Spectral Properties of Dissipation

The novel concept of spectral diffusivity is introduced to analyze the dissipative properties of continua. The dissipative components of a linear system of evolution equations are separated into noninteracting parts. This separation is similar to mode analysis in wave propagation. The new modal quantities characterize dissipation and are best interpreted as effective diffusivities, or, in case of the heat conduction, as effective heat conductivities of the material.

Drying Kinetics and Modelling of Convective Drying of Kedondong Fruit

Kedondong is an underutilized fruit cultivated in a small scale in Malaysia and it contains nutrients that can be preserved through drying. The dried product can be sold as a premium fruit snack that could generate revenue for the producer. We studied the drying of peeled and unpeeled kedondong fruits using hot air (60-80°C). This study aims to investigate the drying kinetics (drying rates and effective diffusivities) of kedondong fruits and model the drying curves using thin layer models. Ten thin layer models were employed and solved using non-linear regression. Drying kinetics showed that only falling rate periods were observed, which implied that internal diffusion was the dominant mechanism for moisture release. Mathematical models showed that Modified Hii et al. (I) and (II) models were able to predict the drying curve well with the highest R2 (0.9992-0.9999), the lowest RMSE (8.0 x 10-4 - 2.5 x 10-3) and the lowest χ2 (4.0 ×10-5 - 2.0 x 10-4). Peeled samples showed higher effective diffusivities (average 3.2 x 10-11 m2/s) than unpeeled samples (average 2.7 x 10-11 m2/s). The activation energy was lower in peeled samples (25.8 kJ/mol) as moisture diffusion could occur more easily than unpeeled samples (32.1 kJ/mol). Results from this study provide kinetic information that can be used in scaling up of dryer and optimizing dryer performances.

Convective Baking Characteristics and Effective Moisture Diffusivities of Yellow Mealworms

Yellow mealworm is an alternative protein source studied by researchers to provide an alternative supply of protein to meet the growing demands of human consumption. In this research, convective baking of yellow mealworms at 80°C, 100°C, and 120°C was carried out to study the baking kinetics and product quality. Studies showed the typical falling trend of the moisture ratio curves, which are typical for most bioproducts that undergo hot air treatment. Mathematical modelling showed that the Page model gave a good prediction on the baking kinetics with high fitting accuracy (R2>0.99). Effective diffusivities were determined from 1.66 x 10-11 to 2.88 x 10-11 m2/s within the temperatures tested. The activation energy was estimated at 15.7 kJ/mol based on the Arrhenius equation. The final baked samples appeared darker in color because the browning reaction and reduction in bulk density and product length were observed in the range of 48-54% and 3.0-16.3%, respectively.

FISH PRE-TREATED WITH SALT BRINE: PROCESS STUDY AND DRYING KINETICS

This work is part of a study for the conservation of fish products through solar drying. The grey seabream is dried after a pre-treatment of 16 hours in a salt brine under two conditions: on a rack in open air and in a solar dryer. The tests were carried out under average irradiance conditions of 592.76 W/m², an average ambient temperature of 30°C and an average air temperature in the dryer of 50°C. The results obtained, allowed us to reach a final humidity of 32% from an initial humidity of 65% in a wet basis. The drying was processed in 15 hours, (i.e. two days in the dryer) and 24 hours (i.e. three days in the open air). The modeling of the drying kinetics of the grey sea bream is carried out from empirical or semi-empirical models taken from the previous works. Several criteria were defined for the choice of the two-term model as being the one that can describe in the best way, the drying of the fish in both conditions. The effective diffusivity was determined using Ficks diffusive model whose solution is given by Crank, so that the logarithm of the reduced moisture allows us to find effective diffusivities for fish of 9.88823 10-7 (m²/s) and 1.72534 10-6 (m²/s) for open-air and in dryer drying respectively.

Modeling in food across the scales: towards a universal mass transfer simulator of small molecules in food

Multiscale modeling in food is the cutting-edge strategy to revisit food structure and food composition to meet specific targets such as bioavailability, oral perception, or to evaluate the contamination of food by chemicals. A special implementation of Langevin dynamics is proposed to describe mass transfer in structured food. The concepts of random walks over discrete times and physicochemical interactions are connected via an exact solution of the Fokker–Planck equation across interfaces. The methodology is illustrated on the calculation of effective diffusivities of small solutes in emulsions in relationship with their polydispersity, the volume fraction of dispersed phase d = [0.1, 0.4], the ratio of diffusion coefficients between the two phases, rD = [10−2, 102], and the partition coefficients between the continuous and disperse phases, K = [10−2, + ∞[. Simulated diffusion paths are detailed in 2D emulsions and the effective diffusivities compared with the core–shell model of Kalnin and Kotomin (J Phys A Math Gen 31(35):7227–7234, 1998). The same effects are finally tabulated for 3D emulsions covering the full range of food applications. The methodology is comprehensive enough to enable various extensions such as chemisorption, adsorption in the surfactant layer, local flows, flocculation/creaming.

Dual impact of different drying treatments and ethanol/water ratios on antioxidant properties and colour attribute of jackfruit leaves (Artocarpus heterophyllus Lam.) Mastura variety (J35)

Artocarpus heterophyllus (jackfruit) leaves (JL) are a waste product that is commonly used as livestock feed. Jackfruit leaves have been revealed to possess many medicinal values such as antioxidant and anti-inflammatory properties. In this study, different drying treatments (shade (SD), sun (SN), and oven (OV)) and ethanol/water ratios (E/W) were investigated to evaluate the impact on drying kinetics, color, and antioxidant properties of jackfruit leaves. Results showed that the Newton model was the best fitted mathematical model for the JL drying kinetics. The moisture effective diffusivities ranged from 2.920 × 10-10 to 6.814 × 10-10 m2/s over the temperature range studied. Shade drying was able to preserve the green pigment better than OV and SN drying treatments. Treatment with ethanol/water ratio at 80% and oven-dried (OV80) revealed the highest phenolic content (195.05 ± 1.21 mg gallic acid equivalent (GAE)/g extract weight (EW)), flavonoid content (11.02 ± 0.17 mg artocarpin equivalent (AE)/g EW), and antioxidant activities (90% scavenging activity and reducing power of 1043.84 ± 5.28 µM trolox equivalent (TE)/g EW) compared to SD and SN treatments. The OV80 also possessed the highest artocarpin, squalene, and β-sitosterol contents determined. The OV80 was selected for improving antioxidant and colour stability, and has the potential to be developed into functional biopolymer production.

Effects of Infrared-Assisted Refractance Window™ Drying on the Drying Kinetics, Microstructure, and Color of Physalis Fruit Purée

The objective of this work was to study the influence of the drying temperature, infrared (IR) radiation assistance, and the Mylar™ film thickness during Physalis fruit purée drying by the Refractance Window™ (RW™) method. For this, a RW™ dryer layout with a regulated bath at working temperatures of 60, 75, and 90 °C, Mylar™ thicknesses of 0.19, 0.25, 0.30 mm and IR radiation of 250 W for assisting RW™ drying process was used. Experimental curves data were expressed in moisture ratio (MR) in order to obtain moisture effective diffusivities (non-assisted RW™: Deff = 2.7–10.1 × 10−10 m2/s and IR-assisted RW™: Deff = 4.2–13.4 × 10−10 m2/s) and further drying curves modeling (Page, Henderson–Pabis, Modified Henderson–Pabis, Two-Term, and Midilli–Kucuk models). The Midilli–Kucuk model obtained the best-fit quality on experimental curves regarding statistical tests applied (Coefficient of Determination (R2), Chi-Square (χ2) and Root Mean Square Error (RMSE). Microscopical observations were carried out to study the RW™ drying conditions effect on microstructural changes of Physalis fruit purée. The main findings of this work indicated that the use of IR-assisted RW™ drying effectively accelerates the drying process, which achieved a decrease drying time around 60%. Thus, this combined RW™ process is strongly influenced by the working temperature and IR-power applied, and slightly by Mylar™ thickness.

Convective Air Drying of Spondias Dulcis and Product Quality

Kedondong (Spondias dulcis) contains polyphenols, vitamin C and carotenoids which are beneficial to human health. Fresh kedondong has short shelf life and drying is an option to preserve the fruit in dried form to avoid spoilage. In this research, kedondong slices were dried at three temperatures (60 °C, 70 °C and 80 °C) using convective air and RH was fixed at 30 %. High drying temperature facilitated faster drying rate but resulted in poor product quality when compared to freeze dried samples. Drying rates were observed only occurred within falling rates period. Effective diffusivities were estimated in the order of magnitude 10–7 - 10–9 m2/s based on Fick’s second law. Quality assessment showed that samples dried at 60 °C had the lowest hardness and the highest total polyphenols content was observed from samples dried at 80 °C. In addition, kedondong flavour note was found favourable from samples dried at 70 °C and 80 °C based on penalty analyses.

Mass Transfer during Osmotic Dehydration of Tunisian Pomegranate Seeds and Effect of Blanching Pretreatment

In this work, the osmotic dehydration (OD) of Tunisian pomegranate seeds of “El Gabsi” variety was investigated. To optimize the process operating conditions, the effect of temperature, hypertonic solution solid content, and stirring speed was studied. The best conditions resulting in the higher water loss and the minimum of fruit damages found are 40°C, 50°Bx, and 440 rpm. In these conditions, the effect of blanching pretreatments on the solute and water transfer kinetics during the OD was investigated. The blanching pretreatments were carried out using two methods: blanching in a boiling water bath and in a microwave oven. The mass diffusion kinetic depends on time, temperature, hypertonic solution solid content, stirring speeds, and pretreatment process. Peleg’s model showed a good fit to the experimental data. By applying blanching pretreatments, the water and solute effective diffusivities passed from the order of 10−9 to the order of 10−8, and the OD equilibrium time was significantly reduced.

Quantitative Imaging of Carrier Distribution in Silicon Solar Cell Using Scanning Nonlinear Dielectric Microscopy

The carrier distribution in solar cell is important evaluation target. Scanning nonlinear dielectric microscopy is applied to the cross section of phosphorus implanted emitter in monocrystalline silicon solar cell and visualizes the carrier distribution quantitatively. The effective diffusivities of phosphorus are estimated from the experimental results. Then, the three-dimensional carrier distribution is simulated. The experimental and simulation results show good correlation.