Vapor Movement of Aminocyclopyrachlor, Aminopyralid, and Dicamba in the Field

2013 ◽  
Vol 27 (1) ◽  
pp. 143-155 ◽  
Author(s):  
Stephen D. Strachan ◽  
Nancy M. Ferry ◽  
Tracy L. Cooper

Vapor movement of synthetic auxin herbicides can injure desirable plants outside the treatment zone. Vapor movement of the synthetic auxin herbicides aminocyclopyrachlor and aminocyclopyrachlor methyl was compared with that of the relatively volatile herbicide dicamba and the low volatile herbicide aminopyralid with a soybean bioassay under greenhouse and field conditions. Soybean is very sensitive to these active ingredients. Under greenhouse conditions, 82 (61 to 104) mg ae ha−1of aminocyclopyrachlor, 26 (18 to 33) mg ae ha−1of aminocyclopyrachlor methyl, 82 (69 to 95) mg ae ha−1of aminopyralid, and 61 (47 to 75) mg ae ha−1of dicamba produced an estimated 25% visual soybean phytotoxicity response when soybean was treated POST at the V3 growth stage (GR25[95% confidence interval]). In field studies, aminocyclopyrachlor, aminocyclopyrachlor methyl, and aminopyralid were applied at 70 g ae ha−1and dicamba was applied at 560 g ae ha−1(labeled application rates) to soybean at the V3 growth stage. All herbicides were applied within an enclosed chamber (3 m by 3 m by 1 m) to mitigate movement of spray droplets. The enclosures were removed shortly after spray application and soybean response immediately surrounding the treated area was recorded in each of eight directions approximately 10 d after treatment. On the basis of bioassay responses, relative amount of vapor movement was dicamba > aminocyclopyrachlor methyl > aminopyralid ≈ aminocyclopyrachlor. Vapor movement of aminocyclopyrachlor was very low indicating that the risk of phytotoxic response of sensitive plants due to volatility of aminocyclopyrachlor is negligible.

Weed Science ◽  
2010 ◽  
Vol 58 (2) ◽  
pp. 103-108 ◽  
Author(s):  
Stephen D. Strachan ◽  
Mark S. Casini ◽  
Kathleen M. Heldreth ◽  
Joseph A. Scocas ◽  
Scott J. Nissen ◽  
...  

Aminocyclopyrachlor, a newly discovered synthetic auxin herbicide, and its methyl ester, appear to control a number of perennial broadleaf weeds. The potential volatility of this new herbicide and its methyl ester were determined under laboratory conditions and were also compared to dicamba and aminopyralid with the use of enclosed chamber and open-air plant bioassays. Bioassays consisting of visual estimates of epinastic responses and kidney bean and soybean leaf-width measurements were developed to measure vapor release from glass and plastic. Vapor release of aminocyclopyrachlor from glass surfaces was undetectable under laboratory conditions, and no phytotoxic responses were observed when plants were exposed to vapors emanating from various surfaces. Results were similar to those of aminopyralid, indicating the risk of plant injury from vapor movement of aminocyclopyrachlor and aminopyralid was very low. When combined with 1% methylated seed oil, vapor release of aminocyclopyrachlor-methyl ester reached 86% 192 h after application to glass surfaces. Phytotoxic responses of plants exposed to vapors emanating from various surfaces treated with aminocyclopyrachlor-methyl ester were similar to responses to dicamba under enclosed incubation conditions, but were less in outdoor, open-air environments. Studies are needed to understand better the risk of injury to nontarget plants due to vapor movement of aminocyclopyrachlor-methyl ester under field applications.


HortScience ◽  
2005 ◽  
Vol 40 (5) ◽  
pp. 1487-1492 ◽  
Author(s):  
Frank J. Peryea

Two multiyear field studies were conducted to compare the phytoavailability and effectiveness of a variety of commercial foliar B fertilizer sprays applied at the pink flowering stage to 'Fuji'/EMLA.26 apple trees grown under irrigated semi-arid conditions. Treatments included products that differed by initial chemical form of B, physical state, and presence of additives of varying composition. Additional treatments were polymeric urea added to one B product and soil application of one B product. Boron application rates varied from 0.56 to 1.68 kg·ha–1·yr–1. All of the B sprays increased flower cluster B concentration in all years. The B sprays at the lower rate sometimes but not always increased leaf B concentration. Increasing the B rate substantially increased plant tissue B concentrations. In general, there was little substantive difference between the tested products/product mixtures on plant tissue B concentrations. Flower cluster B in the ground-applied B treatment was similar to the water control; however, leaf B concentration corresponded to the B spray treatments, indicating effective uptake of B from the soil during the early summer. Sodium polyborate-based products increased flower cluster Na concentration but not leaf Na concentration. The amount of Na contributed by Na polyborate-based products applied at commercial rates apparently was too small to be of horticultural concern. Fruit quality was excellent and was not affected by the experimental treatments in any year. Flower cluster and leaf B concentrations returned to near or at control levels in the season following the last spray application, validating the recommendation for annual B fertilizer applications to maintain adequate tree B status.


2020 ◽  
pp. 1-31
Author(s):  
Geoffrey P. Schortgen ◽  
Aaron J. Patton

The herbicide 2,4-D is used in a variety of cropping systems, especially in grasses since it is a selective postemergence broadleaf herbicide. However, the most common formulation (2,4-D dimethylamine) is antagonized when mixed in hard water. The objective of this research was to determine which formulations of 2,4-D or premixes of various formulations of synthetic auxin herbicides are subject to hard water antagonism. Formulations surveyed for hard water antagonism in the first experiment included 2,4-D dimethylamine, 2,4-D diethanolamine, 2,4-D monomethylamine, 2,4-D isopropylamine salt, 2,4-D choline salt, 2,4-D isooctyl ester, and 2,4-D ethylhexyl ester. Synthetic auxin formulation types in the second experiment included water-soluble, emulsifiable concentrates and emulsion-in-water. All formulations were mixed with both soft and hard water (600 mg CaCO3 L-1) and applied to dandelions to determine if antagonism occurred in hard water. Water-soluble (amine and choline) 2,4-D formulations were antagonized by hard water, but water-insoluble (ester) 2,4-D formulations were not antagonized. Similar results were found by formulation type with water-soluble synthetic auxin premixes antagonized but emulsifiable concentrates not antagonized. Further, water-soluble salt formulations were not antagonized when formulated in premixes with other synthetic auxin herbicides as an emulsion-in-water. This research demonstrates that all 2,4-D water-soluble formulations and water-soluble premixes with phenoxycarboxylic acid herbicides are subject to hard water antagonism. Formulations of 2,4-D containing emulsifying agents protect against antagonism by the water-insoluble nature of ingredients in their formulation.


1962 ◽  
Vol 53 (3) ◽  
pp. 597-608 ◽  
Author(s):  
R. D. MacCuaig

The toxicities of sprays of some insecticides used against locusts have been determined. The LD50's of γ BHC, diazinon, and dieldrin to both flying and settled adults of Schistocerca gregaria (Forsk.) were between 0·9 and 1·5 times those of the same formulations when applied as a single drop to the abdomen. The toxicity of these insecticides was not affected by the size of the spray droplets when these ranged from about 60 to 250 µ in diameter. The toxicity of DNC, however, was always less by spray application than when applied by micro-drop syringe and was affected by the droplet diameter (droplets of 100 µ being 1·5 times as toxic as those of 200–230 µ) and by whether the locusts were sprayed in flight or when tethered on a card (those in flight being about 1·6 times as susceptible to 100 µ droplets as those at rest). A tentative explanation of this effect is given.The speed of action of the insecticides was compared and the effects of flight activity on susceptibility to the insecticides when sprayed over the flying insects was examined, but none could be detected by the technique used.


2018 ◽  
Vol 32 (5) ◽  
pp. 597-602 ◽  
Author(s):  
Marcelo Zimmer ◽  
Bryan G. Young ◽  
William G. Johnson

AbstractSynthetic auxin herbicides such as 2,4-D and dicamba are often utilized to control broadleaf weeds in preplant burndown applications to soybean. Halauxifen-methyl is a new synthetic auxin herbicide for broadleaf weed control in preplant burndown applications to corn, cotton, and soybean at low use rates (5 g ae ha–1). Field experiments were conducted to evaluate efficacy and weed control spectrum of halauxifen-methyl applied alone and in mixtures with 2,4-D (560 g ae ha–1), dicamba (280 g ae ha–1), and glyphosate (560 g ae ha–1). Glyphosate-resistant (GR) horseweed was controlled with halauxifen-methyl applied alone (90% control) and in mixtures (87% to 97% control) 35 d after treatment (DAT). Common ragweed was controlled 93% with halauxifen-methyl applied alone and 91% to 97% in mixtures 35 DAT. Halauxifen-methyl applied alone resulted in poor giant ragweed control 21 DAT (73% control); however, mixtures of halauxifen-methyl with 2,4-D, dicamba, or glyphosate controlled giant ragweed (86% to 98% control). Halauxifen-methyl alone resulted in poor redroot pigweed control (62% control) 21 DAT; however, mixtures of halauxifen-methyl with dicamba, 2,4-D, or glyphosate controlled redroot pigweed (89% to 98% control). Halauxifen-methyl controls GR horseweed and common ragweed applied alone and in mixtures with other synthetic auxin herbicides and glyphosate. Furthermore, mixing 2,4-D or dicamba with halauxifen-methyl can increase the weed control spectrum in preplant burndown applications.


1979 ◽  
Vol 59 (1) ◽  
pp. 93-98 ◽  
Author(s):  
F. A. QURESHI ◽  
W. H. VANDEN BORN

Uptake of 14C-diclofop-methyl {methyl 2-[4-(2,4-dichlorophenoxy)phenoxy propanoate]} by leaves of wild oats (Avena fatua L.) was reduced significantly in the presence of MCPA {[(4-chloro-o-tolyl)oxy]acetic acid]}, especially the dimethylamine formulation. If the herbicides were applied separately, the degree of interference with uptake depended on the extent of overlap of droplets of the two spray preparations on the leaf surface. Spray volume and direction of spray application were important factors in minimizing the mixing of spray droplets on the leaves if the two herbicides were applied separately with a tandem arrangement of two sprayers. Such a sequential application of MCPA ester and diclofop-methyl in a field experiment provided significantly greater wild oat control than could be obtained with a tank mix of the same two herbicides, but the results were not consistent enough to recommend the procedure for practical use.


2011 ◽  
Vol 25 (2) ◽  
pp. 192-197 ◽  
Author(s):  
Jason A. Bond ◽  
Timothy W. Walker

Field studies were conducted to compare the response of one inbred (‘CL161’) and two hybrid (‘CLXL729’ and ‘CLXL745’) Clearfield (CL) rice cultivars to imazamox. Imazamox was applied at 44 and 88 g ai ha−1to rice in the panicle initiation (PI) and PI plus 14 d (PI + 14) growth stages and at 44 g ha−1to rice in the midboot growth stage. Maturity of hybrid CL cultivars was delayed following imazamox at 44 g ha−1applied at PI + 14 and midboot. Furthermore, imazamox at 44 g ha−1, applied at midboot, delayed maturity of CLXL745 more than CLXL729. Expressed as a percentage of the weed-free control plots, rough rice yields for CLXL729 were 91% following imazamox at 44 g ha−1applied at PI + 14, 78% following imazamox at 44 g ha−1applied at midboot, and 77% for imazamox at 88 g ha−1applied at PI + 14. Rough rice yield for CLXL745 was 77 to 92% of the control following all imazamox treatments. All imazamox treatments reduced CLXL745 rough rice yield compared with CL161. Rough rice yield, pooled across CL cultivar, varied with imazamox treatment between years, and these differences may have been a consequence of lower temperatures and solar radiation in the first year. Hybrid CL cultivars CLXL729 and CLXL745 were less tolerant than was CL161 when imazamox was applied at nonlabeled rates (88 g ha−1) and/or timings (PI + 14 or midboot). Because of variability in rice growth stages and irregularities in imazamox application in commercial fields, inbred CL cultivars should be planted where an imazamox application will likely be required.


1988 ◽  
Vol 18 (7) ◽  
pp. 917-921 ◽  
Author(s):  
P. Chakravarty ◽  
L. Chatarpaul

We investigated the effects of Velpar L (hexazinone) on ectomycorrhizal (Laccarialaccata) and nonmycorrhizal Pinusresinosa seedlings in the greenhouse and in the field. In both greenhouse and field studies, seedling growth was reduced by Velpar L at 1, 2, and 4 kg/ha application rates in the short term (2 months' exposure) with significant recovery occurring afterwards. Seedling mortality occurred only with herbicide treatments and was higher in the greenhouse than in the field. The 4 kg/ha Velpar L treatment caused the highest mortality and toxicity was most pronounced in the mycorrhizal (Laccarialaccata inoculated) seedlings. In both experiments mycorrhizal infection was significantly reduced by 2 and 4 kg/ha Velpar L treatments during the 0- to 2-month and 2- to 6-month exposure periods, with significant recovery occurring in the latter. Although seedlings not infected with Laccarialaccata became mycorrhizal through unidentified indigenous species, their infection rates were also affected by Velpar L at all levels during the 0- to 2-month period and at the 2 and 4 kg/ha levels after 2–6 months of exposure to the herbicide.


Weed Science ◽  
2018 ◽  
Vol 66 (6) ◽  
pp. 758-763 ◽  
Author(s):  
Cara L. McCauley ◽  
William G. Johnson ◽  
Bryan G. Young

AbstractHalauxifen-methyl is a new synthetic auxin herbicide for control of broadleaf weeds, including preplant applications for corn (Zea maysL.) or soybean [Glycine max(L.) Merr.]. The objective of this study was to investigate the efficacy of halauxifen-methyl in comparison to the current auxin standards, 2,4-D and dicamba, on glyphosate-resistant (GR) horseweed (Erigeron canadensisL.) at different plant heights. In field experiments, a foliar application of halauxifen-methyl at the recommended use rate of 5 g ae ha−1resulted in 81% control. Dicamba applied at 280 g ae ha−1provided a comparable level of efficacy of 80%, while 2,4-D at 560 g ae ha−1resulted in 49% control. The addition of glyphosate improved GRE. canadensiscontrol with 2,4-D more than with halauxifen-methyl or dicamba, possibly due to the higher level of control observed with halauxifen-methyl or dicamba alone. Even though applied at 50 to 100 times lower application rates, the efficacy of halauxifen-methyl onE. canadensiswas similar to dicamba and greater than 2,4-D. Thus, halauxifen-methyl should be an effective tool for management of GRE. canadensisbefore planting both conventional and herbicide-resistant soybean varieties, and it precludes the extended preplant application interval required for dicamba in some soybean management systems.


2019 ◽  
Vol 33 (2) ◽  
pp. 321-328 ◽  
Author(s):  
John T. Buol ◽  
Daniel B. Reynolds ◽  
Darrin M. Dodds ◽  
J. Anthony Mills ◽  
Robert L. Nichols ◽  
...  

AbstractRecent commercialization of auxin herbicide–based weed control systems has led to increased off-target exposure of susceptible cotton cultivars to auxin herbicides. Off-target deposition of dilute concentrations of auxin herbicides can occur on cotton at any stage of growth. Field experiments were conducted at two locations in Mississippi from 2014 to 2016 to assess the response of cotton at various growth stages after exposure to a sublethal 2,4-D concentration of 8.3 g ae ha−1. Herbicide applications occurred weekly from 0 to 14 weeks after emergence (WAE). Cotton exposure to 2,4-D at 2 to 9 WAE resulted in up to 64% visible injury, whereas 2,4-D exposure 5 to 6 WAE resulted in machine-harvested yield reductions of 18% to 21%. Cotton maturity was delayed after exposure 2 to 10 WAE, and height was increased from exposure 6 to 9 WAE due to decreased fruit set after exposure. Total hand-harvested yield was reduced from 2,4-D exposure 3, 5 to 8, and 13 WAE. Growth stage at time of exposure influenced the distribution of yield by node and position. Yield on lower and inner fruiting sites generally decreased from exposure, and yield partitioned to vegetative or aborted positions and upper fruiting sites increased. Reductions in gin turnout, micronaire, fiber length, fiber-length uniformity, and fiber elongation were observed after exposure at certain growth stages, but the overall effects on fiber properties were small. These results indicate that cotton is most sensitive to low concentrations of 2,4-D during late vegetative and squaring growth stages.


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