Enhanced Tunneling through sub 30 Angstroms Thick Gallium Nitride Cap Layers on Silicon Carbide for Low Contact Resistance

2007 ◽  
Vol 1017 ◽  
Author(s):  
Choudhury Jayant Praharaj

AbstractWe present numerical calculations of tunneling through ultra thin wurtzite Gallium Nitride cap layers on p-doped wurtzite silicon carbide . We demonstrate the predominance of tunneling of the split-off holes to the total carrier flux, with the contribution of the heavy and the light holes damped by the large potential barrier. We calculate the contributions of spontaneous and piezoelectric polarizations to the tunneling profile seen by the holes. Two orders of magnitude enhancement is seen in the transmission probabilities for a 10 angstroms thick Gallium Nitride cap layer for holes very close to the valence band edge, compared to a barrier without any gallium nitride cap. The contact resistances are also calculated for the Gallium Nitride tunneling caps and more than two orders of magnitude lowering is seen with the ultra-thin caps. Larger cap widths induce hole accumulation layers, but the advantages of hole accumulation are offset by the higher effective tunneling width. Our calculations are relevant to nanostructures and nanodevices involving heterojunctions between gallium nitride and silicon carbide and provide the basis for low contact resistances with as-deposited metals. While our calculations focus on the regime of very high barriers to the metal of the order of 1.5 - 2 electron volts, where the method of ultra-thin caps is most useful, similar conclusions also hold for lower barrier heights.

2002 ◽  
Vol 92 (7) ◽  
pp. 3803-3814 ◽  
Author(s):  
J. D. Albrecht ◽  
P. P. Ruden ◽  
T. L. Reinecke

2016 ◽  
Vol 4 (34) ◽  
pp. 8014-8019 ◽  
Author(s):  
Jiaolin Cui ◽  
Zheng Sun ◽  
Zhengliang Du ◽  
Yimin Chao

Mn substitution for Cu in Cu3Ga5Te9 engineers the energy gap (ΔEA) between impurity and valence bands, which is responsible for the reduction of the potential barrier for thermal excitation of carriers.


AIP Advances ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 075013
Author(s):  
F. Meier ◽  
M. Protte ◽  
E. Baron ◽  
M. Feneberg ◽  
R. Goldhahn ◽  
...  

2021 ◽  
Vol 2 (3) ◽  
pp. 274-283
Author(s):  
Masaya Ichimura

The band alignment of Mg(OH)2-based heterostructures is investigated based on first-principles calculation. (111)-MgO/(0001)-Mg(OH)2 and (0001)-wurtzite ZnO/(0001)-Mg(OH)2 heterostructures are considered. The O 2s level energy is obtained for each O atom in the heterostructure supercell, and the band edge energies are evaluated following the procedure of the core-level spectroscopy. The calculation is based on the generalized gradient approximation with the on-site Coulomb interaction parameter U considered for Zn. For MgO/Mg(OH)2, the band alignment is of type II, and the valence band edge of MgO is higher by 1.6 eV than that of Mg(OH)2. For ZnO/Mg(OH)2, the band alignment is of type I, and the valence band edge of ZnO is higher by 0.5 eV than that of Mg(OH)2. Assuming the transitivity rule, it is expected that Mg(OH)2 can be used for certain types of heterostructure solar cells and dye-sensitized solar cells to improve the performance.


1971 ◽  
Vol 9 ◽  
pp. 158-164 ◽  
Author(s):  
D.K. Wickenden ◽  
K.R. Faulkner ◽  
R.W. Brander ◽  
B.J. Isherwood

2021 ◽  
Author(s):  
Giorgia Olivieri ◽  
Gregor Kladnik ◽  
Dean Cvetko ◽  
Matthew A. Brown

The electronic structure of hydrated nanoparticles can be unveiled by coupling a liquid microjet with a resonant photoemission spectroscopy.


MRS Advances ◽  
2019 ◽  
Vol 4 (40) ◽  
pp. 2217-2222
Author(s):  
Renu Choudhary ◽  
Rana Biswas ◽  
Bicai Pan ◽  
Durga Paudyal

AbstractMany novel materials are being actively considered for quantum information science and for realizing high-performance qubit operation at room temperature. It is known that deep defects in wide-band gap semiconductors can have spin states and long coherence times suitable for qubit operation. We theoretically investigate from ab-initio density functional theory (DFT) that the defect states in the hexagonal silicon carbide (4H-SiC) are potential qubit materials. The DFT supercell calculations were performed with the local-orbital and pseudopotential methods including hybrid exchange-correlation functionals. Di-vacancies in SiC supercells yielded defect levels in the gap consisting of closely spaced doublet just above the valence band edge, and higher levels in the band gap. The divacancy with a spin state of 1 is charge neutral. The divacancy is characterized by C-dangling bonds and a Si-dangling bonds. Jahn-teller distortions and formation energies as a function of the Fermi level and single photon interactions with these defect levels will be discussed. In contrast, the anti-site defects where C, Si are interchanged have high formation energies of 5.4 eV and have just a single shallow defect level close to the valence band edge, with no spin. We will compare results including the defect levels from both the electronic structure approaches.


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