Characterization and Modeling of the Conduction and Switching Mechanisms of HfOx Based RRAM

2014 ◽  
Vol 1631 ◽  
Author(s):  
Shimeng Yu ◽  
H.-S. Philip Wong

ABSTRACTThe conduction and switching mechanism of resistive random access memory (RRAM) is reviewed in this paper. The resistive switching in oxides is generally attributed to the conductive filament (made up of oxygen vacancies) formation and rupture in the oxide due to field assisted oxygen ion migration. As a model system for device physics study, HfOx based RRAM devices were fabricated and characterized. To identify the electron conduction mechanism, various electrical characterization techniques such as I-V measurements at various temperatures, low-frequency noise measurements, and AC conductance measurements were employed. It was suggested that the trap-assisted-tunneling is the dominant conduction mechanism. In order to explore the oxygen ion migration dynamics, pulse switching measurements were performed. An exponential voltage-time relationship was found between the switching time and the applied voltage. To obtain a first-order understanding of the variability of resistive switching, a Kinetic Monte Carlo (KMC) numerical simulator was developed. The generation/recombination/migration probabilities of oxygen vacancies and oxygen ions were calculated, and the conductive filament configuration was updated stochastically according to those probabilities. The KMC simulation can reproduce many experimental observations in the DC I-V sweep, pulse switching, endurance cycling, and retention baking, etc. The tail bits in the resistance distribution are attributed to the oxygen vacancy left over in the gap region due to a competition between the oxygen vacancy generation and recombination. To enable circuit and system development using RRAM, a compact device model was developed. The compact model, implemented in MATLAB, HSPICE, and Verilog-A, which can be employed in many commonly available circuit simulators using the SPICE engine.

2020 ◽  
Vol 20 (10) ◽  
pp. 6489-6494
Author(s):  
Batkhuyag Khorolsuren ◽  
Shenmin Lu ◽  
Chao Sun ◽  
Fang Jin ◽  
Wenqin Mo ◽  
...  

To study the substitutability of noble metal electrodes in memristors, the effect of Pt/HfO2/Ti structure on the replacement of noble metal electrode Pt by different electrodes was studied. Compared with the unsubstituted devices, the HfO2-based RRAM devices with TiN and TiOxNy electrodes devices showed good resistive switching performance and resistive switching mechanism under oxygen ion migration. Five devices were prepared, and their resistive switching mechanism under oxygen ion migration was investigated. Moreover, besides the resistive switching phenomenon of these RRAM devices, it was found that significant rectifying characteristics were exhibited in a highresistance state (HRS). This phenomenon can be explained by regulation of the Schottky barrier of the interface between the top electrode and the resistive layer, which can be influenced by the migration of oxygen vacancies.


2013 ◽  
Vol 8 (1) ◽  
pp. 220 ◽  
Author(s):  
Amit Prakash ◽  
Siddheswar Maikap ◽  
Sheikh Rahaman ◽  
Sandip Majumdar ◽  
Santanu Manna ◽  
...  

2021 ◽  
Author(s):  
Jun-Ichiro Makiura ◽  
Takuma Higo ◽  
Yutaro Kurosawa ◽  
Kota Murakami ◽  
Shuhei Ogo ◽  
...  

Efficient activation of CO2 at low temperature was achieved by reverse water–gas shift via chemical looping (RWGS-CL) by virtue of fast oxygen ion migration in a Cu–In structured oxide, even at lower temperatures.


Author(s):  
Alexander M. Antipin ◽  
Olga A. Alekseeva ◽  
Natalia I. Sorokina ◽  
Alexandra N. Kuskova ◽  
Michail Yu. Presniakov ◽  
...  

The La2Mo2O9(LM) and Pr2Mo2O9(PM) single crystals are studied using precision X-ray diffraction and high-resolution transmission microscopy at room temperature. The crystal structures are determined in the space groupP213. La and Pr atoms, as well as Mo1 and O1 atoms, are located in the vicinity of the threefold axes rather than on the axes as in the high-temperature cubic phase. In both structures studied, the O2 and O3 positions are partially occupied. The coexistence of different configurations of the Mo coordination environment facilitates the oxygen-ion migration in the structure. Based on the X-ray data, the activation energies of O atoms are calculated and the migration paths of oxygen ions in the structures are analysed. The conductivity of PM crystals is close to that of LM crystals. The O2 and O3 atoms are the main contributors to the ion conductivity of LM and PM.


1989 ◽  
Vol 44 (12) ◽  
pp. 1167-1171 ◽  
Author(s):  
G. Chiodelli ◽  
G. Campari-Viganò ◽  
G. Flor

Abstract Electrical resistivity measurements were carried out on polycrystalline YBa2Cu3O7-x at temperatures 300 < T < 1023 K and oxygen partial pressures 5 ·10-7 ≤ po2 ≤ 1 atm. The samples, equilibrated in the range from 5 ·10-4 to 1 atm, show metallic behaviour, the one equilibrated at po2 = 2 ·10-5 shows a transition between metallic and semiconducting behaviour at 920 K, and that equilibrated at po2 = 5 ·10-7 shows semiconducting behaviour: for the latter the relevant resistivity is due to the oxygen-ion migration. The isotherms log σ vs. log po2 (in the temperature range from 723 to 1023 K) show slopes of about 1/6 at 723 K (orthorhombic phase) and about 1/2 at 1023 K (tetragonal phase). These results are discussed in terms of appropriate defect models.


Nanoscale ◽  
2020 ◽  
Vol 12 (35) ◽  
pp. 18322-18332
Author(s):  
Thomas Herzog ◽  
Naomi Weitzel ◽  
Sebastian Polarz

In arrays of multi-domain nanowires static antimony doping in combination with mobile doping stemming from oxygen vacancies is utilized to achieve bipolar memristive properties resulting from oxygen vacancy injection in an undoped tin oxide domain.


2011 ◽  
Vol 50 (1R) ◽  
pp. 011501 ◽  
Author(s):  
Myoung-Sun Lee ◽  
Jung-Kyu Lee ◽  
Hyun-Sang Hwang ◽  
Hyung-Cheol Shin ◽  
Byung-Gook Park ◽  
...  

1997 ◽  
Vol 12 (9) ◽  
pp. 2374-2380 ◽  
Author(s):  
Shusheng Jiang ◽  
Walter A. Schulze ◽  
Vasantha R. W. Amarakoon ◽  
Gregory C. Stangle

Nanoparticles of yttria-doped tetragonal zirconia polycrystalline ceramics (Y-TZP) with an average crystallite size of less than 9 nm were prepared by a combustion synthesis process. Dense and fine-grained (<200 nm) Y-TZP ceramics were obtained by fast-firing using temperatures lower than 1400 °C and dwell times of less than 2 min. Impedance spectroscopy was employed to measure conductivities of oxygen vacancies in the grain and the grain boundary of the fine-grained Y-TZP. The relationships between the concentration of the oxygen vacancies in the grain boundary and measurable physical parameters were determined semiquantitatively. The oxygen vacancy concentrations and activation energies for the oxygen-ion conduction in the grain and the grain boundary of the fine-grained Y-TZP were found to be independent of the average grain size in the average grain-size range of 90–200 nm. These experimental results suggest that, in order to retain the abnormally high oxygen vacancy concentrations of the Y-TZP nanoparticles and thus enhance the oxygen-ion conductivity, it may be necessary to decrease the average grain size to approximately 10 nm.


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