Influence of growth parameters on the microstructure of directionally solidified Bi2Sr2CaCu2Oy

1990 ◽  
Vol 5 (9) ◽  
pp. 1834-1849 ◽  
Author(s):  
M. J. Cima ◽  
X. P. Jiang ◽  
H. M. Chow ◽  
J. S. Haggerty ◽  
M. C. Flemings ◽  
...  
Keyword(s):  
Growth Rate ◽  
Directional Solidification ◽  
Growth Rates ◽  
Growth Parameters ◽  
Directionally Solidified ◽  
Primary Solidification Phase ◽  
Float Zone ◽  
The Matrix ◽  
Laser Heated ◽  
Planar Growth

Laser-heated float zone growth was used to study the directional solidification behavior of Bi–Sr–Ca–Cu–O superconductors. The phases that solidify from the melt, their morphology, and their composition are altered by growth rate. Highly textured microstructures are achieved by directional solidification at all growth rates. The superconducting phase is found always to have the composition Bi2.5Sr2CaCu2.2Oy when grown from boules with composition 2:2:1:2 (BiO1.5:SrO:CaO:CuO). Planar growth fronts of Bi2.5Sr2CaCu2.2Oy are observed when the temperature gradient divided by the growth rate (G/R) is larger than 3 ⊠ 1011 K-s/m2 in 2.75 atm oxygen. Thus, the 2212 compound was observed to solidify directly from the melt at the slowest growth rates used in this study. Measurement of the steady-state liquid zone composition indicates that it becomes bismuth-rich as the growth rate decreases. Dendrites of the primary solidification phase, (Sr1−xCax)14Cu24Oy, form in a matrix of Bi2.5Sr2CaCu2.2Oy when G/R is somewhat less than 3 ⊠ 1011 K-s/m2. Observed microstructures are consistent with a peritectic relationship among Bi2.5Sr2CaCu2.2Oy, (Sr1−xCax)14Cu24Oy (x = 0.4), and a liquid rich in bismuth at elevated oxygen pressure. At lower values of G/R, Sr3Ca2Cu5Oy is the primary solidification phase and negligible Bi2.5Sr2CaCu2.2Oy forms in the matrix.

Phase Chemistry and Micro‐Structure of Directionally Solidified Bi2Sr2CaCu2O8

1989 ◽  
Vol 169 ◽  
Author(s):  
H.M. Chow ◽  
X.P. Jiang ◽  
M.J. Cima ◽  
J.S. Haggerty ◽  
H.D. Brody ◽  
...  
Keyword(s):  
Growth Rate ◽  
Growth Rates ◽  
Dendritic Growth ◽  
Slow Growth ◽  
Directionally Solidified ◽  
Float Zone ◽  
Pole Figures ◽  
Rich Liquid ◽  
Phase Chemistry ◽  
Laser Heated

AbstractCeramic rods of Bi2Sr2CaCu2O8 (2212) were directionally solidified by laser‐heated float‐zone crystal growth [1]. The microstructure of the resulting material can be controlled through variation of growth rate. The 2212 phase is Sr‐deficient, having an actual composition Bi2.5Sr2CaCu2.2Oy. At slow growth rates (0.2 cm/h), plane front growth produced highly textured samples of almost phase pure 2212, and pole figures show that the solidification front proceeds along the (200) axis of the 2212 grains. Faster growth rates produced dendritic growth and polyphase microstructures. At the fastest growth rate studied (16 cm/h), no 2212 phase was observed. Observations indicate that Bi2.5Sr2CaCu2.2Oy melts peritectically into (Sr1‐x.Cax.)14Cu24Oy and a Bi‐rich liquid.

scholarly journals Growth of Listeria monocytogenes in Thawed Frozen Foods

2017 ◽  
Vol 80 (3) ◽  
pp. 447-453 ◽  
Author(s):  
Ai Kataoka ◽  
Hua Wang ◽  
Philip H. Elliott ◽  
Richard C. Whiting ◽  
Melinda M. Hayman
Keyword(s):  
Growth Rate ◽  
Listeria Monocytogenes ◽  
Growth Rates ◽  
Storage Temperature ◽  
Growth Parameters ◽  
Quadratic Model ◽  
Lag Phase ◽  
Frozen Foods ◽  
Phase Duration ◽  
Primary Model

ABSTRACT The growth characteristics of Listeria monocytogenes inoculated onto frozen foods (corn, green peas, crabmeat, and shrimp) and thawed by being stored at 4, 8, 12, and 20°C were investigated. The growth parameters, lag-phase duration (LPD) and exponential growth rate (EGR), were determined by using a two-phase linear growth model as a primary model and a square root model for EGR and a quadratic model for LPD as secondary models, based on the growth data. The EGR model predictions were compared with growth rates obtained from the USDA Pathogen Modeling Program, calculated with similar pH, salt percentage, and NaNO2 parameters, at all storage temperatures. The results showed that L. monocytogenes grew well in all food types, with the growth rate increasing with storage temperature. Predicted EGRs for all food types demonstrated the significance of storage temperature and similar growth rates among four food types. The predicted EGRs showed slightly slower rate compared with the values from the U.S. Department of Agriculture Pathogen Modeling Program. LPD could not be accurately predicted, possibly because there were not enough sampling points. These data established by using real food samples demonstrated that L. monocytogenes can initiate growth without a prolonged lag phase even at refrigeration temperature (4°C), and the predictive models derived from this study can be useful for developing proper handling guidelines for thawed frozen foods during production and storage.

Morphological Characteristics of W-Nanowires after Selective Etching

2014 ◽  
Vol 1004-1005 ◽  
pp. 24-27
Author(s):  
Wen Jia Wang ◽  
Zhi Long Zhao ◽  
Ming Tang ◽  
Jian Jun Gao
Keyword(s):  
Growth Rate ◽  
Temperature Gradient ◽  
Directional Solidification ◽  
Morphological Characteristics ◽  
Selective Dissolution ◽  
Stability Diagram ◽  
Selective Etching ◽  
Directionally Solidified ◽  
Solidification Furnace ◽  
Nial Matrix

An eutectic NiAl–1.5 at.% W alloy prepared by using directionally solidified (DS)was employed as a source for producing W-nanowires. Several growth rate of 8,15,25/s was respectively used at a temperature gradient of ~240 K/cm in a Bridgman-type directional solidification furnace. A combined stability diagram was applied to predict proper conditions for the selective dissolution of NiAl matrix to get W-wires. Etching in a mixture of HCl:H2O2released parallel aligned W-nanowires with a wire diameter of ~500 nm. Different morphologies, such as nanobelts, lotus-shaped, conical of W-nanowires are obtained at the different conditions.

Effects of Growth Rates on Directionally Solidified Microstructure of Al-Ni-Y Ternary Alloy

2012 ◽  
Vol 562-564 ◽  
pp. 477-481
Author(s):  
Rui Xu
Keyword(s):  
Temperature Gradient ◽  
Directional Solidification ◽  
Ternary Alloy ◽  
Growth Rates ◽  
Optical Microscope ◽  
Experimental Results ◽  
Al Alloy ◽  
Directionally Solidified ◽  
X Ray Diffraction ◽  
X Ray

The directional solidification of the ternary Al alloy with composition of 2.6 at%Ni, 0.9 at%Y and 96.5 at% Al was carried out under the temperature gradient of 5 K/mm and the droping velocities of 0.5 mm/min, 1 mm/min, 5 mm/min, 10 mm/min, and 25 mm/min. The microstructure of the Al-Ni-Y ternary alloy was also analyzed by X-ray diffraction and optical microscope. The experimental results show that the microstructures of the Al-Ni-Y ternary alloy are consisted of ª-Al2, Al3Ni and Y4Ni6Al23phase when the alloy was directionally solidified in all directionally solidified rates in the experiments. No primary -Al can be found in the sample with directionally solidified rate of 0.5 mm/min. When the rates higher than 1 mm/min, the primary ª-Al can be observed. The microstructure of the directionally solidified alloy becomes finer and the primary ª-Al is smaller gradually with the increasing of growth velocities when the dropping rate of directional solidification is higher than 5 min/min. Two eutectic structures, Y4Ni6Al23andª-Al eutectic and Al3Ni and ª-Al eutectic, can be found when the dropping rate is higher than 10 mm/min.

Effects of low temperature on growth parameters in the entomopathogenic fungus Metarhizium anisopliae

1999 ◽  
Vol 45 (12) ◽  
pp. 1055-1061 ◽  
Author(s):  
J N Amritha De Croos ◽  
Michael J Bidochka
Keyword(s):  
Growth Rate ◽  
Growth Rates ◽  
Metarhizium Anisopliae ◽  
Entomopathogenic Fungus ◽  
Incubation Temperature ◽  
Growth Parameters ◽  
Conidia Production ◽  
Cold Active ◽  
Germination And Growth ◽  
Cold Activity

The effects of temperature (8°C, 15°C, and 22°C) on germination, growth rate and conidia production in thirty-two isolates of the entomopathogenic fungus Metarhizium anisopliae were assessed. Most isolates were obtained from various locations in Ontario, Canada. Ten out of thirty-two (31.3%) isolates were deemed cold-active because of their ability to grow at 8°C. Growth rates in all isolates increased as the incubation temperature was increased. There were significant differences in growth rates and conidia production among isolates. However, conidia production had no relationship with a growth rate. With respect to the geographical origin, there was no general relationship between latitude and growth rates. However, we found that all the cold-active isolates were isolated from the more northern sites and no isolate originating below 43.5° latitude showed cold activity. Cold-active germination and growth of this biocontrol fungus have implications for strain selection and application in Canadian insect control efforts.Key words: Metarhizium anisopliae, cold activity, entomopathogen.

Performance of a-Si-H Solar Cells at Higher Growth Rates

1999 ◽  
Vol 557 ◽  
Author(s):  
G. Ganguly ◽  
G. Lin ◽  
L.F. Chen ◽  
M. He ◽  
G. Wood ◽  
...  
Keyword(s):  
Growth Rate ◽  
Solar Cells ◽  
Growth Rates ◽  
Growth Parameters ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Growth Conditions ◽  
Plasma Decomposition ◽  
Hydrogen Mixtures ◽  
External Growth

AbstractWe have studied the effects of external growth parameters during the deposition of the i-layers of a-Si p-i-n solar cells using dc plasma decomposition of silane-hydrogen mixtures at growth rates of up to 3A/s. The loss of initial performance with increasing growth rate is mainly due to a loss of short-circuit current. The relative degradation of efficiency upon extended light soaking also increases with growth rate, and is mainly due to a decrease in the fill factor. Systematic comparisons of the performance and its degradation with changes in growth conditions reveal that these two components of the total degradation have distinct origins.

INFLUENCE OF GROWTH RATE ON MICROSTRUCTURE AND MICROINDENTATION HARDNESS OF DIRECTIONALLY SOLIDIFIED TIN–CADMIUM EUTECTIC ALLOY

2009 ◽  
Vol 16 (02) ◽  
pp. 191-201 ◽  
Author(s):  
E. ÇADIRLI ◽  
H. KAYA ◽  
M. GÜNDÜZ
Keyword(s):  
Growth Rate ◽  
Temperature Gradient ◽  
Directional Solidification ◽  
Constant Temperature ◽  
Eutectic Alloy ◽  
Directionally Solidified ◽  
Constant Temperature Gradient ◽  
Microindentation Hardness ◽  
Solidification Furnace ◽  
Eutectic Melt

Sn – Cd eutectic melt was first obtained in a hot filling furnace and then directionally solidified upward with different growth rate ranges (8.1–165 μm/s) at a constant temperature gradient G (4.35 K/mm) in the Bridgman-type directional solidification furnace. The lamellar spacings (λ) were measured from both transverse and longitudinal sections of the samples. The influence of the growth rate (V) on lamellar spacings (λ) and undercoolings (Δ T) was analyzed. λ2V, ΔTλ and ΔTV-0.5 values were determined by using λ,ΔT and V values. Microindentation hardness (HV) was measured from both transverse and longitudinal sections of the specimens. HV values increase with the increasing values of V but decrease with increasing λ values. λ-V, λ - ΔT and λ2V results have been compared with the Jackson–Hunt eutectic model and similar experimental results, HV - V and HV - λ results were also compared with the previous work.

Are Growth Parameters Estimated from Tagging and Age–Length Data Comparable?

1988 ◽  
Vol 45 (6) ◽  
pp. 936-942 ◽  
Author(s):  
R. I. C. C. Francis
Keyword(s):  
Growth Rate ◽  
Growth Rates ◽  
Growth Parameters ◽  
Growth Models ◽  
Maximum Length ◽  
Fish Growth ◽  
Data Sets ◽  
Von Bertalanffy ◽  
Length Data ◽  
The Mean

The two most common ways of estimating fish growth use age–length data and tagging data. It is shown that growth parameters estimated from these two types of data have different meanings and thus are not directly comparable. In particular, the von Bertalanffy parameter l∞ means asymptotic mean length at age for age–length data, and maximum length for tagging data, when estimated by conventional methods. New parameterizations are given for the von Bertalanffy equation which avoid this ambiguity and better represent the growth information in the two types of data. The comparison between growth estimates from these data sets is shown to be equivalent to comparing the mean growth rate of fish of a given age with that of fish of length equal to the mean length at that age. How much these growth rates may differ in real populations remains unresolved: estimates for two species of fish produced markedly different results, neither of which could be reproduced using growth models. Existing growth models are shown to be inadequate to answer this question.

Directional Solidification of Mo5Si3-MoSi2 Eutectic

1998 ◽  
Vol 552 ◽  
Author(s):  
S. M. Borowicz ◽  
L. Heatherly ◽  
R. H. Zee ◽  
E. P. George
Keyword(s):  
Phase Diagram ◽  
High Temperature ◽  
Directional Solidification ◽  
Growth Rates ◽  
Eutectic Composition ◽  
Directionally Solidify ◽  
Growth Conditions ◽  
Floating Zone ◽  
Directionally Solidified ◽  
Melting Points

ABSTRACTThe Mo-Si phase diagram exhibits a Mo5Si3-MoSi2 eutectic at the 54% Si composition. Since the terminal phases have comparable melting points and are equidistant from the eutectic composition, there is the possibility of obtaining lamellar microstructures in this system. In addition, if the alloys are directionally solidified, there is the further possibility of obtaining aligned lamellae. In this study, a high temperature (xenon-arc-lamp) optical floating zone furnace is utilized to directionally solidify Mo-Si alloys of the eutectic composition. Growth conditions are systematically varied to investigate their effects on the solidification microstructure. Growth rates and rotation speeds are identified that result in lamellar microstructures.

The Effect of Fluid Convection on Microstructures of Directionally Solidified Castings

2006 ◽  
Vol 508 ◽  
pp. 473-478 ◽  
Author(s):  
Tien Shou Lei ◽  
Wen Shiung Chang ◽  
Shyen Yang Dong
Keyword(s):  
Temperature Distribution ◽  
Directional Solidification ◽  
Ductile Iron ◽  
Lower Degree ◽  
Directionally Solidified ◽  
Matrix Microstructure ◽  
The Matrix ◽  
Fluid Convection ◽  
Cylindrical Casting ◽  
Set Up

Fluid convection during solidification of castings will influence the final structures of the castings. A vertical cylindrical casting set-up has been designed to provide two zones of solidification simultaneously with two moving fronts directionally upward and directionally downward, respectively. This two zone directional solidification casting was composed of a cylindrical Furan sand mold with a water chilled center hole block at the center of the casting. Experimentally it was observed that the cooling rates at different locations of the downward zone were much more even than those of the upward one and this is considered to be the result of a more even temperature distribution along the downward front moving zone due to stronger fluid convection. Fluid convection tends to mix up the liquid and results in a more even temperature distribution and a lower degree of segregation of the element molybdenum which has a strong tendency to segregate to the carbide in ductile iron. The characteristics of the matrix microstructure and the growing direction of carbide of this directionally solidified ductile iron has been investigated with SEM and EBSD techniques.

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