposed, i.e., surface heterogeneous nucleation for primary Si and interface heterogenous nucleation for secondary α-Al. The present study introduces a practical method for a detailed investigation of rapid solidification behavior of metal particles to distinguish surface and interface nucleation.

scholarly journals A semi-analytical method for calculating rates of new sulfate aerosol formation from the gas phase

2007 ◽  
Vol 7 (1) ◽  
pp. 2169-2196 ◽  
Author(s):  
J. Kazil ◽  
E. R. Lovejoy
Keyword(s):  
Steady State ◽  
Gas Phase ◽  
Nucleation Rate ◽  
Atmospheric Modeling ◽  
Sulfate Aerosol ◽  
Nucleation Theory ◽  
Rate Coefficients ◽  
Classical Nucleation Theory ◽  
Aerosol Formation ◽  
Aerosol Model

Abstract. The formation of new sulfate aerosol from the gas phase is commonly represented in atmospheric modeling with parameterizations of the steady state nucleation rate. Such parameterizations are based on classical nucleation theory or on aerosol nucleation rate tables, calculated with a numerical aerosol model. These parameterizations reproduce aerosol nucleation rates calculated with a numerical aerosol model only imprecisely. Additional errors can arise when the nucleation rate is used as a surrogate for the production rate of particles of a given size. We discuss these errors and present a method which allows a more precise calculation of steady state sulfate aerosol formation rates. The method is based on the semi-analytical solution of an aerosol system in steady state and on parameterized rate coefficients for H2SO4 uptake and loss by sulfate aerosol particles, calculated from laboratory and theoretical thermodynamic data.

scholarly journals Analysis of the effect of water activity on ice formation using a new thermodynamic framework

2014 ◽  
Vol 14 (14) ◽  
pp. 7665-7680 ◽  
Author(s):  
D. Barahona
Keyword(s):  
Water Activity ◽  
Nucleation Rate ◽  
Ice Nucleation ◽  
Nucleation Theory ◽  
Cloud Formation ◽  
Classical Nucleation Theory ◽  
Solid Matrix ◽  
Effect Of Water ◽  
Thermodynamic Framework ◽  
New Framework

Abstract. In this work a new thermodynamic framework is developed and used to investigate the effect of water activity on the formation of ice within supercooled droplets. The new framework is based on a novel concept where the interface is assumed to be made of liquid molecules "trapped" by the solid matrix. It also accounts for the change in the composition of the liquid phase upon nucleation. Using this framework, new expressions are developed for the critical ice germ size and the nucleation work with explicit dependencies on temperature and water activity. However unlike previous approaches, the new model does not depend on the interfacial tension between liquid and ice. The thermodynamic framework is introduced within classical nucleation theory to study the effect of water activity on the ice nucleation rate. Comparison against experimental results shows that the new approach is able to reproduce the observed effect of water activity on the nucleation rate and the freezing temperature. It allows for the first time a phenomenological derivation of the constant shift in water activity between melting and nucleation. The new framework offers a consistent thermodynamic view of ice nucleation, simple enough to be applied in atmospheric models of cloud formation.

Molecular Dynamics Simulation of Nano Cluster-Seed Effects on Heterogeneous Nucleation

2009 ◽  
Author(s):  
Donguk Suh ◽  
Seung-chai Jung ◽  
Woong-sup Yoon
Keyword(s):  
Molecular Dynamics ◽  
Heterogeneous Nucleation ◽  
Three Dimensional ◽  
Seed Mass ◽  
Nucleation Theory ◽  
Dynamics Simulation ◽  
Classical Nucleation Theory ◽  
Supersaturation Ratio ◽  
Order Of Magnitude ◽  
Nano Cluster

A three-dimensional heterogeneous nucleation is simulated by classical molecular dynamics, where the Lennard-Jones gas and solid nano cluster-seed molecules have argon and aluminum properties, respectively. All dimensions of the wall are periodic and a soft core carrier gas within the system controls the temperature rise induced by latent heat of condensation. There are three shapes of cluster-seeds being cube, rod, and sphere, three classes of masses, and the simulation took place under nine supersaturation ratios, making a total of 81 calculations. An analysis of variance was performed under a three-way layout to analyze the cluster-seed and supersaturation ratio effects on the system. For supersaturation ratios above the critical value nucleation rates were evaluated, below growth rates, and overall liquefaction rates were each defined and calculated. Results show that the supersaturation ratio dominantly controls all rates, but seed characteristics are important for the growth of the largest cluster under the critical supersaturation ratio. Overall liquefaction increases subject to an escalation of supersaturation ratio and seed mass. However, the significance of the supersaturation ratio for overall liquefaction suggests that thermal diffusion is more dominant than mass interactions for this system. Homogeneous characteristics are also compared with the heterogeneous system to find that though nucleation may occur for an insufficient supersaturation ratio when a seed is within the system, the addition of a seed does not in fact facilitate the increase in rates of the phenomena at high supersaturation ratios. Finally a comparison with the classical nucleation theory asserts a 3 to 4 order of magnitude difference, which is within the lines of deviation when it comes to theory and molecular simulations.

scholarly journals A semi-analytical method for calculating rates of new sulfate aerosol formation from the gas phase

2007 ◽  
Vol 7 (13) ◽  
pp. 3447-3459 ◽  
Author(s):  
J. Kazil ◽  
E. R. Lovejoy
Keyword(s):  
Steady State ◽  
Gas Phase ◽  
Nucleation Rate ◽  
Atmospheric Modeling ◽  
Sulfate Aerosol ◽  
Nucleation Theory ◽  
Rate Coefficients ◽  
Classical Nucleation Theory ◽  
Aerosol Formation ◽  
Aerosol Model

Abstract. The formation of new aerosol from the gas phase is commonly represented in atmospheric modeling with parameterizations of the steady state nucleation rate. Present parameterizations are based on classical nucleation theory or on nucleation rates calculated with a numerical aerosol model. These parameterizations reproduce aerosol nucleation rates calculated with a numerical aerosol model only imprecisely. Additional errors can arise when the nucleation rate is used as a surrogate for the production rate of particles of a given size. We discuss these errors and present a method which allows a more precise calculation of steady state sulfate aerosol formation rates. The method is based on the semi-analytical solution of an aerosol system in steady state and on parameterized rate coefficients for H2SO4 uptake and loss by sulfate aerosol particles, calculated from laboratory and theoretical thermodynamic data.

Analytical Investigation on the Homogeneous Nucleation in a Mono-Component and Bi-Component Droplet

2019 ◽  
Author(s):  
Xi Xi ◽  
Hong Liu ◽  
Chang Cai ◽  
Ming Jia ◽  
Weilong Zhang
Keyword(s):  
Nucleation Rate ◽  
Homogeneous Nucleation ◽  
Ambient Pressure ◽  
Analytical Investigation ◽  
Bubble Nucleation ◽  
Nucleation Theory ◽  
Classical Nucleation Theory ◽  
Liquid Temperature ◽  
Wide Range ◽  
Good Agreement

Abstract The work attempts to analyze the performance of homogeneous nucleation by using the non-equilibrium thermodynamics theory and the classical nucleation theory. A nucleation rate graph was constructed under a wide range of operating temperature conditions. The results indicate that the superheat limit temperature (SLT) estimated by the modified homogeneous nucleation sub-model is in good agreement with the experimental results. The nucleation rate increases exponentially with the liquid temperature rise when the liquid temperature exceeds the SLT under atmospheric pressure. The superheated temperature needed to trigger the bubble nucleation decreases with the elevated ambient pressure.

Molecular Dynamics Based Analysis of Nucleation and Surface Energy of Droplets in Supersaturated Vapors of Methane and Ethane

2009 ◽  
Vol 131 (4) ◽  
Author(s):  
Jadran Vrabec ◽  
Martin Horsch ◽  
Hans Hasse
Keyword(s):  
Molecular Dynamics ◽  
Surface Energy ◽  
Droplet Size ◽  
Nucleation Rate ◽  
Homogeneous Nucleation ◽  
First Passage Time ◽  
Nucleation Theory ◽  
Dynamics Simulation ◽  
Classical Nucleation Theory ◽  
Critical Droplet

Homogeneous nucleation processes are characterized by the nucleation rate and the critical droplet size. Molecular dynamics simulation is applied for studying homogeneous nucleation during condensation of supersaturated vapors of methane and ethane. The results are compared with the classical nucleation theory (CNT) and the Laaksonen–Ford–Kulmala (LFK) model that introduces the size dependence of the specific surface energy. It is shown for the nucleation rate that the Yasuoka–Matsumoto method and the mean first passage time method lead to considerably differing results. Even more significant deviations are found between two other approaches to the critical droplet size, based on the maximum of the Gibbs free energy of droplet formation (Yasuoka–Matsumoto) and the supersaturation dependence of the nucleation rate (nucleation theorem). CNT is found to agree reasonably well with the simulation results, whereas LFK leads to large deviations at high temperatures.

A Justification for the Use of Data from Accelerated Leach Tests of Glass

1992 ◽  
Vol 294 ◽  
Author(s):  
Tae M. Ahn ◽  
Charles G. Interrante ◽  
Richard A. Weller
Keyword(s):  
Nucleation Rate ◽  
Laboratory Data ◽  
Nucleation Theory ◽  
Classical Nucleation Theory ◽  
Short Term ◽  
Continuous Formation ◽  
Laboratory Test Results ◽  
Radionuclide Release ◽  
Colloid Formation

ABSTRACTA case is made for the use of short-term laboratory data in making predictions on the likelihood of significant colloid formation in supersaturated leachates of glass, under long-term repository conditions, using “accelerated tests” with a large ratio of the surface area of the glass to the leachate volume. In the repository conditions in which colloids can form, long-term leaching may be a kinetically-controlled process that involves the continuous formation of colloids. If this kinetic process dominates, it could lead to a significant increase in the predicted rates of radionuclide release. The question is whether or not colloids may form after prolonged times; the delayed formation would make it difficult to use short-term laboratory test results to represent (or predict) the long-term and cumulative effects of radionuclides. In this work, the pertinent long-term kinetic processes are identified in part. Classical nucleation theory for particle formation, as a potential condensation mechanism for colloid formation, is applied to explain pertinent experimental data on colloid formation. The classical theory, which is justified for this discussion, indicates that as supersaturation of a leachate is decreased, the nucleation rate decreases most significantly, while the incubation time increases at a small rate. As a result of this decreased nucleation rate, the significance of colloids tends to vanish, and usefulness of data from “accelerated“ laboratory tests may be applicable to long-term behavior.

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