Effective Diffusivity of Carbon Dioxide and Iodine through “G” Tunnel Tuff

1989 ◽  
Vol 176 ◽  
Author(s):  
Tevfik Bardakci ◽  
Franklin G. King ◽  
Maung K. Sein

ABSTRACTThe effective diffusivity of carbon dioxide and iodine through “G” tunnel tuff were determined using a steady-state method and an unsteady-state method respectively. Results show that the effective diffusivity of carbon dioxide and iodine through dry tuff increased with temperature. The effective diffusivity of carbon dioxide decreased as the moisture content of the “G” tunnel tuff increased. An emprical correlation was obtained to estimate the effective diffusivity of carbon dioxide as a function temperature and the percent saturation. Specific surface area and pore volume of tuff was determined using a mercury porosimeter. A scanning electron microscope was utilized to further characterize the porous structure of the tuff samples.

1991 ◽  
Vol 257 ◽  
Author(s):  
Ajeet Singh ◽  
Gary Tatterson ◽  
Franklin G. King ◽  
Tevfik Bardakci

ABSTRACTThe effective diffusivities of carbon dioxide through Tiva Canyon tuff and the lower lithophysal zone of the Topopah Spring tuff (outcrop sample of the layer above the proposed nuclear repository site layer) were determined using a steady-state method (counter diffusion). The diffusivity of carbon dioxide through the Tiva Canyon and lithophysal zone tuffs increased with temperature and decreased with percent saturation. The following correlation was obtained to estimate the effective diffusivity of carbon dioxide through the Tiva Canyon tuff as a function temperature and percent saturation.De = 1.2168×10−2 − 3.7713×10−5 T + 9.9510×10−8 T2 − 4.2220×10−5 × (Percent Saturation)where De is in cm2/sec and T in K. These units hold for all other correlations in this paper.The effective diffusivity of carbon dioxide through the lower lithophysal zone of the Topopah Spring tuff (layer right above the proposed repository site) also increased with temperature and decreased with percent saturation. For this layer, the following correlation was obtained to estimate the effective diffusivity of carbon dioxide as a function temperature and percent saturation.De = − 1.119×10−3 + 1.2512×10−5 T + 1.8288×10−9 T2 × 2.0725×10−5 × (Percent Saturation)


2021 ◽  
Author(s):  
Abdulla Aljaberi ◽  
Seyed Amir Farzaneh ◽  
Shokoufeh Aghabozorgi ◽  
Mohammad Saeid Ataei ◽  
Mehran Sohrabi

Abstract Oil recovery by low salinity waterflood is significantly affected by fluid-fluid interaction through the micro-dispersion effect. This interaction influences rock wettability and relative permeability functions. Therefore, to gain a better insight into multiphase flow in porous media and perform numerical simulations, reliable relative permeability data is crucial. Unsteady-state or steady-state displacement methods are commonly used in the laboratory to measure water-oil relative permeability curves of a core sample. Experimentally, the unsteady-state core flood technique is more straightforward and less time-consuming compared to the steady-state method. However, the obtained data is limited to a small saturation range, and the associated uncertainty is not negligible. On the other hand, the steady-state method provides a more accurate dataset of two-phase relative permeability needed in the reservoir simulator for a reliable prediction of the high salinity and low salinity waterflood displacement performance. Considering the limitations of the unsteady state method, steady-state high salinity and low salinity brine experiments waterflood experiments were performed to compare the obtained relative permeability curves. The experiments were performed on a carbonate reservoir sample using a live reservoir crude oil under reservoir conditions. The test was designed so that the production and pressure drop curve covers a wider saturation range and provides enough data for analysis. Consequently, reliable relative permeability functions were obtained, initially, for a better comparison and prediction of the high salinity and the low salinity waterflood injections and then, to quantify the effect of low salinity waterflood under steady-state conditions. The results confirm the difference in relative permeability curves between high salinity and low salinity injections due to the micro-dispersion effect, which caused a decrease in water relative permeability and an increase in the oil relative permeability. These results also proved that low salinity brine can change the rock wettability from oil-wet or mixed-wet to more water-wet conditions. Furthermore, the obtained relative permeability curves extend across a substantial saturation range, making it valuable information required for numerical simulations. To the best of our knowledge, the reported data in this work is a pioneer in quantifying the impact of low salinity waterflood at steady-state conditions using a reservoir crude oil and reservoir rock, which is of utmost importance for the oil and gas industry.


2020 ◽  
pp. 82-89
Author(s):  
Paweł Iwański ◽  
Bartłomiej Igliński ◽  
Grzegorz Piechota

The article presents carbonization as a method of waste management from the brine sodium-lime method. It was compared with the previously obtained results for the lye-sodium one. Within it, the fltration and washing times were contrasted for treated and non-carbonised samples. For this aim potentiometric titration analysis was used to determine the precipitation's basic components and by-product brine. Scanning electron microscope with energy dispersive X-ray spectrum and diffractographic analysis were used for morphology analysis what allowed to determine the tested samples' composition. It was found that despite significant differences in the time of washing and filtration, the time of these processes is shortened after the suspension has been exposed to carbon dioxide. In both cases the composition allows the waste brine to be recycled to the purifcation processes and the mixture of calcium and magnesium compounds become alternative raw material. It turned out that in both methods it is possible to utilize the suspension formed.


2013 ◽  
Vol 61 (2) ◽  
pp. 499-505
Author(s):  
D. Miedzińska ◽  
T. Niezgoda ◽  
E. Małek ◽  
D. Zasada

Abstract. The problem of methane existence in coal beds has been known for many years. It was and still it is a danger to coalminers. The aim of the research, presented in the paper, is to show and assess the porosity structure (especially micro and nanoporosity) in accordance to the dimensions of carbon dioxide particle. The characteristic surface morphology of the sample and the disclosure of the carbon porous structure have been obtained using the scanning electron microscope (SEM). The presented study of the coal microstructure is a part of the coal demethanation method with the use of liquid CO2, that has been proposed by the Military University of Technology.


1991 ◽  
Vol 225 ◽  
Author(s):  
C-K. Hu ◽  
P. S. Ho ◽  
M. B. Small ◽  
K. Kelleher

ABSTRACTThe electromigration drift velocity of Al in Al(3wt.% Si), Al(2wt.%Cu), and Al(2wt.%Cu,3wt.%Si) was measured in a temperature range 133 to 220 °C with current densities of 1.0 to 1.5×106A/cm2. In Al(3wt.% Si), a significant Al depletion at the cathode end and accumulation at the anode end of stripe were observed within a few hours at 1.5×106A/cm2 and 200°C. In addition, local hillocks and voids along the metal lines were observed. For Al(Cu,Si), the Al drift velocity was slowed down by Cu addition. The majority of hillocks started to grow at a distance about 6 μm away from the cathode end with current density of 1.5×106 A/cm2. The drift velocity of Al in Al(Cu,Si) was found to be a function of time starting with an initial low value and increasing to a an final steady-state value. The behavior was attributed to the migration of Cu and dissolution of Al2Cu precipitates. The activation energies of the depletion 3 Aμm of Al(2%,Cu, 3%Si) was determined to be 0.90±02 eV. The dissolution and growth of A12Cu in the tested samples of Ti/Al(2%Cu)/Ti/TiN were observed using the scanning electron microscope and an electron microprobe.


2006 ◽  
Vol 3 (2) ◽  
pp. 254-260
Author(s):  
Baghdad Science Journal

In this research study failed Annunciation No. 10 for the fourth phase of the pressure of carbon dioxide of the company for Southern Fertilizers and repeated the failures more than once for the same gospel was a detailed study of the gospel included a series tests for properties Mechanical and Structural addition to the tests microscopic and scanning electron microscope shows m This study parameters and a failure Elal well as the existence of an old internal cracks in the metal of the Annunciation


2012 ◽  
Vol 531 ◽  
pp. 227-230
Author(s):  
Yuan Li Huang ◽  
Lai Jiu Zheng ◽  
Bing Du ◽  
Yu Ping Zhao ◽  
Ruo Yuan Song

This paper adopts reactive disperse bright-red KR-2B to dye wool skeins in supercritical CO2 dyeing equipment. The influencing factors are analyzed by measuring the surface depth of dyed wool skeins, including time, temperature and pressure, and the optimal dyeing parameters are as following: time 60min, temperature 120°C, pressure 24 MPa. Then we adopt the scanning electron microscope (SEM) and the infrared spectrum (FTIR) to observe the apparent shape and structure before dyeing and after dyeing. The results indicate that the global dye structure divide and the dyestuffs have good fixation on the wool skeins.


Sign in / Sign up

Export Citation Format

Share Document