Environmentally Friendly Pretreatment for Enhanced Coating of TiO2 Nanoparticles on PET/Wool Fabric

Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4091
Author(s):  
Zorana Kovačević ◽  
Ana Sutlović ◽  
Ana Matin ◽  
Sandra Bischof

In this study, the natural dye was extracted from Spartium junceum L. (SJL) flowers and applied on cellulose (cotton) and protein (wool) fabric. Fabrics were pre-mordant with alum prior to the dyeing process. Considering the global requirements on zero waste and green policy, the dyeing process was intended to be as much as possible environmentally friendly but still effective. Therefore, mordant concentration was optimized due to the reduction of the negative impact. The efficiency of the dyeing process was investigated by examination of fabrics’ color characteristics and colorfastness to washing properties. In this paper, we have proved that the extracted dye from Spartium junceum L. is an acidic dye (mordant dye) which is more applicable for the treatment of wool fabrics. In this paper, it was proved that phytochemicals responsible for coloring are part of the flavonoids group. The UV absorption spectra of extracted dye show 4 bands in the region of λmax 224, 268, 308 and 346 nm which are ascribed to bands characteristic for flavonoids. Wool fabric pre-mordant with 3% alum and dyed shows great chromatic (C*) properties where C* value is in a range from 47.76 for unwashed samples to 47.50 for samples after 5 washing cycles and color hue (h°) is in a range 82.13 for unwashed samples to 81.52 for samples after 5 washing cycles. The best result regarding the colorfastness properties is shown by the wool sample treated with 3% alum after 5 washing cycles (total difference in color (Delta E*) = 0.87). These results confirm that metal (Al) from alum mordant make strong chemical bonds with wool substrate and dye since Delta E* values decrease in comparison to Delta E* values of the cotton samples treated the same way. The results revealed it is possible to reduce the concentration of mordant up to 3% and obtain satisfactory results regarding the colorfastness. Nevertheless, future research will go in the direction of replacing synthetic mordant with a more environmentally friendly one.


2014 ◽  
Vol 68 ◽  
pp. 130-134 ◽  
Author(s):  
Muhammad Mohsin ◽  
Ummar Farooq ◽  
Zulfiqar Ali Raza ◽  
Muhammad Ahsan ◽  
Ali Afzal ◽  
...  

Scanning ◽  
2018 ◽  
Vol 2018 ◽  
pp. 1-7
Author(s):  
Peng Yu ◽  
Tao Hu ◽  
Hong Hui Chen ◽  
Fangfang Wu ◽  
Hui Liu

A composite of pyrolytic Triarrhena biochar loading with TiO2 nanoparticles has been synthesized by the sol-gel method. The composite shows a well-developed hollow mesoporous and macropore structure as characterized by XRD, BET, and SEM. When used as an absorbent to remove Congo red from aqueous solution, it was found that as-prepared composite performed better absorption capacity than single biochar or TiO2. The results suggest that biochar loading with TiO2 could be promisingly implemented as an environmentally friendly and inexpensive adsorbent for Congo red removal from wastewater.


2019 ◽  
Vol 160 ◽  
pp. 80-88 ◽  
Author(s):  
Yujia Liang ◽  
Esfandiar Pakdel ◽  
Mingwen Zhang ◽  
Lu Sun ◽  
Xungai Wang

2021 ◽  
Vol 12 (3) ◽  
pp. 3647-3663

A durable and environmentally friendly flame-retardant treatment process on wool via graft co-polymerization of vinyl phosphonic acid (VPA) was investigated. The influence of temperature, time, VPA, and catalyst on the grafting yield (GY) was studied. Employing response surface methodology, the grafting parameters were optimized, and the highest GY was achieved. Thermogravimetric studies showed a 3.86% increase in the remaining char ratio at 750°C for the wool fabric after graft co-polymerization of VPA. Flame retardancy of wool fabrics was evaluated with respect to their limiting oxygen indices (LOI) and the ease of ignition measurements. The sample with 8.1% GY exhibited a 35.89% increase in LOI and over a 3.66-fold increase in ignition time. The chemical structure of the grafted wool is proposed according to FTIR and 31P Solid-state MAS NMR evidence. The presented flame-retardant finish process was deemed to be a green and durable substitute for the conventional, semi-durable, and non-environmentally friendly processes.


WRPMD'99 ◽  
1999 ◽  
Author(s):  
Larry A. Roesner ◽  
Robert W. Brashear

INEOS OPEN ◽  
2020 ◽  
Author(s):  
N. A. Samoilova ◽  

The enzyme-containing magnetic composites are presented. The magnetic matrix for enzyme immobilization is obtained by sequential application of an amine-containing polysaccharide—chitosan and a synthetic polymer—poly(ethylene-alt-maleic acid) to the magnetite microparticles to form the interpolyelectrolyte complex shell. Then, the enzyme (trypsin) is immobilized by covalent or noncovalent binding. Thus, the suggested composites can be readily obtained in the environmentally friendly manner. The enzyme capacity of the resulting composites reaches 28.0–32.6 mg/g. The maximum hydrolysis rates of the H-Val-Leu-Lys-pNA substrate provided by these composites range within 0.60·10–7–0.77·10–7 M/min.


2020 ◽  
pp. 9-12
Author(s):  
Viktor E. Lyubimov ◽  

Health of dairy cows ensures human health, so it is important that dairy products do not contain antibiotics that are used to treat any inflammation, including mastitis. In Russia at present, the problem of mastitis in cows exists with both attached and loose housing of cows. Mastitis of dairy cows are the great problem in milking husbandry. Losses from mastitis in milk yield can reach 15-20%. The main reasons for the occurrence of nonspecific mastitis of cows are the shortcomings of the working components of the milking machine: the degree of deterioration of the nipple rubber and the violation of machine milking technology (the reduction in pre-milking time and vacuum fluctuations account for 70% of all causes). Treatment of mastitis with antibiotics is effective, but not environmentally friendly and unacceptable. For the treatment of inflammation of the udder, it is necessary to use more environmentally friendly methods of treatment, one of which is the exposure to ultra-high frequency electromagnetic field tested by medicine. Use of three types of medical-mobile milking machines with the same method of exposure to ultrahigh-frequency electromagnetic fields on cow's nipples through electrodes in milking cups: LPDA-1-UHF, LPDA-2-UHF and LPDA-UHF-30 M, is described in the article. Author proved that cows with subclinical forms of mastitis recovered faster during milking with exposure to the ultrahigh frequency than when treated by antibiotics, and milking with the ultrahigh frequency device helps to recover 82% of the affected quarters with clinical forms and 100% of cows with subclinical forms of mastitis or with udder irritation. The high efficiency of the method of exposure to electromagnetic fields of the ultrahigh frequency during machine milking by means of medical-mobile milking machines LPDA-UHF for the prevention and treatment of mastitis of cows was shown.


Sign in / Sign up

Export Citation Format

Share Document