scholarly journals Optical Parameters of As-Deposited and Annealed (Ga0.3In0.7)2Se3 Thin Films

2021 ◽  
Vol 66 (10) ◽  
pp. 885
Author(s):  
M. Pop ◽  
M. Kranjčec ◽  
I. Studenyak
Keyword(s):  
Refractive Index ◽  
Optical Absorption ◽  
Absorption Edge ◽  
Annealing Temperature ◽  
Wavelength Region ◽  
Inert Atmosphere ◽  
Optical Parameters ◽  
Short Wavelength Region ◽  
Spectral Ellipsometry ◽  
Evaporation Technique

The (Ga0.3In0.7)2Se3 films deposited by the thermal evaporation technique are annealed in the inert atmosphere (argon) for 1 h at temperatures of 50, 100, and 150 ∘C. The spectral ellipsometry is applied for measuring the spectral dependences of the refractive and extinction coefficients of as-deposited and annealed (Ga0.3In0.7)2Se3 films. The optical transmission spectra, as well as the optical absorption spectra of (Ga0.3In0.7)2Se3 films, are studied depending on the annealing temperature. The optical absorption edge for annealed (Ga0.3In0.7)2Se3 films is shifted to the short-wavelength region and broadens, as the annealing temperature increases. Parameters of the Urbach absorption edge are determined for as-deposited and annealed (Ga0.3In0.7)2Se3 films. The spectral dependences of the refractive index are analyzed in the framework of the Wemple–DiDomenico model. The nonlinear increase of the energy pseudogap, Urbach energy, and refractive index with the annealing temperature are revealed.

scholarly journals Ellipsometric and Spectrometric Studies of (Ga0.2In0.8)2Se3 Thin Film

2020 ◽  
Vol 65 (3) ◽  
pp. 231 ◽  
Author(s):  
I. P. Studenyak ◽  
M. Kranjčec ◽  
V. Yu. Izai ◽  
V. I. Studenyak ◽  
M. M. Pop ◽  
...  
Keyword(s):  
Thin Film ◽  
Refractive Index ◽  
Absorption Edge ◽  
Optical Transmission ◽  
Urbach Energy ◽  
Optical Parameters ◽  
Spectral Ellipsometry ◽  
Different Types ◽  
Temperature Dependences ◽  
Evaporation Technique

Thermal evaporation technique is used to deposite (Ga0,2In0,8)2Se3 thin films. The refractive index and extinction coefficient dispersions are obtained from the spectral ellipsometry measurements. The dispersion of the refractive index is described in the framework of the Wemple–Di Domenico model. The optical transmission spectra of a (Ga0,2In0,8)2Se3 thin film are studied in the temperature range 77–300 K. The temperature behavior of the Urbach absorption edge, as well as the temperature dependences of the energy pseudogap and Urbach energy, are investigated. The influence of different types of disordering on the optical absorption edge of a (Ga0,2In0,8)2Se3 thin film is discussed. Optical parameters of a (Ga0,2In0,8)2Se3 thin film and a single crystal are compared.

scholarly journals Synthesis of PVA/CeO2 Based Nanocomposites with Tuned Refractive Index and Reduced Absorption Edge: Structural and Optical Studies

Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1570
Author(s):  
Shujahadeen B. Aziz ◽  
Elham M. A. Dannoun ◽  
Dana A. Tahir ◽  
Sarkawt A. Hussen ◽  
Rebar T. Abdulwahid ◽  
...  
Keyword(s):  
Refractive Index ◽  
Optical Properties ◽  
Absorption Edge ◽  
Ceo2 Nanoparticles ◽  
Poly Vinyl Alcohol ◽  
Optical Parameters ◽  
Single Oscillator Model ◽  
Vis Spectroscopy ◽  
The Impact ◽  
Host Polymer

In the current study, polymer nanocomposites (NCPs) based on poly (vinyl alcohol) (PVA) with altered refractive index and absorption edge were synthesized by means of a solution cast technique. The characterization techniques of UV–Vis spectroscopy and XRD were used to inspect the structural and optical properties of the prepared films. The XRD patterns of the doped samples have shown clear amendments in the structural properties of the PVA host polymer. Various optical parameters were studied to get more insights about the influence of CeO2 on optical properties of PVA. On the insertion of CeO2 nanoparticles (NPs) into the PVA matrix, the absorption edge was found to move to reduced photon energy sides. It was concluded that the CeO2 nanoparticles can be used to tune the refractive index (n) of the host polymer, and it reached up to 1.93 for 7 wt.% of CeO2 content. A detailed study of the bandgap (BG) was conducted using two approaches. The outcomes have confirmed the impact of the nanofiller on the BG reduction of the host polymer. The results of the optical BG study highlighted that it is crucial to address the ɛ” parameter during the BG analysis, and it is considered as a useful tool to specify the type of electronic transitions. Finally, the dispersion region of n is conferred in terms of the Wemple–DiDomenico single oscillator model.

scholarly journals Polymer Composites with 0.98 Transparencies and Small Optical Energy Band Gap Using a Promising Green Methodology: Structural and Optical Properties

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1648
Author(s):  
Muaffaq M. Nofal ◽  
Shujahadeen B. Aziz ◽  
Jihad M. Hadi ◽  
Wrya O. Karim ◽  
Elham M. A. Dannoun ◽  
...  
Keyword(s):  
Refractive Index ◽  
Optical Properties ◽  
Polymer Composites ◽  
Amorphous Phase ◽  
Absorption Edge ◽  
Complex Form ◽  
Bandgap Energy ◽  
Optical Parameters ◽  
Visible Spectroscopy ◽  
Uv Visible

In this work, a green approach was implemented to prepare polymer composites using polyvinyl alcohol polymer and the extract of black tea leaves (polyphenols) in a complex form with Co2+ ions. A range of techniques was used to characterize the Co2+ complex and polymer composite, such as Ultraviolet–visible (UV-Visible) spectroscopy, Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD). The optical parameters of absorption edge, refractive index (n), dielectric properties including real and imaginary parts (εr, and εi) were also investigated. The FRIR and XRD spectra were used to examine the compatibility between the PVA polymer and Co2+-polyphenol complex. The extent of interaction was evidenced from the shifts and change in the intensity of the peaks. The relatively wide amorphous phase in PVA polymer increased upon insertion of the Co2+-polyphenol complex. The amorphous character of the Co2+ complex was emphasized with the appearance of a hump in the XRD pattern. From UV-Visible spectroscopy, the optical properties, such as absorption edge, refractive index (n), (εr), (εi), and bandgap energy (Eg) of parent PVA and composite films were specified. The Eg of PVA was lowered from 5.8 to 1.82 eV upon addition of 45 mL of Co2+-polyphenol complex. The N/m* was calculated from the optical dielectric function. Ultimately, various types of electronic transitions within the polymer composites were specified using Tauc’s method. The direct bandgap (DBG) treatment of polymer composites with a developed amorphous phase is fundamental for commercialization in optoelectronic devices.

CORONENE ORGANIC FILMS: OPTICAL AND SPECTRAL CHARACTERISTICS UNDER ANNEALING TEMPERATURE INFLUENCES

2021 ◽  
pp. 2150081
Author(s):  
ERMAN ERDOGAN
Keyword(s):  
Refractive Index ◽  
Annealing Temperature ◽  
Film Growth ◽  
Low Cost ◽  
Spectral Characteristics ◽  
Thin Film Deposition ◽  
Film Deposition ◽  
Optical Bandgap ◽  
Dielectric Constants ◽  
Optical Parameters

In this study, spin coating, which is a chemical film layer thin film deposition method, was used for coronene films that were grown on Si substrates annealed at 325, 350 and 375[Formula: see text]K to examine the impacts on the optical properties of films. This method allows for easy control of the deposition parameters such as concentration, temperature and time as well as enables the film growth at low cost. Optical (UV–Vis) spectral measurements in the wavelength range from 200[Formula: see text]nm to 800[Formula: see text]nm were used to extract the bandgap information and to calculate various optical parameters of the spin-coated coronene films. The electronic transitions on the absorption of photons of suitable energy are of indirect allowed type. The corresponding optical bandgap ([Formula: see text]) was determined. Complex dielectric constants, dissipation factor, optical and electrical conductances and refractive index of coronene films were analyzed as a function of temperature. As the film annealing temperature was increased, the dielectric constants and the refractive index values increased, whereas the optical bandgap and electrical and optical conductivity values decreased.

scholarly journals Steps Toward the Band Gap Identification in Polystyrene Based Solid Polymer Nanocomposites Integrated with Tin Titanate Nanoparticles

Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2320 ◽  
Author(s):  
Ahang M. Hussein ◽  
Elham M. A. Dannoun ◽  
Shujahadeen B. Aziz ◽  
Mohamad A. Brza ◽  
Rebar T. Abdulwahid ◽  
...  
Keyword(s):  
Refractive Index ◽  
Band Gap ◽  
Polymer Nanocomposites ◽  
Absorption Edge ◽  
Optical Band Gap ◽  
Solid Polymer ◽  
Optical Parameters ◽  
Optical Dielectric Constant ◽  
Solution Cast ◽  
Optical Dielectric

In the current study, the film fabrication of polystyrene (PS) based polymer nanocomposites (NCs) with tuned refractive index and absorption edge was carried out using the solution cast method. X-ray diffraction (XRD) and ultraviolet-visible (UV-Vis) light characterization techniques were performed. The structural and optical properties of the prepared films were specified. The hump of PS decreased significantly when SnTiO3 nanoparticles (NPs) were introduced. Sharp and high intense peaks of SnTiO3 NPs at a high filler ratio were observed. The crystalline size was determined for SnTiO3 NPs from the sharp crystalline peaks using Debye-Scherrer’s equation and was found to be 25.179 nm, which is close enough to that described by the supplier. Several optical parameters, such as absorption coefficient (α), refractive index (n), and optical dielectric properties, were investigated. The absorption spectra were tuned with increasing SnTiO3NPs. Upon the addition of the NPs to the PS host polymer, the absorption edge undergoes shifting to lesser photon energy sides. The optical dielectric constant (ε′) was correlated to the refractive index. The study of the optical band gap was conducted in detail using both Tauc’s model and the optical dielectric loss (ε″) parameter. The results showed that the ε″ parameter is noteworthy to be measured in the optical band gap study of materials.

Effect of Annealing Temperature on the Optical Parameters of CdS Thin Films Prepared by Thermal Evaporation Method

2013 ◽  
Vol 747 ◽  
pp. 329-332
Author(s):  
Thitinai Gaewdang ◽  
Ngamnit Wongcharoen ◽  
Tiparatana Wongcharoen
Keyword(s):  
Thin Films ◽  
Refractive Index ◽  
Annealing Temperature ◽  
Thermal Evaporation ◽  
Optical Parameters ◽  
Spectral Transmission ◽  
Dispersion Energy ◽  
Thermal Evaporation Method ◽  
Transmission Data ◽  
Cds Thin Films

CdS thin films were prepared by thermal evaporation onto glass substrate in vacuum better than 5.5x10-5 mbar. The obtained films were subsequently annealed in a pure nitrogen atmosphere at temperature between 100 to 500°C for 30 min. The crystal structure and surface morphology of the as-deposited and annealed films were investigated by XRD and SEM, respectively. Optical band gap and Urbach tail values of the films, determined from spectral transmission data, were found to be slightly varied in the range 2.36-2.40 eV and 110-160 meV, respectively, due to annealing temperature. The refractive index of the films was also evaluated from the spectral transmission data. The dependence of the refractive index on the wavelength obeys the single oscillator model, from which the important parameters such as refractive index, extinction coefficient, oscillator energy (E0) and dispersion energy (Ed) of the films with different annealing temperatures were determined. From the experimental results, the optical parameters of the films are obviously influenced by annealing temperature.

Refractive Index and Extinction Coefficient of ZnO:Al Thin Films Derived by Sol-Gel Dip Coating Technique

2013 ◽  
Vol 334-335 ◽  
pp. 290-293 ◽  
Author(s):  
N. Baydogan ◽  
T. Ozdurmusoglu ◽  
Huseyin Cimenoglu ◽  
A.B. Tugrul
Keyword(s):  
Thin Films ◽  
Refractive Index ◽  
Extinction Coefficient ◽  
Annealing Temperature ◽  
Sol Gel ◽  
Dip Coating ◽  
Optical Parameters ◽  
Coating Technique ◽  
Glass Substrates ◽  
Dip Coating Technique

Doped ZnO:Al thin films were deposited on glass substrates by the solgel dip technique. Optical parameters such as the refractive index and the extinction coefficient tend to change with increasing annealing temperature.

EFFECT OF ANNEALING TEMPERATURE ON STRUCTURAL AND OPTICAL PARAMETERS OF SOL–GEL ROUTED MOLYBDENUM OXIDE THIN FILM

2015 ◽  
Vol 22 (04) ◽  
pp. 1550054 ◽  
Author(s):  
P. ADAL ARASU ◽  
R. VICTOR WILLIAMS
Keyword(s):  
Refractive Index ◽  
Annealing Temperature ◽  
Sol Gel ◽  
Orthorhombic Phase ◽  
Oxide Thin Film ◽  
Optical Parameters ◽  
X Ray Diffraction ◽  
Absorption Region ◽  
Lower Annealing Temperature ◽  
Transparent Region

The influence of annealing temperature on structural and optical properties of sol–gel routed spin-coated molybdenum tri oxide ( MoO 3) thin films are studied. The higher annealing temperatures improve the crystalline nature of the film. The X-ray diffraction (XRD) study reveals the formation of α-orthorhombic phase at higher annealing temperature and amorphous nature at lower annealing temperature. The optical bandgap of molybdenum tri oxide ( MoO 3) film is found to be 3.3–3.8 eV, and the refractive index of the film is found to be 2.2–2.9. The dispersion curve of the refractive index shows that an abnormal dispersion in the absorption region and normal dispersion in the transparent region are observed. The optical polarizability, optical conductivity, dielectric constant, volume and surface energy loss parameters are evaluated.

scholarly journals Structural and optical characterization of annealed As30Te60Ga10 thin films prepared by thermal evaporation technique

2018 ◽  
Vol 36 (2) ◽  
pp. 193-202 ◽  
Author(s):  
A.M. Abd-Elnaiem ◽  
M. Mohamed ◽  
R.M. Hassan ◽  
M.A. Abdel-Rahim ◽  
A.A. Abu-Sehly ◽  
...  
Keyword(s):  
Annealing Temperature ◽  
Average Crystallite Size ◽  
Optical Parameters ◽  
X Ray Diffraction ◽  
Structural And Optical Properties ◽  
Scanning Calorimetry ◽  
Crystallization Peak ◽  
Evaporation Technique ◽  
Crystalline Nature

Abstract Effect of annealing temperature on the structural and optical properties of As30Te60Ga10 thin film was studied using various techniques such as differential scanning calorimetry (DSC), X-ray diffraction (XRD) and scanning electron microscopy (SEM). The DSC analysis revealed that the As30Te60Ga10 glass has a single glass transition and crystallization peak while XRD results confirmed that the as-prepared and annealed films have crystalline nature. The coexistence of the crystalline phases in the investigated films could be attributed to the formation of orthorhombic As, hexagonal Ga7Te10, and monoclinic As2Te3 phases. It was found that the average crystallite size and optical parameters of the studied films depend on the annealing temperature. For example, the optical band gap decreased from 1.54 eV to 1.11 eV as the annealing temperature increased from 300 K to 433 K.

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