Atomic and Electronic Structure of Amorphous Alloys

1981 ◽  
Vol 7 ◽  
Author(s):  
William L. Johnson

ABSTRACTAmorphous metallic alloys can be synthesized by many techniques including melt quenching, vapor quenching, electrodeposition, and irradiation of crystalline alloys by neutrons or by ions. Certain alloys are prone to glass formation and can be readily made amorphous by all of these methods. In this article, a survey of experimental data on the atomic and electronic structure of such good glass forming alloys is presented. On the basis of this data, it is argued that good glass forming alloys tend to have in common several underlying microscopic features. The article concludes with some general remarks on the relationship of these common features to glass formation.

2012 ◽  
Vol 554-556 ◽  
pp. 374-378 ◽  
Author(s):  
Li Wei Wang

Based on the Planck's quantum hypothesis and the Einstein's light quantum hypothesis , the Zhongjizi (a new elementary particles) hypothesis is proposed. It revealed the quantum nature of light. Light quantum (which is photon) was essentially a collection of Zhongjizi, light was constituted of Zhongjizi, the essence of light was the nature of particle, and the quantum nature of light was essentially the Zhongjizi nature of light. The quantum nature of light revealed out: atomic spectra was produced by the light of different frequencies that emitted and absorbed by the extranuclear electrons of different motion states (different rotation frequencies) under certain conditions. The rotation frequency of extranuclear electrons was equal to the frequencies of light that emitted and absorbed by the electrons. By using this law, and according to the atomic spectra, we can know the state of the electron structure of atoms and the movement of electrons ,according to the frequency (the cycle )that rotate round the nuclear of the extranuclear electron in a state of motion , and the relationship of the distance between the electrons and the atomic nucleus .


2004 ◽  
Vol 19 (3) ◽  
pp. 921-929 ◽  
Author(s):  
Z.P. Lu ◽  
C.T. Liu ◽  
C.A. Carmichael ◽  
W.D. Porter ◽  
S.C. Deevi

Several new bulk metallic glasses based on Fe–Y–Zr–(Co, Cr, Al)–Mo–B, which have a glass-forming ability superior to the best composition Fe61Zr10Co7Mo5W2B15 reported recently, have been successfully developed. The as-cast bulk amorphous alloys showed a distinctly high thermal stability with glass-transition temperatures above 900 K, supercooled liquid regions above 60 K, and high strength with Vickers hardness values larger than HV 1200. The suppression of the growth of primary phases in the molten liquids and the resultant low liquidus temperatures were found to be responsible for the superior glass-forming ability in these new alloys. It was found that the addition of 2% Y not only facilitated bulk glass formation, but the neutralizing effect of Y with oxygen in the molten liquids also improved the manufacturability of these amorphous alloys.


Author(s):  
М.В. Лебедев

Recent experimental and theoretical results on modification of the surface atomic and electronic structure of various III–V semiconductor with electrolyte solutions are reviewed. The relationship between the chemical and charge transfer processes that proceed at the semiconductor/electrolyte interfaces and accompanying modification of the semiconductor surface atomic and electronic structure is revealed. Advances in the application of electrolyte solutions for modification of the semiconductor nanostructures and device performance are discussed.


1980 ◽  
Vol 41 (C8) ◽  
pp. C8-179-C8-182
Author(s):  
K. Suzuki ◽  
F. Itoh ◽  
M. Misawa ◽  
M. Matsuura ◽  
T. Fukunaga

2010 ◽  
Vol 25 (7) ◽  
pp. 1398-1404 ◽  
Author(s):  
Ran Li ◽  
Mihai Stoica ◽  
Gang Wang ◽  
Jin Man Park ◽  
Yan Li ◽  
...  

The compositional dependence of glass formation and thermal and elastic properties was clarified for the ternary La–Al–Co bulk glass-forming system. The existing linear correlation between La concentration and characteristic temperatures, i.e., the glass transition temperature Tg and the onset temperature of crystallization Tx, as well as the elastic moduli in this system can give a useful guideline for the chemical design of desirable bulk metallic glasses (BMGs) with tunable physical properties in advance. The relationship between Tg and elastic constants for the La–Al–Co BMGs can be quantitatively described using a microscopic model proposed by T. Egami.


2020 ◽  
Vol 21 (20) ◽  
pp. 7745
Author(s):  
Wagner Silva ◽  
Marcileia Zanatta ◽  
Ana Sofia Ferreira ◽  
Marta C. Corvo ◽  
Eurico J. Cabrita

In the last few years, ionic liquids (ILs) have been the focus of extensive studies concerning the relationship between structure and properties and how this impacts their application. Despite a large number of studies, several topics remain controversial or not fully answered, such as: the existence of ion pairs, the concept of free volume and the effect of water and its implications in the modulation of ILs physicochemical properties. In this paper, we present a critical review of state-of-the-art literature regarding structure–property relationship of ILs, we re-examine analytical theories on the structure–property correlations and present new perspectives based on the existing data. The interrelation between transport properties (viscosity, diffusion, conductivity) of IL structure and free volume are analysed and discussed at a molecular level. In addition, we demonstrate how the analysis of microscopic features (particularly using NMR-derived data) can be used to explain and predict macroscopic properties, reaching new perspectives on the properties and application of ILs.


2019 ◽  
Vol 74 (1) ◽  
pp. 91-98 ◽  
Author(s):  
Svitlana Polesya ◽  
Sergiy Mankovsky ◽  
Hubert Ebert

AbstractThe electronic structure and magnetic properties of the compound 2H-NbS2 intercalated by 3d elements from Cr to Ni, have been investigated using the Korringa–Kohn–Rostoker electronic structure method. Here, we consider the phases with 33% of intercalation within the ordered phase having a $\sqrt 3 \times \sqrt 3 $ arrangement of the magnetic atoms. We analyze the relationship of the magnetic and electronic properties on the structural parameters dependent on the intercalant. The exchange coupling parameters calculated from first principles have been used for subsequent Monte Carlo simulations. Within these investigations, the FM order was found for the Cr and Mn intercalated phases as ground state configuration with a Curie temperature being in good agreement with the experiment. According to the Monte Carlo simulation, Fe1/3NbS2 has a complicated noncollinear magnetic structure with a noncompensated total magnetic moment, whereas Co1/3NbS2 and Ni1/3NbS2 are found to be antiferromagnetic, all in line with experimental observations.


1995 ◽  
Vol 400 ◽  
Author(s):  
Leonid V. Poperenko ◽  
Mykola V. Vinnichenko ◽  
Vasyl’ V. Vovchak ◽  
Iryna V. Yurgelevych ◽  
Sergei G. Zaichenko

AbstractThe experimental results of research of structural modifications in amorphous magnetic alloys (AMAs) under thermotreatment obtained by angular and spectroellipsometric methods are presented and discussed. The ductile-brittle transition was observed for the ribbons of some 3d-metal-based amorphous alloys. The relationship between the principal angle of incidence φ0 and annealing temperature Ta of alloys was obtained for the ribbons of AMAs. The observed behaviour of φ0 is connected with appearance of the novel amorphous phase’s clusters inside the surface’s layers of alloys.The influence of melt’s overheating on the atomic and electronic structure of AMAs was studied. It was found that the increase of melt’s overheating temperature leads to the decrease of absorption index within the whole spectral range (ħω=0.5–4.38 eV). The structural anisotropy of AMAs and its changes after annealings were determined by reflectometric and ellipsometric measurements.


IAWA Journal ◽  
1997 ◽  
Vol 18 (3) ◽  
pp. 215-228 ◽  
Author(s):  
Guillermo Angeles ◽  
Calixto León-Gómez

Bark anatomy of four species of Vitaceae growing at the tropical rain forest of Veracruz, Mexico, is described. Young and mature individuals were collected at the tropical biology field station 'Los Tuxtlas' . External, gross characteristics of the bark and microscopic features of young and adult individuals are given. Sectorization of the vascular tissues into minor and major areas was found in the three Cissus species, but not in Vitis tiliifolia, where it was apparent only at early stages of development. All the species studied have storied secondary phloem and very tall rays. The potential role of mucilage in water-holding capacity and the relationship of stem anatomy and aerial root formation are discussed.


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