scholarly journals Assessment of heavy metals concentrations in the soil of Mongla industrial area, Bangladesh

2019 ◽  
Vol 6 (3) ◽  
pp. 191-202
Author(s):  
Md. Abu Rayhan Khan ◽  
Mosummath Hosna Ara ◽  
Palash Kumar Dhar

Background: Contamination of soil with heavy metals is an alarming issue around the world. Therefore, this study aimed to assess the contamination status of heavy metals in the soil of Mongla industrial area, Bangladesh. Methods: Soil samples were randomly collected from 20 sites and digested by wet digestion method. The concentrations of heavy metals (Mn, Fe, Cu, Zn, Cd, and Pb) were determined using atomic absorption spectrophotometer (AAS). The quality of soil was assessed based on the contamination factor (CF), geoaccumulation index (Igeo), enrichment factor (EF), and ecological risk index factor (ERIF) analyses. Results: The average concentrations of Mn, Fe, Cu, Zn, Cd, and Pb were obtained to be 258.08±51.61, 3736.90±322.17, 19.55±6.49, 66.76 ± 18.32, 0.59±0.13, and 10.40 ± 1.49 mg kg-1, respectively, which were below the permissible limit. The highest value of CF (0.74±0.16), Igeo (0.35±0.34), EF (24.86±6.27), and PERIF (22.11±4.81) was observed for Cd. The pollution of CF, Igeo, EF, and ERIF was classified as very severely polluted, unpolluted to moderately polluted, strongly to extremely polluted, and slightly polluted, respectively, with these heavy metals due to anthropogenic activities. One-way ANOVA indicated a significant difference between Zn and Cd concentrations (P<0.05), whereas Pearson correlation showed a positive correlation between Zn-Pb (P=0.01) and Fe-Zn (P=0.05). Conclusion: There are different classes of contamination with heavy metals in the study area. Therefore, necessary steps should be taken and people’s awareness of the soil pollution should be raised.

Toxics ◽  
2022 ◽  
Vol 10 (1) ◽  
pp. 16
Author(s):  
Xiaomei Su ◽  
Hong Ling ◽  
Dan Wu ◽  
Qingju Xue ◽  
Liqiang Xie

The contamination of heavy metals (Pb, Cr, Hg, Cd, Ni, Cu, Zn, As, and Sb) in the sediments were investigated in Lake Yangcheng, a eutrophic lake in China. Results showed that the average concentrations of each metal in the surface sediments generally exceeded their corresponding background values. Higher values were observed in deeper zones, supporting the retention and accumulation of heavy metals in the core sediments. The spatial distributions of metal averages, pollution load index (PLI), and combined ecological risk index (RI) revealed that ecological risks were highest in the west lake, followed by middle lake, and were lowest in the east section. For the temporal variations of metal contents, the highest concentration was usually observed in the winter. However, the seasonal dynamics of Hg showed a different pattern with higher values in the autumn and lower values in the winter. According to contamination factor (CF), the Hg and Sb contaminations were considerable, while the other metals were moderate contamination. In terms of geoaccumulation index (Igeo) values, sediments were moderately–heavily polluted by Sb and moderately polluted by Hg, Cd, and Ni. Meanwhile, Hg exhibited a considerable health risk, while Cd and Sb were moderate risks, based on single ecological risk index (Er) values. Significant positive correlations among heavy metals and principal component analysis (PCA) indicated that anthropogenic activities were major sources. The source of Sb might be different from other metals, with industrial discharge as the main loading. This study highlighted the urgency of taking measures to prevent Hg, Sb, and Cd pollutions in Lake Yangcheng, especially the west region of this lake.


2020 ◽  
Vol 10 (25) ◽  
Author(s):  
Temitope Ayodeji Laniyan ◽  
Adeniyi JohnPaul Adewumi

Background. Exposure to heavy metals emanating from cement production and other anthropogenic activities can pose ecological risks. Objectives. A detailed investigation was carried out to assess the contamination and ecological risk of heavy metals associated with dust released during cement production. Methods. Sixty samples, including 30 soils and 30 plants, were collected around Lafarge Cement Production Company. Control samples of soil and plants were collected in areas where human activities are limited. Samples were dried, sieved (for soil; 65 μm), packaged and analyzed using inductively coupled plasma mass spectrometry at Acme Laboratory in Canada. Results. The average concentration of heavy metals in soils of the area are: copper (Cu): 41.63 mg/kg; lead (Pb): 35.43 mg/kg; zinc (Zn): 213.64 mg/kg; chromium (Cr): 35.60 mg/kg; cobalt (Co): 3.84 mg/kg and nickel (Ni): 5.13 mg/kg. Concentrations of Cr in soils were above the recommended standards, while other metals were below recommended limits. The average concentrations of heavy metals in plants were: Cu: 26.32 mg/kg; Pb: 15.46 mg/kg; Zn: 213.94 mg/kg; Cr: 30.62 mg/kg; Co: 0.45 mg/kg and Ni: 3.77 mg/kg. Levels of heavy metals in plants were all above international limits. Geo-accumulation of metals in soils ranged between −0.15 and 6.32, while the contamination factor ranged between 0.53 and 119.59. Ecological risk index of heavy metals in soils ranged between 49.71 and 749. Discussion. All metals in soils of the study area except for Cr were below the allowable limits, while the levels of metals in plants were above the permissible limits. Levels of heavy metals reported in this study were higher than those from similar cement production areas. Soils around the Ewekoro cement production area were low to extremely contaminated by toxic metals. Cement production, processing, transportation in conjunction with the abandoned railway track in the area greatly contribute to the high degree of contamination observed in the area. Metal transfers from soil to plant are a common phenomenon. The metals pose low to considerable ecological risk. Conclusions. Anthropogenic sources, especially cement processing activities, release heavy metals which leads to progressive pollution of the environment and poses high ecological risk. Competing Interests. The authors declare no competing financial interests


2019 ◽  
Vol 6 (2) ◽  
pp. 129-137
Author(s):  
Firouzeh Yadegarnia Naeini ◽  
Hamidreza Azimzadeh ◽  
Asghar Mosleh Arani ◽  
Ahad Sotoudeh ◽  
Bahman Kian

Background: The release of metals from industrial factories is one of the most important sources ofenvironmental pollution. The present study aimed to determine the concentration of heavy metals likecadmium (Cd), chromium (Cr), manganese (Mn), nickel (Ni), and lead (Pb) in dust around the cementfactory.Methods: A total of 22 dust samples were collected from areas around the cement factory in Isfahanprovince in spring and summer and transferred to laboratory for chemical digestion. Risk index (RI),integrated pollution index (IPI), mean of contamination degree (mCd), and contamination factor (Cfi)were calculated to determine the contamination status.Results: The concentration of heavy metals in the falling dust around the factory was expressed as Cd<Ni <Pb <Mn <Cr. Pearson correlation showed that there is only a significant negative relationshipbetween the concentration of Cd and the distance from the factory. By increasing the distance from thefactory, the concentration of Cd in dust decreased. The results of falling dust analysis showed that Crhas a high-risk potential in two seasons of spring and summer and Cd has a middle level of pollutionin spring.Conclusion: According to the results, the deposited dust of study area is considered as a polluted dustand it is at higher risk of pollution with Cd and Cr.


Processes ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 410
Author(s):  
Mohammad Abdus Salam ◽  
Mohammad Ashraful Alam ◽  
Sulav Indra Paul ◽  
Fatama Islam ◽  
Dinesh Chandra Shaha ◽  
...  

This study aimed to determine the levels and possible sources of heavy metals (HMs) in the sediments of Chalan beel (a large lake-like aquatic ecosystem) area located in the northwestern part of Bangladesh. The mean concentrations (mg kg−1) of two HMs, Cd (6.22) and Pb (51.39) exceeded the world normal averages (WNA), whereas the mean concentrations (mg kg−1) of Ni (60.46), Zn (10.75), Mn (8.64) and Cu (4.71) were below the WNA. The sediments showed significant enrichment with Cd, Pb and Ni in the studied area. The geo-accumulation index values of Cd (3.72) and Pb (0.76) were significantly higher in the sediments. The contamination factor and potential ecological risk index values of Cd and Pb revealed that Chalan beel was extremely and moderately contaminated by these heavy metals, respectively. Analysis of dye complexes used in handlooms around the Chalan beel areas revealed that mean concentrations of Cd and Pb exceeded the WNA. Furthermore, analyses of principal component, cluster and correlation matrix indicated that the presence of the higher levels of Cd and Pb in the sediments might be linked to various anthropogenic activities like discharged dyes into the beel water from the nearby handloom dyeing factories.


2021 ◽  
pp. 58-68
Author(s):  
C. E. Igwe ◽  
C. M. U. Ajero ◽  
A. A. Amaechi ◽  
P. O.` Nzenwa

Heavy metals (HM) have been a global concern for its toxic and detrimental effect on the environment especially when it exceeds the permissible limit through anthropogenic activities like kaolin mining. Kaolin mining has improved the economic wellbeing of the local people through employment and otherwise; and at the same time attached with environmental consequences that threatens the livelihood of the community members. This study was carried out to ascertain the concentrations of selected heavy metals in kaolin mined soils and water body and its pollution density using single pollution indices such as contamination factor (CF), geo-accumulation (Igeo) and ecological risk factor (Er ). Soil sample were collected from three different kaolin mined sites labelled (A,B and C) also surface water samples were collected from upper and down streams of Iyi-ugbohoroAmaudara, both samples were digested and elemental analysis was carried out using Atomic Absorption Spectrophotometer (AAS UNICAM 919 model). The concentration of the metals in three different kaolin mined soil samples ranges from Pb(40.00, 52.00 and 55.09 mg/kg) Cr(45.01, 70.00 and 71.00 mg/kg) Ni( 32.10, 50.50 and 51.00 mg/kg) Cd( 2.16, 6.25 and 6.15 mg/kg) Co( 19.68, 57.06 and 56.00 mg/kg) Se(1.06, 0.50, and 1.00 mg/kg) Mn(0.001, 0.01 and 0.01 mg/kg) Hg( 2.01, 2.00 and 2.50 mg/kg) As( 1.07, 1.10 and 1.05 mg/kg) and Cu(33.01, 60.00 and 57.5 mg/kg). Results from single pollution indices used for the selected heavy metals from kaolin mined soil, samples (A,B and C) showed that Mn, As, Cr, Ni and Cu indicated low to moderate contamination factor while Cd, Se, Co and Hg indicated high to very high contamination factor in all the samples. The distribution trend of heavy metals concentrations in the upper and down streams of the river body during wet season, showed that there were significant difference between upper and down streams while dry season showed variations in significant differences between the upper and down streams of some of the heavy metals. The study therefore concludes that kaolin soils are contaminated with heavy metals as a result of kaolin deposit and its mining activities. The single pollution indices used for the study pointed out that Cd, Se, Co and Hg are very high in the kaolin soils. The surface waters of Iyi-ugbohoroAmaudara River at the study area are polluted with heavy metals as a result of kaolin mining activities in the area; more especially during wet season of the study. Consequently, these outcomes would pose a toxic effect to both fauna and flora and possibly threatens the aquatic lives and the local populace.


Plants ◽  
2020 ◽  
Vol 9 (7) ◽  
pp. 910
Author(s):  
Yasser A. El-Amier ◽  
Giuliano Bonanomi ◽  
Saud L. Al-Rowaily ◽  
Ahmed M. Abd-ElGawad

The use of drainage water in the irrigation of agroecosystem is associated with environmental hazards, and can pose threats to human health. Nine heavy metals (Fe, Mn, Zn, Cu, Co, Cr, Ni, Cd and Pb) along three main drains in the middle Nile Delta were measures in the sediments, roots and shoots of three common macrophytes (Echinochloa stagnina, Phragmites australis and Typha domingensis). The physicochemical characteristics, as well as the enrichment factor (Ef), contamination factor (Cf), geoaccumulation index (Igeo), ecological risk factor (Er), degree of contamination (Dc) and potential ecological risk index (PERI), were determined for sediment. The metal bioaccumulation factor (BAF) and translocation factor (TF) were assessed for plants. Data revealed high contents of Cr, Zn and Cd in the upstream of the drains, while Mn, Cu and Ni were recorded in high concentrations in the downstream. Mn, Cr, Co, Cu, Ni and Zn were recorded to be within EU (2002), CSQGD (2007) and US EPA (1999) limits, while Cd and Pb showed high a ecological risk index. This high concentration of pollutants could be attributed to unremitting industrial activities, which can bioaccumulate in the food chains and cause serious problems for humans. The root of P. australis showed the effective accumulation of most of the elements, while T. domingensis revealed the highest accumulation of Pb. However, the highest BAF shoot value was found in T. domingensis for most of the heavy metals, except for Fe and Zn in P. australis and Mn in E. stagnina. Thus, P. australis could be used as a potential phytoextractor of these hazardous metals, as an eco-friendly and cost-efficient method for remediation of the polluted drains. Further, T. domingensis could be integrated as a hyperaccumulator of Pb. Strict laws and regulations must be taken into consideration by the policymaker against unmanaged industrial activities, particularly near the water streams in the Nile Delta.


2020 ◽  
Vol 29 (3) ◽  
pp. 289-297
Author(s):  
Eva Singovszka ◽  
Magdalena Balintova

Quality is one of the most important risk indicators in river basins. Therefore, monitoring and evaluating water and sediment quality has a very important role in process of risk management. The aim of the monitoring is provide for the sustainability of water bodies and these results are the basis for the risk management in the river catchment area. Hornad, Laborec and Poprad are the rivers in Eastern Slovakia. Hornad and Laborec belongs to basin of Danube and Poprad belongs to basin of Vistula. Sediment sampling was carried out according to ISO 5667-6. Monitoring was carried out in the spring on 2017–2018. The chemical composition of sediments was determined by means of X-ray fluorescence (XRF) using SPECTRO iQ II (Ametek, Germany, 2000). The results of sediment quality evaluated by method PERI revealed that the quality of sediment in 2018 was better than 2017. Results of XRF analysis of sediments were compared with the limited values according to the Slovak Act 188/2003 Coll. of Laws on the application of treated sludge and bottom sediments to fields. It can be state that limit values comparing with Slovak legislation were not exceeding in all sediment samples in rivers in Eastern Slovakia. Based on the monitoring data of sediment quality in the study area, a quantitative analysis of heavy-metal pollution in sediment was conducted using the method of potential ecological risk index (PERI) which is method for evaluate the potential ecological risk of heavy metals. It is based exclusively on chemical parameters of sediments because sediment data show mean integrated values in time, with higher stability than water column parameters; sediments are easily sampled at field work; sediment samples are more representative for time and space scales and analytical data are easily obtained, especially because sediments present high concentrations of contaminants, decreasing the possible errors due to detection limits of the applied analytical method. This method comprehensively considers the synergy, toxic level, concentration of the heavy metals and ecological sensitivity of heavy metals. Potential ecological risk index can be obtained using three basic modules: degree of contamination (CD), toxic-response factor (TR) and potential ecological risk factor (ER). The results show on the basis on potential ecological risk index that the quality of sediment in 2018 is better than 2017. The worst result shows Hornad in 2017. Significant improvement occurred at the sampling point S2 in Hornad in 2018. The best results show Laborec in 2018. The results show on the basis on potential ecological risk index that quality of sediment in 2018 is better than 2017.


The study assessed the ecological risk and polluting load of heavy metals (Cd, Cr, Cu, Ni, Pb and Zn) in surface soils within Bori Urban. The composite soil samples collected from different locations were prepared and atomic absorption spectrophotometer (AAS) was used for the analysis of the heavy metals. From the results of the analysis, the mean concentrations (mg/kg) of the heavy metals decreased in the order Cu (37.42) > Ni (34.06) > Cr (28.66) > Zn (7.75) >Pb (2.03) > Cd (0.89). The mean concentrations of Cd, Cu, and Ni were above USEPA soil guidelines and world unpolluted soil average, while those of Pb and Zn were below. The mean concentrations of the heavy metals from the study locations were all above that of the control location. The findings indicated that the urban soils of the study were loaded with heavy metals due to anthropogenic activities. The anthropogenic percentage input was in the range of 63.92 - 89.13 above 50% indicating anthropogenic origin of the heavy metals in soils of the study area. The results of ecological risk index (Er) indicated that Cd with Er (467.40) contributed up to 94.51% to the potential ecological risk index (RI) while Zn (0.78) contributed 0.16%. The heavy metals under study posed highly strongly potential ecological risk with RI value of 494.56 to the Bori urban soil due to anthropogenic activities. The ANOVA result of FCal 6.42 > [F(5.30) = 2.53, P< 0.05)] revealed significant differences between the soil sample mean values due to different anthropogenic pollution sources with different loads of heavy metals as pollutants. The Omega Squared (w2) value of 0.52 > 0.14 showed very strong interactive relationship among the heavy metals to bring about high level of ecological potential risk of the urban soils in the study area. Based on the findings, the surface soils have elevated load of heavy metals thereby posing ecological potential risk to Bori urban soils. Therefore, there should be periodic monitoring and environmental audit by relevant authorities to ensure good soil quality of Bori urban soil. Keywords: Potential ecological risk, pollution load, Bori Urban, Anthropogenic Percentage input, contamination Factor.


Author(s):  
Osikemekha Anthony Anania ◽  
John Ovie Olomukoro ◽  
Alex Ajeh Enuneku

The objectives of this study are to assess the trace and heavy metals pollution in the sediments of Ossiomo river, using geospatial mapping, environmetrics and ecological risk indices. The results from the descriptive statistics showed that there was significant difference (P<0.05) of the mean values of Fe, Mn, Cu, Cr, Cd, Pb, Ni and V. A posterior analysis using Duncan multiple regression analysis showed that stations 2 and 3 were significantly different from stations 1 and 4. While, there was no significant difference (P>0.05) in the mean values of Zn across the stations. The results of the relationship of the metals revealed a negative correlation between Fe and Mn with the other metals correspondingly. The results of the Kriging interpolation indicated a strong bull eye colour for stations 2 and 3 (6.42), while stations 1 and 4 were minimal (1.4). The results of the geospatial mapping indicated Fe, Zn and Mn to be the most dominant metals across the stations. The results of the PCA (principal component analysis) yielded 16 variables under 9 components with Eigenvalues >1 in components 1- 6 and these variables explained 99.99 % of the total variance in the sediment. The results of the degree of suitability and sphericity of the PCA revealed a high significant difference at P<0.001. The results of the potential ecological risk index values were very high in station 2 (824.30) and 3 (802.11) correspondingly. That of index of geo-accumulation was generally low (< 2). The findings from this study generally revealed the source apportionment of the trace and heavy metals to come from anthropogenic influences such as farming; fertilizers. Sustainable agriculture is highly recommended in order to reduce the impacts of anthropogenic activities, deterioration of the ecosystem and possible death of the life forms in this watercourse.  


Atmosphere ◽  
2021 ◽  
Vol 12 (5) ◽  
pp. 614
Author(s):  
Muhammad Faisal ◽  
Zening Wu ◽  
Huiliang Wang ◽  
Zafar Hussain ◽  
Chenyang Shen

Heavy metals in road dust pose a significant threat to human health. This study investigated the concentrations, patterns, and sources of eight hazardous heavy metals (Cr, Ni, Cu, Zn, As, Cd, Pb, and Hg) in the street dust of Zhengzhou city of PR China. Fifty-eight samples of road dust were analyzed based on three methods of risk assessment, i.e., Geo-Accumulation Index (Igeo), Potential Ecological Risk Assessment (RI), and Nemerow Synthetic Pollution Index (PIN). The results exhibited higher concentrations of Hg and Cd 14 and 7 times higher than their background values, respectively. Igeo showed the risks of contamination in a range of unpolluted (Cr, Ni) to strongly polluted (Hg and Cd) categories. RI came up with the contamination ranges from low (Cr, Ni, Cu, Zn, As, and Pb) to extreme (Cd and Hg) risk of contamination. The risk of contamination based on PIN was from safe (Cu, As, and Pb) to seriously high (Cd and Hg). The results yielded by PIN indicated the extreme risk of Cd and Hg in the city. Positive Matrix Factorization was used to identify the sources of contamination. Factor 1 (vehicular exhaust), Factor 2 (coal combustion), Factor 3 (metal industry), and Factor 4 (anthropogenic activities), respectively, contributed 14.63%, 35.34%, 36.14%, and 13.87% of total heavy metal pollution. Metal’s presence in the dust is a direct health risk for humans and warrants immediate and effective pollution control and prevention measures in the city.


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