Chemistry of rhenium as an analogue of technetium: Experimental studies of the dissolution of rhenium oxides in aqueous solutions

2003 ◽  
Vol 91 (4) ◽  
Author(s):  
E. Kim ◽  
J. Boulègue
Keyword(s):  
Aqueous Solutions ◽  
Thermodynamic Data ◽  
Experimental Studies ◽  
Experimental Results ◽  
Radioactive Element ◽  
Oxidation States ◽  
Dissolution Behavior ◽  
High Concentration ◽  
Very High ◽  
Chemical Analogue

SummaryThe migration of fissiogenic Tc into the environment can be predicted by studying the dissolution behavior of Re, a chemical analogue of Tc, avoiding the use of a radioactive element at high concentration. We developed a series of experimental studies of the solubility of Re oxides under various oxidation states (+VII, +IV, and +III), in oxidizing and anoxic media, so as to verify the validity of the available thermodynamic data concerning Re. The experimental results confirm that the predictable solubility of Re, under the conditions found in radioactive wastes storage, is very high when in the form of {ReO

scholarly journals Ultra-High and Near-Zero Refractive Indices of Magnetron Sputtered Thin-Film Metamaterials Based on TixOy

2016 ◽  
Vol 2016 ◽  
pp. 1-9 ◽  
Author(s):  
Vukoman Jokanović ◽  
Božana Čolović ◽  
Miloš Nenadović ◽  
Anka Trajkovska Petkoska ◽  
Miodrag Mitrić ◽  
...  
Keyword(s):  
Oxygen Vacancies ◽  
Band Gaps ◽  
Oxidation States ◽  
Refractive Indices ◽  
Dc Magnetron Sputtering ◽  
High Concentration ◽  
Extinction Coefficients ◽  
Electron Transitions ◽  
Titanium Oxidation ◽  
Very High

Metamaterials based onTixOywith ultra-high and near-zero refractive indices were obtained by DC magnetron sputtering. The data on refractive indices, extinction coefficients, film thickness, and band gaps, obtained by spectroscopic ellipsometry, showed very high potential of these materials as metamaterials. Phase analysis performed by XRD revealed the presence of titanium phases with lower titanium oxidation states resulting from high concentration of oxygen vacancies, which are crucial for such extraordinary jumps and drops of refractive indices. Numerous band gaps for direct and indirect electron transitions additionally confirmed unique properties of these materials.

scholarly journals THE KINETICS OF THE DECOMPOSITION OF PEROXIDE BY CATALASE

1925 ◽  
Vol 7 (3) ◽  
pp. 373-387 ◽  
Author(s):  
John H. Northrop
Keyword(s):  
Hydrogen Peroxide ◽  
Experimental Results ◽  
Inactivation Rate ◽  
High Concentration ◽  
Inactivation Constant ◽  
Monomolecular Decomposition ◽  
High Concentrations ◽  
Kinetics Of ◽  
Very High

It has been shown that the experimental results obtained by Morgulis in a study of the decomposition of hydrogen peroxide by liver catalase at 20°C. and in the presence of an excess of a relatively high concentration of peroxide are quantitatively accounted for by the following mechanisms. 1. The rate of formation of oxygen is independent of the peroxide concentration provided this is greater than about 0.10 M. 2. The rate of decomposition of the peroxide is proportional at any time to the concentration of catalase present. 3. The catalase undergoes spontaneous monomolecular decomposition during the reaction. This inactivation is independent of the concentration of catalase and inversely proportional to the original concentration of peroxide up to 0.4 M. In very high concentrations of peroxide the inactivation rate increases. 4. The following equation can be derived from the above assumptions and has been found to fit the experiments accurately. See PDF for Equation in which x is the amount of oxygen liberated at the time t, A is the total amount of oxygen liberated (not the total amount available), and K is the inactivation constant of the enzyme.

Ground water quality of selected areas of Punjab and Sind Provinces, Pakistan: Chemical and microbiological aspects

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Ionic Concentration ◽  
Chloride Ions ◽  
Potassium Ions ◽  
Ammonium Ions ◽  
High Concentration ◽  
Phosphate Ions ◽  
Sodium Magnesium ◽  
Very High ◽  
Microbiological Aspects

The assessment of groundwater is essential for the estimation of suitability of water for safe use. An attempt has been made to study the groundwater of selected areas of Punjab (Sheikhupura & Sahiwal) and Sindh (Sindh, Jawar Dharki and Dharki), Pakistan. The results indicate that pH, color and odor were all within limits of WHO that is pH ranges 6.5–8.5, colorless and odorless, respectively. The high values of suspended solids were observed in the Sindh-1 and Dharki samples. Microbiologically only Sahiwal and Jawar Dharki were found fit for drinking purpose. Trace metals analysis of Sheikhupura-1 and Sindh-1 showed that values do not fall within limits of WHO for Iron. The ionic concentration analysis showed that high bicarbonate (HCO3-), ions are present in the samples of Sahiwal and Dharki; Sindh-1 and Jawar Dharki samples showed very high concentration for chloride ions, all samples were satisfactory level for sulphate (SO42-), sodium, magnesium and phosphate ions except samples of Sindh-1 and Jawar Dharki. High concentration of calcium and potassium ions was observed in samples of Sindh-1, while all other samples were found fit for drinking purposes in respect of nitrate, nitrite and ammonium ions. The high concentration of Fluoride was found only in Sheikhupura-2 samples.

The metachor as a characteristic of the association of electrolytes in aqueous solutions

1984 ◽  
Vol 49 (5) ◽  
pp. 1061-1078 ◽  
Author(s):  
Jiří Čeleda ◽  
Stanislav Škramovský
Keyword(s):  
Aqueous Solutions ◽  
Apparent Volume ◽  
Solutions Of Electrolytes ◽  
Molal Volumes ◽  
The Difference ◽  
High Concentrations ◽  
Experimental Values ◽  
Suitable Characteristic ◽  
Association Of Ions ◽  
Very High

Based on the earlier paper introducing a concept of the apparent parachor of a solute in the solution, we have eliminated in the present work algebraically the effect which is introduced into this quantity by the additivity of the apparent molal volumes. The difference remaining from the apparent parachor after substracting the contribution corresponding to the apparent volume ( for which the present authors suggest the name metachor) was evaluated from the experimental values of the surface tension of aqueous solutions for a set of 1,1-, 1,2- and 2,1-valent electrolytes. This difference showed to be independent of concentration up to the very high values of the order of units mol dm-3 but it was directly proportional to the number of the free charges (with a proportionality factor 5 ± 1 cm3 mol-1 identical for all studied electrolytes). The metachor can be, for this reason, a suitable characteristic for detection of the association of ions and formation of complexes in the solutions of electrolytes, up to high concentrations where other methods are failing.

scholarly journals Near quantitative synthesis of urea macrocycles enabled by bulky N-substituent

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Yingfeng Yang ◽  
Hanze Ying ◽  
Zhixia Li ◽  
Jiang Wang ◽  
Yingying Chen ◽  
...  
Keyword(s):  
High Efficiency ◽  
Molecular Structures ◽  
High Yield ◽  
Kinetic Control ◽  
High Concentration ◽  
Weak Association ◽  
Quantitative Synthesis ◽  
Thermodynamic Stabilization ◽  
Discrete Structures ◽  
Very High

AbstractMacrocycles are unique molecular structures extensively used in the design of catalysts, therapeutics and supramolecular assemblies. Among all reactions reported to date, systems that can produce macrocycles in high yield under high reaction concentrations are rare. Here we report the use of dynamic hindered urea bond (HUB) for the construction of urea macrocycles with very high efficiency. Mixing of equal molar diisocyanate and hindered diamine leads to formation of macrocycles with discrete structures in nearly quantitative yields under high concentration of reactants. The bulky N-tert-butyl plays key roles to facilitate the formation of macrocycles, providing not only the kinetic control due to the formation of the cyclization-promoting cis C = O/tert-butyl conformation, but also possibly the thermodynamic stabilization of macrocycles with weak association interactions. The bulky N-tert-butyl can be readily removed by acid to eliminate the dynamicity of HUB and stabilize the macrocycle structures.

Small-volume vitrification and rapid warming yield high survivals of one-cell rat embryos in cryotubes

2021 ◽  
Author(s):  
Yasuyoshi Fukuda ◽  
Misako Higashiya ◽  
Takahiro Obata ◽  
Keita Basaki ◽  
Megumi Yano ◽  
...  
Keyword(s):  
Cooling Rate ◽  
Small Volume ◽  
Sucrose Solution ◽  
High Concentration ◽  
Rat Embryos ◽  
Low Concentrations ◽  
Intracellular Ice Formation ◽  
Intracellular Ice ◽  
Warming Rate ◽  
Very High

Abstract To cryopreserve cells, it is essential to avoid intracellular ice formation during cooling and warming. One way to achieve this is to convert the water inside the cells into a non-crystalline glass. It is currently believed that to accomplish this vitrification, the cells must be suspended in a very high concentration (20–40%) of a glass-inducing solute, and subsequently cooled very rapidly. Herein, we report that this belief is erroneous with respect to the vitrification of one-cell rat embryos. In the present study, one-cell rat embryos were vitrified with 5 μL of EFS10 (a mixture of 10% ethylene glycol, 27% Ficoll, and 0.45 M sucrose) in cryotubes at a moderate cooling rate, and warmed at various rates. Survival was assessed according to the ability of the cells to develop into blastocysts and to develop to term. When embryos were vitrified at a 2,613 °C/min cooling rate and thawed by adding 1 mL of sucrose solution (0.3 M, 50 °C) at a warming rate of 18,467 °C/min, 58.1 ± 3.5% of the EFS10-vitrified embryos developed into blastocysts, and 50.0 ± 4.7% developed to term. These rates were similar to those of non-treated intact embryos. Using a conventional cryotube, we achieved developmental capabilities in one-cell rat embryos by rapid warming that were comparable to those of intact embryos, even using low concentrations (10%) of cell-permeating cryoprotectant and at low cooling rates.

Experimental studies on resistance characteristics of high concentration red mud in pipeline transport

2008 ◽  
Vol 14 (1) ◽  
pp. 157-161
Author(s):  
Xing Wang ◽  
Yuan-yuan Qu ◽  
Wei-wei Hu ◽  
Jie Chen ◽  
Xue-yi Zhao ◽  
...  
Keyword(s):  
Red Mud ◽  
Experimental Studies ◽  
Pipeline Transport ◽  
High Concentration

Enhancing the Thermoelectric Properties in Carbon Fiber/Cement Composites by Using Steel Slag

2013 ◽  
Vol 539 ◽  
pp. 103-107 ◽  
Author(s):  
Jun Qing Zuo ◽  
Wu Yao ◽  
Jun Jie Qin
Keyword(s):  
Carbon Fiber ◽  
Linear Relationship ◽  
Thermoelectric Power ◽  
Thermoelectric Properties ◽  
Steel Slag ◽  
Experimental Results ◽  
Cement Composites ◽  
Temperature Differential ◽  
High Concentration ◽  
Good Linear

Thermoelectric properties of steel slag-carbon fiber/cement composites were studied in this paper. The effect of steel slag content on thermoelectric properties was focused on especially. The experimental results show that the addition of steel slag leads to an increase in the positive thermoelectric power of the cabon fiber/cement composites. The highest absolute thermoelectric power of carbon fiber/cement composites was rendered as positive as 14.4µV/°C by using steel slag, which had a high concentration of holes. Beside, a good linear relationship was observed between thermoelectric power and temperature differential on the specimen.

Structural Response and Remaining Life of Damaged Composites

2015 ◽  
Vol 813-814 ◽  
pp. 106-110
Author(s):  
Dalbir Singh ◽  
C. Ganesan ◽  
A. Rajaraman
Keyword(s):  
Hybrid Approach ◽  
Experimental Studies ◽  
Structural Response ◽  
Material Behavior ◽  
Experimental Results ◽  
Life Assessment ◽  
Nonlinear Material ◽  
Remaining Life ◽  
Design Effectiveness ◽  
Remaining Life Assessment

Composites are being used in variety of applications ranging from defense and aircraft structures, where usage is profuse, to vehicle structures and even for repair and rehabilitation. Most of these composites are made of different laminates glued together with matrix for binding and now-a-days fibers of different types are embedded in a composite matrix. The characterizations of material properties of composites are mostly experimental with analytical modeling used to simulate the system behavior. But many times, the composites develop damage or distress in the form of cracking while they are in service and this adds a different dimension as one has to evaluate the response with the damage so that its performance during its remaining life is satisfactory. This is the objective of the present study where a hybrid approach using experimental results on damaged specimens and then analytical finite element are used to evaluate response. This will considerably help in remaining life assessment-RLA- for composites with damage so that design effectiveness with damage could be assessed. This investigation has been carried out on a typical composite with carbon fiber reinforcements, manufactured by IPCL Baroda (India) with trade name INDCARF-30. Experimental studies were conducted on undamaged and damaged specimens to simulate normal continuous loading and discontinuous loading-and-unloading states in actual systems. Based on the experimental results, material characterization inputs are taken and analytical studies were carried out using ANSYS to assess the response under linear and nonlinear material behavior to find the stiffness decay. Using stiffness decay RLA was computed and curves are given to bring the influence of type of damage and load at which damage had occurred.

Sign in / Sign up

Export Citation Format

Share Document