scholarly journals On the basic chemical composition of selected biomass types from four regions of Mexico, for bioenergetic purposes

BioResources ◽  
2021 ◽  
Vol 16 (3) ◽  
pp. 5694-5705
Author(s):  
Julia Montzerrat Gutiérrez-Acosta ◽  
Rocio Orihuela-Equihua ◽  
Luis Fernando Pintor-Ibarra ◽  
Nicolás González-Ortega ◽  
Juan José Hernández-Solís ◽  
...  

The chemical composition of hardwoods sawdust and citrus residues from four states of the Mexican Republic (Quintana Roo, Durango, Veracruz, and Sonora) were determined. The results ranged as follows: total extractives from 8.2% (Quercus spp.) to 35.0% (lime leaves), holocellulose from 45.4% (lime leaves) to 70.6% (Lysiloma latisiliquum), lignin from 3.9% (lemon peels) at 25.4% (Caesalpinia platyloba), ash from 0.4% (orange branches) to 6.3% (lemon peels), pH from 5.1 (Swartzia cubensis) to 7.3 (orange branches), and calorific value of 19.8 MJ/kg (Lysiloma latisiliquum and Quercus spp.) to 21.7 MJ/kg (Olneya tesota). With the exception of the oak samples, in all the biomass samples the extractives content is relatively high (10.1% for Lysiloma latisiliquum to 35% for Persian lime leaves), and could represent a potential for future study and applications in the field of antioxidants. Due to the chemical properties and calorific value, the biomass samples studied present potential for local use as densified biofuels (pellets or briquettes).

BioResources ◽  
2020 ◽  
Vol 16 (1) ◽  
pp. 816-824
Author(s):  
Jonathan Sergio Chávez-Rosales ◽  
Luis Fernando Pintor-Ibarra ◽  
Nicolás González-Ortega ◽  
Rocio Orihuela-Equihua ◽  
Faustino Ruiz-Aquino ◽  
...  

The basic chemical composition and calorific value of 19 samples of pine sawdust from different forest industries located in five states of the Mexican Republic (Chihuahua, Michoacán, Durango, Oaxaca, and Nuevo León) were determined. The results obtained ranged as follows: total extractives (6.1% to 23.4%), holocellulose (60.1% to 70.4%), lignin (20.5% to 25.8%), ash (0.27% to 0.95%), pH (4.1 to 5.3), and calorific value (20.1 MJ/kg to 21.0 MJ/kg). Except for the ash content, significant statistical differences were found according to the origin of the pine sawdust samples. Based on the results obtained, the sawdust biomass has the potential to obtain densified solid biofuels.


Author(s):  
E. A. Elfont ◽  
R. B. Tobin ◽  
D. G. Colton ◽  
M. A. Mehlman

Summary5,-5'-diphenyl-2-thiohydantoin (DPTH) is an effective inhibitor of thyroxine (T4) stimulation of α-glycerophosphate dehydrogenase in rat liver mitochondria. Because this finding indicated a possible tool for future study of the mode of action of thyroxine, the ultrastructural and biochemical effects of DPTH and/or thyroxine on rat liver mere investigated.Rats were fed either standard or DPTH (0.06%) diet for 30 days before T4 (250 ug/kg/day) was injected. Injection of T4 occurred daily for 10 days prior to sacrifice. After removal of the liver and kidneys, part of the tissue was frozen at -50°C for later biocheailcal analyses, while the rest was prefixed in buffered 3.5X glutaraldehyde (390 mOs) and post-fixed in buffered 1Z OsO4 (376 mOs). Tissues were embedded in Araldlte 502 and the sections examined in a Zeiss EM 9S.Hepatocytes from hyperthyroid rats (Fig. 2) demonstrated enlarged and more numerous mitochondria than those of controls (Fig. 1). Glycogen was almost totally absent from the cytoplasm of the T4-treated rats.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Monika Wójcik ◽  
Renata Różyło ◽  
Regine Schönlechner ◽  
Mary Violet Berger

AbstractThe study aimed to determine the effect of pea protein powder on the pasting behavior and physico-chemical properties including the composition of amino and fatty acids of gluten-free bread with low-carbohydrate content. The control bread recipe was based on buckwheat flour (50 g) and flaxseed flour (50 g) as main flours. Additionally, the improving additives for this control bread such as psyllium husk (4 g), potato fiber (2 g), and guar gum (2 g) were used. The mixture of base flour was supplemented with the addition of pea protein powder (PPP) in the amount ranging from 5 to 25%. The results of Visco analyzes measured by RVA apparatus showed that the addition of 10% PPP to the control bread did not significantly differentiate peak viscosity and pasting temperature which was at the level 3115 cP and 3149 cP and 50 °C, respectively. Supplementation of low-carbohydrate bread with 10% of PPP was acceptable and significantly increased the content of all analyzed amino acids, as well as the amount of α-linolenic acid concerning the control bread. The lowest value of chemical score was observed for leucine. The EAAI (essential amino acid index) value increased from 34 to 40 when the optimal protein supplement was added. The developed gluten-free, low-carbohydrate, and high protein bread was characterized by contents of carbohydrate of 16.9%, protein of 17.1%, fiber of 13.7%, fat of 3.3% and its calorific value was 194 kcal/100 g.


Author(s):  
J. S. Chin ◽  
A. H. Lefebvre

The influence of fuel composition on soot emissions from continuous flow combustors is examined. A study of the combustion characteristics of a wide range of present and potential aviation fuels suggests that smoke point provides a better indication of sooting tendency than does hydrogen content. It is concluded from this study that the best empirical relationship between fuel chemical composition and soot emissions is one which combines two fuel composition parameters — smoke point and naphthalene content — into a single parameter which is shown to correlate successfully soot emissions data acquired from several different fuels burning in a variety of gas turbine and model combustors.


2014 ◽  
Vol 548-549 ◽  
pp. 133-136
Author(s):  
Yusoff Way ◽  
Hadi Puwanto ◽  
Farizahani ◽  
P.T. Pham

Selective Laser Sintering (SLS) or Laser Sintering (LS) allows functional parts to be produced in a wide range of powdered materials using a dedicated machine, and is thus gaining popularity within the field of Rapid Prototyping (RP). One of the advantages of employing LS is that the loose powder of the building chamber can be recycled. The properties of polymer powder significantly influence the melt viscosity and sintering mechanism during Laser Sintering (LS) processes which results in a good surface finish. The objective of this research is to investigate the chemical composition of fresh polymer materials used in Laser Sintering. There are seven virgin SLS materials which are PA2200, GF3200, Alumide, PrimeCast, PrimePart, Duraflex and CastForm. Fourier Transform Infrared Spectroscopy (FTIR) was used to analyze the chemical composition of the materials by using infrared radiation and absorbed frequency. The spectra show that similar functional groups were found in the materials apart from PrimePart and Duraflex. Obtained data from this analysis could be used to investigate on how the fresh and recycled powder materials with different chemical properties would affect the part surface finish.


2013 ◽  
Vol 48 (1) ◽  
pp. 42-50 ◽  
Author(s):  
Maraisa Crestani Hawerroth ◽  
Fernando Irajá Félix de Carvalho ◽  
Antonio Costa de Oliveira ◽  
José Antonio Gonzalez da Silva ◽  
Luiz Carlos Gutkoski ◽  
...  

The objective of this work was to characterize the chemical properties of white oat (Avena sativa) caryopsis and to determine the adaptability and stability of cultivars recommended for cultivation in the state of Rio Grande do Sul, Brazil. The trials were carried out in the 2007, 2008 and 2009 crop seasons, in three municipalities: Augusto Pestana, Capão do Leão, and Passo Fundo. Fifteen cultivars were evaluated in a randomized block design, with four replicates. The contents of protein, lipid, and nitrogen-free extract were evaluated in the caryopsis. Cultivar performances for the measured characters varied according to location and year of cultivation. The cultivar URS Guapa showed high content of nitrogen-free extract and low contents of protein and lipid in the caryopsis. 'FAPA Louise' showed high content of lipid, whereas 'Albasul', 'UPF 15', and 'UPF 18' showed high content of protein and low content of nitrogen-free extract. There is no evidence of an ideal biotype for the evaluated characters, which could simultaneously show high average performance, adaptability to favorable and unfavorable environments, and stability.


2020 ◽  
Vol 4 (1) ◽  
pp. 13-18
Author(s):  
E. J. Oziegbe ◽  
V. O. Olarewaju ◽  
O. O. Ocan

Samples of mafic intrusive rock were analyzed for their mineralogical and chemical properties. The textural relationship was studied using the petrographic microscope, elemental composition of minerals was determined using the Electron Microprobe and the whole rock chemical analysis was done using the XRF and ICP-MS. The following minerals were observed in order of abundance; pyroxene, amphibole, plagioclase, biotite, opaque minerals, quartz and chlorite, with apatite and zircon occurring as accessory mineral. Two types of pyroxenes were observed; orthopyroxene (hypersthene) and clinopyroxene. Texturally, amphiboles have inclusions of plagioclase and pyroxene. The plagioclase has undergone sericitization. The chemical composition of the pyroxene is En51.95Fs44.53Wo3.52, biotite has Fe/(Fe+Mg):0.42, Mg/(Fe+Mg):0.59, and plagioclase is Ab63.5An34.55Or1.95. Whole rock chemistry shows a chemical composition; SiO2: 45.15 %, Al2O3: 14.04 %, Fe2O3: 16.01 %, MgO: 5.65 %, CaO: 7.58 % and TiO2: 3.59 %. There is an enrichment of LREE and a depletion of HREE. Based on the minerals, mineral chemistry and the geochemistry of the studied rock, the rock is mafic and hydrous minerals formed by hydration recrystallization of pyroxene. The rock has extensively retrogressed but has not been affected by any form of deformation.


2007 ◽  
Vol 7 (3) ◽  
pp. 6077-6112
Author(s):  
T. Anttila ◽  
V.-M. Kerminen

Abstract. Aitken mode particles are potentially an important source of cloud droplets in continental background areas. In order to find out which physico-chemical properties of Aitken mode particles are most important regarding their cloud-nucleating ability, we applied a global sensitivity method to an adiabatic air parcel model simulating the number of cloud droplets formed on Aitken mode particles, CD2. The technique propagates uncertainties in the parameters describing the properties of Aitken mode to CD2. The results show that if the Aitken mode particles do not contain molecules that are able to reduce the particle surface tension more than 30% and/or decrease the mass accommodation coefficient of water, α, below 10−2, the chemical composition and modal properties may have roughly an equal importance at low updraft velocities characterized by maximum supersaturations <0.1%. For larger updraft velocities, however, the particle size distribution is clearly more important than the chemical composition. In general, CD2 exhibits largest sensitivity to the particle number concentration, followed by the particle size. Also the shape of the particle mode, characterized by the geometric standard deviation (GSD), can be as important as the mode mean size at low updraft velocities. Finally, the performed sensitivity analysis revealed also that the chemistry may dominate the total sensitivity of CD2 to the considered parameters if: 1) the value of α varies at least one order of magnitude more than what is expected for pure water surfaces (10−2–1), or 2) the particle surface tension varies more than roughly 30% under conditions close to reaching supersaturation.


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