Hydrogen Storage using Carbon Materials at Room Temperature

2003 ◽  
Vol 801 ◽  
Author(s):  
H. Kajiura ◽  
S. Tsutsui ◽  
K. Kadono ◽  
Y. Murakami ◽  
M. Kakuta ◽  
...  
Keyword(s):  
Adsorption Capacity ◽  
Room Temperature ◽  
Carbon Materials ◽  
Hydrogen Adsorption ◽  
Constant Pressure ◽  
Graphite Powder ◽  
Milling Process ◽  
Volumetric Method ◽  
Hydrogen Molecules ◽  
Available Carbon

ABSTRACTThe hydrogen adsorption capacity of commercially available carbon materials with different nanostructures was measured at room temperature using an apparatus based on a volumetric method with an error of less than 0.04 wt% per one gram of sample. The obtained results suggest that nanosutures of the sample influence the hydrogen adsorption capacity. To confirm this hypothesis, we prepared nanostructured graphite from graphite powder using a mechanical milling process at a pressure of 2.0 × 10−4 Pa. The untreated graphite adsorbed 0.02wt% of hydrogen at 6 MPa at room temperature, while 0.20 − 0.25 wt% of hydrogen can be repeatedly adsorbed by the nanostructured graphite. Measurements of the hydrogen adsorption rate at constant pressure and pore-size distribution imply that the hydrogen molecules are adsorbed through a diffusion process in pores with a diameter less than 1 nm.

Hybridization of inorganic CoB noncrystal with graphene and its Kubas-enhanced hydrogen adsorption at room temperature

RSC Advances ◽  
2016 ◽  
Vol 6 (96) ◽  
pp. 93238-93244 ◽  
Author(s):  
Xiaobo Li ◽  
Shuchao Sun ◽  
Jianjiao Zhang ◽  
Kan Luo ◽  
Peng Gao ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Ball Milling ◽  
Hybrid Material ◽  
Room Temperature ◽  
Hydrogen Adsorption ◽  
High Energy ◽  
Milling Process ◽  
Electrochemical Hydrogen Storage ◽  
Energy Ball ◽  
Storage Ability

In this work an archetypical hybrid material has been prepared by the reaction of an inorganic CoB noncrystal with graphene by a high-energy ball-milling process, which showed an enhanced electrochemical hydrogen storage ability induced by the Co–B–C structure.

scholarly journals Molecular Simulation of Hydrogen Storage in Ion-Exchanged X Zeolites

2014 ◽  
Vol 2014 ◽  
pp. 1-10
Author(s):  
Xiaoming Du
Keyword(s):  
Adsorption Capacity ◽  
Hydrogen Adsorption ◽  
Isosteric Heat ◽  
Heat Of Adsorption ◽  
Adsorption Sites ◽  
Hydrogen Molecules ◽  
Adsorption Temperature ◽  
X Zeolites ◽  
Cation Type ◽  
Simulated Distribution

Grand Canonical Monte Carlo (GCMC) method was employed to simulate the adsorption properties of molecular hydrogen on ion-exchanged X zeolites at 100–293 K and pressures up to 10 MPa in this paper. The effect of cation type, temperature, and pressure on hydrogen adsorption capacity, heat of adsorption, adsorption sites, and adsorption potential energy of ion-exchanged X zeolites was analyzed. The results indicate that the hydrogen adsorption capacity increases with the decrease in temperatures and the increase in pressures and decreases in the order ofKX<LiX<CaX. The isosteric heat of adsorption for all the three zeolites decreases appreciably with the increase in hydrogen adsorption capacity. The hydrogen adsorption sites in the three zeolites were determined by the simulated distribution of hydrogen adsorption energy and the factors that influence their variations were discussed. Adsorption temperature has an important effect on the distribution of hydrogen molecules in zeolite pores.

Hydrogen storage capacity of commercially available carbon materials at room temperature

2003 ◽  
Vol 82 (7) ◽  
pp. 1105-1107 ◽  
Author(s):  
H. Kajiura ◽  
S. Tsutsui ◽  
K. Kadono ◽  
M. Kakuta ◽  
M. Ata ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Room Temperature ◽  
Carbon Materials ◽  
Storage Capacity ◽  
Hydrogen Storage Capacity ◽  
Available Carbon

Processing of Iridium Doped Materials and Experimental Investigation of Their Hydrogen Adsorption Capacity

2018 ◽  
Vol 69 (6) ◽  
pp. 1468-1472
Author(s):  
Radu Mirea ◽  
Mihai Iordoc ◽  
Gabriela Oprina ◽  
Gimi Rimbu
Keyword(s):  
Adsorption Capacity ◽  
Hydrogen Adsorption ◽  
Weight Ratio ◽  
H2 Adsorption ◽  
Cyclic Voltametry ◽  
Physical Chemical ◽  
Good Consistency ◽  
Metal Doped ◽  
And Storage ◽  
Poly Aniline

The paper aims to present the investigation of H2 adsorption capacity in metal doped nanostructured materials, by using two methods. Carbonic materials are considered to be one of the most promising materials to be used for hydrogen adsorption and storage. They have different applications and one of the most important is considered to be fuel cells technology. By using metals for doping these materials, the adsorption capacity increases, thus approaching the target of 6.5% weight ratio of H2 adsorbed in a substrate. Within these investigations multi-wall nanotubes and poly-aniline have been used as substrates. The poly-aniline has been prepared and doped in laboratory while the nanotubes used in experiments have been purchased from the market and afterwards doped in laboratory. The doping procedure consists of a physical-chemical method which involves salts of the metal for doping and the use of ultrasounds in order to activate the substrate for doping. The adsorption capacity of the carbonic materials has been determined by using spill over phenomena in a PCT Pro-User apparatus, provided by SETARAM and also by cyclic voltametry, by using VoltaLab-40 apparatus. In order to investigate the adsorption capacity of the nanostructured carbonic materials, the experiments have been carried out at different pressures. Both substrates have been characterized in order to determine their porosity, BET surface and structure. The collected data have been processed by using the PCT Pro-User apparatus�s software. The results have been compared with the available data from literature and a good consistency was found.

Piezoresistivity and Electrical Resistance Relaxation of Polyisoprene Nanostructured Carbon Allotrope Hybrid Composites

2015 ◽  
Vol 1117 ◽  
pp. 52-55
Author(s):  
Artis Linarts ◽  
Maris Knite
Keyword(s):  
Electrical Resistance ◽  
Room Temperature ◽  
Constant Pressure ◽  
Hybrid Composites ◽  
Conductive Filler ◽  
Force Sensor ◽  
Filler Concentration ◽  
Nanostructured Carbon ◽  
Carbon Allotrope ◽  
Resistance Relaxation

Polymer conductive filler composites are believed to be promising materials for flexible force sensor manufacture. Polyisoprene various carbon allotrope hybrid composites were made and their piezoresistive properties depending on the two type’s filler concentration and their ratio have been determined. Electrical resistance relaxations of hybrid composites at constant pressure in room temperature were determined as well. Experimental data of resistance relaxation was analyzed and fitted similarly to stress relaxation of polymers at constant pressure.

Investigation of the Hydrogen Transport Processes in Crystalline Silicon of n-Type Conductivity

2007 ◽  
Vol 131-133 ◽  
pp. 425-430 ◽  
Author(s):  
Anis M. Saad ◽  
Oleg Velichko ◽  
Yu P. Shaman ◽  
Adam Barcz ◽  
Andrzej Misiuk ◽  
...  
Keyword(s):  
Hydrogen Concentration ◽  
Room Temperature ◽  
Crystalline Silicon ◽  
Transport Processes ◽  
Concentration Profiles ◽  
Hydrogen Transport ◽  
Hydrogen Atoms ◽  
Near Surface ◽  
Type Conductivity ◽  
Hydrogen Molecules

The silicon substrates were hydrogenated at approximately room temperature and hydrogen concentration profiles vs. depth have been measured by SIMS. Czochralski grown (CZ) wafers, both n- and p-type conductivity, were used in the experiments under consideration. For analysis of hydrogen transport processes and quasichemical reactions the model of hydrogen atoms diffusion and quasichemical reactions is proposed and the set of equations is obtained. The developed model takes into account the formation of bound hydrogen in the near surface region, hydrogen transport as a result of diffusion of hydrogen molecules 2 H , diffusion of metastable complexes * 2 H and diffusion of nonequilibrium hydrogen atoms. Interaction of 2 H with oxygen atoms and formation of immobile complexes “oxygen atom - hydrogen molecule” (O - H2 ) is also taken into account to explain the hydrogen concentration profiles in the substrates of n-type conductivity. The computer simulation based on the proposed equations has shown a good agreement of the calculated hydrogen profiles with the experimental data and has allowed receiving a value of the hydrogen molecules diffusivity at room temperature.

ELECTROCHEMICAL STORAGE OF HYDROGEN IN CARBON NANOSTRUCTURES

2003 ◽  
Vol 02 (04n05) ◽  
pp. 307-317
Author(s):  
M. S. YU ◽  
S. Y. CHENG ◽  
Y. C. LIN ◽  
W. C. HO
Keyword(s):  
Carbon Nanostructures ◽  
Room Temperature ◽  
Hydrogen Adsorption ◽  
Abundance Ratio ◽  
Nanostructured Carbon ◽  
Half Cell ◽  
Carbonaceous Particles ◽  
Catalytic Thermal Decomposition ◽  
Electrochemical Storage ◽  
Preliminary Study

We have synthesized a set of nanostructured carbon samples including a variety of carbon nanotubes and carbonaceous particles, by catalytic thermal decomposition of CH4 on catalyst LaNi 5 powder with different reaction temperatures. Products obtained at reaction temperatures 550~900°C were characterized by means of HR-TEM, SEM and Raman Scattering. In addition, electrochemical charge–discharge cycling method was carried out at room temperature to measure the reversible hydrogen capacity in pressed electrodes containing mixture of catalyst, nanostructured carbon samples and carbonaceous particles. Results showed that the abundance ratio of well-crystallized graphite to amorphous carbon in each product increases with increasing reaction temperatures. This preliminary study showed also that the hydrogen storage capacity of synthesis products measured in an electrochemical half-cell at room temperature correlates with the nanostructure and morphology of the variety of nanostructured carbon samples. Additionally, the hydrogen adsorption capacity against specific surface area (BET) for synthesis products produced at temperatures higher than 670°C is ranging from 14 to 25 wt.%/(1000 m2/g).

Effects of Supports on Hydrogen Adsorption on Pt Clusters

2008 ◽  
Vol 139 ◽  
pp. 41-46 ◽  
Author(s):  
K. Okazaki-Maeda ◽  
Y. Morikawa ◽  
Shingo Tanaka ◽  
Masanori Kohyama
Keyword(s):  
Catalytic Activity ◽  
First Principles ◽  
Carbon Materials ◽  
Hydrogen Adsorption ◽  
Nano Particles ◽  
High Dispersion ◽  
Graphene Sheets ◽  
First Principles Calculations ◽  
Small Clusters ◽  
Atom Absorption

Pt nano-particles are supported on carbon materials at the electrode catalysts of protonexchange menbrane fuel cells. Pt nano-particles are desirable to be strongly adsorbed on carbon materials for high dispersion, although strong Pt-C interactions may affect the catalytic activity of small clusters. Thus we have examined H-atom absorption on Pt clusters supported or unsupported on graphene sheets, using first-principles calculations. For Pt-atom/graphene systems, a H atom is more weakly adsorbed than for a free Pt atom, and the H-Pt interaction becomes weaker if the interaction between a Pt atom and graphene becomes stronger. For the Ptn-cluster/graphene systems (n=2-4), the H-Pt interactions are also substantially changed from those for free Pt clusters. In the Pt clusters on graphene, the Pt-Pt distances are substantially changed associated with the electronicstructure changes by the Pt-C interactions. These structural and electronic changes in the Pt clusters as well as the presence of graphene itself seem to cause the changes in the absorption energies and preferential sites of H-atom absorption.

Using of Sukary and Khlass Date Pits as a Bio-adsorbents for Adsorption of Lead and Copper Ions from Waste Water

2021 ◽  
Vol 37 (2) ◽  
pp. 302-307
Author(s):  
Abdulrahman G. Alhamzan
Keyword(s):  
Adsorption Capacity ◽  
Room Temperature ◽  
Copper Ions ◽  
Phoenix Dactylifera ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
Palm Trees ◽  
Phoenix Dactylifera L ◽  
Temperature Equilibrium ◽  
Date Pits

In this study date pits of two types of date-palm trees (Phoenix Dactylifera L.), in Saudi Arabia were used as bio-sorbents for heavy metals (e.g. lead and copper) from aqueous solutions. Investigation of equilibrium time and the effect of different concentrations of metals were performed. Adsorption capacity of bio-sorbents increased when increasing concentration of metal ions. Maximum adsorption capacity at room temperature of Sukary date pits was 17.53 mg g-1 and 9.86 mg g-1 for lead and copper ions, respectively. Whereas, Khlass date pits showed maximum adsorption capacity at 14.1 mg g-1 and 7.91 mg g-1 for lead and copper ions, respectively at room temperature. Equilibrium isotherm models, (Langmuir and Freundlich models), were used for analysis of equilibrium experimental results. these models describe the experimental data well.

Pressure Isotherms of Hydrogen Adsorption in Carbon Nanostructures

2001 ◽  
Vol 706 ◽  
Author(s):  
Xiaohong Chen ◽  
Urszula Dettlaff-Weglikowska ◽  
Miroslav Haluska ◽  
Martin Hulman ◽  
Siegmar Roth ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Activated Carbon ◽  
Hydrogen Storage ◽  
Carbon Nanostructures ◽  
Room Temperature ◽  
Storage Capacity ◽  
Hydrogen Adsorption ◽  
Single Wall Carbon Nanotubes ◽  
Hydrogen Storage Capacity ◽  
Carbon And Graphite

AbstractThe hydrogen adsorption capacity of various carbon nanostructures including single-wall carbon nanotubes, graphitic nanofibers, activated carbon, and graphite has been measured as a function of pressure and temperature. Our results show that at room temperature and a pressure of 80 bar the hydrogen storage capacity is less than 1 wt.% for all samples. Upon cooling, the capacity of hydrogen adsorption increases with decreasing temperature and the highest value was observed to be 2.9 wt. % at 50 bar and 77 K. The correlation between hydrogen storage capacity and specific surface area is discussed.

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