Saturation of Metastable-Defect Density in a-Si:H

1990 ◽  
Vol 192 ◽  
Author(s):  
David Redfield ◽  
Richard H. Bube

ABSTRACTThe existence of saturation (or steady state) in the density of light-induced defects in amorphous Si:H is shown to have major importance for the interpretation of the nature and origin of these defects. First, a number of characteristics of the steady-state and transient responses to light and temperature are described and contrasted. These lead to the conclusion that the saturation value is the only useful criterion of the number of defects in these materials. We then describe a new atomic model for defects, unifying both dopant-induced and light-induced defects. This model invokes foreign atoms in defects, and saturation reflects the limitation imposed by the numbers of such atoms. Many other observed properties of defects are explained by this model.

1993 ◽  
Vol 297 ◽  
Author(s):  
R.A. Street ◽  
W.B. Jackson ◽  
M. Hack

Metastable defect creation by illumination and by a forward current in p-i-n devices are compared using CPM and reverse current measurements of the defect density. The data show that the same defects are formed by the two mechanisms, but with different spatial profiles. Numerical modelling shows how the spatial profile influences the reverse bias current.


1992 ◽  
Vol 258 ◽  
Author(s):  
N.W. Wang ◽  
P.A. Morin ◽  
V. Chu ◽  
S. Wagner

ABSTRACTIt is a question as yet unresolved whether the density of light-induced defects in a-Si:H reaches a saturated value that cannot fundamentally be exceeded, or whether the defect density is in all conditions a steady-state value that reflects carrier concentration and temperature. In our experiments on a-Si:H we have observed defect saturation at low temperature and high light intensity; on the other hand, data exhibiting no saturation have also been published. To learn more about this question we have carried out saturation experiments on a-SiGe:H(F) alloys. These alloys have lower defect freeze-in temperatures than a-Si:H and, presumably, lower annealing energies. Therefore, saturation should be more difficult to achieve in the alloys than in a-Si:H.We have studied saturation for a-SiGe:H(F) samples to temperatures above the onset of thermal annealing and have observed that its behavior is similar to that seen in a-Si:H.


1995 ◽  
Vol 377 ◽  
Author(s):  
Qiming Li ◽  
R. Biswas

ABSTRACTMolecular dynamics with the tight-binding approach are utilized to examine the fundamental process of dangling bond creation via the rebonding of H from Si-H bonds to weak Si-Si bonds. The defect formation energy is found to strongly correlate with the bond-length of the weak Si-Si bond, indicating that the distribution of weak Si-Si bonds controls the total defect density. Rate equations for thermally generated and light-induced defects are developed and utilized to calculate the equilibrium and saturated defect density. The results agree well with experimental data.


1991 ◽  
Vol 219 ◽  
Author(s):  
Lisa E. Benatar ◽  
Michael Grimbergen ◽  
David Redfeeld ◽  
Richard H. Bube

ABSTRACTThe effects of excitation rate and temperature on the kinetics and steady-state behavior of metastable defect formation in hydrogenated amorphous silicon (a-Si:H) have been studied. The dependences on temperature of the lifetime, τ, and stretching parameter, β, from a stretched exponential description of the kinetics were measured for one sample. We do not see a linear dependence of β on temperature over die entire temperature range studied (270K–370K), and τ increases monotonically with decreasing temperature. Steady-state results show defect density to be dependent on bodi temperature and excitation rate over the ranges measured (from 395K to 470K and from 6 × 1020 to 2 × 1022 s-l cm-3). The gradual change in temperature dependence is explained by a distribution of barrier heights between the ground and metastable states.


1993 ◽  
Vol 297 ◽  
Author(s):  
M. Grimbergen ◽  
R. Mcconville ◽  
D. Redfield ◽  
R.H. Bube

Relaxation of the metastable defect density in undoped amorphous silicon is observed after keV electron irradiation. The time constant for relaxation has an activation energy close to 1 eV, similar to that for light-induced defects. Relaxation appears to follow two or more stages. A large initial density relaxes rapidly, followed by slower relaxation more characteristic of light-induced defects. Separation of these components allows for a better comparison of e-beam and light-induced saturation defect density.


2005 ◽  
Vol 864 ◽  
Author(s):  
P. K. Giri ◽  
R. Kesavamoorthy ◽  
B. K. Panigrahi ◽  
K.G.M. Nair

AbstractGe nanocrystals (NCs) of diameter 4–13 nm are grown embedded in a thermally grown SiO2 layer by Ge ion implantation and subsequent annealing. Steady state and time-resolved photoluminescence (PL) studies are performed on these embedded Ge nanocrystals to understand the origin of the PL emission at room temperature. Steady state PL spectra show a broad peak consisting of a peak at ∼2.1 eV originating from Ge NCs and another peak at ∼2.3 eV arising from ion-beam induced defects in the Ge/SiO2 interface. Time-resolved PL studies reveal double exponential decay dynamics of the PL emission on the nanoseconds time scale. The faster component of the decay with large amplitude and having a time constant τ1∼3.1 ns is attributed to the nonradiative lifetime, since the time constant reduces with increasing defect density. The slower component with time constant τ2∼10 ns is attributed to radiative recombination at the Ge NCs. These results are in close agreement with the theoretically predicted radiative lifetime for small Ge NCs.


2011 ◽  
Vol 403-408 ◽  
pp. 4880-4887
Author(s):  
Sassan Azadi

This research work was devoted to present a novel adaptive controller which uses two negative stable feedbacks with a positive unstable positive feedback. The positive feedback causes the plant to do the break, therefore reaching the desired trajectory with tiny overshoots. However, the two other negative feedback gains controls the plant in two other sides of positive feedback, making the system to be stable, and controlling the steady-state, and transient responses. This controller was performed for PUMA-560 trajectory planning, and a comparison was made with a fuzzy controller. The fuzzy controller parameters were obtained according to the PSO technique. The simulation results shows that the novel adaptive controller, having just three parameters, can perform well, and can be a good substitute for many other controllers for complex systems such as robotic path planning.


1997 ◽  
Vol 467 ◽  
Author(s):  
C. Godet

ABSTRACTIn hydrogenated amorphous silicon (a-Si:H) films, the increase of the metastable defect density under high-intensity illumination is usually described by an empirical two-parameter stretched-exponential time dependence (characteristic time τSE and dispersion parameter β). In this study, a clearly different (one-parameter) analytic function is obtained from a microscopic model based on the formation of metastable H (MSH) atoms in a-Si:H films. Assuming that MSH atoms are the only mobile species, only three chemical reactions are significant : MSH are produced from doubly hydrogenated (SiH HSi) configurations and trapped either at broken bonds or Si-H bonds, corresponding respectively to light-induced annealing (LIA) and light-induced creation (LIC) of defects. Competition between trapping sites results in a saturation of N(t) at a steady-state value Nss. A one-parameter fit of this analytical function to experimental data is generally good, indicating that the use of a statistical distribution of trap energies is not necessary.


2001 ◽  
Vol 664 ◽  
Author(s):  
Stephan Heck ◽  
Howard M. Branz

ABSTRACTWe report experimental results that help settle apparent inconsistencies in earlier work on photoconductivity and light-induced defects in hydrogenated amorphous silicon (a-Si:H) and point toward a new understanding of this subject. After observing that light-induced photoconductivity degradation anneals out at much lower T than the light-induced increase in deep defect density, Han and Fritzsche[1] suggested that two kinds of defects are created during illumination of a-Si:H. In this view, one kind of defect degrades the photoconductivity and the other increases defect sub-bandgap optical absorption. However, the light-induced degradation model of Stutzmann et al.[2] assumes that photoconductivity is inversely proportional to the dangling-bond defect density. We observe two kinds of defects that are distinguished by their annealing activation energies, but because their densities remain in strict linear proportion during their creation, the two kinds of defects cannot be completely independent.In our measurements of photoconductivity and defect absorption (constant photocurrent method) during 25°C light soaking and during a series of isochronal anneals between 25 < T < 190°C, we find that the absorption measured with E ≤1.1 eV, first increases during annealing, then exhibits the usual absorption decrease found for deeper defects. The maximum in this absorption at E ≤1.1eV occurs simultaneously with a transition from fast to slow recovery of photoconductivity. The absorption for E ≤1.1eV shows two distinct annealing activation energies: the signal rises with about 0.87 eV and falls with about 1.15 eV. The 0.87 eV activation energy roughly equals the activation energy for the dominant, fast, recovery of photoconductivity. The 1.15 eV activation energy roughly equals the single activation energy for annealing of the light-induced dangling bond absorption.


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