How Reliable is the Thermal Conductivity of Biobased Building Insulating Materials Measured with Hot Disk Device?

Thermal conductivity is of high importance for insulating materials since it strongly influences the thermal performance of the building. Generally, it is recommended to measure this property with steady-state methods like guarded hot plate (GHP) or heat flow meter (HFM). These methods are reliable, but steady-state condition can take a long time to be reached. Therefore, transient methods were developed to speed-up the measurements. For instance, the hot disk transient plane source method is a widely used standard technique (ISO 22007-2) for measuring thermal conductivity of various materials. In the last 20 years, this technique has been applied also to bio-based insulating materials. However, overestimated thermal conductivity (compared to steady state method) are frequently measured. More generally, such differences are also observed for low thermal conductivity materials. The aim of this work is to evaluate the influence of numerous factors to explain the origin of these differences. The factors include the experimental setting parameters, the measurement analysis parameter or even the discrepancies between the theoretical model and the real experimental set-up. The analysis is performed for a light-earth biobased concrete made of raw earth and hemp shiv. Recommendations are proposed in conclusion.

An Experimental Investigation of High and Low Salinity Waterflood Displacement Under the Steady-State Condition

Oil recovery by low salinity waterflood is significantly affected by fluid-fluid interaction through the micro-dispersion effect. This interaction influences rock wettability and relative permeability functions. Therefore, to gain a better insight into multiphase flow in porous media and perform numerical simulations, reliable relative permeability data is crucial. Unsteady-state or steady-state displacement methods are commonly used in the laboratory to measure water-oil relative permeability curves of a core sample. Experimentally, the unsteady-state core flood technique is more straightforward and less time-consuming compared to the steady-state method. However, the obtained data is limited to a small saturation range, and the associated uncertainty is not negligible. On the other hand, the steady-state method provides a more accurate dataset of two-phase relative permeability needed in the reservoir simulator for a reliable prediction of the high salinity and low salinity waterflood displacement performance. Considering the limitations of the unsteady state method, steady-state high salinity and low salinity brine experiments waterflood experiments were performed to compare the obtained relative permeability curves. The experiments were performed on a carbonate reservoir sample using a live reservoir crude oil under reservoir conditions. The test was designed so that the production and pressure drop curve covers a wider saturation range and provides enough data for analysis. Consequently, reliable relative permeability functions were obtained, initially, for a better comparison and prediction of the high salinity and the low salinity waterflood injections and then, to quantify the effect of low salinity waterflood under steady-state conditions. The results confirm the difference in relative permeability curves between high salinity and low salinity injections due to the micro-dispersion effect, which caused a decrease in water relative permeability and an increase in the oil relative permeability. These results also proved that low salinity brine can change the rock wettability from oil-wet or mixed-wet to more water-wet conditions. Furthermore, the obtained relative permeability curves extend across a substantial saturation range, making it valuable information required for numerical simulations. To the best of our knowledge, the reported data in this work is a pioneer in quantifying the impact of low salinity waterflood at steady-state conditions using a reservoir crude oil and reservoir rock, which is of utmost importance for the oil and gas industry.

Interstitial condensation in Chinese residential buildings: cliché or challenge?

In this paper, we compare the predictions of interstitial condensation by the steady-state method and the transient method under different climate conditions in China. Simulations reveal significant differences between the two methods, and the wind-driven rain also plays an important role. As a result, the transient hygrothermal simulation considering wind-driven rain should be recommended instead of the steady-state method for predicting interstitial condensation under complicated climate conditions.

Thermal Conductivity Prediction Model for Composite Thermal Interface Materials Using Copper Metal Foam

In the previous research, we prototyped the TIC in which a conventional TIM composed of silicone resin and filler was filled in pores of copper foam, and measured its thermal conductivity by a steady-state method. In addition, the effective thermal conductivity of TIC was predicted by Bhattacharya’s equation and Boomsma’s equation. As a result, it was reported that the experimental value and the predicted value match within 0.7 W/(m·K) by modifying the thermal conductivity of copper to 120 W/(m·K) in the Boomsma’s equation. The issue of that was to investigate the cause of the decrease in thermal conductivity of copper to 120 W/(m·K). In this paper, the effective thermal conductivity of TIC was predicted using the WP structure instead of the Kelvin structure, which is the basis of the Bhattacharya’s equation and Boomsma’s equation. As the result, it was clarified that the effective thermal conductivity predicted by the three-dimensional thermal conductivity calculation model based on the WP structure is more accurate than that predicted by the Kelvin model. And it was found that the experimental value and the predicted value match in the range of 0.4 W/(m·K) by considering the TIC surface structure without modifying the thermal conductivity of copper.

A Case Study on the Water-Oil Interface of Shunbei Oilfield Based on Dynamic Data

Shunbei Oilfield is characterized by substantial heterogeneity and a complex oil–water relationship. The water-oil interface is dynamically changing, and it is a crucial parameter for reserve calculation and evaluation. The main purpose is to analyze the effect of fluid flow in multi-scale media on the water-oil interface. It is well known that the fracture-cavity reservoirs have well-developed fractures and karst caves, and their distribution is complex in Shunbei Oilfield. This paper presents a way to simplify the fracture-cavity system first, then uses a unit of oil wells as a system to study the water-oil interface, which avoids impact on the water-oil interface due to oil production. A detailed step by step procedure for solving the semi-analytical solution of water-oil interface in a fracture-cavity reservoir by using an explicit algorithm and a successive steady-state method is presented. The solution can be used to investigate water-oil interface behavior. In this paper, we validated this method with the actual data for a relatively similar actual reservoir. Sensitivity analyses about the effects of the main parameters including production rates, cave volume and initial oil–water volume ratio on interfacial migration velocity are also presented in detail. The water breaking time of oil wells is fully investigated. The water-oil interface movement chart under different development conditions is established to predict the water-oil interface in the late stage of oil well production and extend the waterless developing period. Being based on this chart, a water breakthrough warning can be realized, and oil recovery can be improved. The findings of the research have led to the conclusion that the rising speed of water-oil interface is proportional to the production rate, on the contrary, it is inversely proportional to cave volume and initial oil–water volume ratio. As well production goes on, the water-oil interface rises at different rates. After the well is put into production for one year, the water-oil interface rises by 16.38%, 12.56% and 4.24% according to the condition that production rate is 10%, the initial oil–water volume ratio is 0.7, and the cave volume is 100 × 104 m3. This method is not only suitable for any period and any well type in the development of Shunbei Oilfield; it also has the function of calculating the real-time water-oil interface of a single well and multi-wells. This new method has the characteristics of easy calculation and high accuracy. The method in this paper can be further developed as it has great applicability in fracture-cavity reservoirs.

Work With Chemical Additives Advances Understanding of Relative Permeability Shifts

This article, written by JPT Technology Editor Chris Carpenter, contains highlights of paper SPE 201520, “Advances in Understanding Relative Permeability Shifts by Imbibition of Surfactant Solutions Into Tight Plugs,” by Mohammad Yousefi, Lin Yuan, and Hassan Dehghanpour, SPE, University of Alberta, prepared for the 2020 SPE Annual Technical Conference and Exhibition, originally scheduled to be held in Denver, Colorado, 5–7 October. The paper has not been peer reviewed. Various chemical additives have been proposed recently to enhance imbibition oil recovery from tight formations during shut-in periods after hydraulic fracturing operations. In the complete paper, the authors develop and apply a laboratory protocol mimicking leakoff, shut-in, and flowback processes to evaluate the effects of fracturing-fluid additives on oil regained permeability. A conventional coreflooding apparatus is modified to measure oil effective permeability (koeff) before and after the surfactant-imbibition experiments. Methodology Proposed Technique for Measuring Oil Effective Permeability. Despite the simplicity of the steady-state method, measuring permeability of tight rocks with this technique is challenging because of its time-consuming nature and the fact that accurate measurement is necessary of extremely low flow rates corresponding to low injectivity of tight rocks. The authors use a pair of plugs from a well drilled in the Montney formation that is a stratigraphic unit of the Lower Triassic age in the western Canadian sedimentary basin located in British Columbia and Alberta. It is mainly a low-permeability siltstone reservoir. In the modified coreflooding apparatus, the authors reduce the effect of compressibility in order to reduce the duration of the transient period by approximately one order of magnitude. Because monitoring changes in pressure is much easier and more accurate than monitoring flow-rate changes, a constant flow-rate mode is used and pressure is recorded with time. Oil is injected at different constant flow rates (qo), and the inlet pressure is monitored. The stable pressure difference across the plug is recorded for each flow rate. After steady-state conditions are reached based on the pressure profile, the qo is increased. This process is repeated until four stable pressure differences corresponding to four different qo are obtained. After the highest qo is reached, it is decreased in similar steps to check the repeatability of each data point. The permeability is calculated with the Darcy equation and slope of the qo vs. stable pressure difference across the plug.

Comparative Analysis between Dynamic and Quasi-Steady-State Methods at an Urban Scale on a Social-Housing District in Venice

The residential building stock represents one of the major players in energy use and greenhouse gas emissions; thus, it is fundamental to reduce the energy used. Simulation tools are becoming more and more accurate in compliance with the new requirements both at the single-building and at the district scale, although they are not affordable by non-specialist users such as policymakers. The research concerns the evaluation of the energy demand for space heating for a historical district that is representative of the Italian building stock. The work compares dynamic and specialist-oriented urban scale tools such as Energy Urban Resistance Capacitance Approach (EUReCA) and City Energy Analyst (CEA)) as well as a quasi-steady-state calculation method (Excel spreadsheet), which is more affordable for non-specialist users. The work was carried out to assess the possible deviation of the results between the dynamic and quasi-steady-state calculation methods, as well as to identify any limits and opportunities in the application of the latter procedure, which is currently the official national calculation tool for the implementation of Directive 2010/31/EU. The study shows how the quasi-steady-state method predicts a reliable building energy demand, in line with the results obtained by the two dynamic tools, when considering only geometry and infiltrations as input. However, the limits of the quasi-steady-state method emerge when introducing internal loads, significantly underestimating the energy demand compared to CEA and EUReCA simulations. The results underline the potential application of the quasi-steady-state method to predict energy demand, although dynamics tools are more reliable but far more complex. Major findings through two methods concern the impact of solar heat gains on the overall heating demand at both the single building and the district scale. The different results between the tools provided evidence of a gap in the use of the simplest tool and demonstrated the accuracy and reliability of the proposed approach with a lower computational effort.

Research on the Correction Method of the Capillary End Effect of the Relative Permeability Curve of the Steady State

Relative permeability curve is a key factor in describing the characteristics of multiphase flow in porous media. The steady-state method is an effective method to measure the relative permeability curve of oil and water. The capillary discontinuity at the end of the samples will cause the capillary end effect. The capillary end effect (CEE) affects the flow and retention of the fluid. If the experimental design and data interpretation fail to eliminate the impact of capillary end effects, the relative permeability curve may be wrong. This paper proposes a new stability factor method, which can quickly and accurately correct the relative permeability measured by the steady-state method. This method requires two steady-state experiments at the same proportion of injected liquid (wetting phase and non-wetting phase), and two groups of flow rates and pressure drop data are obtained. The pressure drop is corrected according to the new relationship between the pressure drop and the core length. This new relationship is summarized as a stability factor. Then the true relative permeability curve that is not affected by the capillary end effect can be obtained. The validity of the proposed method is verified against a wide range of experimental results. The results emphasize that the proposed method is effective, reliable, and accurate. The operation steps of the proposed method are simple and easy to apply.

Estimating ventilation rates in rooms with varying occupancy levels: Relevance for reducing transmission risk of airborne pathogens

Background In light of the role that airborne transmission plays in the spread of SARS-CoV-2, as well as the ongoing high global mortality from well-known airborne diseases such as tuberculosis and measles, there is an urgent need for practical ways of identifying congregate spaces where low ventilation levels contribute to high transmission risk. Poorly ventilated clinic spaces in particular may be high risk, due to the presence of both infectious and susceptible people. While relatively simple approaches to estimating ventilation rates exist, the approaches most frequently used in epidemiology cannot be used where occupancy varies, and so cannot be reliably applied in many of the types of spaces where they are most needed. Methods The aim of this study was to demonstrate the use of a non-steady state method to estimate the absolute ventilation rate, which can be applied in rooms where occupancy levels vary. We used data from a room in a primary healthcare clinic in a high TB and HIV prevalence setting, comprising indoor and outdoor carbon dioxide measurements and head counts (by age), taken over time. Two approaches were compared: approach 1 using a simple linear regression model and approach 2 using an ordinary differential equation model. Results The absolute ventilation rate, Q, using approach 1 was 2407 l/s [95% CI: 1632–3181] and Q from approach 2 was 2743 l/s [95% CI: 2139–4429]. Conclusions We demonstrate two methods that can be used to estimate ventilation rate in busy congregate settings, such as clinic waiting rooms. Both approaches produced comparable results, however the simple linear regression method has the advantage of not requiring room volume measurements. These methods can be used to identify poorly-ventilated spaces, allowing measures to be taken to reduce the airborne transmission of pathogens such as Mycobacterium tuberculosis, measles, and SARS-CoV-2.

Thermal Insulation Properties of Hollow Y2O3:Eu Spheres Laminated with Er2O3

Currently, hollow sphere insulating materials are of importance for applications such as energy storage and savings and cryogenic engineering. The structures are formed by single hollow spheres, which can be joined, for example, by sintering. In this study, a 15 wt% Er-EDTA complex aqueous solution in which hollow Y2O3 spheres were mixed was used as the deposition body, and pencil spraying and sintering (PSS) was used to synthesize an Er2O3 hollow Y2O3 sphere composite film on a polished Si substrate. The structure of the composite film was successfully controlled by adjusting the 15 wt% Er-EDTA solution/hollow Y2O3 sphere mass ratio and the jet-to-substrate distance in the PSS process. In addition, the thermal insulation capability of the films was evaluated by the thermal steady-state method. The results show that the Er2O3/hollow Y2O3:Eu sphere composite films have a higher thermal insulation capability at a jet-to-substrate distance of 150 mm and a mass ratio (g) of 3.5:1. For the composite films with thicknesses of 38–92 µm, cross-sectional hollow ratio of 0.8–8.7% and void ratio of 6.3–13.1%, the temperature drop due to the porous (including hollow spheres and voids) structure films at 440°C is ΔTf =47°C. This is mainly associated with the film having more complicated microstructures. Therefore, the Er2O3/Y2O3:Eu composite film has good thermal insulation performance, and a simple preparation method for many kinds of hollow sphere films with complex structures and high porosities by using complex solutions with different compositions is provided.